• 제목/요약/키워드: Energy Materials

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전기증착법으로 제조된 다공성 텅스텐 산화물의 고대비 전기변색 특성 (High-Contrast Electrochromism of Porous Tungsten Oxide Thin Films Prepared by Electrodeposition)

  • 박성혁;모호진;임재근;김상권;최재효;이승현;장세화;차경호;나윤채
    • 한국분말재료학회지
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    • 제25권1호
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    • pp.7-11
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    • 2018
  • In this study, we synthesize tungsten oxide thin films by electrodeposition and characterize their electrochromic properties. Depending on the deposition modes, compact and porous tungsten oxide films are fabricated on a transparent indium tin oxide (ITO) substrate. The morphology and crystal structure of the electrodeposited tungsten oxide thin films are investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). X-ray photoelectron spectroscopy is employed to verify the chemical composition and the oxidation state of the films. Compared to the compact tungsten oxides, the porous films show superior electrochemical activities with higher reversibility during electrochemical reactions. Furthermore, they exhibit very high color contrast (97.0%) and switching speed (3.1 and 3.2 s). The outstanding electrochromic performances of the porous tungsten oxide thin films are mainly attributed to the porous structure, which facilitates ion intercalation/deintercalation during electrochemical reactions.

NUCLEAR ENERGY MATERIALS PREDICTION: APPLICATION OF THE MULTI-SCALE MODELLING PARADIGM

  • Samaras, Maria;Victoria, Maximo;Hoffelner, Wolfgang
    • Nuclear Engineering and Technology
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    • 제41권1호
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    • pp.1-10
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    • 2009
  • The safe and reliable performance of fusion and fission plants depends on the choice of suitable materials and an assessment of long-term materials degradation. These materials are degraded by their exposure to extreme conditions; it is necessary, therefore, to address the issue of long-term damage evolution of materials under service exposure in advanced plants. The empirical approach to the study of structural materials and fuels is reaching its limit when used to define and extrapolate new materials, new environments, or new operating conditions due to a lack of knowledge of the basic principles and mechanisms present. Materials designed for future Gen IV systems require significant innovation for the new environments that the materials will be exposed to. Thus, it is a challenge to understand the materials more precisely and to go far beyond the current empirical design methodology. Breakthrough technology is being achieved with the incorporation in design codes of a fundamental understanding of the properties of materials. This paper discusses the multi-scale, multi-code computations and multi-dimensional modelling undertaken to understand the mechanical properties of these materials. Such an approach is envisaged to probe beyond currently possible approaches to become a predictive tool in estimating the mechanical properties and lifetimes of materials.

EFFECTS OF HEAT TREATMENTS ON MICROSTRUCTURES AND MECHANICAL PROPERTIES OF DUAL PHASE ODS STEELS FOR HIGH TEMPERATURE STRENGTH

  • Noh, Sanghoon;Choi, Byoung-Kwon;Han, Chang-Hee;Kang, Suk Hoon;Jang, Jinsung;Jeong, Yong-Hwan;Kim, Tae Kyu
    • Nuclear Engineering and Technology
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    • 제45권6호
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    • pp.821-826
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    • 2013
  • In the present study, the effects of various heat treatments on the microstructure and mechanical properties of dual phase ODS steels were investigated to enhance the high strength at elevated temperature. Dual phase ODS steels have been designed by the control of ferrite and austenite formers, i.e., Cr, W and Ni, C in Fe-based alloys. The ODS steels were fabricated by mechanical alloying and a hot isostatic pressing process. Heat treatments, including hot rolling-tempering and normalizing-tempering with air- and furnace-cooling, were carefully carried out. It was revealed that the grain size and oxide distributions of the ODS steels can be changed by heat treatment, which significantly affected the strengths at elevated temperature. Therefore, the high temperature strength of dual phase ODS steel can be enhanced by a proper heat treatment process with a good combination of ferrite grains, nano-oxide particles, and grain boundary sliding.

투명 디스플레이 실현을 위한 상부 전극용 TCO 박막제조 및 특성 분석 (A Study on TCO thin film for transparent display upper electrode)

  • 김은서;박형준;김호운;김해문;박진수;김영은;김인수
    • 한국콘텐츠학회:학술대회논문집
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    • 한국콘텐츠학회 2014년도 추계 종합학술대회 논문집
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    • pp.253-254
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    • 2014
  • 본 연구에서는 DC magnetron sputter 장비를 사용하여 투명 디스플레이 실현을 위한 상부전극용 박막을 제작하였고, 제작된 박막의 광학적 특성과 물리적 특성을 분석하였다. 소다라임 유리기판 인가된 전판 위에 증착한 ITO의 경우에는 박막의 증착률압에 따라 두께와 굴절률이 증가함을 보였으며, 증착된 박막의 광학적 투과도는 박막의 두께에 따라 접차 감소함을 확인 하였고, 반면 고전도 특성을 가진 알루미늄 박막은 증착된 박막의 두께가 두꺼울수록 전면의 반사도가 증가하여 투명전극으로 사용할 수 없었으나 스퍼터의 내부의 분위기압을 높이고 인가된 전압을 높고 단시간에 박막을 증착하였을 경우에 약 70%정도 현재 보다 향상된 투명전극으로의 광학적 투과도 특성을 보였다.

