• Nuclear Engineering and Technology
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• v.52 no.10
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• pp.2394-2401
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• 2020

Octadecylamine is an effective film-forming amine that protects carbon steel from corrosion. In the present study, the effect of octadecylamine concentration on adsorption on a carbon steel surface was investigated in anaerobic alkaline solution by using SEM/EDS, TEM and the Materials Studio simulation techniques. TEM morphology observation and EDS elemental detection determine the thicknesses of octadecylamine film on a carbon steel surface, which are confirmed by the in-situ electrochemical impedance spectroscopy measurement and resistance calculation. The Materials Studio simulation reveals the number of octadecylamine film layers at different concentrations. Results obtained in this study indicate that adsorption of octadecylamine film on carbon steel proceeds with the multi-layer adsorption mechanism.

• Applied Chemistry for Engineering
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• v.33 no.3
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• pp.322-327
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• 2022

Fucoidans were degraded by hydrogen peroxide under the electron beam (2.5 MeV) with various radiation doses (5 kGy, 10 kGy, 15 kGy, and 20 kGy) at room temperature. The degradation property was analyzed with a gel permeation chromatography (GPC-MALLS) method. An average molecular weight of fucoidan decreased from 99,956 at the irradiation dose of 0 kGy to 6,725 at the irradiation dose of 20 kGy. The solution viscosity of fucoidans showed a similar pattern to the molecular weight change. The number of chain breaks per molecule (N) increased with increasing the irradiation dose and concentration of hydrogen peroxide. The radiation yield of scission value markedly increased with increasing the irradiation dose up to 15 kGy. Also a 10% hydrogen peroxide concentration was more efficient than that of 5%. The structures of degraded fucoidan samples were studied with Fourier transform infrared spectroscopy (FT-IR). The results showed that the degradation process did not significantly change the chemical structure or the content of sulfate group. The sulfur content of each sample was determined with an Elemental Analyzer. With increasing the concentration of hydrogen peroxide, the ratios of sulfur/carbon, hydrogen/carbon, and nitrogen/carbon slightly decreased. The antioxidant activities of fucoidans were investigated based on hydroxyl radical scavenging activities. The ability of fucoidan to inhibit the hydroxyl radical scavenging activity was depended on its molecular weight.

• Journal of Powder Materials
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• v.31 no.1
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• pp.1-7
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• 2024

This study explores the profound impact of varying oxygen content on microstructural and mechanical properties in specimens HO and LO. The higher oxygen concentration in specimen HO is found to significantly influence alpha lath sizes, resulting in a size of 0.5-1 ㎛, contrasting with the 1-1.5 ㎛ size observed in specimen LO. Pore fraction, governed by oxygen concentration, is high in specimen HO, registering a value of 0.11%, whereas specimen LO exhibits a lower pore fraction (0.02%). Varied pore types in each specimen further underscore the role of oxygen concentration in shaping microstructural morphology. Despite these microstructural variations, the average hardness remains consistent at ~370 HV. This study emphasizes the pivotal role of oxygen content in influencing microstructural features, contributing to a comprehensive understanding of the intricate interplay between elemental composition and material properties.

• Clean Technology
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• v.28 no.1
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• pp.38-45
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• 2022

