• Title/Summary/Keyword: Energy Capture

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$CO_2$ Removal Process Analysis and Modeling for 300MW IGCC Power Plant (300MW급 IGCC Power Plant용 $CO_2$ 제거공정 분석 및 모델링)

  • Jeon, Jinhee;Yoo, Jeongseok;Paek, Minsu
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.130.2-130.2
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    • 2010
  • 2020년까지 대형 CCS (Carbon Capture and Storage) Demo Plant 시장 (100MW 이상) 이 형성될 전망이다. 발전 부문에서 대규모 CCS 실증 프로젝트는 총 44개이며 연소전(41%), 연소후(28%), 순산소(3%) 프로젝트가 계획되어 있다. 순산소 연소 기술은 실증진입단계, 연소후(USC) 기술은 상용화 추진단계, 연소전 (IGCC) 기술은 실증완료 이후 상용화 진입 단계이다. IGCC 발전의 석탄가스화 기술은 타 산업분야에 서 상용화 되어있어 기술신뢰성이 높다. IGCC 단위설비 기술 개발을 통한 성능개선 및 비용절감에 대한 잠재력을 가지고 있기 때문에 미래의 석탄발전기술로 고려되고 있다. IGCC 기술은 가장 상용화에 앞서있지만 아직까지 IGCC+CCS 대형 설비가 운전된 사례가 전 세계적으로 없으며 미국 EPRI 등에서 Feasibility Study 단계이다. 현재 국책과제로 수행중인 300MW급 태안 IGCC 플랜트를 대상으로 향후 CCS 설비를 적용했을 경우에 대해 기술 타당성 검증을 목적으로 IGCC+CCS 모델링을 수행하였다. 모델링은 스크러버 후단의 합성 가스를 대상으로 하였다. Water Gas Shift Reaction (WGSR) 공정 및 Selexol 공정을 구성하여 최종 단에서 수소 연료를 생산할 수 있도록 하였다. WGSR 공정은 Co/Mo 촉매반응기로 구성되었다. WGSR 모델링을 통하여 주입되는 스팀량 (1~2 mol-steam/mol-CO) 및 온도 변화 ($220-550^{\circ}C$)에 따른 CO가스의 전환율을 분석하여 경제적인 설계조건을 선정하였다. Selexol 공정은 $H_2S$ Absorber, $H_2S$ Stripper, $CO_2$ Absorber, $CO_2$ Flash Drum으로 구성된다. Selexol 공정의 $CO_2$$H_2S$ 선택도를 분석 하였으며 단위 설비별 설계 조건을 예측하였다. 모델링 결과 59kg/s의 합성가스($137^{\circ}C$, 41bar, 가스 조성은 $CO_2$ 1.2%, CO 57.2%, $H_2$ 23.2%, $H_2S$ 0.02%)가 WGSR Process를 통해 98% CO가 $CO_2$ 로 전환되었다. Selexol 공정을 통해 $H_2S$ 제거율은 99.9%, $CO_2$제거율은 96.4%이었고 14.9kg/s의 $H_2$(86.9%) 연료를 얻었다. 모델링 결과는 신뢰성 검증을 통해 IGCC+CCS 전체 플랜트의 성능예측과 Feasibility Study를 위한 자료로 활용될 예정이다.

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Characteristics of Carbon Dioxide Reduction in the Gliding Arc Plasma Discharge (글라이딩 아크 플라즈마 방전에 의한 이산화탄소 저감 특성)

  • Lim, Mun Sup;Kim, Seung Ho;Chun, Young Nam
    • Applied Chemistry for Engineering
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    • v.26 no.2
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    • pp.205-209
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    • 2015
  • CCU (Carbon Capture & Utilization) has a potential technology for the reduction and usage of carbon dioxide which is greenhouse gas emitting from a fossil fuel buring. To decompose the carbon dioxide, a three phase gliding arc plasma-catalytic reactor was designed and manufactured. Experiments of carbon dioxide reduction was performed by varying the gas flow rate with feeding the $CO_2$ only as well as the input power, the catalyst type and steam supply with respect to the injection of the mixture of $CO_2$ and $CH_4$. The $CO_2$ decomposition rate was 7.9% and the energy efficiency was $0.0013L/min{\cdot}W$ at a $CO_2$ flow rate of 12 L/min only. Carbon monoxide and oxygen was generated in accordance with the destruction of carbon dioxide. When the injection ratio of $CH_4/CO_2$ reached 1.29, the $CO_2$ destruction and $CH_4$ conversion rates were 37.8% and 56.6% respectively at a power supply of 0.76 kW. During the installation of $NiO/Al_2O_3$ catalyst bed, the $CO_2$ destruction and $CH_4$ conversion rates were 11.5% and 9.9% respectively. The steam supply parameter do not have any significant effects on the carbon dioxide decomposition.