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액체질소의 연속 누출 실험 (Experiments of Continuous Release of Liquid Nitrogen)

  • 한용식;김명배;르-두이 응옌;김민창;김창현;김태훈;도규형;최병일
    • 한국수소및신에너지학회논문집
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    • 제34권5호
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    • pp.526-534
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    • 2023
  • To evaluate the risk of leakage when using liquid hydrogen, a leakage test was conducted using liquid nitrogen in an outdoor environment rather than a laboratory environment. To assume a real-scale continuous leak, liquid nitrogen was allowed to leak for 5 minutes through a pipe with a diameter of 25.4 mm at a design spill rate of 60 L/min. The measurement system consisted of devices for climate conditions, LN2 spread and vapor clouds. The main experimental results are the liquid pool radius and the concentration of vapor cloud, and the radius of the liquid pool was compared with the numerical analysis results.

Functional Li-M (Ti, Al, Co, Ni, Mn, Fe)-O Energy Materials

  • Kim, In Yea;Shin, Seo Yoon;Ko, Jea Hwan;Lee, Kang Soo;Woo, Sung Pil;Kim, Dong Kyu;Yoon, Young Soo
    • 한국세라믹학회지
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    • 제54권1호
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    • pp.9-22
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    • 2017
  • Many new functional materials have been studied for efficient production and storage of energy. Many new materials such as sodium-based and sulfide-based materials have been proposed for energy storage, but research on Li batteries is still dominant. Due to the influence of environmental concerns regarding nuclear energy, interest in and research on fusion power are steadily increasing. For the commercialization of nuclear fusion, a design standard based on a considerable level of physical analysis and modeling is proposed. Nevertheless, limitations of existing materials in nuclear fusion environments limit practical applications. Tritium propagation material for continuous fusion reaction is one of the core materials, and therefore research on this material is being carried out intermittently. The key material for Li-based energy storage and tritium generation is the functional material Li-M-O. In this review, a structural description of functional Li-M-O system materials and technical trends for its applications are introduced.

DED 적층 제조된 Stellite 6 조성합금의 열간등방압성형 후처리 (Effect of Hot Isostatic Pressing on the Stellite 6 Alloy prepared by Directed Energy Deposition)

  • 서주원;고재현;천영범;김영도;장진성;강석훈;한흥남
    • 한국분말재료학회지
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    • 제31권2호
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    • pp.152-162
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    • 2024
  • The directed energy deposited (DED) alloys show higher hardness values than the welded alloys due to the finer microstructure following the high cooling rate. However, defects such as microcracks, pores, and the residual stress are remained within the DED alloy. These defects deteriorate the wear behavior so post-processing such as heat treatment and hot isostatic pressing (HIP) are applied to DED alloys to reduce the defects. HIP was chosen in this study because the high pressure and temperature uniformly reduced the defects. The HIP is processed at 1150℃ under 100 MPa for 4 hours. After HIP, microcracks are disappeared and porosity is reduced by 86.9%. Carbides are spherodized due to the interdiffusion of Cr and C between the dendrite and interdendrite region. After HIP, the nanohardness (GPa) of carbides increased from 11.1 to 12, and the Co matrix decreased from 8.8 to 7.9. Vickers hardness (HV) decreased by 18.9 % after HIP. The dislocation density (10-2/m2) decreased from 7.34 to 0.34 and the residual stress (MPa) changed from tensile 79 to a compressive -246 by HIP. This study indicates that HIP is effective in reducing defects, and the HIP DED Stellite 6 exhibits a higher HV than welded Stellite 6.

확산하는 액체질소의 증발에 관한 실험적 연구 (Experimental Study of the Evaporation of Spreading Liquid Nitrogen)

  • 김명배;최병일;김태훈;도규형;한용식;정경열
    • 한국수소및신에너지학회논문집
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    • 제29권5호
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    • pp.466-472
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    • 2018
  • The investigation of cryogenic liquid pool spreading is an essential procedure to assess the hazard of cryogenic liquid usage. In this experimental study, to measure the evaporation velocity when the pool is spreading, liquid nitrogen was continuously released onto unconfined concrete ground. Almost all of the reported results are based on a non-spreading pool in which cryogenic liquid is instantaneously poured onto bounded ground for a very short period of time. A simultaneous measurement of the pool location using thermocouples and of the pool mass using a digital balance was carried out to measure the evaporation velocity and the pool radius. A greater release flow rate was found to result in a greater average evaporation velocity, and the evaporation velocity decreased with the spreading time and the pool radius.

Synthesis and Luminescence Characterization of En3+ Doped Gd2O3 Phosphors by Combustion Method

  • Jeong, Young-Ho;Myung, Kwang-Shik;Kim, Jung-Duk;Han, Sang-Do;Park, Jin-Won;Singh, K.C.
    • Transactions on Electrical and Electronic Materials
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    • 제4권5호
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    • pp.28-32
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    • 2003
  • Europium-doped gadolinium oxide ($Gd_2O_3;Eu^{3+}$) phosphors have been prepared by combustion method using urea[H$_2$NCONH$_2$] or carbohydrazide[H$_2$NNHCONHNH$_2$] as fuel materials in a preheated furnace at 500$^{\circ}C$. The phosphors obtained were fired at 1200$^{\circ}C$ for 3 hours to get better luminescent properties. The combustion method used was found to be a simple and fast method for the preparation of fine-sized particles. The influence of the fuel/oxidant (urea or carbohydrazide/nitrate) mole ratio on the phosphor has been investigated and the optimum values for various parameters have been determined. By this method, phosphor that has better brightness and smaller size particles than that obtained by conventional method has been prepared.d has been prepared.