• Journal of Photoscience
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• 제7권2호
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• pp.59-61
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• 2000

As a potential electroluminescent material, tetrahydrochrysene (THC) is prepared using the dehydrocyclization following the acyloin condensation of methyl-3-phenyl propionate as key step from trans-mehyl cinnamate in 3 steps. THC showed emission at 428 and 456 nm after the photo- and electro-excitation, respectively. The luminance of THC doped on PVK was about /$25 cdm^2$ at 30 voltage with 70 nm of thickness. The results suggests that a new fluorescent organic dye, THC can be used organic electroluminescent device.

• Journal of Pharmaceutical Investigation
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• 제40권4호
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• pp.219-223
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• 2010

The hyaluronic acid (HA) conjugate bearing $\alpha$-cyclodextrin ($\alpha$-CD) was synthesized as the potential carrier of poly(ethylene glycol) (PEG)-drug conjugates. The HA conjugate was prepared by the reaction between the carboxylic acid of HA and the primary amine of $\alpha$-CD in the presence of 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide and 1-hydroxybenzotriazole. The chemical structure of the conjugate was confirmed using $^1H$ NMR and FT-IR spectroscopy. The conjugate could form nano-sized particles in the presence of PEG by forming the inclusion complexes between $\alpha$-CD at the backbone of HA, which was demonstrated using electrophoretic light scattering and field emission transmission electron microscopy. It is anticipated that this novel kind of nanoparticles can serve as a useful delivery system for PEGylated drugs.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.1279-1282
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• 2009

The luminescence properties of a potential blue-emitting $RbBaPO_4:Eu^{2+}$ phosphor substituted with various metal ions have been investigated. The main emission wavelength of the phosphor samples was red-shifted by the substitution with K and Sr ions. The maximum peak intensity was obtained from the sample $Rb_{0.25}K_{0.75}Ba_{0.99}Eu_{0.01}PO_4$ which showed 144% relative intensity versus that of BAM:$Eu^{2+}$ phosphor under 254 nm excitation.

• 진공이야기
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• 제4권4호
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• pp.4-13
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• 2017

Quantum structures containing nanoparticles have attracted much attention because of their promising potential applications in electronic and optoelectronic devices operating at lower currents and higher temperatures. The quantum dot is a particle of matter so small that the addition or removal of an electron changes its properties in some useful way. The Quantum dots typically have dimensions measured in nanometers, where one nanometer is 10-9 meter or a millionth of a millimeter. The emission and absorption spectra corresponding to the energy band gap of the quantum dot is governed by quantum confinement principles in an infinite square well potential. The energy band gap increases with a decrease in size of the quantum dot. In this review paper, we will discuss the quantum dot and their application.

• Applied Microscopy
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• 제36권spc1호
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• pp.63-69
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• 2006

By utilizing a field emission gun and a biprism installed on a transmission electron microscope (TEM), electron holography is extensively carried out to visualize the electric and magnetic fields of nanomaterials. In the electric field analysis, the distribution of electric potential in a sharp tip made of W coated with $ZrO_2$ is visualized by applying the voltage to the tip. Denser contour lines due to the electric potential are observed with an increase in the bias voltage. In the magnetic field analysis by producing the strong magnetic field with a sharp magnetic needle made of a permanent magnet, the in situ experiment is carried out to investigate the magnetization of hard magnetic materials. The results of these experiments clearly demonstrate that electron holography is a promising advanced transmission electron microscopy technique to characterize the electric and magnetic properties of nanomaterials.

• Bulletin of the Korean Chemical Society
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• 제15권12호
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• pp.1050-1054
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• 1994

Eu(Ⅲ) exhibits one electron-transfer reduction at E$_{1/2}$ =-0.617 V vs. Ag/AgCl and the hypersensitive peak at 618 nm corresponding to $^5D_0$ ${\leftrightarro}$ $^7F_2$ transition in 0.10 M LiClO$_4$ aqueous solutions. Upon the addition of carboxylate or sulfonate anions to the Eu(Ⅲ) aqueous solutions, the reduction potential shifts negatively and the reduction current decreases because of the complex formation between Eu(Ⅲ) ions and the anions. However, for the case of carboxylate anion (acetate or propionate) the shift of reduction peak potential and the emission intensity at 618 nm are greater. The results are interpreted in terms of the differences in the formation constants and the hypersensitivity.

