• Bulletin of the Korean Chemical Society
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• 제35권5호
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• pp.1469-1478
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• 2014

Use of acetonitrile in electrolytes promotes better operation of supercapacitors. Recent efforts show that electrolytes containing acetonitrile can also function in a wide range of operating temperatures. Therefore, this paper addresses the dielectric relaxation processes, structure and dynamic properties of the bulk acetonitrile at various temperatures. Systems of acetonitrile were modeled using canonical ensemble and simulated by employing Molecular Dynamics method. Results show that interactions among the molecules were correlated within a cut-off radius while parallel and anti-parallel arrangements are observed beyond this radius at relatively high and low temperatures respectively. Furthermore, effects of C-C-N and C-H bending modes were greatly appreciated on the power spectral density of time rate change of dipole-dipole correlations whereas frequency shifts were observed on all modes at the lowest temperature under consideration. Linear variations with temperature were depicted for reorientation times and self-diffusion coefficients. Shear viscosity was also computed with a good accuracy within a certain range of the temperature as well.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 춘계학술대회 논문집
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• pp.653-654
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• 2006

In case of ultrashort laser ablation of metals, the transfer of energy from the electronic system causing strong absorption of laser light to the lattice needs relaxation times of the order of some picoseconds. Under the above theoretical background, nickel was ablated using femtosecond, picosecond and nanosecond laser. As a result, nickel ablation by picosecond laser and femtosecond laser, which are called ultrashort laser, has similar machinability because of relaxation time of metals, whereas nanosecond Nd:YAG laser has lower absorption, higher thermalization effect in comparison with ultrashort laser.

• 한국지반공학회지:지반
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• 제10권4호
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• pp.103-118
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• 1994

입자물질의 빠른 움직임을 미시적으로 관찰하고 이를 연속체이론에 적용하였다. 두 입자의 상호충돌현상에서 두 종류의 시간 즉 미행시간과 접촉시간을 나누었다. 전자는 시간에 따라 변하는 움직임과 체적의 변화를 나타내며, 후자는 두 입자가 접촉시에 걸린 시간을 뜻하며 이 크기는 입자의 탄성성질을 나타낸다. 이러한 두 종류의 시간을 이용하여 4개의 상태변수 즉 압축응력, 점성, 에너지전달률 그리고 에너지손실률로서 동력학적 구조거동식을 세웠다. 연속체이론의 질량, 운동량 및 에너지방정식을 위의 상태변수로서 표기하고 이를 다시 두 가지의 모델에 적용한 결과 탄성성질로 인한 이완 및 에너지 흡수현상이 나타났다.

• 한국세라믹학회지
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• 제24권6호
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• pp.586-592
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• 1987

The role of the strain energy and phase stability in the diffuse phase transition have been investigated in the highly disordered solid solution, (Pb1-xBax)(Zr0.4Ti0.6)O3 (0.2 x 0.4). X-ray diffraction analysis indicates that tetragonality (c/a) decreases with the increasing Ba content. Also as the Ba content increases, phase transition becomes more diffuse and at the same time dielectric relaxation as a function of measured frequencies in the 1KHz-10MHz range occurs very pronouncedly. In the Ba content range, 0.2 x 0.35, hysteresis loops are routinely observed and the loop is observed to narrow shape as the Ba content increases but becomes very slim at 40mol% Ba content. Moreover thermal analysis shows that there is no abrupt change in the thermal expansion coefficient below the apparent transition temperature at which dielectric constant becomes maximum. From the above results, it has been concluded that creation of the strain energy due to the distorthion that occurred during the phase transition suppresses diffuse phase transition.

• KSII Transactions on Internet and Information Systems (TIIS)
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• 제13권2호
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• pp.565-581
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• 2019

This paper investigates the wireless powered two way relay network (WPTWRN), where two single-antenna users and one single-antenna relay firstly harvest energy from signals emitted by a multi-antenna power beacon (PB) and then two users exchange information with the help of the relay by using their harvested energies. In order to improve the energy transfer efficiency, energy beamforming at the PB is deployed. For such a network, to explore the performance limit of the presented WPTWRN, an optimization problem is formulated to obtain the achievable rate region bounds by jointly optimizing the time allocation and energy beamforming design. As the optimization problem is non-convex, it is first transformed to be a convex problem by using variable substitutions and semidefinite relaxation (SDR) and then solve it efficiently. It is proved that the proposed method achieves the global optimum. Simulation results show that the achievable rate region of the presented WPTWRN architecture outperforms that of wireless powered one way relay network architecture. Results also show that the relay location has significant impact on achievable rate region of the WPTWRN.

