• 제목/요약/키워드: Electron recombination

검색결과 248건 처리시간 0.024초

A CONFIRMATION OF ELECTRON TEMPERATURE GRADIENT IN OUR GALAXY

  • Hong, Seung-Soo
    • 천문학회지
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    • 제13권1호
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    • pp.35-44
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    • 1980
  • Various assumptions used in interpreting the observations of hydrogen recombination lines are critically assessed to confirm the gradient of electron temperature with distance from the galactic center. The total temperature increase from 5 to 13 kpc is about 2,500 K. Among many suggestions, we have singled out the decrease of trace dement abundances with the galactoccntric distance as the most viable cause for the temperature gradient. This will impose an important constraint on evolutionary models of the Galaxy.

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Grain Boundaries Imaged by Integration of Sobel Filtered Scanning Transmission Electron Micrographs

  • Kang, Min-Chul;Oh, Jinsu;Yang, Cheol-Woong
    • Applied Microscopy
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    • 제48권4호
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    • pp.132-133
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    • 2018
  • One of the most important factors determining the properties of a material is its grain size. However, unclear grain boundaries in the image hinder an accurate measurement of grain size. We demonstrate that grain boundaries existing in the images obtained by scanning transmission electron microscopy (STEM) can be clearly distinguished by applying a Sobel filter to a tilting series of STEM images of a hydrogenation-disproportionation-desorption-recombination processed Nd2Fe14B magnet sample.

TiO2와 Graphene 혼합물을 전극으로 사용한 염료감응형 태양전지특성 연구 (Dye-Sensitized Solar Cell Based on TiO2-Graphene Composite Electrodes)

  • 바트무르;양우승;암바데;이수형
    • Korean Chemical Engineering Research
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    • 제50권1호
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    • pp.177-181
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    • 2012
  • 본 연구에서는 $TiO_2$ 필름에 그라핀나노시트(graphenenanosheet, GNS)의 양을 다르게 함으로써 형성한 전극을 이용하여 염료감응형 태양전지를 제작하였고 그 특성을 연구하였다. $TiO_2$-GNS 혼합물 전극은 단순한 혼합방식에 의하여 제작되었으며, N3를 염료로 사용하여 태양전지의 효율을 평가하였다. $TiO_2$-GNS 혼합물 전극을 사용한 염료감응형 태양전지의 전환효율은 GNS의 양에 의해 영향을 받았으며, $TiO_2$에 GNS를 0.01 wt% 혼합한 전극을 사용하여 제작한 염료감응형 태양전지가 가장 높은 효율인 5.73%를 나타내었다. 이는 GNS를 혼합하지 않은 전극을 사용한 태양전지보다 26% 높은 효율이었다. 이와 같은 효율 증가의 원인으로는 GNS 첨가에 의한 N3의 흡착량 증가, 전자 재결합(electron recombination)과 back transport reaction의 감소, 전자 수송의 증가로부터 기인한 것으로 생각된다. 본 연구에서 $TiO_2$(anatase)와 GNS의 존재는 Field-Emission Scanning Electron Microscopy를 통하여 확인하였으며, 흡착된 염료의 양은 자외선분광기(UV-vis Spectroscopy), 전자 재결합의 감소 및 전자 수송에 대한 분석은 전기화학적 임피던스분광법(Electrochemical Impedance Spectroscopy)을 이용하였다.

유전자 발현 조절과 DNA 3차원적 구조와의 관계 (Regulation of Gene Expression and 3-Dimensional Structure of DNA)

