• Elastomers and Composites
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• v.41 no.2
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• pp.97-107
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• 2006

The recycled polyethylene composites with various ratio of ground waste tire powder were manufactured by using a fully intermeshing co-rotating twin screw extruder for the reuse of waste tire scrap. In this investigation, the ground waste tire powders (GWTP) were blended with virgin HDPE and recycled polyethylene in the weight ratio of 0 to 50 wt.%. Mechanical properties such as tensile strength, elongation at break and impact strength were measured by using ASTM standard. The experimental results for the various composite showed that the tensile strength of composites decreased with increasing GWTP ratio, while elongation at break increased with the amounts of GWTP. On the other hand, the impact strength for the three kinds of composites showed maximum at the 30 wt.% of GWTP and then decreased. Morphology of the fracture surface tends to be rough with increasing waste tire powder content. Rheological properties were investigated by measuring the shear viscosity against shear rates and softening temperatures. They showed that melt viscosity of rubber composites in this study subsequently increased with increasing GWTP content as a result of increase of flow resistance against external stress and followed a Power-law behavior.

• Elastomers and Composites
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• v.52 no.4
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• pp.237-241
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• 2017

The tensile strength (TS) and elongation-at-break (EB) loss of a CR/CB rubber composite sample prepared for the automotive parts were measured after accelerated thermal ageing at temperatures of 100, 120, 140, and $150^{\circ}C$. The change in TS was observed to be linear from the master curve prepared using the time-temperature superposition-principle (TTSP). An Arrhenius type of shift factor, $a_T$ was used to predict the life time of the sample, and a plot of ln $a_T$ vs. 1/T was also shown to be linear. The activation energy ($E_a$) of the sample was calculated as 70.30 kJ/mole from the Arrhenius plot. The expected life time of the sample was predicted at the given operating conditions by applying Arrhenius analysis. Assuming the $E_a$ value was constant at lower operating condition, life time of the sample was calculated as 2.3 years when the life limit was set as time to reach the 20% decrease of the initial TS value at operating temperature of $40^{\circ}C$.

• Journal of the Korean Wood Science and Technology
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• v.34 no.2
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• pp.10-21
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• 2006

Recycled polypropylene (RPP) - Wood Saw Dust (WSD) composites with and without acetylation of filler were produced at different filler loading (15%, 25%, 35% and 45% w/w) and filler size (300, 212 and $100{\mu}m$). The RPP-WSD was compounded using a Haake Rheodrive 500 twin screw compounder at $190^{\circ}C$ at 8 MPa for 30 minutes. The mechanical properties and water absorption properties of modified and unmodified WSD-PP composites were investigated. Acetylation of WSD improved the mechanical and water absorption characteristic of composites. The decrease of filler size (300 to $100{\mu}m$) of the unmodified and acetylated WSD showed increase of tensile strength and impact properties. The composites exhibited higher tensile modulus properties as the filler loading increased (15% to 45%). However tensile strength, elongation at break and impact strength showed the opposite phenomenon. Water absorption increased as the mesh number and filler loading increased. With acetylation, lower moisture absorption was observed as compared to unmodified WSD. The failure mechanism from impact fracture of the filler-matrix interface with and without acetylation was analyzed using Scanning Electron Microscope (SEM).

• Journal of Sericultural and Entomological Science
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• v.37 no.1
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• pp.33-38
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• 1995

The mechanical properties and structure of degummed silk fiber stretched after being treated with 8M LiBr aqueous solution were investigated. The mechanical properties of degummed silk fiber were depended upon the treatment temperature of 8M LiBr aqueous solution. That is, the strength and elongation had a tendancy to increase with the temperature, whereas the Young's modulus tended to decrease. The X-ray diffraction pattern showed that the crystalline orientation was disordered by 8$0^{\circ}C$ treatment neverthless destruction of the crystallites did not occur. rho silk fiber could be successfully stretched up 160% under the condition of 8M LiBr aqueous solution at 80 * after immersed for 1hr. For the highly stretched sample(160%), the tensile strength and Young's modulus were significantly improved in spite of lower elongation at break. According to the examination of X-ray diffraction pattern and SEM, the orientation tends to be occured more and more with stretching ratio. From the DSC thermograms, it shows that the thermal decomposition behavior was different between untreated and treated specimen with 8M LiBr aqueous solution. The maximun endothermic peak of thermal decomposition tends to increase to high temperature with the increase of stretching ratio.

• Nuclear Engineering and Technology
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• v.43 no.3
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• pp.279-286
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• 2011

The aging degradation and lifetime assessment of a domestic class 1E Ethylene-Propylene-Diene-Monomer (EPDM), which is a popular insulating elastomer for electrical cables in the nuclear power plants, were studied for equipment qualification verification under the Loss of Coolant Accident (LOCA) conditions. The specimens were acceleratively aged, underwent a LOCA environment, as well as tested mechanically, thermo-gravimetrically, and spectroscopically according to the American Society of the Testing of Materials (ASTM) procedures. The tensile test results revealed that the elongation at break gradually decreased with an increasing aging temperature. The lifetime of EPDM aged isothermally at $140^{\circ}C$ was 1,316 hours and reduced to 1,120 hours after experiencing the severe accident test. The activation energies of the elongation reduction were $1.10{\pm}0.196$ eV and $0.93{\pm}0.191$ eV before and after the LOCA condition, respectively. The TGA test results also showed that the activation energy of the aging decomposition decreased from 1.35 eV to 1.02 eV after undergoing the LOCA environment. Although the mechanical property changes were discernibly observed during the aging process, along with the LOCA simulation, the FT-IR analysis showed that the spectroscopic peaks and their intensities did not alter significantly. Therefore, it can be concluded that the degradation of the domestic class 1E EPDM due to aging can be tolerable, even in severe accident conditions such as LOCA, and thus it qualifies as a suitable insulating material for electrical cables in the nuclear power plants.

