• Title/Summary/Keyword: Elevated temperatures

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Combined effect of mineral admixture and curing temperature on mechanical behavior and porosity of SCC

  • Djamila, Boukhelkhal;Othmane, Boukendakdji;Said, Kenai;El-Hadj, Kadri
    • Advances in concrete construction
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    • v.6 no.1
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    • pp.69-85
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    • 2018
  • In order to provide sufficient stability and resistance against bleeding and segregation during transportation and placing, mineral admixtures are often used in self-compacting concrete mixes (SCC). These fine materials also contribute to reducing the construction cost and the consumption of natural resources. Many studies have confirmed the benefits of these mineral admixtures on properties of SCC in standard curing conditions. However, there are few published reports regarding their effects at elevated curing temperatures. The main objective of this study is to investigate the effect of three different mineral admixtures namely limestone powder (LP), granulated blast furnace slag (GS) and natural pozzolana (PZ) on mechanical properties and porosity of SCC when exposed to different curing temperatures (20, 40, 60 and $80^{\circ}C$). The level of substitution of cement by mineral admixture was fixed at 15%. The results showed that increasing curing temperature causes an improvement in performance at an early age without penalizing its long-term properties. However the temperature of $40^{\circ}C$ is considered the optimal curing temperature to make economical and high performance SCC. On the other hand, GS is the most suitable mineral admixture for SCC under elevated curing temperature.

Elevared Temperature Mechanical Properties of Mechanically Alloyed Al-4Mg Alloys (기계적합금화로 제조된 Al-4Mg기 합금의 고온 기계적성질)

  • Lee, Yong Gak;Jeon, Chae Hong;Kwun, S.I.;Yeon, Yun Mo
    • Journal of the Korean Society for Heat Treatment
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    • v.11 no.3
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    • pp.168-176
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    • 1998
  • The mechanical properties of mechanically alloyed Al-4wt%Mg alloys dispersed with $MgAl_2O_4$ dispersoilds at room and elevated temperatures were investigated. The powders in steady state during mechanical alloying consisted of Mg-supersatu rated Al solid solution and $Al_4C_3$ which resulted from the reaction of Al with C in process control agent (methanol). The hot-extruded materials consisted of uniformly dispersed fine $MgAl_2O_4$, ${\gamma}-Al_2O_3$, $Al_2O_3$ and matrix with extremly fine substructure. Tensile specimens prepared from the extruded bars were tested at room temperature to $400^{\circ}C$ under different strain rates. The tensile strength of alloys at room temperature ranged from 500 to 594MPa. At elevated temperatures, the tensile strengths and elongations decreased with increasing temperature. Adding 3% $MgAl_2O_4$ to Al-4wt%Mg increased the tensile strength of 50MPa at rowan temperature and 20MPa at $400^{\circ}C$.

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Microstructures and Grain Stabilities of Mg-Zn-(Zr) Alloys (Mg-Zn-(Zr) 합금의 미세조직과 결정립의 안정성)

  • Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.23 no.6
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    • pp.309-314
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    • 2010
  • Microstructures and grain growth behaviors at elevated temperatures have been investigated for extruded Mg-2%Zn and Mg-2%Zn-0.3%Zr alloys, in order to clarify the role of Zr in grain stability of Mg-Zn alloy. The grain size of Zr-free alloy increased continuously with an increase in annealing temperature, when isochronally annealed for 60 min from 573 to 723K, while the grains of the Zr-containing alloy were relatively stable up to 723 K. The activation energies for grain growth ($E_g$) between 573 and 723 K were calculated as 77.8 and 118.6 kJ/mole for the Mg-2%Zn and Mg-2%Zn-0.3%Zr alloys, respectively, which indicates that grains in the Zr-added alloy possess higher thermal stabilities at elevated temperatures. TEM observations on the annealed Mg-2%Zn and Mg-2%Zn-0.3%Zr alloys revealed that enhanced grain stability resulting from Zr addition into Mg-Zn alloy would be ascribed to the restriction of grain growth by stable Zn-Zr nano-precipitates distributed in the microstructure.