  • 김병동
    • 한국식물학회:학술대회논문집
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    • 한국식물학회 1987년도 식물생명공학 심포지움 논문집 Proceedings of Symposia on Plant Biotechnology
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    • pp.149-155
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    • 1987
  • Growth and development of a higher plant, or any living organism for that matter, could be defined as an orderly expression of the genome in time and space in close interaction with the environment. During differentiation and development of a tissue or organ a group of genes must be selectively turned on or turned off mainly by trans-acting regulators. In this general concept of regulation of regulation of gene expression, a DNA molecule is recognized at a specific nucleotide sequence by DNA-binding factors. Molecular biology of the regulatory factors such as hormones, and their receptors, target DNA sequences and DNA-binding proteins are well advanced. What is not clearly understood is the molecular basis of the interactions between DNA and binding factors, expecially of the usages of the dyad symmetry of the target DNA sequences and the dimeric nature of the DNA-binding proteins. A unique 3-dimensional structure of DNA has been proposed that may play an important role in the orderly expression of the gene. A foldback intercoil (FBI) DNA configuration which was originally found by electron microscopy among mtDNA molecules from pearl millet has some unique features. The FBI configuration of DNA is believed to be formed when a flexible double helix folds back and interwines in the widened major grooves resulting in a four stranded, intercoil DNA whose thickness is the same as that of double stranded DNA. More recently, the FBI structure of DNA has been also induced in vitro by a novel enzyme which was purified from pearl millet mitochondria. It has been proposed that the FBI DNA could be utillized in intramolecular recombination which leads to inversion or deletion, and in intermolecular recombination which can lead to either site-specific recombination, genetic recombination via single strand invasion, or cross strand recombination. The structure and function of DNA in 3-dimensional aspect is emphasized for better understanding orderly expression of genes during growth and development.

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디지털 X-선 변환물질 a-Se:As의 수송변수 (Transport parameters in a-Se:As films for digital X-ray conversion material)

  • 박창희
    • 대한디지털의료영상학회논문지
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    • 제8권1호
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    • pp.51-55
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    • 2006
  • moving photocarrier grating(MPG)기술을 이용하여 디지털 X-선 변환물질 a-Se:As 필름에서 As 첨가효과에 관하여 연구하였다. 이 방법은 시료를 조사하기 위하여 주파수를 변화시킨 2개 레이저 빔의 중첩으로 얻어진 움직이는 간섭패턴을 이용한다. 시료의 수송변수는 시료에서 변조 방향으로 유도되는 grating-속도에 의존하는 전류밀도로부터 얻어진다. As 첨가에 따른 a-Se 필름의 전자와 정공 이동도 그리고 재결합 수명을 구하였다. 전자의 이동도는 결함 상태 때문에 As 첨가에 따라 감소하는 반면, 특히 a-Se 필름에 0.3% As 첨가할 때 정공 이동도와 재결합 수명이 증가하였다. MPG 기술로 얻은 As가 첨가된 a-Se 필름의 수송성질을 a-Se:As로 제작한 X-선 detector의 X-선 감도와 비교하였다. 실험결과 0.3% As가 첨가된 a-Se으로 제작한 X-선detector가 가장 우수한 X-선 감도를 나타내었다.

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ZnO로 후처리된 TiO2 광전극을 이용한 고효율의 염료감응형 태양전지의 개발 (Development of Highly Efficient Dye-Sensitized Solar Cells Using ZnO Post-Treated TiO2 Photoelectrodes)

  • 박준용;윤병로;김태오
    • 한국수소및신에너지학회논문집
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    • 제28권4호
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    • pp.419-425
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    • 2017
  • In this study, an efficient dye-sensitive solar cells (DSSC) was developed after post-treatment of ZnO on $TiO_2$ photoelectrode. The $TiO_2$ electrode with ZnO post treatment was prepared with Titanium isoporopoxide in Zinc Nitrate Hexahydrate aqueous solution by incineration for 30 min at $450^{\circ}C$. The ZnO-post treated $TiO_2$ electrode showed strong dispersion force between particles in relation to the control $TiO_2$, referring high specific surface area and dye-adsorption rate. Proper addition of ZnO enhanced electron mobility and reduced internal resistance and electron recombination. Light conversion efficiency of DSSCs containing the ZnO-posttreated $TiO_2$ electrode increased 35.4% when compared to the DSSCs using $TiO_2$ electrode. It is similar to the DSSCs with $TiCl_4$ post treatment $TiO_2$ electrode. Increasing of light conversion efficiency was due to high specific surface area and dispersion force, and low dye-adsorption rate and electron recombination. Taken together, ZnO may be used as posttreatment of photoelectrode and replaced $TiCl_4$ that has high toxicity and causticity.

