• Title/Summary/Keyword: Elemental Distribution

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Estimation of Weight Distribution of Rockfall Block by Joint Measurement And Study on Its Application to Rockfall Simulation (절리조사결과에 의한 현장 낙석무게분포추정 및 추정결과의 낙석시뮬레이션 적용성 검토)

  • Kim, Dong-Hee;Ryu, Dong-Woo;Kim, Su-Chul;Yoon, Sang-Kil;Lee, Woo-Jin
    • Journal of the Korean Geotechnical Society
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    • v.23 no.11
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    • pp.67-76
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    • 2007
  • The characteristics of rockfall are determined by virtually all factors and conditions e.g. the physical figure of the slope such as inclination, height, roughness, the elemental figure of the slope such as vegetation and material deposited, and the shape and weight of the rockfall itself. Although it is one of the major factors to be considered in rockfall simulation, little attention has been given to the weight of the rockfall. And, since the size of the rockfall is dominated by joint spacing, the distribution of the rockfall block weight can be predicted as a function of the joint spacing. In this study, the weight distribution of rockfall was estimated by using the method of volumetric joint count, $J_{\nu}$, based on joint spacing, and $RQD-J_{\nu}$. The results indicate that the weight distributions were analogous in two methods, and the distribution was to be $75.3{\sim}76.7%$ for 200 kilograms or lesser, $15.0{\sim}16.6%$ for $200{\sim}400$ kilograms, and $6.7{\sim}9.7%$ for 400 kilograms or more, which show good matches with the actual on-site weight distribution. Therefore, the weight distribution of rockfall suggested in this paper is able to be considered as appropriate data for rockfall simulation.

Characterization of Humic and Fulvic Acids Extracted from Soils in Different Depth: Proton Exchange Capacity, Elemental Composition and 13C NMR Spectrum (깊이별 토양 휴믹산과 풀빅산의 특성 분석: 양성자교환용량, 원소성분비, 13C NMR 스펙트럼)

  • Shin, Hyun-Sang;Lee, Chang-Hoon;Rhee, Dong-Sock;Chung, Kun-Ho;Lee, Chang-Woo
    • Analytical Science and Technology
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    • v.16 no.4
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    • pp.283-291
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    • 2003
  • Humic and fulvic acids present in soils of different depth were extracted and their acidic functional groups and structural characteristics were analyzed and compared. The purpose of this study was to present a basic data needed to evaluate the effect of humic substances on depth distribution and migrational behaviour of radioactive elements deposited on soil. Acidic functional groups of the humic and fulvic acids were analyzed by pH titration method, and their proton exchange capacity (PEC, $mq\;g^{-1}$) and average $pK_a$ values were obtained. Structural characteristics of the humic and fulvic acids were analyzed using their CPMAS $^{13}C$ NMR spectra and elemental composition data. pH titration data showed that fulvic acids have higher acidic functional group contents ranging from 5.5 to $7.0meq\;g^{-1}$ compared with that of humic acids ($3.8{\sim}4.8meq\;g^{-1}$). From depth profiles, it has been found that PEC values of humic acids in deeper soil (> 8 cm) were higher than those at the surface soils. Elemental compositions (H/C ratio) and spectral features ($C_{arom}/C_{aliph}$ ratio) obtained from CPMAS $^{13}C$ NMR spectra showed that the aromatic character in humic acids was a relatively higher than that of fulvic acids, while lower in carboxyl carbon content. The aromatic character and carboxyl carbon contents of humic acids tend to increase as soil depth increased, but those of fulvic acid showed little differences by the soil depth range.

Cloud Generation Using a Huge Vertical Mine

  • Ma, Chang-Jin
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.E2
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    • pp.78-88
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    • 2006
  • In order to study the characteristics of cloud, a real-scale experiment for cloud generation was carried out using an extinct vertical mine (430 m height) located in the northeastern Honshu, Japan. The dry particles generated from the three-step concentrations of NaCl solutions were used for cloud generation. The number size distributions of initial dry particles and cloud droplets were monitored by Scanning Mobility Particle Sizer (SMPS) and Forward Scattering Spectrometer Probe (FSSP) at bottom and upper sites of pit, respectively. The polymeric water absorbent film (PWAF) method was employed to measure liquid water content ($W_L$) as a function of droplet size. Moreover the chemical properties of individual droplet replicas were determined by micro-PIXE. The CCN number concentration shows the lognormal form in dependence of the particle size, while the number size distributions of droplets are bimodal showing the peaks around $9{\mu}m$ and $20{\mu}m$ for every case. In comparison to background mineral particles, right shifting of size distribution line for NaCl particles was occurred. When NaCl solutions with three-step different concentrations were neulized, $W_L$ shows the strong droplet size dependence. It varied from $10.0mg\;m^{-3}$ up to $13.6mg\;m^{-3}$ with average $11.6mg\;m^{-3}$. A good relationship between $W_L$ and cloud droplet number concentration was obtained. Both chemical inhomogeneities (mixed components with mineral and C1) and homogeneities (only mineral components or C1) in individual droplet replicas were obviously observed from micro-PIXE elemental images.