• 자원ㆍ환경경제연구
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• 제18권2호
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• pp.279-309
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• 2009

산업에서 발생되는 온실가스를 줄이기 위해서는 각 산업별 온실가스 발생량을 정확히 예측해야 한다. 이에 본 연구에서는 2003년 산업연관표와 에너지 사용량 통계자료를 기초로 401개 산업별 직 간접 $CO_2$ 원단위를 산출하고 이를 활용하는 방안을 검토하였다. 본 연구는 국내에 없는 일부 데이터 대신 해외 데이터 사용, 석유정제부문에 대한 분배 문제, 카본뉴트럴 측면에서 재검토 필요성, 폐기물처리 부문 과정의 일부 미고려 등에 따른 결과의 한계를 가지고 있다. 그럼에도 불구하고 부산물로 얻어지는 코크스로가스나 철강계 가스, 자원순환 관점에서 주목받고 있는 폐기물 영향까지를 고려한 401개 상세 산업별 직 간접 $CO_2$ 원단위를 산출했다는 측면에서 의미가 있다. 산업별 $CO_2$ 배출 원단위 분석 결과를 살펴보면, 간접 $CO_2$ 원단위가 크게 나타난 대표적인 산업으로는 조강, 레미콘, 선재 및 궤조, 주철물, 철근 및 봉강 산업이다. 이들 산업은 직접 $CO_2$ 원단위가 큰 산업에서 생산된 원료물질을 이용하여 제품을 생산하고 있다. 직접 $CO_2$ 배출 원단위가 크게 나타난 대표적인 산업으로는 시멘트, 선철, 석회 및 석고 제품, 석탄화합물 등 자연으로부터 채취한 원광석 등을 이용하여 다른 산업에 유용한 원료물질로 정제하는 산업이었다. 본 연구 결과는 산업별 특성이 반영된 저감 목표치 산정, $CO_2$ 저감정책별 감축 잠재량 산정, 기업의 $CO_2$ 배출량 수준 파악 및 저감 목표량을 설정할 때 유용하게 활용될 수 있다. 그 밖에도 국내에서 활발히 연구되고 있는 환경경제통합계정, 산업별 물질흐름분석 분야에서 널리 응용될 수 있을 것이다.

• 에너지공학
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• 제11권1호
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• pp.34-46
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• 2002

Carbon accounting is a key issue in the discussions on global warming/CO$_2$mitigation. This paper applies both the IPCC Approach and the NEAT (Non-Energy use Emission Accounting Tables) model, a bottom-up approach, to estimate the potential CO$_2$ emissions (carbon storage) originating from the non-energy use as to assess the actual CO$_2$ emissions (carbon release) from the use of fossil fuels in Korea. The current Korean carbon accounting seems to overestimate the potential CO$_2$ emissions and with it to underestimate the actual CO$_2$ emissions. The estimation shows that the potential CO$_2$ emissions calculated according to the IPCC Approach are lower than those calculated using the NEAT model. This is because the IPCC default storage fraction for naphtha seems to be low for the Korean petrochemical production structure, on the one hand and because the IPCC Approach does not consider the trade with short life petrochemical products, on the other hand. This paper shows that a bottom-up approach like the NEAT model can contribute to overcome some of limitations of the IPCC guidelines, especially by considering the international trade with short life petrochemical products and by estimating the storage fractions of fossil fuels used as feedstocks for the country in consideration. This paper emphasizes the importance of accurate energy statistics for carbon accounting.

• 한국산학기술학회논문지
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• 제14권12호
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• pp.6469-6477
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• 2013

인터넷의 규모가 확대됨에 따라, 인터넷의 에너지 소모와 GHG(Green House Gas) 배출에 대한 문제는 최근의 새로운 이슈로 등장하였다. 그러나 이러한 문제를 다루는 인터넷 그리닝(Greening)에 대한 관심은 주로 엣지(Edge) 장비에 집중되어 있으며, 과도한 네트워크 연결성으로 인한 유선 네트워크 장비의 에너지 낭비량과 절약 잠재성에 대해서는 깊이 있는 연구가 부족한 실정이다. 본 연구에서는 유선 네트워크에서 에너지 효율성에 대한 관심의 배경과 연구의 타당성을 환경적, 경제적, 에너지 사용의 측면에서 상세히 제시한다. 그리고 네크워크 장비에서의 에너지 소모량과 절약 잠재성을 추정하고 도출한 데이터를 바탕으로 유선 네트워크 장비의 에너지 소모의 주된 요인을 분석하여, 향후 미래 인터넷 기술의 발전 방향을 제시한다.

• Journal of Forest and Environmental Science
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• 제25권3호
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• pp.157-165
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• 2009

Forests potentially contribute to global climate change through their influence on the global carbon (C) cycle. The Kyoto Protocol provides for the involvement of developing countries in an atmospheric greenhouse gas reduction regime under its Clean Development Mechanism (CDM). Carbon credits are gained from reforestation and afforestation activities in developing countries. Bangladesh, a densely populated tropical country in South Asia, has a huge degraded forestland, which can be reforested by CDM projects. To realize the potential of the forestry sector in developing countries like Bangladesh for full-scale emission mitigation, the carbon sequestration potential should be integrated with the carbon trading system under the CDM of the Kyoto Protocol. This paper discusses the prospects of carbon trading in Bangladesh, in relation to the CDM, in the context of global warming.