• Title/Summary/Keyword: Energy Materials

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Piezoelectric Nanogenerators: Energy Harvesting Technology (압전 나노발전기: 에너지 수확 기술)

  • Shin, Dong-Myeong;Hwang, Yoon-Hwae
    • Vacuum Magazine
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    • v.3 no.2
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    • pp.17-20
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    • 2016
  • Piezoelectric nanogenerators are energy harvesting device to convert a mechanical energy into an electric energy using nanostructured piezoelectric materials. This review summarizes works to date on piezoelectric nanogenerators, starting with a basic theory of piezoelectricity and working mechanism, and moving through the reports of numerous nanogenerators using nanorod arrays, flexible substrates and alternative materials. A sufficient power generated from nanogenerators suggests feasible applications for either power supplies or strain sensors of highly integratedl nano devices. Further development of nanogenerators holds promise for the development of self-powered implantable and wearable electronics.

A Study on Ammonia Partial Oxidation over Ru Catalyst (Ru 촉매에서의 암모니아 부분산화에 대한 연구)

  • SANGHO LEE;HYEONGJUN JANG;CHEOLWOONG PARK;SECHUL OH;SUNYOUP LEE;YONGRAE KIM
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.6
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    • pp.786-794
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    • 2022
  • Green ammonia is a promising renewable energy carrier. Green ammonia can be used in various energy conversion devices (e.g., engine, fuel cell, etc.). Ammonia has to be fed with hydrogen for start-up and failure protection of some energy conversion devices. Ammonia can be converted into hydrogen by decomposition and partial oxidation. Especially, partial oxidation has the advantages of fast start-up, thermally self-sustaining operation and compact size. In this paper, thermodynamics, start-up and operation characteristics of ammonia partial oxidation were investigated. O2/NH3 ratio, ammonia flow rate and catalyst volume were varied as operation parameters. In thermodynamic analysis, ammonia conversion was maximized in the O2/NH3 range from 0.10 to 0.15. Ammonia partial oxidation reactor was successfully started using 12 V glow plug. At 0.13 of O2/HN3 ratio and 10 LPM of ammonia flow rate, ammonia partial oxidation reactor showed 90% of ammonia conversion over commercial Ru catalyst. In addition, Increasing O2/NH3 ratio from 0.10 to 0.13 was more effective for high ammonia conversion than increasing catalyst volume at 0.10 of O2/NH3.

Experiments for Pressure Drop of Scrubbing Layer in a Scrubber System (스크러버 내 충진층에서의 압력강하 특성에 관한 실험적 연구)

  • Yong-Shik Han;Kyu Hyung Do;Kyungyul Chung;Byungil Choi;Hwalong You;Changhyun Kim;Minchang Kim;Taehoon Kim
    • Journal of the Society of Naval Architects of Korea
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    • v.60 no.3
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    • pp.186-192
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    • 2023
  • According to the regulation on the pollution of the marine environment, SOx emission from ships has to be reduced. A SOx scrubbing system installed in a funnel of a ship is considered in order to reduce SOx emission. A scrubbing layer with a porous material is present in the funnel to increase the contact area between exhaust gas and water. In this study, experiments on the pressure drop characteristics in the scrubbing layer are conducted to investigate the effect of the scrubber on the engine load. The pressure drop according to flow rate of air instead of exhaust gas was measured for fillers such as sphere, pall ring and saddle in the scrubbing layer. First of all, porosity is experimentally measured for the three types of filler and it is confirmed that the porosity of the saddle-type filler was the largest. The pressure drop according to the change in air flow rate was measured for the three types of fillers in the scrubbing layer. As a result, the pressure drop was the smallest in the scrubbing layer with the saddle-type filler which has the largest porosity. In addition, the effect of spraying water flowing counter flow against air flow is experimentally examined. It is known that the pressure drop is increased because the air flow space is reduced when water is sprayed. In the case of the saddle, the pressure drop is about 1.5 to 2 times greater than that when only air flows at the optimum exhaust gas-water injection ratio.

Degradation and Stability of Organic-Inorganic Perovskite Solar Cells (유 무기 페로브스카이트 태양전지의 열화와 안정성)

  • Cho, Kyungjin;Kim, Seongtak;Bae, Soohyun;Chung, Taewon;Lee, Sang-won;Lee, Kyung Dong;Lee, Seunghun;Kwon, Guhan;Ahn, Seh-Won;Lee, Heon-Min;Ko, Min Jae;Kang, Yoonmook;Lee, Hae-seok;Kim, Donghwan
    • Current Photovoltaic Research
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    • v.4 no.2
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    • pp.68-79
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    • 2016
  • The power conversion efficiency of perovskite solar cells has remarkably increased from 3.81% to 22.1% in the past 6 years. Perovskite solar cells, which are based on the perovskite crystal structure, are fabricated using organic-inorganic hybrid materials. The advantages of these solar cells are their low cost and simple fabrication procedure. Also, they have a band gap of about 1.6 eV and effectively absorb light in the visible region. For the commercialization of perovskite solar cells in the field of photovoltaics, the issue of their long term stability cannot be overlooked. Although the development of perovskite solar cells is unprecedented, their main drawback is the degradation of the perovskite structure by moisture. This degradation is accelerated by exposure to UV light, temperature, and external bias. This paper reviews the aforesaid reasons for perovskite solar cell degradation. We also discuss the research directions that can lead to the development of perovskite solar cells with high stability.