Analysis of the Bogus Routing Information Attacks in Sensor Networks (센서 네트워크에서 AODV 라우팅 정보 변조공격에 대한 분석)

  • Lee, Myung-Jin;Kim, Mi-Hui;Chae, Ki-Joon;Kim, Ho-Won
    • The KIPS Transactions:PartC
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    • v.14C no.3 s.113
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    • pp.229-238
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    • 2007
  • Sensor networks consist of many tiny sensor nodes that collaborate among themselves to collect, process, analyze, and disseminate data. In sensor networks, sensor nodes are typically powered by batteries, and have limited computing resources. Moreover, the redeployment of nodes by energy exhaustion or their movement makes network topology change dynamically. These features incur problems that do not appear in traditional, wired networks. Security in sensor networks is challenging problem due to the nature of wireless communication and the lack of resources. Several efforts are underway to provide security services in sensor networks, but most of them are preventive approaches based on cryptography. However, sensor nodes are extremely vulnerable to capture or key compromise. To ensure the security of the network, it is critical to develop suity mechanisms that can survive malicious attacks from "insiders" who have access to the keying materials or the full control of some nodes. In order to protect against insider attacks, it is necessary to understand how an insider can attack a sensor network. Several attacks have been discussed in the literature. However, insider attacks in general have not been thoroughly studied and verified. In this paper, we study the insider attacks against routing protocols in sensor networks using the Ad-hoc On-Demand Distance Vector (AODV) protocol. We identify the goals of attack, and then study how to achieve these goals by modifying of the routing messages. Finally, with the simulation we study how an attacker affects the sensor networks. After we understand the features of inside attacker, we propose a detect mechanism using hop count information.

Mineral Carbonation of High Carbon Dioxide Composition Gases Using Wollastonite-distilled Water Suspension (규회석-증류수 현탁액을 이용한 고농도 CO2 가스의 탄산염 광물화)

  • Song, Haejung;Han, Sang-Jun;Wee, Jung-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.5
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    • pp.342-351
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    • 2014
  • The present paper investigates the performance of direct wet mineral carbonation technology to fix carbon dioxide ($CO_2$) from relatively high $CO_2$ concentration feeding gas using wollastonite ($CaSiO_3$)-water (and 0.46 M acetic acid) suspension solution. To minimize the energy consumed on the process, the carbonation in this work is carried out at atmospheric pressure and slightly higher room temperature. As a result, carbon fixation is confirmed on the surface of $CaSiO_3$ after carbonation with wollastonite-water suspension solution and its amount is increased according to the $CO_2$ composition in the feeding gas. The leaching and carbonation ratio of wollastonite-water suspension system obtained from the carbonation with 50% of $CO_2$ composition feeding gas is 13.2% and 10.4%, respectively. On the other hand, the performance of wollastonite-acetic acid in the same condition is 63% for leaching and 1.39% for carbonation.

Simulation of Scooped Swing in High Bar Using Lagrange's Method : A Case Study (라그랑지 방법을 이용할 철봉 몸굽혀 휘돌기 동작의 시뮬레이션)

