• 한국수소및신에너지학회논문집
• /
• 제33권3호
• /
• pp.202-208
• /
• 2022

Pt-Ni nanocatalysts were loaded on carbon black by spontaneous reduction reaction of platinum (II) acetylacetonate and nickel (II) acetylacetonate, and they were characterized by transmission electron microscopy (TEM), thermogravimetric analyzer (TGA), energy dispersive x-ray analyzer (EDS), BET surface area and fuel cell test station. The distribution of the Pt and Ni nanoparticles was observed by TEM, and the loading weight of Pt-Ni nanocatalysts on the carbon black was measured by TGA. The elemental ratio of Pt and Ni was estimated by EDS. It was found that the loading weight of Pt-Ni nanoparticles was 5.54 wt%, and the elemental ratio of Pt and Ni was 0.48:0.35. Specific surface area was measured by BET analysis instrument and I-V characteristics were estimated.

• 한국수소및신에너지학회논문집
• /
• 제33권6호
• /
• pp.715-722
• /
• 2022

Pt-Fe/carbon black nanocatalysts were prepared by spontaneous reduction reaction of Platinum(II) acetylacetonate and Iron(II) acetylacetonate in a nucleophilic solvent and they were characterized by scanning electron microscopy (SEM), energy dispersive X-ray analyzer (EDS), thermogravimetric analyzer (TGA), transmission electron microscopy (TEM), Brunauer, Emmett and Teller (BET) surface area analysis and anion exchange membrane (AEM) water electrolysis test station. The distribution of the Pt and Fe nanoparticles on carbon black was observed by TEM, and the loading weight of Pt-Fe nanocatalysts on the carbon black was measured by TGA. Elemental ratio of Fe:Pt was estimated by EDS and it was found that elemental ratio of Pt and Fe was changed in the range of 1:0 to 0:1, and the loading weight of Pt-Fe nanoparticles on the carbon black was 5.95-6.78 wt%. Specific surface area was greatly reduced because Pt-Fe nanocatalysts blocked the pores. I-V characteristics were estimated.

• 한국건설관리학회논문집
• /
• 제4권4호
• /
• pp.192-200
• /
• 2003

본 연구는 공공건설 공사에 실적자료에 의한 공사비산정 방법의 전산화 적용을 목적으로 먼저 실적공사비의 정의 및 구조와 현행 실적공사비 운영체계 이해를 통해 전산화의 문제점 및 개선기준을 공사비 산정방법 중심으로 분석 기술하였으며 제안한 기준에 따라 전산화 알고리즘을 제시하였다. 기존 예정공사비 산정방법은 일반적인 공종별 분류에 따른 실적자료조건과 단순히 물가지수, 연면적규모에 따른 시공단가를 적용함으로서 공사비산정의 정확성이 요구되며, 본 연구는 이에 대한 개선 안으로 부위와 부분별 공종분류 방식에 의한 데이터 추출조건으로 실적자료의 적용성과 신뢰성을 높였다. 또한 물량규모에 의한 공사비 변동요인을 물량규모 대비 단가의 확률적 회귀분석으로 예측 추정하여 실행 가능한 적정 공사비 산정방법을 제시하였다. 따라서 본 연구에서는 전산화 적용 방안으로 확률적 예정공사비산정방법을 기준으로 시스템 프로세스를 각 영역별로 구축하고 그에 따른 윈도우 어플리케이션 활용 툴과 개별 전산화에 대한 알고리즘을 구축하였다.

• 분석과학
• /
• 제16권3호
• /
• pp.232-239
• /
• 2003

청주시 석남천 유역의 4개 지점, 미호천 유역의 1개 지점, 석남천과 미호천 합류지역의 1개 지점 등 6개 지점을 기준지점으로 택하고, 각 지점의 상층, 중층, 하층에서 침전물을 채취하여 조사용 시료를 제작하였다. 한국원자력연구소의 연구용 원자로(HANARO)의 중성자 선을 이용한 중성자 방사화 분석법으로 원소함량을 분석하였다. 미국 표준연구원(NIST)의 인증표준물질을 이용하여 시료 중의 30 개 원소들의 함량을 비교법으로 분석하였다. 그 분석 결과로부터 하천오염원지역에서 하류로 이어지는 지역의 침전물 오염도분포조사 및 예측시 오염물질의 원소비중과 유속을 고려해야 하며 하천침전물의 함량분석을 위한 시료를 채취할 때 시료의 지역적 대표성을 확립하기 위해서는 원소의 비중과 유속 등을 고려하여 수직적 범위를 정할 필요가 있음을 알았다.

