• 한국재료학회지
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• 제22권6호
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• pp.316-320
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• 2012

$Co_3O_4$, $Al_2O_3$ and $Co_3O_4$/$Al_2O_3$ mesoporous powders were prepared by a sol-gel method with starting matierals of aluminum isopropoxide and cobalt (II) nitrate. A P123 template is employed as an active organic additive for improving the specific surface area of the mixed oxide by forming surfactant micelles. A transition metal cobalt oxide supported on alumina with and without P123 was tested to find the most active and selective conditions as a heterogeneous catalyst in the reaction of styrene epoxidation. A bBlock copolymer-P123 template was added to the staring materials to control physical and chemical properties. The properties of $Co_3O_4$/$Al_2O_3$ powder with and without P123 were characterized using an X-ray diffractometer (XRD), a Field-Emission Scanning Electron Microscope (FE-SEM), a Bruner-Emmertt-Teller (BET) surface analyzer, and $^{27}Al$ MAS NMR spectroscopy. Powders with and without P123 were compared in catalytic tests. The catalytic activity and selectivity were monitored by GC/MS, $^1H$, and $^{13}C$-NMR spectroscopy. The performance for the reaction of epoxidation of styrene was observed to be in the following order: [$Co_3O_4$/$Al_2O_3$ with P123-1173 K > $Co_3O_4$/$Al_2O_3$ with P123-973 K > $Co_3O_4$-973 K>$Co_3O_4$/$Al_2O_3$-973 K > $Co_3O_4$/$Al_2O_3$ with P123-1473 K > $Al_2O_3$-973 K]. The existence of ${\gamma}$-alumina and the nature of the surface morphology are related to catalytic activity.

• 한국항해항만학회지
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• 제38권4호
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• pp.335-341
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• 2014

최근 고유가와 환율변동 등 어려운 시장상황 속에서 해운선사는 선박의 대형화와 고속화를 요구하고 있다. 선사들은 선박의 운용유지비 절감을 우선적으로 요구하고 있으며, 이에 조선소에서는 기술경쟁력 유지를 위한 방안으로 속도성능 향상에 중점을 두고 지속적으로 노력 하고 있다. 본 논문에서는 에너지 절약형 선형개발에 중점을 두고 유동제어 띠를 사용한 선박의 저항성능 향상에 관하여 소개한다. 본 연구는 혹등고래(Humpback Whale)의 배 주위에 있는 기다란 줄 무늬 형상을 응용하여 선체표면에 "오목하고 길게 팬 줄 형상 또는 볼록하고 기다란 줄 형상"(이하, 유동제어 띠라고 함)을 단일로 적용하였다. 현재, 제안된 형상은 특허출원이 되어 있다. 이 형상은 선체표면의 압력분포 변화와 압력강하 현상 등을 효과적으로 제어하는 역할을 한다. 실선 적용 시 장점은 블록조립이 완성된 후에 선체표면에 부가물을 부착하는 종래기술과 비교하여 볼 때 블록제작 단계에서 단면형상을 반영할 수 있다는 점에서 비용을 절약할 수 있다고 판단된다.

• 자원ㆍ환경경제연구
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• 제18권3호
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• pp.523-544
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• 2009

본 연구는 목적은 내생적 환경정책모형(endogenous environmental policy)에 기초하여 외국인직접투자(foreign direct investment), 경제성장, 환경규제의 상호관계를 실증적으로 분석하는 것이다. 외국인자본비율의 1% 증가는 0.044%(고정효과), 0.047%(확률효과)의 경제성장효과를 유발하였으며, 노동자 1인당 생산량의 1% 증가는 2.038%(고정효과), 1.890%(확률효과)의 환경규제강화를 유도하는 것으로 계측되었다. 그러나 생산 과정에 있어 강력한 환경규제가 기술혁신의 유인으로 작용한다는 포터의 가설(Porter's theory)을 지지할 만한 실증결과는 보여주지 못하였다. 또한 2개의 대기오염물질 (NOx, $CO_2$)을 기준으로 규모효과(0.0119, 0.0172)가 기술효과(-0.0048, -0.0007)보다 크게 추정되었다. 이는 국제사회의 꾸준한 노력에도 불구하고 더욱 적극적인 환경보호를 위해 각국의 공공지출액을 증액시킬 필요성이 있음을 의미한다.