  • Hah, Chong-Ku
    • The Journal of the Korea Contents Association
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    • v.7 no.4
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    • pp.234-240
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    • 2007
  • The purpose of this paper was to architecture optimal model of the scooped swing in high bar. The scooped swing was modeled to the double pendulum and was simulated with the Lagrange's equation of motion. Lagrange's method based on a energy approaching method was implemented as a equation of motion. The subject was a national man-gymnast(age 18yrs, height 153 cut mass 48 kg) and the high bar of SPIETH company was used to measure the scooped swing. Qualisys system(six MCU-240 cameras, QTM software)was used to capture data for imaging analysis. The solution of a model and data processing were solved in Mathematica5.0. The results were as follows: First model value of maximum bar displacement was longer than experimental value, that is, 0.02 m. Second, both angular pattern of segment1(HAT) had a increasing curve but curve patterns had a different concave and convex me. Third the experimental value of maximum angular angle of segment2(total leg) had larger than model value, that is, $4^{\circ}$. Conclusively, model parameters were quasi-optimized to obtain a quasi-match between simulated and actual performances. It hopes to simulate a human model by means of integrating musculoskeletal and neuromuscular system in the future study.

Process gas purification using cyclone recirculation and cooling process (싸이클론 재순환, 냉각공정을 이용한 공정가스 정제 연구)

  • Kim, Ju-Hoe;Jo, Woo-Jin;Choi, Young-Tae;Jo, Young-Min;Kim, Sang-Bum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.1
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    • pp.25-33
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    • 2018
  • Renewable energy has been of interests in the area of modern alternative fuels. Biogas is produced in waste landfill sites through anaerobic digestion processes, including hydrolysis, acidogenesis, organic acid fermentation (acetogenesis), and methane fermentation (methanogenesis). High contents of fine dust and moisture limited its utilization for direct combustion, town gas and vehicle fuel. Thus, this study proposed a new design for a cooling device using a centrifugal cyclone for simultaneous removal of fine dust and moisture as a pretreatment in the purification processes. A heat exchanger and an ID fan, which are installed inside and outside of the cyclone, in order to cool the humid gas below the freezing point and form a foggy mist. Such an atmosphere enhanced to capture fine dust as recirculating the cold mist flow. The water removal rate was 80.8% at a relative humidity of 95%, and the particle removal efficiency was 98.3% for $2.5{\mu}m$. Simultaneous removal efficiency was 70.8% and 99.6% for particle and moisture respectively.

A Study on Separation Control by Local Suction in Front of a Hemisphere in Laminar Flow (층류경계층 내 반구 전방의 국부적인 흡입에 의한 표면 박리 제어)

  • Kang, Yong-Duck;An, Nam-Hyun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.24 no.1
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    • pp.92-100
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    • 2018
  • Vortical systems are considered a main feature to sustain turbulence in a boundary layer through interaction. Such turbulent structures result in frictional drag and erosion or vibration in engineering applications. Research for controlling turbulent flow has been actively carried out, but in order to show the effect of vortices in a turbulent boundary layer, it is necessary to clarify the mechanism by which turbulent energy is transferred. For this purpose, it is convenient to demonstrate and capture phenomena in a laminar boundary layer. Therefore, in this study, the interactions of disturbed flow around a hemisphere on a flat plate in laminar flow were analyzed. In other words, a street of hairpin vortices was generated following a wake region formed after flow separation occurred over a hemisphere. Necklace vortices surrounding the hemisphere also appeared due to a strong adverse pressure gradient that brought high momentum fluid into the wake region thereby leading to an increase in the frequency of hairpin vortices. To mitigate the effect of these necklace vortices, local suction control was applied through a hole in front of the hemisphere. Flow visualization was recorded to qualitatively determine flow modifications, and hot-film measurements quantitatively supported conclusions on how much the power of the hairpin vortices was reduced by local wall suction.

A Study on the Theory of $\frac {1}{f}$ Noise in Electronic Devies (전자소자에서의 $\frac {1}{f}$잡음에 관한 연구)

  • 송명호
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.3 no.1
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    • pp.18-25
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    • 1978
  • The 1/f noise spectrum of short-circuited output drain current due to the Shockley-Read-Hal] recombination centers with a single lifetime in homogeneous nondegenerate MOS-field effcte transtors with n-type channel is calculated under the assumptions that the quasi-Fermi level for the carriers in each energy band can not be defined if we include the fluctuation for time varying quantities. and so 1/f noise is a majority carrier effect. Under these assumptions the derived 1/f noise in this paper show some essential features of the 1/f noise in MOS-field effect transistors. That is, it has no lowfrequency plateau and is proportionnal to the channel cross area A and to the driain bias voltage Vd and inversely proportional to the channel length L3 in MOS field effect transistors. This model can explain the discrepancy between the transition frequency of the noise spectrum from 1/f- response to 1/f2 and the frequency corresponding to the relaxation time related to the surface centers in p-n junction diodes. In this paper the results show that the functional form of noise spectrum is greatly influenced by the functional forms of the electron capture probability cn (E) and the relaxation time r (E) for scattering and the case of lattice scattering show to be responsible for the 4 noise in MOS fold effect transistors. So we canconclude that the source of 1/f noise is due to lattice scattering.