• 한국분말재료학회지
• /
• 제26권5호
• /
• pp.375-382
• /
• 2019

Homogeneous multicomponent indium gallium zinc oxide (IGZO) ceramics for transparent electrode targets are prepared from the oxides and nitrates as the source materials, and their properties are characterized. The selected compositions were $In_2O_3:Ga_2O_3:ZnO$ = 1:1:2, 1:1:6, and 1:1:12 in mole ratio based on oxide. As revealed by X-ray diffraction analysis, calcination of the selected oxide or nitrides at $1200^{\circ}C$ results in the formation of $InGaZnO_4$, $InGaZn_3O_6$, and $InGaZn_5O_8$ phases. The 1:1:2, 1:1:6, and 1:1:12 oxide samples pressed in the form of discs exhibit relative densities of 96.9, 93.2, and 84.1%, respectively, after sintering at $1450^{\circ}C$ for 12 h. The $InGaZn_3O_6$ ceramics prepared from the oxide or nitrate batches comprise large grains and exhibit homogeneous elemental distribution. Under optimized conditions, IGZO multicomponent ceramics with controlled phases, high densities, and homogeneous microstructures (grain and elemental distribution) are obtained.

• Journal of the Korean Wood Science and Technology
• /
• 제44권2호
• /
• pp.231-240
• /
• 2016

The change in chemical compositions of leachate and medium density fiberboard (MDF) from a laboratory-scale simulated landfill which constructed in a plastic container containing alternating layers of soil and MDF was investigated to evaluate decomposing of MDF in soil. Four treatments were conducted: 1) MDF in soil, 2) MDF only, 3) cured UF resin in soil, and 4) soil only. Molecular weight (MW) distribution of compounds in leachate from soil only treatment did not change over time. In UF resin in soil treatment, the MW distribution shifted to a lower MW distribution over time, while the peak shifted to the left indicated changing to higher MW distribution in leachate from treatment 1 and 2 contained MDF. Higher percent nitrogen in leachate was observed in MDF containing treatments due to the UF resin in the MDF. The percent carbon slightly increased in MDF only while that greatly decreased in MDF in soil treatment maybe due to bacterial activity. The percent of extractable materials from the MDF decreased greatly on day 35 compare to day 0, and subsequently did not change much on day 77. In contrast, percent holocellulose and lignin did not change much over time. No structural change of the wood fiber in MDF occurs during the study. Water-soluble materials from MDF in soil contributed the change in chemical composition of leachate.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 1993년도 추계학술대회 논문집
• /
• pp.218-223
• /
• 1993

An UBET(Upper Bound Elemental Technique) program has been developed to analyze forging load, die-cavity filling and effective strain distribution for flashless forging. To analyze the process easily, it is suggested that the deformation is divided into two different parts. Those are axisymmetric part in corner and plane-strain part in lateral. The total power consumption is minimized through combination of two deformation parts by building block method, from which the upper-bound forging load, the flow pattern, the grid pattern, the veocity distribution and the effective strain are determined. To show the merit of flashless forging, the result of flashless and flash forging processes are compared through theory and experiment. Experiments have been carried out with plasticine billets at room temperature. The theoretical predictions of the forging load and the flow pattern are in good agreement with the experimental results.

• 대한기계학회논문집
• /
• 제19권5호
• /
• pp.1211-1219
• /
• 1995

An upper bound elemental technique (UBET) program has been developed to analyze forging load, die-cavity filling and effective strain distribution for flash and flashless forgings. The simulation for flash and flashless forgings are applied axisy mmetric and plane-strain closed-die forging with rib-web type cavity. Inverse triangular and inverse trapezoidal elements are used to analyze flashless forging. The analysis is described for merit of flashless precision forging. Experiments have been carried out with pure plasticine billets at room temperature. Theoretical predictions of the forging load and the flow pattern are in good agreement with experimental results.

• 한국분말재료학회지
• /
• 제18권3호
• /
• pp.297-302
• /
• 2011

Colloidal stability is one of crucial factors for many applications of nanodiamond. Despite recent development, nanodiamonds available on the market often exhibit a high impurity content, wide size distribution of aggregates and low resistance to sedimentation. In the current study, four commercial nanodiamond powders synthesized by detonation synthesis were surface modified and then separated with respect to the size into six fractions by centrifugation. The fractions were evaluated by zeta potential, particle size distribution and elemental composition. The results showed that the modified nanodiamonds form stable colloidal suspensions without sedimentation for a long time.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
• /
• pp.397-400
• /
• 2003

In this study, humic and fulvic acids in soils at the vicinity of domestic atomic power plants(NPPs), located in Yungkwang(YK), Uljin(UJ), Kori(KR), Koseong(KS), Wolseong(WS) area, and in volcanic ash soils of the Cheju island(Mt. Hanla(HL), Manjanggul(MJ)) were isolated, and characterized using chemical(elemental analysis, proton exchange capacity, molecular size distribution) and spectroscopic(UV/Vis., IR, FL, $^{13}$ C NMR spectra) methods. The results were compared with one another and compiled for their DB establishments. The humic substances distribution (humic acid, fulvic acid, Humin) in the soils were also determined by IHSS standard method. Main purpose of this study was to provide a basic data needed to evaluate the effect of humic substances on the migrational behaviour of radioactive elements in contaminated surface soil.