• Title/Summary/Keyword: Elemental Compositions

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Calculation of X-ray attenuation coefficients for normal and cancerous breast tissues

  • Aysun Boke
    • Nuclear Engineering and Technology
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    • v.56 no.1
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    • pp.241-246
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    • 2024
  • The study was carried out by numerical integration based on the diffraction properties and elemental composition. The elemental compositions of breast tissues in the literature were tested. The photon attenuation coefficients calculated using the recent elemental composition were found within 0.2-16% for adipose tissue and within 0.04-17% for glandular tissue with the experimental reference data. The attenuation coefficients of cancerous breast tissue calculated according to the elemental content previously measured in breast cancer patients were found within 0-17% with experimental data in the literature. The attenuation coefficients are of great interest to medical research. To calculate realistic attenuation coefficients, the characteristic coherent scatter, which is most intense at small angles, must be considered. For this reason, experimentally measured form factor data were reviewed, and the most compatible one with the theoretical form factor data produced in this study was used at low momentum transfer x (0 < x ≤ 8 nm-1). The differential linear coherent scattering distributions were calculated for an energy value of 17.44 keV and compared with their experimental counterparts.

Preliminary Study on the Visualization and Quantification of Elemental Compositions in Individual Microdroplets using Solidification and Synchrotron Radiation Techniques

  • Ma, Chang-Jin;Tohno, Susumu;Kasahara, Mikio
    • Asian Journal of Atmospheric Environment
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    • v.5 no.1
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    • pp.56-63
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    • 2011
  • Quantifying the solute composition of a cloud droplet (or a whole droplet) is an important task for understanding formation processes and heating/cooling rates. In this study, a combination of droplet fixation and SR-XRF microprobe analysis was used to visualize and quantify elements in a micro-scale droplet. In this study, we report the preliminary outcome of this experiment. A spherical micro-scale droplet was successfully solidified through exposure to ${\alpha}$-cyano-acrylate vapor without affecting its size or shape. An X-ray microprobe system equipped at the beam line 37XU of Super Photon ring 8 GeV (SPring-8) was applied to visualize and quantify the elemental composition in an individual micro-scale droplet. It was possible to reconstruct 2D elemental maps for the K and Cl contained in a microdroplet that was dispensed from the 10-ppm KCl standard solution. Multi-elemental peaks corresponding to X-ray energy were also successfully resolved. Further experiments to determine quantitative measures of elemental mass in individual droplets and high-resolution X-ray microtomography (i.e., 3D elemental distribution) are planned for the future.

Elemental Mercury Adsorption Behaviors of Chemically Modified Activated Carbons

  • Kim, Byung-Joo;Bae, Kyong-Min;An, Kay-Hyeok;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.32 no.4
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    • pp.1321-1326
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    • 2011
  • In this work, the effects of different surface functional groups on the elemental mercury adsorption of porous carbons modified by chemical treatments were investigated. The surface properties of the treated carbons were observed by Boehm's titration and X-ray photoelectron spectroscopy (XPS). It was found that the textural properties, including specific surface area and pore structures, slightly decreased after the treatments, while the oxygen content of the ACs was predominantly enhanced. Elemental mercury adsorption behaviors of the acidtreated ACs were found to be four or three times better than those of non-treated ACs or base-treated ACs, respectively. This result indicates that the different compositions of surface functional groups can lead to the high elemental mercury adsorption capacity of the ACs. In case of the acid-treated ACs, the $R_{C=O}/R_{C-O}$ and $R_{COOH}/R_{C-O}$ showed higher values than those of other samples, indicating that there is a considerable relationship between mercury adsorption and surface functional groups on the ACs.

Experimental Investigation of Clay Fly Ash Bricks for Gamma-Ray Shielding

  • Mann, Harjinder Singh;Brar, Gurdarshan Singh;Mann, Kulwinder Singh;Mudahar, Gurmel Singh
    • Nuclear Engineering and Technology
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    • v.48 no.5
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    • pp.1230-1236
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    • 2016
  • This study aims to determine the effect of fly ash with a high replacing ratio of clay on the radiation shielding properties of bricks. Some interaction parameters (mass attenuation coefficients, half value layer, effective atomic number, effective electron density, and absorption efficiency) of clay fly ash bricks were measured with a NaI(Tl) detector at 661.6 keV, 1,173.2 keV, and 1,332.5 keV. For the investigation of their shielding behavior, fly ash bricks were molded using an admixture to clay. A narrow beam transmission geometry condition was used for the measurements. The measured values of these parameters were found in good agreement with the theoretical calculations. The elemental compositions of the clay fly ash bricks were analyzed by using an energy dispersive X-ray fluorescence spectrometer. At selected energies the values of the effective atomic numbers and effective electron densities showed a very modest variation with the composition of the fly ash. This seems to be due to the similarity of their elemental compositions. The obtained results were also compared with concrete, in order to study the effect of fly ash content on the radiation shielding properties of clay fly ash bricks. The clay fly ash bricks showed good shielding properties for moderate energy gamma rays. Therefore, these bricks are feasible and eco-friendly compared with traditional clay bricks used for construction.