Characteristics of Sulfides Distribution and Formation in the Sediments of Seonakdong River (서낙동강 퇴적물 내 황화물의 분포 및 생성 특성)

  • Park, Seong-Yeol;Hwang, Kyung-Yup;Lee, Nam Joo;Yoon, Young-Sam;Lee, Sang-Ho;Kim, Il-Kyu;Yu, Kwon Kyu;Hwang, Inseong
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.6
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    • pp.843-853
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    • 2009
  • The sediment samples were collected from Seonakdong River and were analyzed for sulfide species such Acid Volatile Sulfide(AVS) and Elemental Sulfur(ES) and Chromium Reducible Sulfide(CRS). Then characteristics of the formation of sulfide species were investigated for six selected samples. Finally the relationship between environmental factors and sulfate reducing rate(SRR) was investigated using two selected samples. Concentrations of AVS and CRS were relatively high, which suggests that organics input to the sediments has been continued until recently and that potential of heavy metals leaching from the sediments is low. SRR in the sediments was closely related to fraction of fine particles(silt+clay) and also to dissolved organic carbon content of the sediment(DOCsed). The dependences of environmental factors such as organic content, temperature, sulfate concentration on the SRR was relatively strong in the selected experiments conducted with the samples from Noksan gate and Daejeo gate samples. The environmental factor dependencies were stronger in the Noksan gate samples than in the Daejeo gate samples, which is probably due to higher surface area of the Noksan gate sediments.

Physical Property with the Manufacturing Conditions of Activated Carbon for Mercury Adsorption (제조조건에 따른 활성탄의 특성 및 수은 흡착 효율)

  • Min, Hyo-Ki;Ahmad, Tanveer;Park, Min;Lee, Sang-Sup
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.3
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    • pp.302-314
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    • 2015
  • There is an adsorption method using activated carbon as a typical method for removing elemental mercury. Physical characteristics of activated carbon such as specific surface area and volume of pore (micro and meso) have positive effect for mercury adsorption. Activated carbon is carbon-based material with a high specific surface area. This activated carbon can be manufactured through carbonization and activation process. In this process, physical characteristics of specific surface area and pore distribution are changed by controlling operating parameters like temperature, time and reagent of activation. In this study, we evaluated characteristics of activated carbons manufactured from pinewood and coal with the operating parameters. We evaluated mercury adsorption capacities of the activated carbons having excellent physical characteristics and compared those to the commercial activated carbon.

Chemical Constitution, Morphological Characteristics, and Biological Properties of ProRoot Mineral Trioxide Aggregate and Ortho Mineral Trioxide Aggregate

  • Kum, Kee Yeon;Yoo, Yeon Jee;Chang, Seok Woo
    • Journal of Korean Dental Science
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    • v.6 no.2
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    • pp.41-49
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    • 2013
  • Purpose: This study sought to compare the elemental constitution, morphological characteristics, particle size distribution, biocompatibility, and mineralization potential of Ortho MTA (OMTA) and ProRoot MTA (PMTA). Materials and Methods: OMTA and PMTA were compared using energy-dispersive spectrometry, particle size analysis, and scanning electron microscopy. The biocompatibility and mineralization-related gene expression (osteonectin and osteopontin) of both MTAs were also compared using methylthiazol tetrazolium assay and reverse transcription-polymerization chain reaction analysis, respectively. The results were analyzed by Kruskal-Wallis test with Bonferroni correction. P-value of <0.05 was considered significant. Result: The morphology of OMTA powders was similar to that of PMTA. The constituent elements of both MTAs were calcium, silicon, and aluminum. The mean particle sizes of OMTA and PMTA were 4.60 and 3.34 mm, respectively. Both MTAs had equally favorable in vitro biocompatibility and affected the messenger RNA expression of osteonectin and osteopontin. Conclusion: Within the limitations of this study, OMTA could be a promising biomaterial in clinical endodontics.

