• Title/Summary/Keyword: Emission potential

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Emission Properties of Europium Complex Utilizing Multilayer Quantum-Well Structure Properties by Vacuum Vapor Deposition Method (진공증착법으로 제작한 다층 구조의 Europium Complex의 발광특성)

  • 이상필;이제혁;이한성;김영관;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.609-612
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    • 1999
  • Organic electroluminescent(EL) devices have received a great deal of attention due to their potential application as full-color displays. They are attractive because of their capability of multicolor emission, ease of fabrication, and operation at a low driving voltage. In this study, single and multiple quantum-well structures consisting of Eu(TTA)$_3$(bpy) complex well layer sandwiched between triphenyldiamine derivative (TPD) layers were fabricated and their photoluminescent electroluminescent characteristics were also investigated. Sharp emission at 616 nm has been observed from the Eu complex in multilayer, single and multiple quantum-well structures. Details on the explanation of electrical properties of these structures will be discussed.

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Radiolabeled Benzamide Derivatives for Development of Malignant Melanoma Imaging Agents

  • Ayoung Pyo;Boreum Song;Heejung Kim;Dong-Yeon Kim
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • v.8 no.1
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    • pp.25-32
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    • 2022
  • Malignant melanoma has an aggressive nature and high metastatic potential that result in one of the highest cancer mortality rates. Over the past three decades, primary and metastatic melanoma incidence has rapidly increased. The recent advances in diagnostic technology have shown promise, but there is still an enormous need for specific detection methods to diagnose malignant melanoma. Positron emission tomography can visualize a particular biomarker of malignant melanoma and promise a noninvasive image of micrometastases. However, the development of PET radiopharmaceuticals remains necessary for diagnosing malignant melanoma by using positron emission tomography. In this review, the history and a general overview of PET radionuclide labeled benzamide derivatives, including their radiosynthesis, in vivo characterization, and evaluation, are provided as imaging agents for malignant melanoma.

Haematococcus pluvialis Cell-Mass Sensing Using Ultraviolet Fluorescence Spectroscopy

  • Lababpour, Abdolmajid;Hong, Seong-Joo;Lee, Choul-Gyun
    • Journal of Microbiology and Biotechnology
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    • v.17 no.12
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    • pp.1922-1929
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    • 2007
  • A simple whole-cell-based sensing system is proposed for determining the cell mass of H. pluvialis using ultraviolet fluorescence spectroscopy. An emission signal at 368 nm was used to detect the various kinds of green, green-brown, brown-red, and red H. pluvialis cells. The fluorescence emission intensities of the cells were highest at 368 nm with an excitation wavelength of 227 nm. An excitation wavelength of 227 nm was then selected for cell-mass sensing, as the emission fluorescence intensities of the cell suspensions were highest at this wavelength after subtracting the background interference. The emission fluorescence intensities of HPLC-grade water, filtered water, and HPLC-grade water containing a modified Bold's basal medium (MBBM) were measured and the difference was less than 1.6 for the selected wavelengths. Moreover, there was no difference in the emission intensity at 368 nm among suspensions of the various morphological states of the cells. A calibration curve of the fluorescence emission intensities. and cell mass was obtained with a high correlation ($R^2=0.9938$) for the various morphological forms of H. pluvialis. Accordingly, the proposed method showed no significant dependency on the various morphological cell forms, making it applicable for cell-mass measurement. A high correlation was found between the fluorescence emission intensities and the dry cell weight with a mixture of green, green-brown, brown-red, and red cells. In conclusion, the proposed model can be directly used for cell-mass sensing without any pretreatment and has potential use as a noninvasive method for the online determination of algal biomass.

