• 한국기계가공학회지
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• 제6권3호
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• pp.16-23
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• 2007

An experimental investigation with diode laser system was carried out to study the effect of surface heat treatment on the die materials(SM45C, SKD11, SK3). The surface heat treatment characteristics of the laser beam are evaluated using hardness tests, optical microscopy, X-ray diffraction and energy dispersive X-ray spectroscopy(EDS). Results indicated that the beam size, focal length, feed rates are changed surface hardened characteristics. SM45C is higher hardness than other materials and composed to martensite grain at hardened zone, whereas other materials(SKD11, SK3)are low hardness than expected and composed to austenite and allayed martensite at hardened zone. The intensive X-ray diffraction patterns of (110)-(200)-(211) is detected hardened surface and the hardened surface distributed plenty of carbon density than metal zone.

• 한국전기전자재료학회논문지
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• 제24권8호
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• pp.647-653
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• 2011

In this study, a method to measure the thickness of thin film by EDS (energy dispersive spectroscopy) is suggested. We have developed a model which calculates the thickness of thin film from the characteristic x-ray intensity ratio of the elements in thin film and substrate by considering incident electron beam energy, x-ray generation curve, backscattering and absorption of x-ray, take-off angle of x-ray and tilt angle of the sample. We obtained the relation curve between the film thickness measured experimentally and the x-ray intensity ratio of elements. The film thicknesses calculated from the model agrees quite well with those measured experimentally. Therefore, the thin film thickness can be measured rapidly and accurately by using the model developed in this study and the x-ray intensity ratio obtained in EDS analysis.

• Korean Chemical Engineering Research
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• 제48권1호
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• pp.98-102
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• 2010

목련잎 추출액을 이용하여 Au core-Ag shell 합금 나노입자를 합성하였다. 환원제인 식물잎 추출액을 먼저 $HAuCl_4$ 용액과 반응시키고 다음에 $AgNO_3$ 용액과 반응시켜 금 seed와 은 shell을 형성시켰다. 반응시간에 따른 UV-visible spectroscopy의 변화를 모니터링하여 합금 나노입자의 형성을 관찰하였다. 합성된 합금 나노입자를 transmission electron microscopy(TEM), energy dispersive X-ray spectroscopy(EDS), X-ray photoelectron spectroscopy(XPS) 등으로 특성화 하였다. TEM image로부터 관찰된 합금 나노입자는 삼각형, 오각형, 육각형 등의 평판과 구 구조의 혼합물이었다. EDS와 XPS 분석으로부터 결정된 금/은 합금 나노입자의 원자 은 함량은 각각 34와 65 wt%로 Au core-Ag shell 나노구조가 형성되었음을 알 수 있었다. 이러한 core-shell 형태의 나노구조는 표면 강화 라만 분광 및 생물분자의 고감도 검출 등에 잠재적인 응용이 기대된다.

• 공업화학
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• 제25권6호
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• pp.645-647
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• 2014

본 연구에서는 수열합성법을 이용하여, 한단계의 과정으로 $TiO_2$와 Ru (Ruthenium)가 도입된 $TiO_2$ ($Ru_x/TiO_2$)를 합성하였다. 합성된 샘플의 결정성과 조성 및 형태를 X-ray diffraction (XRD)과 energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM)를 통하여 확인하였으며, Benzyl alcohol의 Benzaldehyde로의 산화반응에 촉매로서 적용하였다. 높은 선택성을 가지는 산화반응이 진행되었으며, $TiO_2$에 도입된 Ru의 양이 증가할수록 촉매로서의 더 좋은 촉매활성을 보였다.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2015년도 춘계학술대회 논문집
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• pp.112-112
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• 2015

The purposed of this work was to determine nanotube shape variation on the Ti-xNb alloys with alloying elements and applied potentials. Samples were prepared by arc melting, followed by followed by homogenization for 12 hr at $1000^{\circ}C$ in argon atmosphere. This study was evaluated the phase and microstructure of Ti-xNb alloys using an X-ray diffraction (XRD) and optical microscopy (OM). The morphology of the samples was investigated with a field-emission scanning electron microscope (FE-SEM) and energy dispersive X-ray spectroscopy (EDS). The nanotube on the alloy surface was formed in 1 M $H_3PO_4$ with small additions of NaF 0.8 wt.%. All anodization treatments were carried out using a scanning potentiostat (Model 362, EG&G, USA) at constant voltage 30 V for 120 min, respectively. The morphology of the samples was investigated with a field-emission scanning electron microscope (FE-SEM) and energy dispersive X-ray spectroscopy (EDS). Surface characteristics of nanotbue formed on Ti-xNb alloys was investigated by potentiodynamic test and potentiostatic in 0.9% NaCl solution at $36.5{\pm}1^{\circ}C$. It was observed that the changed ${\alpha}$ phase to ${\beta}$ phase with Nb content.

• 한국의류학회지
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• 제25권10호
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• pp.1770-1778
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• 2001