Lithium Air Battery: Alternate Energy Resource for the Future

  • Zahoor, Awan;Christy, Maria;Hwang, Yun-Ju;Nahm, Kee-Suk
    • Journal of Electrochemical Science and Technology
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    • v.3 no.1
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    • pp.14-23
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    • 2012
  • Increasing demand of energy, the depletion of fossil fuel reserves, energy security and the climate change have forced us to look upon alternate energy resources. For today's electric vehicles that run on lithium-ion batteries, one of the biggest downsides is the limited range between recharging. Over the past several years, researchers have been working on lithium-air battery. These batteries could significantly increase the range of electric vehicles due to their high energy density, which could theoretically be equal to the energy density of gasoline. Li-air batteries are potentially viable ultra-high energy density chemical power sources, which could potentially offer specific energies up to 3000 $Whkg^{-1}$ being rechargeable. This paper provides a review on Lithium air battery as alternate energy resource for the future.

Fabrication and Properties of SiC Candle Filter by Vacuum Extrusion and Ramming Process (II) (진공 압출성형 및 래밍성형 공정에 의한 탄화규소 캔들 필터 제조 및 특성 (II))

  • Han, In-Sub;Seo, Doo-Won;Kim, Se-Young;Hong, Ki-Seog;Woo, Sang-Kuk;Kim, Young-Wook
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.515-523
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    • 2010
  • Porous SiC candle filter preforms were fabricated by extrusion and ramming process. To fabricate SiC candle filter preform, commercially available F180 mesh ($85\;{\mu}m$) $\alpha$-SiC powder and $44\;{\mu}m$ mullite, $CaCO_3$ powder were used as the starting materials. The candle type preforms were fabricated by vacuum extrusion and ramming process, and sintered at $1400^{\circ}C$ 2 h in air atmosphere. Corrosion test of the sintered candle filter specimens as forming method was performed at $600^{\circ}C$ for 2,400 h in simulated IGCC syngas atmosphere. The effect of forming method on mechanical properties, pore distribution, microstructure and crystalline phase was investigated.

Development of a Cost-Effective 20K Hydrogen BET Measurement for Nanoporous Materials (나노다공체 물성 측정을 위한 극저온(20K) 수소 BET 개발 및 응용)

  • Park, Jaewoo;Oh, Hyunchul
    • Korean Journal of Materials Research
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    • v.27 no.9
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    • pp.466-470
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    • 2017
  • With the matters of climate change, energy security and resource depletion, a growing pressure exists to search for replacements for fossil fuels. Among various sustainable energy sources, hydrogen is thought of as a clean energy, and thus efficient hydrogen storage is a major issue. In order to realize efficient and safe hydrogen storage, various porous materials are being explored as solid-states materials for hydrogen storage. For those purposes, it is a prerequisite to characterize a material's textural properties to evaluate its hydrogen storage performance. In general, the textural properties of porous materials are analyzed by the Brunauer-Emmett-Teller (BET) measurement using nitrogen gas as a probe molecule. However, nitrogen BET analysis is sometimes not suitable for materials possessing small pores and surfaces with high curvatures like MOFs because the nitrogen molecule may sometimes be too large to reach the entire porous framework, resulting in an erroneous value. Hence, a smaller probe molecule for BET measurements (such as hydrogen) may be required. In this study, we describe a cost-effective novel cryostat for BET measurement that can reach temperatures below the liquefaction of hydrogen gas. Temperature and cold volume of the cryostat are corrected, and all measurements are validated using a commercial device. In this way, direct observation of the hydrogen adsorption properties is possible, which can translate directly into the determination of textural properties.

Corrosion of Selected Materials in Boiling Sulfuric Acid for the Nuclear Power Industries

  • Kim, Dong-Jin;Lee, Han Hee;Kwon, Hyuk Chul;Kim, Hong Pyo;Hwang, Seong Sik
    • Corrosion Science and Technology
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    • v.6 no.2
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    • pp.37-43
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    • 2007
  • Iodine sulfur (IS) process is one of the promising processes for a hydrogen production by using a high temperature heat generated by a very high temperature gas cooled reactor(VHTR) in the nuclear power industries. Even though the IS process is very efficient for a hydrogen production and it is not accompanied by a carbon dioxide evolution, the highly corrosive environment of the process limits its application in the industry. Corrosion tests of selected materials were performed in sulfuric acid to select appropriate materials compatible with the IS process. The materials used in this work were Fe-Cr alloys, Fe-Ni-Cr alloys, Fe-Si alloys, Ni base alloys, Ta, Ti, Zr, SiC, Fe-Si, etc. The test environments were 50 wt% sulfuric acid at $120^{\circ}C$ and 98 wt% at $320^{\circ}C$. Corrosion rates were measured by using a weight change after an immersion. The surface morphologies and cross sectional areas of the corroded materials were examined by using SEM equipped with EDS. Corrosion behaviors of the materials were discussed in terms of the chemical composition of the materials, a weight loss, the corrosion morphology, the precipitates in the microstructure and the surface layer composition.