Decomposition of primary tar influenced by char particle types and reaction time during biomass gasification (바이오매스 가스화시 촤 입자 종류 및 반응시간에 따른 일차타르의 분해 특성)

  • Park, Jinje;Lee, Yongwoon;Ryu, Changkook
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.33-36
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    • 2014
  • Gasification of biomass produces syngas containing CO, $H_2$ and/or $CH_4$, which can then be converted into energy or value-added fuels. One of key issues for efficient gasification is to minimize tar concentration in the syngas for use in a final conversion device such as gas engine. This study investigated the decomposition of primary tar by catalytic cracking using char as catalyst, of which the feature can be integrated into a fixed bed gasifier design. The pyrolysis vapor containing tar from pyrolysis of wood at $500^{\circ}C$ was passed through a reactor filled with or without char at $800^{\circ}C$ for a residence time of 1, 3 or 5 sec. Then, the condensable vapor (water and tar) and gases were analyzed for the yields and elemental composition. Four types of char particles with different microscopic surface area and pore size distribution: wood, paddy straw, palm kernel shell and activated carbon. The results were analyzed for the mass and carbon yields of tar and the composition of product gases to conclude the effects of char types and residence time.

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Determination of Amino Acids on Wintertime PM2.5 using HPLC-FLD (HPLC-FLD를 이용한 겨울철 PM2.5 중 아미노산 성분 분석)

  • Park, Da-Jeong;Cho, In-Hwan;Bae, Min-Suk
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.5
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    • pp.482-492
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    • 2015
  • Ground-based measurements were conducted from January 6 to 12 of 2015 for understanding characteristics of nitrogen containing carbonaceous aerosols as 16 amino acids at the Mokpo National University, Korea. The detailed amino acid components such as Cystine ($(SCH_2CH(NH_2)CO_2H)_2$) and Methionine ($C_5H_{11}NO_2S$) and their sources were analyzed by High-Performance Liquid Chromatography with Fluorescence Detection (HPLC-FLD) for behavior of secondary products in particulate matter. In addition, organic carbon (OC) and elemental carbon (EC) based on the carbonaceous thermal distribution (CTD), which provides detailed carbon signature characteristics relative to analytical temperature, and water soluble organic carbon (WSOC) by total organic carbon (TOC) analyzer were used to understand the carbon compound behaviors. The backward trajectories were discussed for originations of carbonaceous aerosols as well. Different airmasses were classified with the amino acids and OC thermal signatures. The results can provide to understand the aging process influenced by the long-range transport from East Sea area.

Effects of Foreign Direct Investment and Human Capital on Labour Productivity: Evidence from Vietnam

  • LE, Nguyen Hoang;DUY, Luong Vinh Quoc;NGOC, Bui Hoang
    • The Journal of Asian Finance, Economics and Business
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    • v.6 no.3
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    • pp.123-130
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    • 2019
  • The paper aims to investigate whether foreign direct investment (FDI) has positive effect on the labour productivity in Vietnam. Labour productivity is the elemental determinant of a country's development level in long-term. In recent years, although increasing consistently, labour productivity of Vietnam remains low in comparison to other South East Asian countries. To identify the direction of effect and the level of effect of FDI and human capital on the labour productivity of Vietnam, Autoregressive Distributed Lag (ARDL) model was used to examine the effect of FDI and human capital on labour productivity in Vietnam from 1986 to 2014. The results of bounds test confirm the existence of cointegration among the variables. Further, the Toda and Yamamoto Granger causality test affirms that there is unidirectional causality running from foreign direct investment and human capital index to labour productivity. The empirical results provide strong statistical evidence that foreign direct investment and human capital has a positive impact on labour productivity in Vietnam in long-term. These findings imply that workers are expected to further improve their knowledge, skills and that policy-maker should establish concrete plans to increase human capital. Results from this study provide suggestion necessary for Vietnam to achieve sustainable development.

Characterization of Clay Minerals in Ranch Pasture

  • Kang, Sangjae;Jang, Jeonghun;Park, Nayun;Park, Junhong;Choi, Seyeong;Park, Man;Lee, Changhee;Lee, Donghoon;Zhang, Yongseon
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.1
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    • pp.53-59
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    • 2016
  • This study deals with the distribution of the clay minerals separated from clay fractions of ranch pastures in Korea and their chemical and mineralogical properties. Crystalline phases of the clay minerals were identified by powder X-ray diffraction (XRD) pattern and FT-IR spectra, and their relative chemical compositions were also analyzed by X-ray flourescence spectrometry (XRF). Primary minerals consisted mainly of quartz and mica and chlorite and kaolinite along with a trace of swelling micas were identified as secondary clay minerals. However, the relative content of these clay minerals was different with the locations, which led to significant effects on physical and chemical properties of soils like inorganic elemental composition. In particular, $SiO_2$ content was higher in Gochang ranch pasture than in other ranch pasture. Infrared (IR) spectra did not indicate any significant differences in organic functional groups among the locations. This study clearly showed that ranch pastures had different relative content of clay minerals and chemical properties depending on the location and consequently that those properties are worthy to be taken into account for soil amendment.