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Encounter of Lattice-type coding with Wiener's MMSE and Shannon's Information-Theoretic Capacity Limits in Quantity and Quality of Signal Transmission (신호 전송의 양과 질에서 위너의 MMSE와 샤논의 정보 이론적 정보량 극한 과 격자 코드 와의 만남)

  • Park, Daechul;Lee, Moon Ho
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.8
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    • pp.83-93
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    • 2013
  • By comparing Wiener's MMSE on stochastic signal transmission with Shannon's mutual information first proved by C.E. Shannon in terms of information theory, connections between two approaches were investigated. What Wiener wanted to see in signal transmission in noisy channel is to try to capture fundamental limits for signal quality in signal estimation. On the other hands, Shannon was interested in finding fundamental limits of signal quantity that maximize the uncertainty in mutual information using the entropy concept in noisy channel. First concern of this paper is to show that in deriving limits of Shannon's point to point fundamental channel capacity, Shannon's mutual information obtained by exploiting MMSE combiner and Wiener filter's MMSE are interelated by integro-differential equantion. Then, At the meeting point of Wiener's MMSE and Shannon's mutual information the upper bound of spectral efficiency and the lower bound of energy efficiency were computed. Choosing a proper lattice-type code of a mod-${\Lambda}$AWGN channel model and MMSE estimation of ${\alpha}$ confirmed to lead to the fundamental Shannon capacity limits.

Numerical simulation of gasification of coal-water slurry for production of synthesis gas in a two stage entrained gasifier (2단 분류층 가스화기에서 합성가스 생성을 위한 석탄 슬러리 가스화에 대한 수치 해석적 연구)

  • Seo, Dong-Kyun;Lee, Sun-Ki;Song, Soon-Ho;Hwang, Jung-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.417-423
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    • 2007
  • Oxy-gasification or oxygen-blown gasification, enables a clean and efficient use of coal and opens a promising way to CO2 capture. The coal gasification process of a slurry feed type, entrained-flow coal gasifier was numerically predicted in this paper. The purposes of this study are to develop an evaluation technique for design and performance optimization of coal gasifiers using a numerical simulation technique, and to confirm the validity of the model. By dividing the complicated coal gasification process into several simplified stages such as slurry evaporation, coal devolatilization, mixture fraction model and two-phase reactions coupled with turbulent flow and two-phase heat transfer, a comprehensive numerical model was constructed to simulate the coal gasification process. The influence of turbulence on the gas properties was taken into account by the PDF (Probability Density Function) model. A numerical simulation with the coal gasification model is performed on the Conoco-Philips type gasifier for IGCC plant. Gas temperature distribution and product gas composition are also presented. Numerical computations were performed to assess the effect of variation in oxygen to coal ratio and steam to coal ratio on reactive flow field. The concentration of major products, CO and H2 were calculated with varying oxygen to coal ratio (0.2-1.5) and steam to coal ratio(0.3-0.7). To verify the validity of predictions, predicted values of CO and H2 concentrations at the exit of the gasifier were compared with previous work of the same geometry and operating points. Predictions showed that the CO and H2 concentration increased gradually to its maximum value with increasing oxygen-coal and hydrogen-coal ratio and decreased. When the oxygen-coal ratio was between 0.8 and 1.2, and the steam-coal ratio was between 0.4 and 0.5, high values of CO and H2 were obtained. This study also deals with the comparison of CFD (Computational Flow Dynamics) and STATNJAN results which consider the objective gasifier as chemical equilibrium to know the effect of flow on objective gasifier compared to equilibrium. This study makes objective gasifier divided into a few ranges to study the evolution of the gasification locally. By this method, we can find that there are characteristics in the each scope divided.

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