Browse > Article
http://dx.doi.org/10.7316/KHNES.2022.33.6.715

Preparation and Characterization of Pt-Fe/Carbon Black Nanocatalyst for Anion Exchange Membrane in Alkaline Electrolysis  

SUNGKOOK CHO (Department of Energy & Electrical Engineering, Woosuk University)
JAEYOUNG LEE (Hydrogen Fuel Cell Regional Innovation Center, Woosuk University)
HONGKI LEE (Department of Energy & Electrical Engineering, Woosuk University)
Publication Information
Transactions of the Korean hydrogen and new energy society / v.33, no.6, 2022 , pp. 715-722 More about this Journal
Abstract
Pt-Fe/carbon black nanocatalysts were prepared by spontaneous reduction reaction of Platinum(II) acetylacetonate and Iron(II) acetylacetonate in a nucleophilic solvent and they were characterized by scanning electron microscopy (SEM), energy dispersive X-ray analyzer (EDS), thermogravimetric analyzer (TGA), transmission electron microscopy (TEM), Brunauer, Emmett and Teller (BET) surface area analysis and anion exchange membrane (AEM) water electrolysis test station. The distribution of the Pt and Fe nanoparticles on carbon black was observed by TEM, and the loading weight of Pt-Fe nanocatalysts on the carbon black was measured by TGA. Elemental ratio of Fe:Pt was estimated by EDS and it was found that elemental ratio of Pt and Fe was changed in the range of 1:0 to 0:1, and the loading weight of Pt-Fe nanoparticles on the carbon black was 5.95-6.78 wt%. Specific surface area was greatly reduced because Pt-Fe nanocatalysts blocked the pores. I-V characteristics were estimated.
Keywords
Anion exchange membrane; AEM water electrolysis; Pt nanocatalyst; Fe nanocatalyst;
Citations & Related Records
Times Cited By KSCI : 7  (Citation Analysis)
연도 인용수 순위
1 M. K. Cho, A. Lim, S. Y. Lee, H. J. Kim, S. J. Yoo, Y. E. Sung, H. S. Park, and J. H. Jang, "A review on membranes and catalysts for anion exchange membrane water electrolysis single cells", J. Electrochem. Sci. Technol, Vol. 8, No. 3, 2017, pp. 183196, doi: https://doi.org/10.5229/JECST.2017.8.3.183.   DOI
2 D. Gamage, M. Thompson, M. Sutherland, N. Hirotsu, A. Makino, and S. Seneweera, "New insights into the cellular mechanisms of plant growth at elevated atmospheric carbon dioxide concentrations", Plant Cell Environ., Vol. 41, No. 6, 2018, pp. 12331246, doi: https://doi.org/10.1111/pce.13206.   DOI
3 L. Lu, G. Dai, J. Y. Lee, and H. K. Lee, "Effect of the mixture ratio of Ni-Pt nanocatalysts on water electrolysis characteristics in AEM system", Trans. of the Korean Hydrogen and New Energy Society, Vol. 32, No. 5, 2021, pp. 285292, doi: https://doi.org/10.7316/KHNES.2021.32.5.285.   DOI
4 S. S. Kumar and V. Himabindu, "Hydrogen production by PEM water electrolysis a review", Materials Science for Energy Technologies, Vol. 2, No. 3, 2019, pp. 442454, doi: https://doi.org/10.1016/j.mset.2019.03.002.   DOI
5 G. Dai, L. Lu, J. Y. Lee, and H. K. Lee, "Preparation and characterization of Fe/Ni nanocatalyst in a nucleophilic solvent for anion exchange membrane in alkaline electrolysis", Trans. of the Korean Hydrogen and New Energy Society, Vol. 32, No. 5, 2021, pp. 293298, doi: https://doi.org/10.7316/KHNES.2021.32.5.2932.   DOI
6 B. Lee, H. Lee, J. Heo, C. Moon, S. Moon, and H. Lim, "Stochastic technoeconomic analysis of H2 production from power-to-gas using a highpressure PEM water electrolyzer for a smallscale H2 fueling station", Sustainable Energy & Fuels, Vol. 3, No. 9, 2019, pp. 25212529, doi: https://doi.org/10.1039/C9SE00275H.   DOI
7 J. Chi and H. Yu, "Water electrolysis based on renewable energy for hydrogen production", Chinese Journal of Catalysis, Vol. 39, No. 3, 2018, pp. 390394, doi: https://doi.org/10.1016/S18722067(17)629498.   DOI
