• 제목/요약/키워드: Emission Control

검색결과 1,564건 처리시간 0.026초

산업폐기물 소각시설에서 폐기물 유형에 따른 입자상물질의 배출특성 (Emission Characterization of Particulate Matters According to the Types of Wastes from Industrial Waste Incinerator)

  • 박정호;서정민;조정구;류재용;한성종
    • 한국환경과학회지
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    • 제16권11호
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    • pp.1225-1230
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    • 2007
  • The emissions characteristics of particulate matters(PM) according to the types of wastes from industrial waste incinerator of 800 kg/hr treatment capacity were investigated. For this study, the incinerate waste are as follows; waste resin, waste wood, waste urethane, waste gunny, and waste paper. The particulate samples were collected to be emitted in stack and air pollution control(both cyclone and bag filter). In stack, the concentrations of PM were in the range of 2.61 to $26.51 mg/Sm^3$ and the major chemical species were C, Si, Cl, K, Na, Ca in all the wastes. In cyclone fly ash, the mean content of heavy metal were in the order of Fe > Zn > Pb > Cu > Mn > Cr > Ni > Cd > As > Hg and the heavy metal content of waste resin were Zn 34,197.5 mg/kg, Fe 27,587.6 mg/kg, Pb 6,055.8 mg/kg, respectively. In bag filter fly ash, the mean content of heavy metal were in the order of Zn > Pb > Fe > Cu > Mn > Cd > Cr > Ni > As > Hg and the heavy metal content of waste wood were Pb 36,405.2 mg/kg, Fe 15,762.9 mg/kg, Cu 9,989.5 mg/kg, Cd 2,230.1 mg/kg, respectively. Comparing the heavy metal content of both cyclone and bag filter, in cyclone, the Cr, Fe, Ni content were higher than in bag filter and the Cd, Cu, Hg content were lower than in bag filter.

배기가스 규제 대응을 위한 LNG연료추진선박의 HAZID 사례 분석에 관한 연구 (A Study on the Risk Assessment Case Analysis of LNG Fuelled Ships for Emission Control)

  • 이윤혁;;김유택;정진원;강호근
    • 한국항해항만학회:학술대회논문집
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    • 한국항해항만학회 2018년도 춘계학술대회
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    • pp.162-163
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    • 2018
  • 해양환경 및 배출가스 규제로 지금까지와는 다른 새로운 연료공급시스템을 적용하게 되는 LNG 추진 선박의 경우 초기 설계 단계에서 위해도 평가가 수행된다. 위해도 평가는 위험에 대한 분석과 평가를 체계적으로 가능하게 하는 일련의 논리적인 단계이다. LNG 연료추진선박은 크게 LNG Tank, Fuel Gas Supply System, Bunkering Manifold, LNG Engine으로 구성되며 이는 해당 선박의 특성, 크기, 항로, 운항거리, 사용엔진 등에 따라 구성요소가 달라지므로 각각의 선박에 대한 위험 요소가 달라지며, 위해도 분석 또한 달라진다. 본 연구에서는 LNG를 연료로 하는 선박들의 시스템에 대해 고찰하고, 실제 위험도 평가가 진행된 몇 가지 사례 선박들의 위해도 평가에 대한 분석을 하고자 한다.

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유도결합 플라즈마를 이용한 $Al_2O_3$ 식각 특성 (The etching properties of $Al_2O_3$ thin films in $N_2/Cl_2/BCl_3$ and Ar/$Cl_2/BCl_3$ gas chemistry)

