• Journal of Welding and Joining
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• v.31 no.3
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• pp.31-38
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• 2013

The transition of serrated grain boundary and its effect on liquation behavior in the simulated weld heat-affected zone (HAZ) have been investigated in a wrought Ni-based superalloy Alloy 263. Recently, the present authors have found that grain boundary serration occurs in the absence of adjacent coarse ${\gamma}^{\prime}$ particles or $M_{23}C_6$ carbides when a specimen is direct-aged with a combination of slow cooling from solution treatment temperature to aging temperature. The present study was initiated to determine the interdependence of the serration and HAZ property with a consideration of this serration as a potential for the use of a hot-cracking resistant microstructure. A crystallographic study indicated that the serration led to a change in grain boundary character as special boundary with a lower interfacial energy as those terminated by low-index {111} boundary planes. It was found that the serrated grain boundaries are highly resistant to boron enrichment, and suppress effectively grain coarsening in HAZ. Furthermore, the serrated grain boundaries showed a higher resistance to susceptibility of liquation cracking. These results was discussed in terms of a significant decrease in interfacial energy of grain boundary by the serration.

• Journal of Powder Materials
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• v.30 no.6
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• pp.516-520
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• 2023

Highly safe lithium-ion batteries (LIBs) are required for large-scale applications such as electrical vehicles and energy storage systems. A highly stable cathode is essential for the development of safe LIBs. LiFePO₄ is one of the most stable cathodes because of its stable structure and strong bonding between P and O. However, it has a lower energy density than lithium transition metal oxides. To investigate the high energy density of phosphate materials, vanadium phosphates were investigated. Vanadium enables multiple redox reactions as well as high redox potentials. LiVPO₄O has two redox reactions (V⁵⁺/V⁴⁺/V³⁺) but low electrochemical activity. In this study, LiVPO₄O is doped with fluorine to improve its electrochemical activity and increase its operational redox potential. With increasing fluorine content in LiVPO₄O_1-xF_x, the local vanadium structure changed as the vanadium oxidation state changed. In addition, the operating potential increased with increasing fluorine content. Thus, it was confirmed that fluorine doping leads to a strong inductive effect and high operating voltage, which helps improve the energy density of the cathode materials.

• Korean Journal of Materials Research
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• v.23 no.7
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• pp.379-384
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• 2013

In order to produce size-controllable Ag nanoparticles and a nanomesh-patterned Si substrate, we introduce a rapid thermal annealing(RTA) method and a metal assisted chemical etching(MCE) process. Ag nanoparticles were self-organized from a thin Ag film on a Si substrate through the RTA process. The mean diameter of the nanoparticles was modulated by changing the thickness of the Ag film. Furthermore, we controlled the surface energy of the Si substrate by changing the Ar or $H_2$ ambient gas during the RTA process, and the modified surface energy was evaluated through water contact angle test. A smaller mean diameter of Ag nanoparticles was obtained under $H_2$ gas at RTA, compared to that under Ar, from the same thickness of Ag thin film. This result was observed by SEM and summarized by statistical analysis. The mechanism of this result was determined by the surface energy change caused by the chemical reaction between the Si substrate and $H_2$. The change of the surface energy affected on uniformity in the MCE process using Ag nanoparticles as catalyst. The nanoparticles formed under ambient Ar, having high surface energy, randomly moved in the lateral direction on the substrate even though the etching solution consisting of 10 % HF and 0.12 % $H_2O_2$ was cooled down to $-20^{\circ}C$ to minimize thermal energy, which could act as the driving force of movement. On the other hand, the nanoparticles thermally treated under ambient $H_2$ had low surface energy as the surface of the Si substrate reacted with $H_2$. That's why the Ag nanoparticles could keep their pattern and vertically etch the Si substrate during MCE.