8 I. Vincent, E. C. Lee, and H. M. Kim, "Highly cost-effective platinum-free anion exchange membrane electrolysis for large scale energy storage and hydrogen production", RSC Adv., Vol. 10, No. 61, 2020, pp. 3742937438, doi: https://doi.org/10.1039/D0RA07190K.   DOI
9 B. H. Oh, A. R. Kim, and D. J. Yoo, "Profile of extended chemical stability and mechanical integrity and high hydroxide ion conductivity of poly(ether imide) based membranes for anion exchange membrane fuel cells", International Journal of Hydrogen Energy, Vol. 44, No. 8, 2019, pp. 42814292, doi: https://doi.org/10.1016/j.ijhydene.2018.12.177.   DOI
10 J. Y. Chu, K. H. Lee, A. R. Kim, and D. J. Yoo, "Study on the chemical stabilities of poly(arylene ether) random copolymers for alkaline fuel cells: effect of main chain structures with different monomer units", ACS Sustainable Chem. Eng. Vol. 7, No. 24, 2019, pp. 2007720087, doi: https://doi.org/10.1021/acssuschemeng.9b05934.   DOI
11 M. J. Jang, M. S. Won, K. H. Lee, and S. M. Choi, "Optimization of operating parameters and components for water electrolysis using anion exchange membrane", Journal of the Korean Institute of Surface Engineering, Vol. 49, No. 2, 2016, pp. 159165, doi: https://doi.org/10.5695/JKISE.2016.49.2.159.   DOI
12 W. Li, H. Tian, L. Ma, Y. Wang, X. Liu, and X. Gao, "Low-temperature water electrolysis: fundamentals, prog ress, and new strategies", Mater. Adv., Vol. 3, No. 14, 2022, pp. 55985644, doi: https://doi.org/10.1039/D2MA00185C.   DOI
13 V. Elayappan, R. Shanmugam, S. Chinnusamy, D. J. Yoo, G. Mayakrishnan, K. Kim, H. S. Noh, M. K. Kim, and H. Lee, "Three-dimensional bimetal TMO supported carbon based electrocatalyst developed via dry synthesis for hydrogen and oxygen evolution", Applied Surface Science, Vol. 505, 2020, pp. 144642, doi: https://doi.org/10.1016/j.apsusc.2019.144642.   DOI
14 J. Y. Lee, Y. Liao, R. Nagahata, and S. Horiuchi, "Effect of metal nanoparticles on thermal stabilization of polymer/metal nano-composites prepared by a onestep dry process", Polymer, Vol. 47, No. 23, 2006, pp. 79707979, doi: https://doi.org/10.1016/j.polymer.2006.09.034.   DOI
15 C. Sathiskumar, S. Ramakrishnan, M. Vinothkannan, A. R. Kim, S. Karthikeyan, and D. J. Yoo, "Nitrogendoped porous carbon derived from biomass used as trifunctional electrocatalyst toward oxygen reduction, oxygen evolution and hydrogen evolution reactions", Nanomaterials, Vol. 10, No. 1, 2020, pp. 76, doi: https://doi.org/10.3390/nano10010076.   DOI
16 F. Qin, Y. Ma, L. Miao, Z. Wang, and L. Gan, "Influence of metal-ligand coordination on the elemental growth and alloying composition of Pt-Ni octahedral nano-particles for oxygen reduction electrocatalysis", ACS Omega, Vol. 4, No. 5, 2019, pp. 83058311, doi: https://doi.org/10.1021/acsomega.8b03366.   DOI
17 J. Y. Lee, D. Yin, and S. Horiuchi, "Site and morphology controlled ZnO deposition on Pd catalyst prepared from Pd/PMMA thin film using UV lithography", Chem. Mater., Vol. 17, No. 22, 2005, pp. 5498-5503, doi: https://doi.org/10.1021/cm0506555.   DOI
18 G. Dai, L. Lu, J. Y. Lee, and H. K. Lee, "Preparation and characterization of Fe/Ni nanocatalyst in a nucleophilic solvent for anion exchange membrane in alkaline electrolysis", Trans. of the Korean Hydrogen and New Energy Society, Vol. 32, No. 5, 2021, pp. 293298, doi: https://doi.org/10.7316/KHNES.2021.32.5.293.   DOI
19 P. Zhang, J. Y. Lee, H. K. Lee, "Preparation and characterization of PtNi nanocatalyst for anion exchange membrane in alkaline electrolysis by spontaneous reduction re action", Trans. of the Korean Hydrogen and New Energy Society, Vol. 33, No. 3, 2022, pp. 202208, doi: https://doi.org/10.7316/KHNES.2022.33.3.202.   DOI