황토는 대표적인 천연 무기염재의 일종으로서 바람에 의해 운반되어 퇴적된 담황색 내지는 황회색을 띠는 실트질의 퇴적물을 일컫는다. 황토의 구성물질은 주로 석영, 장석, 산화철광물, 깁사이트 등의 여러 가지 점토광물을 포함하는데, 주로 적색을 띠는 것은 소량의 산화철 광물에 기인되는 경우가 많으며 황토를 구성하는 점토광물로는 버미큘라이트, 카오린 광물인 캐올리나이트와 할로이사이트, 일라이트 등이 있다. 본 연구에서는 면직물에 천연 무기염재인 황토를 사용한 염색시에 황토 단독염색과 콩즙 전처리 후 황토염색으로 나누어 염색을 실시하고, 원료 황토와 황토염색 후 면직물에 부착된 성분 간에 차이가 있는지를 확인하기 위해 X선 형광분석(X-ray fluorescence analysis, XRF)을 이용하여 염색 전.후 황토의 성분을 분석하였고, X선 회절분석(X-ray diffraction analysis, XRD)을 이용하여 황토 및 염색 전 후 면직물에 부착된 광물질의 주성분을 분석하였으며, energy dispersive spectrometer (EDS)가 장착된 주사전자현미경을 이용하여 면직물에 부착된 광물의 성분을 조사하였다. 그 결과, 황토로 면직물을 염색하는 경우 면직물에 부착되는 황토의 양과 K/S 값은 거 의 비례하여 증가하는 것으로 나타났다. 황토 염색 후 면직물에 부탁되는 주성분은 주로 SiO$_2$, A1$_2$O$_3$, Fe$_2$O$_3$등인 것으로 나타났으며, X선 회절분석과 EDS분석에 의해 캐올리나이트, 일라이트 등의 점토광물의 형태로 존재하는 것이 확인되었다.

• Maxillofacial Plastic and Reconstructive Surgery
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• 제36권3호
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• pp.103-110
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• 2014

Purpose: The current gold standard for clinical jawbone formation involves autogenous bone as a graft material. In addition, demineralized dentin can be an effective graft material. Although demineralized dentin readily induces heterotopic bone formation, conventional decalcification takes three to five days, so, immediate bone grafting after extraction is impossible. This study evaluated the effect of vacuum ultrasonic power on the demineralization and processing of autogenous tooth material and documented the clinical results of rapidly processed autogenous demineralized dentin (ADD) in an alveolar defects patient. Methods: The method involves the demineralization of extracted teeth with detached soft tissues and pulp in 0.6 N HCl for 90 minutes using a heat controlled vacuum-ultrasonic accelerator. The characteristics of processed teeth were evaluated by scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). Bone grafting using ADD was performed for narrow ridges augmentation in the mandibular area. Results: The new processing method was completed within two hours regardless of form (powder or block). EDS and SEM uniformly demineralized autotooth biomaterial. After six months, bone remodeling was observed in augmented sites and histological examination showed that ADD particles were well united with new bone. No unusual complications were encountered. Conclusion: This study demonstrates the possibility of preparing autogenous tooth graft materials within two hours, allowing immediate one-day grafting after extraction.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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• pp.164-164
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• 2008

금속배선공정에서 높은 전도율과 재료의 값이 싸다는 이유로 최근 Cu를 사용하였으나, 디바이스의 구조적 특성을 유지하기 위해 높은 압력으로 인한 새로운 다공성 막(low-k)의 파괴와, 디싱과 에로젼 현상으로 인한 문제점이 발생하게 되었다. 이러한 문제점을 해결하고자, 본 논문에서는 Cu 표면에 Passivation layer를 형성 및 제거하는 개념으로 공정시 연마제를 사용하지 않으며, 낮은 압력조건에서 공정을 수행하기 위해, 전해질의 농도 변화에 따른 Liner sweep voltammetry 법을 사용하여 전압활성화에 의한 전기화학적 반응이 Cu전극에 어떤 영향을 미치는지 연구하였으며, 표면 조성을 알아보기 위하여 Energy Dispersive Spectroscopy (EDS) 분석을 하였고, Cu disk의 결정성과 배향성 관찰을 위해 X-Ray diffraction (XRD)로 금속 표면을 비교하여 실험 결과로 얻어진 데이터를 통하여 ECMP 공정에 적합한 전해액 선정과 농도를 선택하였다.

• 반도체디스플레이기술학회지
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• 제21권4호
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• pp.99-105
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• 2022

Public attention to the indoor environment of underground subway stations, which is a representative multi-use facility, has been increasing along with the increase in indoor activities. In underground stations, fine iron oxide, which affects the health of users, is generated because of the friction between wheels and rails. Among particulate pollutant reduction technologies, plants have been considered as a non-chemical air purification method, and their effects in reducing certain chemical species have been identified in previous studies. The present study aimed to derive the total quantitative and qualitative reduction effects of a bio-filter system comprising air purifying plants, installed in an underground subway station. The experiment proceeded in two ways. First, PM(particulate matter) reduction effect by vegetation biofilter was monitored with the IAQ(indoor air quality) station. In addition, chemical speciation analysis conducted on the samples collected from the experimental and control areas where plants and irrigation using SEM-EDS(scanning electron microscopy-energy dispersive X-ray spectroscopy). This study confirmed the effect of the vegetation bio-filter system in reducing the accumulation of particulate pollutants and transition and other metals that are harmful to the human body.

• Journal of the Korean Association of Oral and Maxillofacial Surgeons
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• 제49권1호
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• pp.43-48
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• 2023

The biocompatibility and durability of implant fixtures are major concerns for dentists and patients. Mechanical complications of the implant include abutment screw loosening, screw fracture, loss of implant prostheses, and implant fracture. This case report aims to describe management of a case of fixture damage that occurred after screw fracture in a tissue level, internal connection implant and microscopic evaluation of the fractured fixture. A trephine bur was used to remove the fixture, and the socket was grafted using allogeneic bone material. The failed implant was examined by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS), which revealed a fractured fixture with both normal and irregular bone patterns. The SEM and EDS results give an enlightenment of the failed fixture surface micromorphology with microfracture and contaminated chemical compositions. Noticeably, the significantly high level of gold (Au) on the implant surface and the trace amounts of Au and titanium (Ti) in the bone tissue were recorded, which might have resulted from instability and micro-movement of the implant-abutment connection over an extended period of time. Further study with larger number of patient and different types of implants is needed for further conclusion.