Evaluating Carbon Dioxide Emission from Cadastral Category based on Tier 3 Approach (Tier 3 방식에 의거한 지목별 온실가스 배출 실태평가)

  • Kim, Dae-Ho;Um, Jung-Sup
    • Spatial Information Research
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    • v.19 no.3
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    • pp.11-22
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    • 2011
  • It is usual for the carbon dioxide emission to be calculated by official energy consumption statistics produced from a number of specialized industrial process such as refinery, power plant etc. The aim of this research was to evaluate potential of cadastral system in monitoring carbon dioxide emitted from land use. An empirical study for a cadastral category was conducted to demonstrate how a on-site measurement can be used to assist in estimating the carbon dioxide emission in terms of land use specific settings. The cadastral category based analysis made it possible to identify area-wide patterns of carbon dioxide emission, which cannot be acquired by traditional Government statistics. It was possible to identify successively increasing trends in the human-related parcels such as housing land while decreasing trends of carbon dioxide in sink parcels(eg. forest). The results indicate that the cadastral parcel could be used not only as a tool to monitor carbon dioxide emission, but also as an evidence to restrict initiation of development activities causing negative influence to carbon dioxide emission such as road construction. As a result, the research findings have established the new concept of "carbon dioxide emission monitoring based on cadastral category", proposed as an initial aim of this paper.

The Analysis of Differences by Improving GHG Emission Estimation Methodology for Agricultural Sector in Recent 5 Years (최근 5년간 농업부문 온실가스 산정방법 개선과 그에 따른 배출량 차이 분석)

  • Jeong, Hyun Cheol;Choi, Eun Jung;Lee, Jong Sik;Kim, Gun Yeob;Lee, Sun Il
    • Journal of Climate Change Research
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    • v.8 no.4
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    • pp.347-355
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    • 2017
  • Methane and nitrous oxide are main greenhouse gases from agricultural system and their global warming potential are 25 and 258 times stronger than that of $CO_2$, respectively. In 2016, the emission was $21,290Gg\;tone\;CO_2-eq$. which was emitted from agriculture sector and about 3.1% of total GHG emission of Korea. Those guidelines that were published by IPCC have methodology for GHGs emission calculation as well as emission factor and so on. For recent 5 years, GHGs emissions in Korea have calculated by MRV which has been improved every year based on IPCC guidelines. Analysis as estimating method improvement showed that the methane emissions from rice cultivation were the lowest on 2012 methodology, and the highest on 2014 methodology. On the other hand, the emissions of agricultural soils were the lowest on 2015 methodology and the highest on 2012 methodology. Total emissions from agriculture sector were the lowest on 2015 methodology and the highest on 2012 methodology. Compared with 2016 methodology, the GHGs emitted as few as $-1,865Gg\;tone\;CO_2-eq$ and as many as $2,717Gg\;tone\;CO_2-eq$. GHGs emissions can vary greatly, depending on how to use the emission factor and activity data. Therefore, it need constantly a detailed analysis for methodology and GHGs emission in the future.