  • 구성모;김동표;김경태;김창일
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.72-74
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    • 2004
  • In this study, we used a inductively coupled plasma (ICP) source for etching $Al_2O_3$ thin films because of its high plasma density, low process pressure and easy control bias power. $Al_2O_3$ thin films were etched using $Cl_2/BCl_3$, $N_2/Cl_2/BCl_3$, and Ar/$Cl_2/BCl_3$ plasma. The experiments were carried out measuring the etch rates and the selectivities of $Al_2O_3$ to $SiO_2$ as a function of gas mixing ratio, rf power, and chamber pressure. When $Cl_2$ 50% was added to $Cl_2/BCl_3$ plasma, the etch rate of the $Al_2O_3$ films was 118 nm/min. We also investigated the effect of gas addition. In case of $N_2$ addition, the etch rate of the $Al_2O_3$ films decreased while $N_2$ was added into $Cl_2/BCl_3$ plasma. However, the etch rate increased slightly as Ar added into $Cl_2/BCl_3$ plasma, and then further increase of Ar decreased the etch rate. The maximum etch rate was 130 nm/min at Ar 20% in $Cl_2/BCl_3$ plasma, and the highest etch selectivity was 0.81 in $N_2$ 20% in $Cl_2/BCl_3$ plasma. And, we obtained the results that the etch rate increases as rf power increases and chamber pressure decreases. The characteristics of the plasmas were estimated using optical emission spectroscopy (OES).

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광촉매 응용을 위한 TiO2 나노 섬유의 미세구조 제어 (Control of Microstructure on TiO2 Nanofibers for Photocatalytic Application)

  • 이창규;김완태;나경한;박동철;양완희;최원열
    • 한국전기전자재료학회논문지
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    • 제31권6호
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    • pp.417-421
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    • 2018
  • $TiO_2$ has excellent photocatalytic properties and several studies have reported the increase in its specific surface area. The structure of $TiO_2$ nanofibers indicates promising improved photocatalytic properties and these nanofibers can thus potentially be applied in air pollution sensors and pollutant removal filters. In this study, a $TiO_2$ nanofiber was fabricated by the electrospinning method. The fabrication processing factors such as the applied voltage, the distance between nozzle and collector, and the inflow rate of solution were controlled. The precursor was titanium (IV) isopropoxide and as-spun $TiO_2$ nanofibers were heated at $450^{\circ}C$ for 2 h to obtain an anatase crystalline structure. The microstructure was analyzed using field emission scanning electron microscope (FE-SEM) and X-ray diffraction analysis (XRD). The anatase phase was observed in the $TiO_2$ nanofibers after heat treatment. The diameter of $TiO_2$ nanofibers increased with the flow rate, but decreased with decreasing applied voltage and nozzle to collector distance. The diameter of $TiO_2$ nanofibers was controlled in the range of 364 nm to 660 nm. These nanofibers are expected to be very useful in photocatalytic applications.

도시 환경용량평가에 관한 연구 -청주시를 사례로- (A Study on the Environmental Carrying Capacity Assessment of Chongju City)

  • 임재호;이종호
    • 환경영향평가
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    • 제11권1호
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    • pp.25-36
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    • 2002
  • The purpose of this study is to assess the environmental carrying capacity of Chongju City for the environmental management and the urban growth management. The urban environmental carrying capacity assessment of the city by the index of ecological footprint(EF), shows that the ecosystem of the city has been overloaded and most of the deficiencies has come from outside of the city. The EF index, the area of land per capita required for production and consumption in the city, was 1.731 ha per capita in 1989 and 1.901 ha per capita in 1999. On the other side, the ecologically productive land is 0.0175 ha per capita. It means that every citizen owes 1.88 ha per capita to the ecosystem in 1999. The land consumption of the city has increased by 0.1705 ha per capita during the last 10 years. The capacity of infrastructure and the service supply estimated by the Onishi model does not exceed the demand of the city in 1999. But the rapidly increasing population and fast urban growth need the expansion of the capacity. The water supply capacity of the city appears to be sufficient in 1999, but the water supply demand will increase in the future. The capacity of sewage treatment facilities seems to be sufficient, but the higher level of sewage treatment facilities should be adopted for the improvement of water quality as the generation of sewage will increase and its characteristics will also make the wastewater treatment difficult. Due to the decrease of solid waste generated, the land fill capacity for solid waste disposal is not insufficient at present, but the capacity will be saturated in the near future. Therefore, the scientific management system of solid wastes should be introduced. The air quality of the city meets both the national air quality standard and WHO recommendation standard, but the strong regulation and control of automobile emission gas such as CO, $CO_2$, NOx and HC is required for clean air.