• Asian Journal of Atmospheric Environment
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• 제5권4호
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• pp.228-236
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• 2011

Since most Green House Gases (GHGs) and air pollutants are generated from the same sources, it will be cost-effective to develop a GHGs reduction plan in combination with simultaneous removal of air pollutants. However, effects on air pollutants reduction according to implementing any GHG abatement plans have been rarely studied. Reflecting simultaneous removal of air pollutants along with the GHGs emission reduction, this study investigated relative cost effectiveness among GHGs reduction action plans in Busan Metropolitan City. We employed the Data Envelopment Analysis (DEA), a methodology that evaluates relative efficiency of decision-making units (DMUs) producing multiple outputs with multiple inputs, for the investigation. Assigning each GHGs reduction action plan to a DMU, implementation cost of each GHGs reduction action plan to an input, and reduction potential of GHGs and air pollutants by each GHGs reduction action plan to an output, we calculated efficiency scores for each GHGs reduction action plan. When the simultaneous removal of air pollutants with the GHGs reduction were considered, green house supply-insulation improvement and intelligent transportation system (ITS) projects had high efficiency scores for cost-positive action plans. For cost-negative action plans, green start network formation and running, and daily car use control program had high efficiency scores. When only the GHGs reduction was considered, project priority orders based on efficiency scores were somewhat different from those when both the removal of air pollutants and GHGs reduction were considered at the same time. The expected action plan priority difference is attributed to great difference of air pollutants reduction potential according to types of energy sources to be reduced.

• Ocean and Polar Research
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• 제42권2호
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• pp.171-178
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• 2020

R/V EARDO, commissioned in 1992, has successfully carried out ocean research campaigns in Korean jurisdictional and adjacent waters, including continental margins and coastal zones within the Korean Exclusive Economic Zone (EEZ), for 29 years. However, it will soon be reaching the end of its useful service life. A replacement for R/V EARDO is urgently needed to ensure the safety of vessel itself and its crews, and efficient ship operation and maintenance, as well as to meet modern scientific mission requirements (SMRs). Basic specifications for a replacement ship have been devised and reviewed over the past nine months. A test of the proposed hull form was also performed. The total tonnage of the proposed vessel is approximately 740 tons, and the overall length and width are 62.0 and 11.6 m, respectively. The new ship will thus be 73% larger than the current R/V EARDO; in particular, the research workspace will be 4.4 times larger. The major design priorities are the propulsion system, efficiency of radiated noise and vibration control, and the dynamic positioning system. An environmentally friendly emission system, meeting International Maritime Organization (IMO) Tier III regulations, will be installed in the third exhaust pipe. Various wet and dry lab spaces as well as 32 different scientific instruments have also been considered in the ship design.

• 한국가스학회지
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• 제21권4호
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• pp.42-46
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• 2017

화석연료의 무분별한 사용으로 인한 이산화탄소의 대기 중 방출은 지구의 연평균 기온을 상승시키는 원인으로 작용하고 있다. 이를 해결하기 위한 대체에너지로써 지열은 연중 일정한 온도를 갖는 무한자원이다. 지열에너지를 널리 보급하기 위해서는 히트펌프의 성능과 지중열교환기의 열교환 효율이 매우 중요하다. 이에 본 연구는 히트펌프의 성능을 증가시키기 위해 팽창변을 이중으로 구성하고 지중열교환기의 열교환 효율을 높이기 위해 입출관과 유입관 사이에 간격유지부재를 사용하여 실험하였다. 실험한 결과 팽창변을 이중으로 구성하였을 때 냉난방 능력이 최대 11.4%가 증가됨을 얻을 수 있었고, 간격유지부재를 사용 시 열교환 효율이 17.5% 향상되었다. 이러한 결과를 토대로 지열시스템의 설치 시 히트펌프의 성능과 지중열교환기의 열교환 효율의 상승으로 인해 설치비용이 많이 절감될 것으로 판단된다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.189-189
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• 2016

Recently, many researchers have shown an increased interest in colloidal quantum dots (QDs) due to their unique physical and optical properties of size control for energy band gap, narrow emission with small full width at half maxima (FWHM), broad spectral photo response from ultraviolet to infrared, and flexible solution processing. QDs can be widely used in the field of optoelectronic and biological applications and, in particular, colloidal QDs based light emitting diodes (QDLEDs) have attracted considerable attention as an emerging technology for next generation displays and solid state lighting. A few methods have been proposed to fabricate white color QDLEDs. However, the fabrication of white color QDLEDs using single QD is very challenging. Recently, hybrid nanocomposites consisting of CdTe/ZnO heterostructures were reported by Zhimin Yuan et al.[1] Here, we demonstrate a novel but facile technique for the synthesis of CdTe/ZnO/G.O(graphene oxide) quasi-core-shell-shell quantum dots that are applied in the white color LED devices. Our best device achieves a maximum luminance of 484.2 cd/m2 and CIE coordinates (0.35, 0.28).