• Journal of the Korean Society of Combustion
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• v.21 no.1
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• pp.18-30
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• 2016

Pyro-process of solids is the way to heat solid materials under high temperature. In this processing, energy efficient use is one of the main concerns due to its high energy consumption of bulk materials. To calculate the energy use of processes, heat & mass balance in simplified 0-dimensional model was performed. Energy calculation by this simplified model can lead to confusion due to simplification. Thus, it is necessary to understand considerations of energy analysis. In this study, cement manufacturing as a very common example of pyro-processing of solids, was introduced for explaining considerations of energy analysis for energy efficient use.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.28 no.6
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• pp.717-725
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• 2004

A power generation systems are proposed to convert ambient mechanical vibration into electrical energy using cantilever-type piezoelectric materials. The vibration-based power device can be used for self-powered systems without batteries. This paper presents the theoretical analysis for the coupled equations of piezoelectric and structural motions and investigates the dynamic characteristics of the self-power system using transfer function method. The theoretical model is verified by the finite element analysis of the resonance frequency, the dynamic response of the structure and the sensor sensibility. Experimental results measured using a prototype system agree with the theoretical predictions. The system is shown to produce 34.5 ㎼ in average. Finally, we perform the optimal design for system variables to maximize output power.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.28 no.9
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• pp.1306-1313
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• 2004

This paper addresses a theoretical approach to calculate the amount of the stored energy during high strain-rate deformations using atomistic level simulation. The dynamic behavior of materials at high strain-rate deformation are of great interest. At high strain-rates deformations, materials generate heat due to plastic work and the temperature rise can be significant, affecting various properties of the material. It is well known that a small percent of the energy input is stored in the material, and most of input energy is converted into heat. However, microscopic analysis has not been completed without construction of a material model, which can simulate the movement of dislocations and vacancies. A major cause of the temperature rise within materials is traditionally credited to dislocations, vacancies and other defects. In this study, an atomistic material model for FCC such as copper is used to calculate the stored energy.

• 한국정보디스플레이학회:학술대회논문집
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• 2002.08a
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• pp.98-101
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• 2002

The effect of morphology on energy transfer and device performance in phosphorescent dye doped polymer light emitting diodes is reported. We selected two host polymers (PVK and PFHP) which have nearly the same potential for the energy transfer to Ir(ppy)$_3$. The PFHP:Ir(ppy)$_3$ film showed b-micron size aggregation, whereas the PVK:Ir(ppy)$_3$ film showed homogeneous and smooth images. As a result, energy transfer is efficient with high emission efficiency in PVK:Ir(ppy)$_3$ whereas little energy transfer and low quantum efficiency are obtained in PFHP:Ir(ppy)$_3$.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2003.11a
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• pp.1059-1066
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• 2003

A power generation system are proposed to convert ambient mechanical vibration into electrical energy using cantilever-type piezoelectric materials. The vibration-based power device can be used for self-powered systems without batteries. This paper presents the theoretical analysis for the coupled equations of piezoelectric and structural motions and investigates the dynamic characteristics of the self-power system using transfer function method. The theoretical model is verified by the finite element analysis of the resonance frequency, the dynamic response of the structure and the sensor sensibility. Experimental results measured using a prototype system agrees with the theoretical predictions. The system is shown to produce 2.53㎼ in average. Finally, we perform the optimal design for system variables to maximize output power.

• International Journal of Automotive Technology
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• v.7 no.6
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• pp.741-747
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• 2006

It has been almost impossible to predict the fatigue life in the field of rubber materials by numerical methods. One of the reasons is that there are no obvious fracture criteria and excessively various ways of mixing processes. Tearing energy is considered as a fracture criterion which can be applied to rubber compounds regardless of different types of fillers, relative to other fracture factors. Fatigue life of rubber materials can be approximately predicted based on the assumption that the latent defect caused by contaminants or voids in the matrix, imperfectly dispersed compounding ingredients, mold lubricants and surface flaws always exists. Numerical expression for the prediction of fatigue life was derived from the rate of rough cut growth region and the formulated tearing energy equation. Endurance test data for dumbbell specimens were compared with the predicted fatigue life for verification. Also, fatigue life of industrial rubber components was predicted.

• Carbon letters
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• v.1 no.1
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• pp.1-5
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• 2000

The effect of surface free energy on the positive temperature coefficient (PTC) of carbon black/thermoplastic resin composites was investigated. The thermoplastic resins such as EVA, LDPE, LLDPE and HDPE were used with the addition of 30 wt.% of the carbon black. The surface free energy of the composites was studied in the context of two-liquid contact angle measurements, i.e., deionized water and diiodomethane. It was observed that the resistivity on PTC composites Was greatly increased near the crystalline melting temperature, due to the thermal expansion of polymeric matrix. From the experimental results, it was proposed that the decrease of surface free energy induced by interactions between carbon black surfaces and polymer chains is an important factor to the fabrication of a PTC composite made of carbon black and polymeric matrix.