• Title/Summary/Keyword: Emission unit

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Electroluminescence Characteristics of Blue Light Emitting Copolymer Containing Perylene and Triazine Moieties in the Side Chain (페릴렌과 트리아진기를 측쇄로 가지는 청색 발광 공중합체의 전기발광 특성)

  • Lee Chang Ho;Ryu Seung Hoon;Oh Hwan Sool;Oh Se Young
    • Polymer(Korea)
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    • v.28 no.5
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    • pp.367-373
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    • 2004
  • Novel non-conjugated blue light-emitting copolymers containing perylene and triazine moieties as light emitting and electron transporting units, respectively in the polymer side chain were synthesized. The resulting copolymers were soluble in most organic solvents such as chlorobenzene, THF, chloroform and benzene. The single-layered electroluminescence (EL) device consisting of indium tin oxide (ITO) /copolymer/aluminium (Al) exhibited a maximum external quantum efficiency ($0.003\%$) and a good carrier balance when the triazine content was $30\%$. In particular, the device emitted blue light (479 nm) corresponding to the emission of perylene moiety. The drive voltage was observed at 5 V and the CIE coordinate was x=0.16, y=0.17.

A study on membrane technology for surface water treatment: Synthesis, characterization and performance test

  • Haan, Teow Yeit;Shah, Mubassir;Chun, Ho Kah;Mohammad, Abdul Wahab
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.69-77
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    • 2018
  • The use of membrane as an innovative technology for water treatment process has now widely been accepted and adopted to replace the conventional water treatment process in increasing fresh water production for various domestic and industrial purposes. In this study, ultrafiltration (UF) membranes with different formulation were fabricated via phase inversion method. The membranes were fabricated by varying the polymer concentration (16 wt%, 18 wt%, 20 wt%, and 21 wt%). A series of tests, such as field emission scanning electron microscope (FESEM), pore size and porosity, contact angle, and zeta potential were performed to characterize the membranes. The membrane performance in terms of permeation flux and rejection were evaluated using a laboratory bench-scale test unit with mine water, lake water and tube well as model feed solution. Long hour filtration study of the membranes provides the information on its fouling property. Few pore blocking mechanism models were proposed to examine the behaviour of flux reduction and to estimate the fouling parameters based on different degree of fouling. 21 wt% PVDF membrane with smaller membrane pore size showed an excellent performance for surface water treatment in which the treated water complied with NWQS class II standard.

Effect of the Number of Detectors on Performance of Industrial SPECT (산업용 SPECT의 검출기 개수가 영상 해상도에 미치는 영향 평가)

  • Park, Jang Guen;Kim, Chan Hyeong;Kim, Jong Bum;Moon, Jinho;Jung, Sung-Hee
    • Journal of Radiation Industry
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    • v.5 no.4
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    • pp.325-330
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    • 2011
  • To predict the details of flow in industrial process unit, single photon emission computed tomography (SPECT) is a promising technique. Recently, industrial SPECT based on medical system has developed by researchers of the Korea Atomic Energy Research Institute (KAERI) and Hanyang University. In the present study, to confirm the effect of the number of detectors on image quality, and determine the optimal number of detectors in industrial SPECT, industrial SPECT system with various geometries were evaluated by the Monte Carlo simulation. CsI(Tl) detectors ($12mm{\times}12mm{\times}20mm$) with collimators (the geometric resolution of collimator $R_g$ was 4 cm at the center of the 30 cm diameter cylindrical vessel object) were modeled in a hexagonal array, and the point sources of $^{99m}Tc$, $^{68}Ga$, and $^{137}Cs$ were simulated at the center of the cylindrical vessel object using the MCNPX code. Then, the reconstruction images of each geometry were reconstructed using the expectation maximization (EM) algorithm. In this study, the reciprocity theorem was used to improve computation time required for system matrix of the EM algorithm. The result shows that the resolution of the reconstructed image was significantly improved by increasing the number of detectors in industrial SPECT system and more than 60 detectors will be required for the resolution of the reconstructed image.