CuCl₂-loaded V₂O₅-WO₃/TiO₂ catalyst showed excellent activity in the catalytic oxidation of elemental mercury to oxidized mercury even under SCR condition in the presence of NH₃, which is well known to significantly inhibit the oxidation activity of elemental mercury by HCl. Moreover, it was confirmed that, when SO₂ was present in the reaction gas together with HCl, excellent elemental mercury oxidation activity was maintained even though CuCl₂ supported on the catalyst surface was converted to CuSO₄. This is thought to be because not only HCl but also the SO₄ component generated on the catalyst surface promotes the oxidation of elemental mercury. However, in the presence of SO₂, the total mercury balance before and after the catalytic reaction was not matched, especially as the concentration of SO₂ increased. In order to understand the cause of this, further studies are needed to investigate the effect of SO₂ in the SnCl₂ aqueous solution employed for mercury species analysis and the effect of sulfate ions generated on elemental mercury oxidation. It was confirmed that SO₂ also promotes NO_x removal activity, which is thought to be because the increase in acid sites by SO₄ generated on the catalyst surface by SO₂ facilitates NH₃ adsorption. The composition change and structure of the components present on the catalyst surface under various reaction conditions were measured by XRD and XRF. These measurement results were presented as a rational explanation for the results that SO₂ enhances the oxidation activity of elemental mercury and the NO_x removal activity in this catalyst system.

• Journal of Korean society of Dental Hygiene
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• v.12 no.2
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• pp.431-438
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• 2012

Objectives : The aim of this study was assessment of the variation of urinary mercury concentrations after removal of amalgam fillings in children. Methods : 10 elemental school children with amalgam filling tooth surfaces were took part in this study. One dentist recorded the number of amalgam filling surface, and general characteristics of subjects were surveyed by questionnaire. Each urine samples were collected before, immediately after and after 24 hours amalgam removal. The statistical analysis was performed using the SPSS 18.0. Results : The mean concentration urinary mercury immediately after amalgam removal was higher ($5.70{\pm}1.20{\mu}g/g$ creatinine) than before amalgam removal ($5.28{\pm}1.53{\mu}g/g$ creatinine). The mean concentration urinary mercury level whose have 1-10 amalgam removal surfaces was increased after amalgam removal compared with before. Conclusions : Mercury concentration in urine was influenced by amalgam removal.

• Journal of Forest and Environmental Science
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• v.34 no.1
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• pp.53-56
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• 2018

Elemental carbon (EC) and organic carbon (OC) mass concentrations in PM2.5 were measured from March through October 2015 in Taehwa Research Forest (TRF). The concentration of carbon in the TRF was $3.4{\mu}g/m^3$ and the concentration of EC was $1.4{\mu}g/m^3$. Also the concentration of $OC_{sec}$ was the highest at $2.84{\mu}g/m^3$ in the summer and the lowest at 1.66 in the spring. The ratio of the secondary generation OC in the total OC was the highest at 62% in the summer. Monthly OC concentration was the lowest at $2.38{\mu}g/m^3$ in April and the highest at $6.60{\mu}g/m^3$ in July. In case of EC concentration was the lowest in April ($0.98{\mu}g/m^3$) and the highest in July ($3.41{\mu}g/m^3$). The OC/EC ratio showed the lowest ratio in March and the highest rate in September. It is suggested that the secondary generation reaction of OC component was active due to sufficient irradiation amount in summer.

• Atmosphere
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• v.21 no.3
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• pp.301-309
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• 2011

In this study, we compared light-absorption properties of aerosols observed in East and South Asia from black carbon (BC) mass concentration, aerosol scattering (${\sigma}_s$) and absorption (${\sigma}_a$) coefficients measurements at four sites: Korea Climate Observatory-Gosan (KCO-G), Korea Climate Observatory-Anmyeon (KCO-A), Maldives Climate Observatory-Hanimaadhoo (MCO-H) and Nepal Climate Observatory-Pyramid (NCO-P). No significant seasonal variations of BC mass concentration, ${\sigma}_s$ and ${\sigma}_a$, despite of wet removal of aerosols by precipitation in summer, were observed in East Asia, whereas dramatic changes of light-absorbing aerosol properties were observed in South Asia between dry and wet monsoon periods. Although BC mass concentration in East Asia is generally higher than that observed in South Asia, BC mass concentration at MCO-H during winter dry monsoon is similar to that of East Asia. The observed solar absorption efficiency (${\alpha}$) at 550 nm, where ${\alpha}={\sigma}_a/({\sigma}_s+{\sigma}_a)$, at KCO-G and KCO-A is higher than that in MCO-H due to large portions of BC emission from fossil fuel combustion. Interestingly, ${\alpha}$ at NCO-P is 0.14, which is two times great than that in MCO-H and is about 40% higher than that in East Asia, though BC mass concentration at NCO-P is the lowest among four sites. Consistently, the highest elemental carbon to sulphate ratio is found at NCO-P.