다이옥신 전구물질인 Chlorophenol 의 열분해에 관한 연구 (The Study of Pyrolysis Characteristics of Dioxin Precursor Chlorophenol)

  • 정태섭;김종국;김경수;윤병석
    • 대한환경공학회지
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    • 제22권1호
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    • pp.179-185
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    • 2000
  • 도시쓰레기 소각로에서 다이옥신류의 생성과 대기로의 방출을 최소화하기 위해 소각로의 후 연소 영역에서 다이옥신 전구물질의 원인이 되는 클로로페놀(이하 CP로 표기)의 거동에 대해 검토하였다. 전기관상로를 이용하여 온도조건 $300{\sim}500^{\circ}C$ 에서 CP을 주입하고 질소가스를 이용하여 반응시간을 조절하였으며 CP의 이성질체별 연소에 필요한 산소량은 계산된 실험식을 이용하여 주입하였다. 반응기내의 공간속도가 60~80/초의 조건에서 Mo-V계 촉매를 사용하여 촉매유무에 따른 CP의 분해 효율을 살펴보았다. 무촉매 열분해시 mono-CP은 74~80%, di-CP은 55~66%, tri-CP은 50~58%의 효율을 보였고, Mo-V계 촉매가 존재할 때 mono-CP은 90~99.9%, di-CP은 86~97%, tri-CP은 76~99%의 효율을 나타내 Mo-V계 촉매를 사용함으로써 약 20~30%의 효율이 증가함을 확인할 수 있다.

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유해화학물질 취급사업장 통합관리 연구 (Study of the Intergrated Management for Business Handling Hazardous Chemicals)

  • 김성범;박춘화;안성용;김정민;천광수;노혜란;석광설;윤이
    • 한국재난정보학회 논문집
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    • 제9권3호
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    • pp.259-265
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    • 2013
  • 유해화학물질관리법에서는 화학물질의 제조 수입부터 판매 사용 배출 전과정에 대한 감시제도를 두어 화학물질의 불법적인 유통을 방지하고, 적정관리를 유도하고 있다. 그러나 부처별 점검체계가 다양하고, 점검기관도 지자체 환경청으로 이원화되어 있어 정보의 공유와 업무의 연계성 유지가 어렵다. 화학물질 취급사업장 전반에 대한 종합적인 분석이나 체계적인 관리를 위해서 현재의 관리현황을 분석하고, 이를 통해 사업장관리에 대한 개선방안을 마련하고자 한다.

직분식 CNG 엔진에서 연료 분사시기의 변화가 연소 및 출력 특성에 미치는 영향 (The Effect of Fuel Injection Timing on Combustion and Power Characteristics in a DI CNG Engine)

  • 강정호;윤수한;이중순;박종상;하종률
    • 한국자동차공학회논문집
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    • 제15권1호
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    • pp.193-200
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    • 2007
  • Natural gas is one of the most promising alternatives to gasoline and diesel fuels because of its lower harmful emissions, including $CO_2$, and high thermal efficiency. In particular, natural gas is seen as an alternative fuel for heavy-duty Diesel Engines because of the lower resulting emissions of PM, $CO_2$ and $NO_x$. Almost all CNG vehicles use the PFI-type Engine. However, PFI-type CNG Engines have a lower brake horse power, because of reduced volumetric efficiency and lower burning speed. This is a result of gaseous charge and the time losses increase as compared with the DI-type. This study was conducted to investigate the effect of injection conditions (early injection mode, late injection mode) on the combustion phenomena and performances in the or CNG Engine. A DI Diesel Engine with the same specifications used in a previous study was modified to a DI CNG Engine, and injection pressure was constantly kept at 60bar by a two-stage pressure-reducing type regulator. In this study, excess air ratios were varied from 1.0 to the lean limit, at the load conditions 50% throttle open rate and 1700rpm. The combustion characteristics of the or CNG Engine - such as in-cylinder pressure, indicated thermal efficiency, cycle-by-cycle variation, combustion duration and emissions - were investigated. Through this method, it was possible to verify that the combustion duration, the lean limit and the emissions were improved by control of injection timing and the stratified mixture conditions. And combustion duration is affected by not only excess air ratio, injection timing and position of piston but gas flow condition.

