• Title/Summary/Keyword: Electrolytic treatment

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Electrolytic Treatment of Emulsified Oily Wastewater Using DSA Electrode (I) - Batch Treatment - (DSA 전극을 사용한 에멀젼 함유폐수의 전해처리 (I) -회분식 전해처리-)

  • 김인수;송영채
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.2 no.1
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    • pp.67-75
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    • 1996
  • An innovative batch electrolytic system consisted of electrolytic basin, which was equipped with DSA(Dimensionally Stable Anode) type insoluble electrode, Ti/IrO2 anode and H-C metal cathode, and flotation separator was developed for the efficient treatment of shipboard emulsified oily wastewater. The electorod cleance and current density of elecrolytic basin to ensure maximum treatment efficiency of oily wastewater was evaluated as 6 mm, 3 A/dm3, respectively. The electrolytic efficiency of oily wastewater was affected by the operationtemperature, and it means that the temperature controller to ensure the stabiity of the process is required. The conductivity in the electrolytic basin was increased with the percentage of sea water in the oily wastewater, and over 90% of treatment efficiency of oily wastewater could be obtained at 7% of sea water. The oil removal rate was increased according to the increase of the quantity of electricity, and the maximum value of electrilyic rate constant was 288 mgoil/A.min. The information obtained from this study might be used for development of an efficient continuous electrolytic system treating the emulsified oily wastewater.

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The Effects of Acidic Electrolytic Water on the Development of Barley Chloroplast (산성 전해수가 보리(Hordeum vulgae L.) 엽록체의 발달에 미치는 영향)

  • 정화숙;송승달;노광수;송종석;박강은
    • Journal of Environmental Science International
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    • v.8 no.2
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    • pp.255-261
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    • 1999
  • To investigate the effects of strong acidic electrolytic water on the chloroplast, barley leaves were treated with strong acidic electrolytic water(pH 2.5). And to investigate the effects of weak acidic electrolytic water on the chloroplast development, etiolated barley leaves were treated with weak acidic electrolytic water(pH 6.5) during greening period. Chl contents, Fo, Fv, and Chl fluorescence quenching coefficient in barley leaves were measured during and after treatment of acidic electrolytic water. The following results were obtained. Chl a, b, and carotenoid were decreased with treatment of strong acidic electrolytic water. Chl contents were significantly decreased than that of the control after 5 min. These results provide evidence that the strong acidic electrolytic water dissimilate the Chl and so that the value of Fo was slightly increased. The strong acidic electrolytic water damaged PS II because Fo was increased and Fv, Fm, and Fv/Fm ratio were decreased. qP, qNP and qE were decreased. On the other hand qI was increased than that of the control. But Chl content and Chl fluorescence patterns were a little changed as the pH increase over 4.0 Chl a, b, and carotenoid were increased with treatment of weak acidic electrolytic water during greening period. Chl contents were significantly increased than that of control after 12 hours greening. These results provide evidence that the weak acidic electrolytic water accelerated the chlorophyll synthesis. And the weak acidic electrolytic water accelerated PS II development because Fv, Fm, qP and Fv/Fm ratio were increased than that of the control.

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An Electrolytic Treatment of Shipboard Sewage by Using DSA Electrode(II) -Continuous Electrolytic Treatment- (DSA 전극에 의한 선박오폐수의 전해처리(II))

  • 김인수;조권희;남청도
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.3 no.2
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    • pp.77-84
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    • 1997
  • For the effective treatment of shipboard sewage continuously, a non-diaphragm electrolytic treatment device using DSA type insoluble electrode, Ti/IrO2, anode and H-C metal cathode, was studied. The most effective electrolytic conditions were obtained when cell clearance, 6mm, pH 5-6 and the concentration of seawater, more than 20% as batch test results. The COD removal rate was varied in logarithmic function, showed as C=Coe-KE and the required current was E = A/QCo [A.min/mgCOD]. When the COD removal effeciency was more than 90%, the electrolytic reaction constant was 0.02.

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Characteristics of COD Removal in the Electrolytic Treatment of Dyeing-Wastewater (전기분해에 의한 염색폐수의 COD 제거 특성)

  • 강광남;윤용수
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.139-146
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    • 1998
  • The characteristics of color and COD removal for dyeing-wastewater using electrochemical reaction were investigated. >From the result, the removal efficiency of color and COD were increased with increase of temperature, decrease of electrode distance, increase of electrolyte concentration and increase of potential and these were obtained above 99%, above 75% within 30 min, individually. Cause of higher COD removal efficiency, it is more suitable that dyeing-wastewater is treated by electrolytic treatment prior to biological treatment. It is concluded that the electrolytic treatment of dyeing-wastewater can be used as the effective and economical method in practical treatment.

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An Electrolytic Treatment of Shipboard Sewage by Using DSA Electrode (I) -Batch Electrolytic Treatment- (DSA 전극에 의한 선박오폐수의 전해처리(I)-회분식 전해처리-)

  • 김인수;조권희;남청도
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.3 no.2
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    • pp.69-76
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    • 1997
  • Each factor for the most effective electrolytic reaction in treating shipboard sewage was enhanced by means of batch electrolyitc reactor using DSA electrode. The effective clearance was 6mm and pH was 5-6. In such case, more than 20% of sea water concentration was needed to attain 90% of COD removal rate. The suspended solids was effectively removed by electro-floatation in proportion as charged current density. The nitrogen and posporous were effectively removed in the electrolytic device when mixed seawater.