A real-time sorting algorithm for in-beam PET of heavy-ion cancer therapy device

  • Ke, Lingyun;Yan, Junwei;Chen, Jinda;Wang, Changxin;Zhang, Xiuling;Du, Chengming;Hu, Minchi;Yang, Zuoqiao;Xu, Jiapeng;Qian, Yi;She, Qianshun;Yang, Haibo;Zhao, Hongyun;Pu, Tianlei;Pei, Changxu;Su, Hong;Kong, Jie
    • Nuclear Engineering and Technology
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    • v.53 no.10
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    • pp.3406-3412
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    • 2021
  • A real-time digital time-stamp sorting algorithm used in the In-Beam positron emission tomography (In-Beam PET) is presented. The algorithm is operated in the field programmable gate array (FPGA) and a small amount of registers, MUX and memory cells are used. It is developed for sorting the data of annihilation event from front-end circuits, so as to identify the coincidence events efficiently in a large amount of data. In the In-Beam PET, each annihilation event is detected by the detector array and digitized by the analog to digital converter (ADC) in Data Acquisition Unit (DAQU), with a resolution of 14 bits and sampling rate of 50 MS/s. Test and preliminary operation have been implemented, it can perform a sorting operation under the event count rate up to 1 MHz per channel, and support four channels in total, count rate up to 4 MHz. The performance of this algorithm has been verified by pulse generator and 22Na radiation source, which can sort the events with chaotic order into chronological order completely. The application of this algorithm provides not only an efficient solution for selection of coincidence events, but also a design of electronic circuit with a small-scale structure.

A Risk Assessment of Asbestos Fiber Leaks to Environment during Asbestos Removal Activity in Buildings (건물 내 석면제거 작업과 공기 중 석면의 외부누출 위험성 평가)

  • Paik, Namwon;Lee, Soungcheoul;Byeon, Jaecheol;Lee, Donghee
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.30 no.4
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    • pp.405-411
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    • 2020
  • Objectives: The objectives of this study were to investigate whether airborne fibers were released to the outside air from the asbestos removal area in buildings, and to confirm the existence of asbestos fibers in samples using transmission electron microscopy(TEM). Methods: A total of 1,295 samples was collected from inside and outside 155 asbestos removal areas. To investigate the release of asbestos fibers from the removal area, samples were collected at three locations, such as an entrance to change room, an exit of negative pressure unit(NPU) and perimeter areas. Samples were also collected in the removal area prior to and after removal activity. All samples were analyzed by phase contrast microscopy(PCM) and one-tenth of the samples was analyzed using TEM to discriminate asbestos fibers. Results: During the asbestos removal activity, 27(4.1%) of 662 samples collected outside the removal area showed airborne fiber concentrations equal to or in excess of 0.01 f/cc, the permissible emission standard of the Korean Ministry of Environment. Further, 111 samples were analyzed using TEM. The distribution of asbestos fiber concentrations was log-normal. It was found that 51 of 111 samples(46%) contained asbestos fibers. Conclusions: There is a potential risk of asbestos exposure among neighbors and the public outside the asbestos removal areas. It is recommended that the asbestos removal work be conducted strictly following the specifications required by government and/or professional organizations.

A Study on Improvement of Air Quality Dispersion Model Application Method in Environmental Impact Assessment (I) - Focusing on AERMOD Meteorological Preprocessor - (환경영향평가에서의 대기질 확산모델 적용방법 개선 연구(I) - AERMOD 기상 전처리를 중심으로 -)

  • Kim, Suhyang;Park, Sunhwan;Tak, Jongseok;Ha, Jongsik;Joo, Hyunsoo;Lee, Naehyun
    • Journal of Environmental Impact Assessment
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    • v.31 no.5
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    • pp.271-285
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    • 2022
  • The AERMET, the AERMOD meteorological preprocessing program, mainly used for environmental impact assessment and Integrated Environmental Permit System (IEPS) in Korea, has not considered the land covers characterasitics, and used only the past meteorological data format CD-144. In this study, two results of AERMET application considering CD-144 format and ISHD format, being used internationally, were compared. Also, the atmospheric dispersion characteristics were analyzed with consideration of land cover. In the case of considered the CD-144 format, the actual wind speed was not taken into account in the weak wind (0.6~0.9m/s) and other wind speed due to the unit conversion problem. The predicted concentration considering land cover data was up to 387% larger depending on the topographic and emission conditions than without consideration of land cover. In conclusion, when using meteorological preprocessing program in AERMOD modelling, AERMET, with ISHD format, land cover characterasitics in the area should be considered.