Water chemistry controlled by drainage basin: Case study in the Han River, South Korea

  • Ryu Jong-Sik;Lee Gwang-Sik;Sin Hyeong-Seon;An Gyu-Hong;Jang Ho-Wan
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.405-407
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    • 2005
  • To evaluate the main hydrogeochemical characteristics, river waters are investigated using element리 and isotopic compositions in South Korea. In this area, the chemical compositions are mostly classified into three groups; $Ca^{2+}-{HCO_3}^-$ type, $Ca^{2+}-Cl^{-}-{NO_3}^-$ type and $Ca^{2+}-{HCO_3}^{-}-Cl^{-}-{NO_3}^-$ type. These types are affected by two major factors: water-rock interaction and anthropogenic inputs such as sewage and fertilizers. Based on the values of ${\delta}^{18}O$ and ${\delta}D$, most of waters are originated from precipitation except two samples contaminated. The lithology and geography of basins mainly control the water chemistry. Elemental and isotopic compositions show that water chemistry are mainly controlled by three end members, especially by carbonate dissolution, and suggest that anthropogenic input affect the water chemistry. Also, three weathering sources are identified: silicates, dolomite and limestone.

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Influence of Compositions of Sintered Ti-Ni Alloys on their Thermo-mechanical Properties

  • Kyogoku, Hideki;Ikeda, Tetsuya;Komatsu, Shinichiro
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.81-82
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    • 2006
  • This paper presents the influence of the compositions of sintered Ti-Ni alloys on their thermo-mechanical properties. The Ti-Ni alloys having various compositions from 50at%Ni to 51at%Ni were sintered using elemental Ti and Ni powders by a pulse-current pressure sintering equipment. The deformation resistance in stress-strain curves increased with an increase in Ni content. In the case of Ti-50at%Ni, tensile strength and elongation were more than 500 MPa and 7%, respectively. The increase in Ni content also makes the transformation temperatures lower. The deformation resistance at a test temperature change from 293K and 353K in isothermal tensile test increased with elevating test temperature.

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New composites based on low-density polyethylene and rice husk: Elemental and thermal characteristics

  • Anshar, Muhammad;Tahir, Dahlang;Makhrani, Makhrani;Ani, Farid Nasir;Kader, Ab Saman
    • Environmental Engineering Research
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    • v.23 no.3
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    • pp.250-257
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    • 2018
  • We developed new composites by combining the solid waste from Low-Density Polyethylene in the form of plastic bag (PB) and biomass from rice husk (RH),in the form of $(RH)_x(PB)_{1-x}$ (x = (1, 0.9, 0.7, 0.5)), as alternative fuels for electrical energy sources, and for providing the best solution to reduce environmental pollution. Elemental compositions were obtained by using proximate analysis, ultimate analysis, and X-ray fluorescence spectroscopy, and the thermal characteristics were obtained from thermogravimetric analysis. The compositions of carbon and hydrogen from the ultimate analysis show significant increases of 20-30% with increasing PB in the composite. The activation energy for RH is 101.22 kJ/mol; for x = 0.9 and 0.7, this increases by 4 and 6 magnitude, respectively, and for x = 0.5, shows remarkable increase to 165.30 kJ/mol. The range of temperature of about $480-660^{\circ}C$ is required for combustion of the composites $(RH)_x(PB)_{1-x}$ (x = (1, 0.9, 0.7, 0.5)) to perform the complete combustion process and produce high energy. In addition, the calorific value was determined by using bomb calorimetry, and shows value for RH of 13.44 MJ/kg, which increases about 30-40% with increasing PB content, indicating that PB has a strong effect of increasing the energy realized to generate electricity.

Physico-Chemical Properties and Methane Production Rates for Busan Harbor Sediments (부산항만 퇴적물의 성분분석 및 메탄발생량 산정 연구)

  • Choi, boram;Lee, taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.5
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    • pp.37-42
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    • 2011
  • The main objective of this study was to evaluate the current condition of harbor sediments and to estimate biochemical methane potentials from the harbor sediments. Sediment samples were collected from 10 different sampling sites. Ignition loss, elemental analyses, X-ray diffraction(XRD), X-ray fluorescence(XRF) tests were conducted to determine characteristics of the sediment. All sediments had similar elemental compositions and ignition loss were 8~10%. From the conventional BMP tests for 5 samples, cumulative methane production ranged from 11.9~15.5mL methane/(g of volatile solids), which were significantly lower than that for foods and paper. However, methane production rates for sediments were 5 to 20 times faster than those for foods and paper.

HIGH DISPERSION OPTICAL SPECTROSCOPY OF PLANETARY NEBULAE

  • HYUNG SIEK
    • Journal of The Korean Astronomical Society
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    • v.37 no.4
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    • pp.273-279
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    • 2004
  • Chemical compositions of planetary nebulae are of interest for a study of the late stage of stellar evolution and for elemental contributions to the interstellar medium of reprocessed elements since possibly a large fraction of stars in 0.8 - 8 $M_{\bigodot}$ range go through this stage. One of the methods for getting chemical composition is a construction of theoretical photoionization models, which involves geometrical complexities and a variety of physical processes. With modelling effort, one can analyze the high dispersion and find the elemental abundances for a number of planetary nebulae. The model also gives the physical parameter of planetary nebula and its central star physical parameter along with the knowledge of its evolutionary status. Two planetary nebulae, NGC 7026 and Hu 1-2, which could have evolved from about one solar mass progenitor stars, showed radically different chemical abundances: the former has high chemical abundances in most elements, while the latter has extremely low abundances. We discuss their significance in the light of the evolution of our Galaxy.