Pulsed ionization Chamber Technique for Measurement of Recombination Rate of Plasmas

  • Kim, Sang-Hoon
    • Nuclear Engineering and Technology
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    • 제6권4호
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    • pp.253-259
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    • 1974
  • 펄스된 이온화상자(PIC)의 출력 신호전압이 전자밀도가 $10^{13}$-$10^{17}$ m$^{-3}$인 플라즈마들에 대해 측정되었다. 이 PIC 기술치 한 응용으로서 이체 재결합 상수들이 PIC의 출력신호전압으로 측정된 전자밀도들로부터 구해졌다. 압력의 함수로서의 이 값들은 이론적인 예측과 잘 부합하며, 수치는 300$^{\circ}$K에 있는 1-10기압의 $^3$He 플라즈마에 대해 5$\times$$10^{-14}$ -3$\times$$10^{-13}$ ㎥/sec의 범위에 있다.

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전리수소 영역의 물리량 측정을 위한 방출선 모형연구 (MODELING FOR PROBING THE PHYSICAL STATES OF HII REGIONS)

  • 성현일
    • 천문학논총
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    • 제26권1호
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    • pp.25-35
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    • 2011
  • A diagnostic tool has been proposed to convert the observed surface distribution of hydrogen recombination line intensities into the radial distributions of the electron temperature and the density in HII regions. The observed line intensity is given by an integral of the volume emission coefficient along the line of sight, which comprises the Abel type integral equation for the volume emission coefficient. As the emission coefficient at a position is determined by the temperature and density of electrons at the position, the local emission coefficient resulted from the solution of the Abel equation gives the radial distribution of the temperature and the density. A test has been done on the feasibility of our diagnostic approach to probing of HII regions. From model calculations of an HII region of pure hydrogen, we have theoretically generated the observed surface brightness of hydrogen recombination line intensities and analyzed them by our diagnostic tool. The resulting temperatures and densities are then compared with the model values. For this case of uniform density, errors in the derived density are not large at all the positions. For the electron temperature, however, the largest errors appear at the central part of the HII region. The errors in the derived temperature decrease with the radial distance, and become negligible in the outer part of the model HII region.

페로브스카이트 태양전지에서의 저온 용액 공정의 BCP 버퍼층 효과 (Impact of Solution-Processed BCP Buffer Layer on Efficient Perovskite Solar Cells)

  • 정민수;최인우;김동석
    • 한국전기전자재료학회논문지
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    • 제34권1호
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    • pp.73-77
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    • 2021
  • Inorganic-organic hybrid perovskite solar cells have demonstrated considerable improvements, reaching 25.5% of certified power conversion efficiency in 2020 from 3.8% in 2009. In normal structured perovskite solar cells, TiO2 electron-transporting materials require heat treatment process at a high temperature over 450℃ to induce crystallinity. Inverted perovskite solar cells have also been studied to exclude the additional thermal process by using [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as a non-oxide electron-transporting layer. However, the drawback of the PCBM layer is a charge accumulation at the interface between PCBM and a metal electrode. The impact of bathocuproin (BCP) buffer layer on photovoltaic performance has been investigated herein to solve the problem of PCBM. 2-mM BCP-modified perovskite solar cells were observed to exhibit a maximum efficiency of 12.03% compared with BCP-free counterparts (5.82%) due to the suppression of the charge accumulation at the PCBM-Au interface and the resulting reduction of the charge recombination between perovskite and the PCBM layer.

양자점 감응 태양전지의 광전 특성 향상을 위한 ZnS/SiO2 이중 오버레이어 개발 (Development of ZnS/SiO2 Double Overlayers for the Enhanced Photovoltaic Properties of Quantum Dot-Sensitized Solar Cells)

  • 송인철;정성목;서주원;김재엽
    • 한국수소및신에너지학회논문집
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    • 제32권6호
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    • pp.656-662
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    • 2021
  • For the high efficiencies of quantum dot-sensitized solar cells (QDSCs), it is important to control the severe electron recombination at the interface of photoanode/electrolyte. In this work, we optimize the surface passivation process of ZnS/SiO2 double overlayers for the enhanced photovoltaic performances of QDSCs. The overlayers of zinc sulfide (ZnS) and SiO2 are coated on the surface of QD-sensitized photoanode by successive ionic layer adsorption and reaction (SILAR) method, and sol-gel reaction, respectively. In particular, for the sol-gel reaction of SiO2, the influences of temperature of precursor solution are investigated. By application of SiO2 overlayers on the ZnS-coated photoanode, the conversion efficiency of QDSCs is increased from 5.04% to 7.35%. The impedance analysis reveals that the electron recombination at the interface of photoanode/electrolyte is obviously reduced by the SiO2 overlayers.