CO2 절감을 위한 콘크리트 2차제품 양생단계저감용 결합재 종류에 따른 모르타르 강도특성 (Strength Properties of Mortar According to Types of Binders for Reducing Curing Process of Concrete Secondary Products for Reduction CO2)

  • 김하석;백대현;이세현
    • 자원리싸이클링
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    • 제23권4호
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    • pp.37-46
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    • 2014
  • 건설 분야 중 건설 재료와 건자재 산업에서 발생하는 $CO_2$는 약 6,700만톤으로 건설 분야에서 발생하는 $CO_2$의 약 30 %를 점유하고 있다. 건설 분야에서 $CO_2$ 저감은 건자재 산업에서 $CO_2$를 발생시키는 2차, 3차 양생을 줄여 소비되는 화석연료 사용과 배출가스 저감의 조절이 필수적이다. 따라서 본 연구는 시멘트 결합재를 기초로 하여 결합재를 40 % 까지 대체하여 모르타르를 제조한 후 양생방법을 달리하여 응결 및 강도 특성을 분석하였다. 결합재 치환율에 따른 강도 특성 결과 증기양생 후 고로슬래그와 CSA 15%, CAMC 5%를 치환한 시험체의 강도 증진이 활발하였다. 특히 고로슬래그 50%, CSA 15%, CAMC 5%를 치환한 시험체가 가장 높게 강도가 증진되었다. 하지만 CAMC 10%의 경우 열팽창에 의한 균열과 온도차에 의한 건조수축, 과도하게 생성된 에트린가이트에 의해 강도가 저하되는 결과를 가져왔다.

Ceramic 분말의 첨가가 산란계의 생산성, 맹장 및 배설물중 병원성 미생물의 수, 배설물충의 악취물질 및 난황중 지방산 조성에 미치는 영향 (Effect of Dietary Ceramic Powder on Laying Performance, Pathogenic Bacterial Count in Caecal Content and Excreta, Malodorous Substances in Excreta and Fatty Acid composition or Egg Yolk in Laying Hens)

  • 손장호
    • 한국가금학회지
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    • 제32권4호
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    • pp.261-268
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    • 2005
  • 본 연구는 Ceramic분말의 첨가가 산란계의 생산성, 맹장 및 배설물중 병원성 미생물(E. coli, salmolella)의 수, 배설물 중의 악취물질$(NH_3,\;H_2S,\;VFA)$ 및 난황중 지방산 조성에 미치는 영향을 구명하기 위해서 실시하였다. 총 360수의 34주령의 산란계를 120마리씩 3처리구로 구분하여서 Ceramic 분말 $0.0\%$ (대조구), $0.4\%$$0.8\%$를 첨가한 사료로 6주 동안의 사양시험을 실시하였다. 결론적으로 34에서 40주령의 산란계 사료에 $0.4\%$의 Ceramics 분말의 첨가는 생산성 향상, 장관내 E. coli 및 Salmonella 수가 감소되어 배설물 중의 $NH_3$ 및 VFA의 발생량 감소 및 난황중의 지방산 조성을 개선시킬 가능성이 인정되었다.