The Impact of Urban Characteristics on Carbon Emissions of Buildings in Seoul: Application of Spatial Regression Analysis (도시특성이 건축물의 탄소배출에 미치는 영향에 관한 연구: 서울시 424개 행정동에 대한 공간회귀분석의 적용)

  • Hang Hun Jo;Heung Soon Kim
    • Land and Housing Review
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    • v.14 no.3
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    • pp.77-92
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    • 2023
  • The aim of the study is to analyze urban characteristics that affect carbon emissions of buildings. The analysis was conducted at the level of 424 administrative districts in Seoul. The main variables used in the analysis were energy consumption and carbon emissions of buildings published in the Seoul Metropolitan Government's energy information platform 2021. It was found that carbon emissions per unit building were high in Jongno, Gangnam, Guro, and Mok-dong. A regression analysis using the spatial lag model (SLM) identifies that the variables that affect the carbon emissions of buildings were; commercial, educational, business and industrial facility variables as built environment factor; number of residents; traffic volume, number of bus routes and number of subway stations as transportation facilities factors; and environmental factors such as green area and river area.

Analysis of Contribution to Net Zero of Non-Urban Settlement - For Green Infrastructure in Rural Areas - (비도시 정주지의 탄소중립 기여도 분석 - 농촌지역 그린인프라를 대상으로 -)

  • Lee, Dong-Kyu;An, Byung-Chul
    • Journal of the Korean Institute of Landscape Architecture
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    • v.50 no.3
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    • pp.19-34
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    • 2022
  • This study was conducted to provide basic data that can be used when establishing Net Zero policies and implementation plans for non-urban settlements by quantitatively analyzing the Net Zero contribution to green infrastructure in rural areas corresponding to non-urban settlements. The main purpose is to first, systematize green infrastructure in rural areas, secondly derive basic units for each element of green infrastructure, and thirdly quantify and present the impact on Net Zero in Korea using these. In this study, CVR(Content Validity Ration) analysis was performed to verify the adequacy of green infrastructure elements in rural areas derived through research and analysis of previous studies, is as follows. First, Hubs of Green infrastructure in rural area include village forests, wetlands, farm land, and smart farms with a CVR value of .500 or higher. And Links of Green infrastructure in rural area include streams, village green areas, and LID (rainwater recycling). Second, the basic unit for each green infrastructure element was presented by classifying it into minimum, maximum, and median values using the results of previous studies so that it could be used for spatial planning and design for Net Zero. Third, when Green infrastructure in rural areas is applied to non-urban settlements in Korea, it is analyzed that it has the effect of indirectly reducing CO2 by at least 70.76 million tons and up to 141.16 million tons. This is 3.4 to 6.7 times the amount of CO2 emission from the agricultural sector in 2019, and it can be seen that the contribution to Net Zero is very high. It is expected to greatly contribute to the transformation of the ecosystem. This study quantitatively presented the carbon-neutral contribution to settlements located in non-urban areas, and by deriving the carbon reduction unit for each element of green infrastructure in rural areas, it can be used in spatial planning and design for carbon-neutral at the village level. It has significance as a basic research. In particular, the basic unit of carbon reduction for each green infrastructure factors will be usable for Net Zero policy at the village level, presenting a quantitative target when establishing a plan, and checking whether or not it has been achieved. In addition, based on this, it will be possible to expand and apply Net Zero at regional and city units such as cities, counties, and districts.