고에너지 이온빔에 의한 이차전자 발생 수율 및 에너지 측정

  • Kim, Gi-Dong;Kim, Jun-Gon;Hong, Wan;Choi, Han-Woo;Kim, Young-Seok;Woo, Hyung-Joo
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.190-190
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    • 1999
  • 박막 표면에 대한 경원소 분석법인 탄성 되튐 반도법을 개발하여 수소, 탄소, 질소등 분석에 이용하고 있다. 이때 입사 입자로 Cl 9.6MeV를 이용하였는데, 표적 표면에 탄소막이 흡착되는 현상을 발견하였다. cold trap 및 cold finger를 사용하여 진공도를 개선하므로서, 탄소막 흡착의 한 원인으로 알려져 잇는 chamber 주변의 진공도 변화를 시켜보았다. 하지만 전혀 탄소막이 생기지 않는 10-10torr 이하 진공을 만드는 것은 많은 비용과 장비를 필요로 하는 상당히 힘든 작업이어서, 이차적으로 탄소막이 표적 표면에 달라 붙게 하는 원인으로 추정되는 이차 전자의 발생을 고에너지 이온빔으로 조사하였다. 일반적으로 이차전자의 발생은 이온빔과 표적과의 충돌에 의한 고체 표면으로부터의 전자방출 현상으로 오래전부터 연구되어져 왔다. 여기에는 두가지 다른 구조가 존재하는 것으로 알려져 있다. 그 중 하나는 입사 입자의 전하와 표적 표면사이 작용하는 potential 에너지가 표적 표면의 일함수(재가 function) 보다 클 때에 일어나는 potential emission이다. 즉 표적 궤도에 존재하는 전자와 입사 이온빔 사이의 potential 이 표적의 전자를 들뜨게 만들고, 이 potential의 크기가표적의 표면 장벽 potential 보다 충분히 클 뜸 전자가 방출하는 현상을 말한다. 다른 또 하나의 방출구조로는 입사 이온이 표적 표면의 원자와의 충돌에 의해 직접저인 에너지 전달을 통한 전자 방출을 말하는데, 이를 kienetic emission(이하 KE)이라 한다. 본 연구에서는 Tandem Van de graaff 가속기로 고에너지 이온빔을 만들어 Au에 충돌시키므로서 kinetic emission을 통하여 Au에서 발생한는 이차전자의 방출 수율 및 에너지를 측정하였다.장구조로 전체 성장 양식을 예견할 수 있다. 일반적인 경향은 Ep가 커질수록 fractal 성장형태가 되며, Ed가 적을수록 cluster 밀도가 작아지나, 같은 Ed+Ep에 대해서는 동일한 크기의 팔 넓이(수평 수직 방향 cluster 두께)를 가진다. 따라서 실험으로부터 얻은 cluster의 팔 넓이로부터 Ed+Ep 값을 결정할 수 있고, cluster 밀도와 fractal 차원으로부터 각각 Ed와 Ep값을 분리하여 얻을 수 있다. 또한 다층 성장에 대한 거칠기(roughness) 값으로부터 Es값도 구할 수 있다. 양방향 대칭성을 갖지 않은 fcc(110) 표면과 같은 경우, 형태는 다양하지만 동일한 방법으로 추정이 가능하다. (110) 표면의 경우 nearest neighbor 원자가 한 축으로 형성되고 따라서 이 축과 이것과 수직인 축에 대한 상호작용이나 분산 장벽 모두가 비대칭적이다. 따라서 분산 장벽도 x-축, y-축 방향에 따라 분리하여 Edx, E요, Epx, Epy 등과 같이 방향에 따라 다르게 고려해야 한다. 이러한 비대칭적인 분산 장벽을 고려하여 KMC 시뮬레이션을 수행하면 수평축과 수직축의 분산 장벽의 비에 따라 cluster의 두께비가 달라지는 성장을 볼 수 있었고, 한 축 방향으로의 팔 넓이는 fcc(100) 표면의 경우 동일한 Ed+Ep값에 대응하는 팔 넓이와 거의 동일한 결과가 나타나는 것을 볼 수 있다. 따라서 이러한 비대칭적인 모양을 가지는 성장의 경우도 cluster 밀도, cluster 모양, cluster의 양 축 방향 길이 비, 양 축 방향의 평균 팔 넓이로부터 각 축 방향의 분산 장벽을 얻어낼 수 있을 것으로 보인다. 기대할 수 있는 여러 장점들을 보고하고자 한다.성이 우수한 시편일수록 grain의 크기가 큰 것으로 나타났고 결정성이 우수한 시편의 경우에서는 XR

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Characteristics of N2O Emission Factor and Measurements from Gasoline-Powered Passenger Vehicles (국내휘발유 승용차량으로부터의 N2O배출인자 특성연구)

  • Kim, Deug-Soo;Ryu, Jeong-Ho;Yoo, Young-Sook;Jung, Sung-Woon;Kim, Dae-Wook
    • Journal of Environmental Science International
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    • v.16 no.2
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    • pp.179-185
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    • 2007
  • Nitrous oxide ($N_2O$) is an important trace gas in the atmosphere not only because of its large global warming potential (GWP) but also because of the role in the ozone depletion in the stratosphere. It has been known that soil is the largest natural source of $N_2O$ in global emission. However, anthropogenic sources contributing from industrial section is likely to increase with rising the energy consumption, and transportation as well. In this study, a total of 32 gasoline-powered passenger vehicles (ranging from small to large engine's displacement and also ranging from aged catalyst to new catalyst) were tested on the chassis dynamometer system in order to elucidate the characteristics of $N_2O$ emission from automobiles under different driving modes. Ten different driving modes developed by NIER were adapted for the test. The results show that the $N_2O$ emission decreases logarithmically with increase of vehicle speed over the all test vehicles ($N_2O$) emission = -0.062 Ln (vehicle speed) + $0.289,\;r^2=0.97$). It revealed that the larger engine's displacement, the more $N_2O$ emission were recorded. The correlation between $N_2O$ emission and catalyst aging was examined. It found that the vehicles with aged catalyst (odometer record more than 8,0000km) emit more $N_2O$ than those with new catalyst. Average $N_2O$ emission was $0.086{\pm}0.095\;N_2O-g/km$ (number of samples=210) for the all test vehicles over the test driving modes.