Geomechanical study of well stability in high-pressure, high-temperature conditions

  • Moradi, Seyyed Shahab Tabatabaee;Nikolaev, Nikolay I.;Chudinova, Inna V.;Martel, Aleksander S.
    • Geomechanics and Engineering
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    • v.16 no.3
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    • pp.331-339
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    • 2018
  • Worldwide growth in hydrocarbon and energy demand is driving the oil and gas companies to drill more wells in complex situations such as areas with high-pressure, high-temperature conditions. As a result, in recent years the number of wells in these conditions have been increased significantly. Wellbore instability is one of the main issues during the drilling operation especially for directional and horizontal wells. Many researchers have studied the wellbore stability in complex situations and developed mathematical models to mitigate the instability problems before drilling operation. In this work, a fully coupled thermoporoelastic model is developed to study the well stability in high-pressure, high-temperature conditions. The results show that the performance of the model is highly dependent on the truly evaluated rock mechanical properties. It is noted that the rock mechanical properties should be evaluated at elevated pressures and temperatures. However, in many works, this is skipped and the mechanical properties, which are evaluated at room conditions, are entered into the model. Therefore, an accurate stability analysis of high-pressure, high-temperature wells is achieved by measuring the rock mechanical properties at elevated pressures and temperatures, as the difference between the model outputs is significant.

The Effect of Pd addition on Mechanical Properties at High Temperature of Mg-4Al-2Sn Alloy (Mg-4Al-2Sn 합금의 고온 기계적 특성에 미치는 Pd첨가의 영향)

  • Yim, Si-On;Kang, Byoung-Soo;Cho, Dae-Hyun;Park, Ik-Min
    • Journal of Korea Foundry Society
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    • v.37 no.4
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    • pp.101-107
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    • 2017
  • This study investigated the effect of Pd on the microstructure, tensile and creep properties of Mg-4Al-2Sn (AT42) alloy at a high temperature for transportation-related industrial applications. AT42-xPd (x = 0, 1 and 2 wt. %) alloys were prepared using a permanent mould casting method. The microstructures of the as-cast alloys were characterized by the presence of the intermetallic phases $Mg_{17}Al_{12}$, $Mg_2Sn$ and $Al_4Pd$. The addition of Pd was found to improve the tensile properties of AT42 at room and at elevated temperatures, and to increase the creep resistance at elevated temperatures. A small amount of Pd could markedly improve the tensile properties of AT42 by means of grain-refinement and the dispersion of secondary phase strengthening. Moreover, the thermally stable phase $Al_4Pd$ effectively improves the creep resistance of AT42 due to the strengthened grain boundaries and the suppressed formation of $Mg_{17}Al_{12}$.

FRP Confinement of Heat-Damaged Circular RC Columns

  • Al-Nimry, Hanan Suliman;Ghanem, Aseel Mohammad
    • International Journal of Concrete Structures and Materials
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    • v.11 no.1
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    • pp.115-133
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    • 2017
  • To investigate the effectiveness of using fiber reinforced polymer (FRP) sheets in confining heat-damaged columns, 15 circular RC column specimens were tested under axial compression. The effects of heating duration, stiffness and thickness of the FRP wrapping sheets were examined. Two specimen groups, six each, were subjected to elevated temperatures of $500^{\circ}C$ for 2 and 3 h, respectively. Eight of the heat-damaged specimens were wrapped with unidirectional carbon and glass FRP sheets. Test results confirmed that elevated temperatures adversely affect the axial load resistance and stiffness of the columns while increasing their ductility and toughness. Full wrapping with FRP sheets increased the axial load capacity and toughness of the damaged columns. A single layer of the carbon sheets managed to restore the original axial resistance of the columns heated for 2 h yet, two layers were needed to restore the axial resistance of columns heated for 3 h. Glass FRP sheets were found to be less effective; using two layers of glass sheets managed to restore the axial load carrying capacity of columns heated for 2 h only. Confining the heat-damaged columns with FRP circumferential wraps failed in recovering the original axial stiffness of the columns. Test results confirmed that FRP-confining models adopted by international design guidelines should address the increased confinement efficiency in heat-damaged circular RC columns.

High Temperature Fiber Fragmentation Characteristics of SiC Single-Fiber Composite With Titanium Matrices