• 한국자기학회지
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• 제25권6호
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• pp.185-188
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• 2015

본 연구에서는 FT-NMR 분광기를 사용하여 $NaMgCl_3$ 단결정의 구성 원자인 $^{23}Na$ 원자핵에 대한 핵 자기 공명 실험을 하였다. 이로부터 $^{23}Na$ 원자핵이 모결정 내에서 입방정계 대칭성 내에 존재한다는 것을 알았고, 200 K~410 K 온도 범위에서 $^{23}Na$ 원자핵에 대한 스핀-격자 완화 시간 $T_1$을 온도 변화에 따라 계산하였다. 온도가 증가함에 따라서 $^{23}Na$ 원자핵의 $T_1$ 값이 점차적으로 감소하였다. 스핀-격자 완화율 $1/T_1$ 이 온도 T에 선형적으로 비례하였고, $^{23}Na$ 원자핵의 스핀-격자 완화 메커니즘을 $^{23}Na$ 원자핵 스핀과 단일 포논이 직접적으로 작용하는 직접과정(direct process)으로 설명하였다. 또한 $^{23}Na$ 원자핵의 활성화 에너지를 계산하여 $E_a=4.82J/mol$를 얻었다.

• 한국생산제조학회지
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• 제7권6호
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• pp.117-125
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• 1998

The paper attempts to estimate the incubation time of a cavity in the interface between a power law creep particle and an elastic matrix subjected to a uniaxial stress. Since the power law creep particle is time dependent, the stresses in the interface relax. The volume free energy associated with Helmholtz free energy includes strain energies caused by applied stress and dislocations piled up in interface(DPI). The energy due to DPI is found by modifying the result of Dundurs and Mura[4]. The volume free energies caused by both applied stress and DPI are a function of the cavity size(r) and elapsed time(t) and arise from stress relaxation in the interface. Critical radius $r^*$ and incubation time $t^*$ to maximise Helmholtz free energy is found in present analysis. Also, kinetics of cavity formation are investigated using the results obtained by Riede [7]. The incubation time is defined in the analysis as the time required to satisfy both the thermodynamic and kinetic conditions. Through the analysis it is found that 1) strain energy caused by the applied stress does not contribute significantly to the thermodynamic and kinetic conditions of a cavity formation, 2) in order to satisfy both thermodynamic and kinetic conditions, critical radius $r^*$ decreases or holds constant with increase of the time until the kinetic condition(eq. 2.3) is satisfied. there for the cavity may not grow right after it is formed, as postulated by Harris [15], and Ishida and Mclean [16], 3) the effects of strain rate exponent (m), material constant $\sigma$0, volume fraction of the particle to matrix(f)and particle size on the incubation time are estimated using material constants of the copper as matrix.

• 대한전기학회논문지
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• 제36권9호
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• pp.609-615
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• 1987

The optimal operation of power system is developed by alternately using real power dispatch and reactive power dispatch problem. The real power system scheduling process is formulated as an optimization problem with linear inequality constraints. A.C. loadflow method is used for the problem solution and line losses are considered. The constraints under consideration are generator power limits, load scehdling limits and line capacity limits. In solving the objective function the Dual Relaxation method is adopted. Tests indicate that the method is practical for real time application. The reactive power control problem uses the Dual Simplex Relaxation method as in the real scheduling case. Insted of minimizing the cost of power system, the objective is selected as to determine the highest possible voltage schedule. The constraints under consideration are the voltage limits at each node and the possibilities of supply or absobtion of reactive energy by generator units and the compensation facilities. Tests indicate that the method is practical for real time applications. The overall optimization methods developed in this paper proved to obtained fine results in minimizing object function compared with the method without using voltage control. And the overall voltage profiles were also improved.

• Earthquakes and Structures
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• 제8권6호
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• pp.1299-1323
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• 2015

A model for reflection and refraction of magneto-thermoelastic SV-waves at the interface of two transversely isotropic and homogeneous solid half spaces under initial stress by applying classical dynamical theory of thermoelasticity is purposed. The reflection and refraction coefficients of SV-waves are obtained with ideal boundary conditions for SV-wave incident on the solid-solid interface. The effects of magnetic field, temperature and initial stress on the amplitude ratios after numerical computations are shown graphically with MATLAB software for the particular model.

• 한국안광학회지
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• 제1권1호
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• pp.1-14
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• 1996

Magic-Angle-Spinning NMR에 나타나는 $Li^+$ 이온의 운동과 관련된 알칼리 혼합 효과에 미치는 전이금속 산화물의 영향을 조사하기 위하여 불순물 $Fe_2O_3$를 0.1 mol% 첨가시킨 혼합 알칼리 Silicate 유리들을 제조하였고, 온도에 따라 $^7Li$ MAS-NMR 스펙트럼과 상온에서 $^7Li$ 스핀-살창 완화시간을 측정하였다. $Fe_2O_3$가 첨가되었을 때, 스펙트럼의 선폭이 조금 변화되었을 뿐이며 선 모양이 거의 변하지 않고 있다. 이 때문에, 스핀-스핀 완화 과정에서는 혼합 알칼리 효과가 충분히 나타나는 것으로 불수도 있지만 반드시 그렇지만은 않아 보인다. $Li^+$ 이온의 활성화 에너지가 혼합 알칼리 유리에서 오히려 감소하는 경향이 나타났다. 이것은 혼합 알칼리 효과가 아니다. 스핀-살창 완화시간, 완화 과정 분석을 통한 $Li^+$ 이온의 확산 환경, 그리고 핵 자가화 (nuclear magnetization) 등의 비교에 의하면, $^7Li$ 스핀-살창 완화 과정에서 알칼리 혼합 효과는 거의 나타나지 않는 것을 확인 할 수 있었다.