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ELECTROLYTIC RECOVERY OF PRECIOUS METALS FROM DILUTED SOLUTIONS

  • Roland Kammel;Lieber, Hans-Wilhelm
    • Journal of the Korean institute of surface engineering
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    • v.14 no.4
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    • pp.209-214
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    • 1981
  • Electrolytic recovery of gold and silver from diluted solutions has at first been applied nearly 100 years ago. Compared with other recovery techniques electrolytic treatment offers several advantages. But to achieve high space-time yields special constructions of electrolytic cells for improved mass transfer are necessary. Ex-tended cathode surface areas and vigorous agitation are important features. Gold and silver recovery by use of newly developed electrolytic cell constructions - rotating tubular bed reactor and impact rod reactor - has been described. Calculations based on industrial application during several years are confirming that electrolytic recovery of precious metalss from diluted solutions has been operated in a very economic way.

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Effect of Flow Rate on the Continuous Cycling Electrolytic Treatment Process for Silver Ion Containing Wastewater (은 함유 폐수의 연속 순환 전해처리 시 유량변화가 회수 공정에 미치는 영향)

  • Chung, Won-Ju;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.577-580
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    • 2007
  • The influence of flow rate has been investigated on the treatment efficiency of continuous cycling electrolytic process employing artificial and actual photographic wastewater which containing silver ion. For artificial wastewater, the treatment efficiency of process was found to rise ca. three times when the flow rate of wastewater was increased from 3 mL/min to 15 mL/min. The process efficiency was doubled under the same condition regarding actual wastewater. The effect of flow rate on the treatment efficiency was observed to be altered according to the metal ionic form and solution composition. The coefficient of mass transfer was estimated using model equation, which verified that the raised treatment efficiency at higher flow rate was due to the increased mobility of ionic species.

Electrochemical Deburring System by the Electroplated CBN Wheel (입방정질화붕소입자 전착지석에 의한 전해디버링 시스템)

  • 최인규;김정두
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1996.04a
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    • pp.19-23
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    • 1996
  • Deburring and edge finishing technology as the last process of machining operation is required for manufacturing of advanced procesion components, duburring has treated as a difficult problem on going tothe highefficency, automation in the FMS. Removal of butt with various shapes, dimensions and properties coultn't has a standard and has depended on manual treatment. Especially, deburring for cross hole inside owing to passing through out perpendicular to a main hole is more difficult, the electrolytic method is proper as its solution at practical aspects. Therefore, for the high effciency and automation of intermal deburring in the cross hole, development of electrolytic debutting technology is needed. So, the new process in the burr treatment is supposed. In this study, in the eliminating burr inside cross hole, the principle and machining performances of electrochemical deburring by Cubic-Boron-Nitrade abrasive electroplate wheel are investigated, Design and manufacture of CBN electroplated wheel and analysis of characteristics with electrolytic debutting are achieved. Also deburring efficiency and electrolytic performance for cross hole were examined according to electrolytic current and electrolytic deburring condition corresponding to acquired edge quality was found out.

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Influence of Electrolytic KF on the Uniform Thickness of Oxide Layers Formed on AZ91 Mg Alloy by Plasma Electrolytic Oxidation

  • Song, Duck-Hyun;Lim, Dae-Young;Fedorov, Vladimir;Song, Jeong-Hwan
    • Korean Journal of Materials Research
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    • v.27 no.9
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    • pp.495-500
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    • 2017
  • Oxide layers were formed by an environmentally friendly plasma electrolytic oxidation (PEO) process on AZ91 Mg alloy. PEO treatment also resulted in strong adhesion between the oxide layer and the substrate. The influence of the KF electrolytic solution and the structure, composition, microstructure, and micro-hardness properties of the oxide layer were investigated. It was found that the addition of KF instead of KOH to the $Na_2SiO_3$ electrolytic solution increased the electrical conductivity. The oxide layers were mainly composed of MgO and $Mg_2SiO_4$ phases. The oxide layers exhibited solidification particles and pancake-shaped oxide melting. The pore size and surface roughness of the oxide layer decreased considerably with an increase in the concentration of KF, while densification of the oxide layers increased. It is shown that the addition of KF to the basis electrolyte resulted in fabricating of an oxide layer with higher surface hardness and smoother surface roughness on Mg alloys by the PEO process. The uniform thickness of the oxide layer formed on the Mg alloy substrates was largely determined by the electrolytic solution with KF, which suggests that the composition of the electrolytic solution is one of the key factors controlling the uniform thickness of the oxide layer.

Characteristics of Electrolytic Treatment for Chromium and Cyanide containing Wastewater (크롬과 시안이 공존하는 폐수의 전해처리 특성)

  • 정일현;윤용수
    • Journal of environmental and Sanitary engineering
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    • v.13 no.3
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    • pp.85-92
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    • 1998
  • In this study, the electrolytic treatment by one-stage electrolysis was investigated for electroplating wastewater containing $Cr^{6+}$ and $CN^{-}$. From the results, we concluded as follows : Optimum initial pH of wastewater was pH : 3. Amount of optimum addition of electroltyte(NaCl) was 0.1 wt%. Optimum potential for electrolysis was 5 volt. Concentration and removal efficiency for $Cr^{6+}$ and $CN^{-}$ were under 1 mg/L and above 99% at optimum conditions. And the feasibility of electrolytic treatment for electroplating wastewater containing $Cr^{6+}$ and $CN^{-}$ was certified.

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