  • Matikas, Theodore E.
    • Advanced Composite Materials
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    • v.17 no.1
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    • pp.75-87
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    • 2008
  • Aerospace structural applications, along with high performance marine and automotive applications, require high-strength efficiency, which can be achieved using metal matrix composites (MMCs). Rotating components, such as jet-engine blades and gas turbine parts, require materials that maximize strength efficiency and metallurgical stability at elevated temperatures. Titanium matrix composites (TMCs) are well suited in such applications, since they offer an enhanced resistance to temperature effects as well as corrosion resistance, in addition to optimum strength efficiency. The overall behavior of the composite system largly depends on the properties of the interface between fiber and matrix. Characterization of the fiber.matrix interface at operating temperatures is therefore essential for the developemt of these materials. The fiber fragmentation test shows good reproducibility of results in determining interface properties. This paper deals with the evaluation of fiber fragmentation characteristics in TMCs at elevated temperature and the results are compared with tests at ambient temperature. It was observed that tensile testing at $650^{\circ}C$ of single-fiber TMCs led to limited fiber fragmentation behavior. This indicates that the load transfer from the matrix to the fiber occurs due to interfacial friction, arising predominantly from mechanical clamping of the fiber by radial compressive residual and Poisson stresses. The present work also demonstrates that composite processing conditions can significantly affect the nature of the fiber.matrix interface and the resulting fragmentation of the fiber.

Fabrication of Soda Borosilicate Class-Coated Electrostatic Chucks (소다붕규산염유리 도포형 정전척의 제조)

  • 방재철
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.1
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    • pp.49-52
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    • 2002
  • This study demonstrated the feasibility of tape casting method to fabricate soda borosilicate glass-coated stainless steel electrostatic chucks(ESC) for low temperature semiconductor processes. Glass coating on the stainless steel substrate was 125 $\mu\textrm{m}$ thick. The adhesion of glass coating was found to be excellent such that it was able to withstand temperature cycling to over $300^{\circ}C$ without cracking and delamination. The electrostatic clamping pressure generally followed the theoretical voltage-squared curve except at elevated temperatures and high applied voltages. The deviations at elevated temperatures and high applied voltages are due to increased leakage current as the electrical resistivity of glass coating drops.

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Volatilization and Toxicity Control of Heavy Metal Chlorides under Combustion Conditions (연소조건에서 중금속 염화물의 휘발 및 유독성 제어)

  • 서용칠
    • Journal of the Korean Society of Safety
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    • v.8 no.4
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    • pp.175-182
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    • 1993
  • Volatilization of toxic heavy metals, especially, metal chlorides at elevated temperatures in oxidation conditions was observed using a thermogravimetric furnace since such metal chlorides used to be a cause for the disease of industrial workers by their toxicity and high volatile extent. Most of tested metal chloride compounds were evaporated or decomposed into gas phase at elevated temperatures ranged from 200~90$0^{\circ}C$, while CrCl$_3$ and NiC1$_2$became stable with converting into oxide forms. A kinetic model for evaporation/condensation could predict maximum evaporation flux and the calculated values were compared with real evaporation flux. The ratio of two fluxes could be explained as the fraction of impinging gas molecules to the condensing surface( $\alpha$ ) and obtained in the range of 10$^{-3}$ ~10$^{-9}$ for the experimented toxic heavy metal chlorides. This ratio might be used to define the volatile extent or toxicity of such toxic metal compounds. The schemes to avoid volatilization of toxic heavy metals Into the atmosphere were suggested as follows ; 1 ) controlling the compositions of metals and Chlorine produced substances( such as PVC ) in the treated materials using a reverse estimation from regulatory limit and characteristics of a processing facility, 2) Installation of wet type devices such as a scrubber for condensing the metal compounds.

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Dynamics of Hydrogen on Si (100)

  • Boland, John J.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.25-25
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    • 2000
  • In this talk we discuss the dynamics of hydrogen on the Si(100)-2xl surface. At room temperature the sticking coefficient for molecular hydrogen on this surface is less than 10sup-12. However, hydrogen molecules desorbing from the surface do not have an excess of energy, suggesting at best a small barrier on the exit channel. These observations have led to speculation about the validity of detailed balance in this system. Here we show that this discrepancy can be explained by considering both the surface-molecule co-ordinate and that associated with the Si-Si dimer bond tiltangle. By preparing the surface dimers with a specific tiltangle we demonstrate that the barrier to adsorption is a function of this angle and that the sticking coefficient dramatically increase for certain angles. The adsorption-desopption dynamics can then be described in terms of a common potential energy hypersurface involving both of these co-ordinates. The implications of these observations are also discussed. The dynamics of adsorbed hydrogen atoms on the Si(100) surface is also described. Paired dangling bonds produced following recombinative hydrogen desorption are mobile at elevated temperatures. Pairs of dangling bonds are observed to dissociate, diffuse, and ultimately recombine. At sufficiently elevated temperatures dangling bond exchange reactions are observed. These data are analyzed in terms of an attractive zone and an effective binding interaction between dangling bonds. Insights that this provides into the nature of surface defects and the localized chemistry that occurs on this surface, are also discussed.

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