• Analytical Science and Technology
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• v.15 no.6
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• pp.509-513
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• 2002

In this study, instrumental neutron activation analysis was used to assess the concentration level of inorganic trace elements in Korean women blood serum. It was found out that high concentration of Na and Cl incurs analytical interference, but 12 elements of Br, Ca, Cl, Co, Cr, Cs, Fe, K, Na, Rb, Se, Zn can be determined under the condition of interference minimization. Serum samples collected from 63 women were analyzed and the concentration level and range of the elements were evaluated. NIST SRMs were analyzed simultaneously for analytical quality control. The average values of Na and Cl determined in serum samples are around 3000 mg/L, Ca is 100 mg/L and K is 200 mg/L. Besides, Br, Se and Zn have concentration level of 6.0, 0.1 and 1.0 mg/L, respectively. It was found that there is no significant difference between the present values and reported values.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.E2
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• pp.78-88
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• 2006

In order to study the characteristics of cloud, a real-scale experiment for cloud generation was carried out using an extinct vertical mine (430 m height) located in the northeastern Honshu, Japan. The dry particles generated from the three-step concentrations of NaCl solutions were used for cloud generation. The number size distributions of initial dry particles and cloud droplets were monitored by Scanning Mobility Particle Sizer (SMPS) and Forward Scattering Spectrometer Probe (FSSP) at bottom and upper sites of pit, respectively. The polymeric water absorbent film (PWAF) method was employed to measure liquid water content ($W_L$) as a function of droplet size. Moreover the chemical properties of individual droplet replicas were determined by micro-PIXE. The CCN number concentration shows the lognormal form in dependence of the particle size, while the number size distributions of droplets are bimodal showing the peaks around $9{\mu}m$ and $20{\mu}m$ for every case. In comparison to background mineral particles, right shifting of size distribution line for NaCl particles was occurred. When NaCl solutions with three-step different concentrations were neulized, $W_L$ shows the strong droplet size dependence. It varied from $10.0mg\;m^{-3}$ up to $13.6mg\;m^{-3}$ with average $11.6mg\;m^{-3}$. A good relationship between $W_L$ and cloud droplet number concentration was obtained. Both chemical inhomogeneities (mixed components with mineral and C1) and homogeneities (only mineral components or C1) in individual droplet replicas were obviously observed from micro-PIXE elemental images.

• Bulletin of the Korean Chemical Society
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• v.31 no.2
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• pp.435-441
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• 2010

We report the preparation and characterization of a new and water soluble complex of palladium(II) with 1,10- phenanthroline and butyldithiocarbamate ligands. This compound has been studied through spectroscopic techniques, $^1H$ NMR, IR, electronic spectra and elemental analysis and conductivity measurements. The complex shows 50% cytotoxic concentration ($Ic_{50}$) value against chronic myelogenous leukemia cell line, K562, much lower than that of cisplatin. Thus the mode of binding of this complex to calf thymus DNA have been extensively investigated by isothermal titration UV-visible spectrophotometry, fluorescence, gel filteration and other methods. UV-visible studies show that the complex exhibits cooperative binding with DNA and remarkably denatures the DNA at extremely low concentration ($~13\;{\mu}M$). Fluorescence studies indicate that the complex intercalate into DNA. Gel filtration studies suggest that the binding of Pd(II) complex with DNA is strong enough that it does not readily break. In these interaction studies, several thermodynamic and binding parameters are also determined which may reflect the mechanism of action of this type of compound with DNA.