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.427-427
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• 2016

Organic-inorganic hybrid perovskite have attracted significant attention as a new revolutionary light absorber for photovoltaic device due to its remarkable characteristics such as long charge diffusion lengths (100-1000nm), low recombination rate, and high extinction coefficient. Recently, power conversion efficiency of perovskite solar cell is above 20% that is approached to crystalline silicon solar cells. Planar heterojunction perovskite solar cells have simple device structure and can be fabricated low temperature process due to absence of mesoporous scaffold that should be annealed over 500 oC. However, in the planar structure, controlling perovskite film qualities such as crystallinity and coverage is important for high performances. Those controlling methods in one-step deposition have been reported such as adding additive, solvent-engineering, using anti-solvent, for pin-hole free perovskite layer to reduce shunting paths connecting between electron transport layer and hole transport layer. Here, we studied the effect of alkali metal halide to control the fabrication process of perovskite film. During the morphology determination step, alkali metal halides can affect film morphologies by intercalating with PbI2 layer and reducing $CH3NH3PbI3{\cdot}DMF$ intermediate phase resulting in needle shape morphology. As types of alkali metal ions, the diverse grain sizes of film were observed due to different crystallization rate depending on the size of alkali metal ions. The pin-hole free perovskite film was obtained with this method, and the resulting perovskite solar cells showed higher performance as > 10% of power conversion efficiency in large size perovskite solar cell as $5{\times}5cm$. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and inductively coupled plasma optical emission spectrometry (ICP-OES) are analyzed to prove the mechanism of perovskite film formation with alkali metal halides.

• 전자공학회논문지
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• 제53권11호
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• pp.99-106
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• 2016

라돈이 기관지나 폐포에 머무르게 될 때 라돈의 붕괴로 인해 자핵종(알파선, 베타선, 감마선 등)들이 생성되면서 이것들이 방사선을 방출하는데 세포의 염색체에 돌연변이를 일으켜 폐암을 발생할 가능성이 존재한다. 다시 말해 폐암의 원인이 라돈가스 때문이라기보다는 흡수된 일부 라돈의 붕괴로 인해 생기는 부산물이 방사선을 방출하기 때문이라고 할 수 있다. 사람이 연간 노출되는 방사선의 82%가 자연방사선에 의한 것인데 그중 대부분이 라돈이다. 실내의 라돈 농도를 적절하게 제어할 수 있다면 폐암의 발생확률을 30%나 억제할 수 있다고 알려져 있다. 아직까지 실내의 라돈의 농도를 측정하는 데는 외국의 라돈 센서를 사용하고 있는 실정이다. 실내 라돈 방출량에 대한 데이터 구축과 국내에 맞는 실용적인 라돈측정기기를 개발하도록하는 연구가 필요하다. 본 논문에서는 PIN Photodiode를 이용하여 라돈의 농도를 측정하는 라돈 검출기 구현 방법을 제안한다. 실험을 통해서, PIN photodiode의 라돈 센서 모듈로서의 이용 가능성에 대하여 확인하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.136.1-136.1
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• 2015

In the present study, UHF (320 MHz) in combination with RF (13.56 MHz) plasmas was used for the synthesis of hydrogenated silicon nitride (SiNx:H) films by PECVD process at low temperature. RF/UHF hybrid plasmas were maintained at a fixed pressure of 410 mTorr in the N2/SiH4 and N2/SiH4/NH3 atmospheres. To investigate the radical generation and plasma formation and their control for the growth of the film, plasma diagnostic tools like vacuum ultraviolet absorption spectroscopy (VUVAS), optical emission spectroscopy (OES), and RF compensated Langmuir probe (LP) were utilized. Utilization of RF/UHF hybrid plasmas enables very high plasma densities ~ 1011 cm-3 with low electron temperature. Measurements using VUVAS reveal the UHF source is quite effective in the dissociation of the N2 gas to generate more active atomic N. It results in the enhancement of the Si-N bond concentration in the film. Consequently, the deposition rate has been significantly improved up to 2nm/s for the high rate synthesis of highly transparent (up to 90 %) SiNx:H film. The films properties such as optical transmittance and chemical composition are investigated using different analysis tools.