• Polymer(Korea)
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• v.35 no.4
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• pp.342-349
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• 2011

The effect of the amount of vinyltriethoxysilane (VTEOS) in precipitated silica filled silicone rubbers was extensively investigated in terms of the change of mechanical properties, heat resistance, oil resistance, compression set, resilience, and curing characteristics. As the content of VTEOS increased from 0 to 2.0 phr, the hardness of the silicone rubber increased, however, tensile strength, elongation at break, and tear strength decreased. From heat resistance test, the change of mechanical properties was pronounced for silicone rubber treated with more VTOES. The best heat resistance was achieved at 2.0 phr VTOES. In addition, oil resistance was proportionally improved with VTEOS content. From oil resistance test. it was found that the decrease in hardness and maximum elongation was reduced for VTEOS-added systems. Finally, resilience, compression set, degree of cure and crosslink density were significantly enhanced with the amount of VTEOS.

• Journal of Korean Association for Spatial Structures
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• v.9 no.2
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• pp.77-82
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• 2009

ETFE is the abbreviation of Ethlene Tetra Fluoro Ethlene, a sort of colorless and transparent granules. The advantage of ETFE film has chemical resistance, anti-stick property, very lightly material. The thickness of ETFE film is used to from 50 ${\mu}m$ to 300 ${\mu}m$ and have superior ability of daylight transmission and elongation, while the strength is lower than of fabric membrane. The tensile strength of ETFE film changes from 40Mpa to 60Mpa and the tensile strain at break can get to about 300-400%. The mechanical characteristic test of ETFE film is described in this paper. The tensile strain at break, the tensile strength and the stress-strain curve are obtained from the test. And then it was analyzed stress-strain characteristic by temperature and mechanical characteristic by cycling load.

• Elastomers and Composites
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• v.35 no.3
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• pp.173-179
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• 2000

Cure characteristics. tensile properties, and dynamic properties were investigated on the carbon black-filled natural rubber compounds, in which three typical vulcanization types conventional vulcanization(Conv), semi-efficient(Semi-EV), and efficient(EV) vulcanizations were used. The effects of vulcanization temperature on both the mechanical property and aging resistance of rubber compounds were also investigated. The Conv cure system showed a slightly slower rate of vulcanization than those of Semi-EV and EV ones. On the other hand, it showed a higher value in the maximum torque of cure curve. Higher tensile moduli were observed in Conv system than those in Semi-EV and EV ones, while lower elongation at break were obtained in Conv one. The tensile strength at break were found to be about the same for three cute systems. Hardness, modulus, and tensile strength decreased with increasing the vulcanization temperature, and the degree of changes in the properties was found to be smaller for EV and Semi-EV systems than that in Conv one. The EV system was found to be superior in thermal-aging resistance to Conv one.

• Textile Coloration and Finishing
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• v.30 no.2
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• pp.117-129
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• 2018

Cellulose has been widely applied into various medical fields including scaffolding, tissue engineering and tissue formation. In this study, we manufactured cellulose medical fiber from Styela clava tunics(SCT-CS) and analyzed the tensile strength, elongation at break, fluid uptake and surface morphology. And then, the biocompatibility and toxicity of SCT-CS were measured in Sprague-Dawley(SD) rats after the implantation for 30, 60 and 90 days. The level of tensile strength and fluid uptake were lower in SCT-CS than chromic catgut(CCG), while elongation at break level were maintained the higher in SCT-CS. Also, the roughness with pronounced surface patterns as a result of in vivo degradation was significantly greater in CCG than this of SCT-CS although these levels gradually appeared with time in both groups. After implantation for 90 days, SCT-CS and CCG was successfully implanted around muscle of thigh without any significant immune response. Furthermore, no significant alterations were measured in serum parameters and the specific pathological features induced by most toxic compounds for liver and kidney toxicity. Therefore, these results suggest that SCT-CS showing good biocompatibility and non-toxicity can be successfully prepared from cellulose powder of SCT as well as has the potential for use as a powerful biomaterial for medical sutures.

• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.161-167
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• 2008

Multi-walled carbon nanotubes (MWCNT)-reinforced poly(ethylene-co-ethyl acrylate) (EEA) nanocomposites were prepared by both melt and solution mixing methods. The mechanical, thermal, and electrical properties were investigated as a function of type and loading of CNT. The tensile strength and modulus increased, while elongation at break decreased with increasing MWCNT content. The hollow-type MWCNT showed an improved tensile strength and elongation at break compared with a conventional MWCNT. The thermal degradation temperature was increased by around $40^{\circ}C$ with increasing the amount of MWCNT. The melt-mixed composites showed the highest volume resistivity. In the case of solution-mixed composites, the conventional MWCNT was estimated to show much lower volume resistivity than that of hollow MWCNT. The number and length of extruded CNT onto the fractured surface increased by both increasing the content of CNT and employing the tensile strain to the sample. The melt-mixed specimens showed much smaller number and shorter length of extruded CNT.