A Case Study to Estimate the Greenhouse-Gas Mitigation Potential on Conventional Rice Production System

  • Ryu, Jong-Hee;Lee, Jong-Sik;Kim, Kye-Hoon;Kim, Gun-Yeob;Choi, Eun-Jung
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.6
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    • pp.502-509
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    • 2013
  • To estimate greenhouse gas (GHG) emission, we established inventory of conventional rice cultivation from farmers in Gunsan and Iksan, Jeonbuk province in 2011~2012. This study was to calculate carbon footprint and to analyse the major factor of GHGs. We carried out a sensitivity analysis using the analyzed main factors of GHGs and estimated the mitigation potential of GHGs. Also we tried to suggest agricultural methods to reduce GHGs that farmers of this case study can apply. Carbon footprint of rice production unit of 1 kg was 2.21 kg $CO_2.-eq.kg^{-1}$. Although amount of $CO_2$ emissions is largest among GHGs, methane had the highest contribution of carbon footprint on rice production system after methane was converted to carbon dioxide equivalent ($CO_2$-eq.) multiplied by the global warming potential (GWP). Source of $CO_2$ in the cultivation of rice farming is incomplete combustion of fossil fuels used by agricultural machinery. Most of the $CH_4$ emitted during rice cultivation and major factor of $CH_4$ emission is flooded paddy field in anaerobic condition. Most of the $N_2O$ emitted from rice cultivation process and major sources of $N_2O$ emission is application of fertilizer such as compound fertilizer, urea, orgainc fertilizer, etc. As a result of sensitivity analysis due to the variation in energy consumption, diesel had the highest sensitivity among the energies inputs. If diesel consumption is reduced by 10%, it could be estimated that $CO_2$ potential reduction is about 2.5%. When application rate of compound fertilizer reduces by 10%, the potential reduction is calculated to be approximately 1% for $CO_2$ and approximately 1.8% for $N_2O$. When drainage duration is decreased until 10 days, methane emissions is reduced by approximately 4.5%. That is to say drainage days, tillage, and reducing diesel consumption were the main sources having the largest effect of GHG reduction due to changing amount of inputs. Accordingly, proposed methods to decrease GHG emissions were no-tillage, midsummer drainage, etc.

Estimation of Carbon Emission and Application of LCA (Life Cycle Assessment) from Barely (Hordeum vulgare L.) Production System (보리의 생산과정에서 발생하는 탄소배출량 산정 및 전과정평가 적용)

  • So, Kyu-Ho;Park, Jung-Ah;Lee, Gil-Zae;Ryu, Jong-Hee;Shim, Kyo-Moon;Roh, Kee-An
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.5
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    • pp.722-727
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    • 2010
  • This study was conducted to estimate the carbon footprint and to establish the database of the LCI (Life Cycle Inventory) for barely cultivation system. Barley production system was separated into the naked barley, the hulled barley and the two-rowed barley according to type of barley species. Based on collecting the data for operating LCI, it was shown that input of fertilizer was the highest value of 9.52E-01 kg $kg^{-1}$ for two-rowed braley. For LCI analysis focussed on the greenhouse gas (GHG), it was observed that carbon footprint were 1.25E+00 kg $CO_2$-eq. $kg^{-1}$ naked braley, 1.09E+00 kg $CO_2$-eq. $kg^{-1}$ hulled braley and 1.71E+00 $CO_2$-eq. $kg^{-1}$ two-rowed barley; especially two-rowed barley cultivation system had highest emission value as 1.09E+00 kg $CO_2$ $kg^{-1}$ barley. It might be due to emit from mainly fertilizer production for barley cultivation. Also $N_2O$ was emitted at 7.55E-04 kg $N_2O\;kg^{-1}$ barley as highest value from hulled barley cultivation system because of high N fertilizer input. The result of life cycle impcat assessment (LCIA), it was observed that most of carbon emission from barely cultivation system was mainly attributed to fertilizer production and cropping unit. Characterization value of GWP was 1.25E+00 (naked barley), 1.09E+00 (hulled barley) and 1.71E+00 (two-rowed barely) kg $CO_2$-eq. $kg^{-1}$, respectively.