Enhanced UV-Light Emission in ZnO/ZnS Quantum Dot Nanocrystals (산화아연/황화아연 양자점 나노결정에서의 향상된 자외선 방출)

  • Kim, Ki-Eun;Kim, Woong;Sung, Yun-Mo
    • Korean Journal of Materials Research
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    • v.18 no.12
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    • pp.640-644
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    • 2008
  • ZnO/ZnS core/shell nanocrystals (${\sim}5-7\;nm$ in diameter) with a size close to the quantum confinement regime were successfully synthesized using polyol and thermolysis. X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM) analyses reveal that they exist in a highly crystalline wurtzite structure. The ZnO/ZnS nanocrystals show significantly enhanced UV-light emission (${\sim}384\;nm$) due to effective surface passivation of the ZnO core, whereas the emission of green light (${\sim}550\;nm$) was almost negligible. They also showed slight photoluminescence (PL) red-shift, which is possibly due to further growth of the ZnO core and/or the extension of the electron wave function to the shell. The ZnO/ZnS core/shell nanocrystals demonstrate strong potential for use as low-cost UV-light emitting devices.

Characteristics of Carbon Nanotube FED

  • Uemura, Sashiro;Yotani, Junko;Nagasako, Takeshi;Kurachi, Hiroyuki;Yamada, Hiromu;Ezaki, Tomotaka;Maesoba, Tsuyoshi;Nakao, Takehiro;Ito, Masaaki;Saito, Yahachi;Yumura, Motoo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.860-865
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    • 2004
  • Field emission display(FED) using carbon nanotubes (CNT) as field emitters is expected to large-area panels with high luminance and low power consumption. In order to perform the uniform luminance with low driving voltage, we introduced a new electrode to apply higher electric potential over the CNT cathode in 2003.[1] In the study, we described the luminance uniformity of the panel and the improvement of emission uniformity by increasing the emission-site density. The luminance uniformity of the several ideal dots which were selected over the display area in the panel was 2.8%. [2] The CNT cathode was irradiated by excimer-laser, which was effective to improve emission uniformity and lower driving voltage. A prototype of CNT-FED character display was performed for middle size message displays. The prototype panel had 48 x 480-dots and the resolution was 1-mm. The panel realized high luminance at low power consumption. It will be important characteristics for legible and ubiquitous displays. [3]

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Nitrous Oxide Emission from Livestock Compost applied Arable Land in Gangwon-do

  • Seo, Young-Ho;Kim, Se-Won;Choi, Seung-Chul;Jeong, Byeong-Chan;Jung, Yeong-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.1
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    • pp.25-29
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    • 2012
  • Agriculture activities account for 58% of total anthropogenic emissions of nitrous oxide ($N_2O$) with global warming potential of 298 times as compared to carbon dioxide ($CO_2$) on molecule to molecule basis. Quantifying $N_2O$ from managed soil is essential to develop national inventories of greenhouse gas (GHG) emissions. The objective of the study was to compare $N_2O$ emission from livestock compost applied arable land with that for fertilizer treatment. The study was conducted for two years by cultivating Chinese cabbage (Brassica campestris L.) in Chuncheon, Gangwon-do. Accumulated $N_2O$ emission during cultivation of Chinese cabbage after applying livestock compost was slightly greater than that for chemical fertilizer. Slightly greater $N_2O$ emission factor for livestock compost was observed than that for chemical fertilizer possibly due to lump application of livestock compost before crop cultivation compared with split application of chemical fertilizers and enhanced denitrification activity through increased carbon availability by organic matter in livestock compost.