• Title/Summary/Keyword: Electroless-Ni

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Ni-P Coated Sn Powders as Anode for Lithium Secondary Batteries

  • Jo, Yong-Nam;Im, Dong-Min;Kim, Jae-Jung;Oh, Seung-M.
    • Journal of the Korean Electrochemical Society
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    • v.10 no.2
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    • pp.88-93
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    • 2007
  • Nano-sized Sn particles were coated with Ni-P layer using an electroless deposition method and their anodic performance was tested for lithium secondary batteries. Uniform coating layers were obtained, of which the thickness was controlled by varying the $Ni^{2+}$ concentration in the plating bath. It was found that the Ni-P layer plays two important roles in improving the anodic performance of Sn powder electrode. First, it prevents the inter-particle aggregation between Sn particles during the charge/discharge process. Second, it provides an electrical conduction pathway to the Sn particles, which allows an electrode fabrication without an addition of conductive carbon. A pseudo-optimized sample showed a good cyclability and high capacity ($>400mAh\;g^{-1}$) even without conductive carbon loading.

The Wetting Property of Indium Solder (인듐 솔더의 젖음특성)

  • 김대곤;이창배;정승부
    • Journal of Welding and Joining
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    • v.20 no.5
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    • pp.106-112
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    • 2002
  • In the present study, the wettability and interfacial tension between (bare Cu, electroless Ni/cu, immersion Au/Ni/Cu) substrates and indium solder were investigated as a function of soldering temperature, types of flux. The wettability of In solder increased with soldering temperature and solid content of flux. The wettability of In solder was affected by the substrate metal finish used, i.e., nickel, gold and copper. On the bare Cu substrate, In solder wet better than any of the substrate metal finishes tested. Intermetallic compound formation between liquid solder and substrate reduced the interfacial energy and improved wettability. For the identification of intermetallic compounds, X-Ray Diffraction(LRD) were employed. Experimental results showed that the intermetallic compounds, such as Cu11In9 and In27Ni10 are observed f3r different substrates respectively. The wetting kinetics is investigated by measuring wetting time with the wetting balance technique. The activation energy of wetting calculated for the In solder/cu substrate and In solder/electroless Au/Ni/Cu substrate are 36.13 and 27.36 kJ/mol, respectively.

Corrosion Resistance of the Roll Formed Steel Bolts with the Various Types of Coating Methods (2) (다양한 코팅 방법에 따른 전조한 강 볼트의 내부식성 (2))

  • Mamatov, S.;Hamrakulov, B.;Son, Y.H.;Kim, I.
    • Transactions of Materials Processing
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    • v.28 no.2
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    • pp.77-82
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    • 2019
  • Corrosion occurs well on surface of roll formed and Zn alloy subsequently electro-deposited on steel bolt under wet condition. In this study, variations in corrosion resistance were investigated through the measurement of polarization curves on steel bolts which were roll formed and subsequently coated with various types of coating methods. According to the measured polarization curve, Ni-P electroless deposits on roll formed steel increased the resistance to corrosion. The corrosion resistance of Zn alloy powder coated steel bolt was found to be better than that of Zn-Ni electro-deposited sample.

Interfacial Adhesion between Electroless Plated Ni Film and Polyimide by Post-baking Treatment Conditions (후속 열처리 조건에 따른 무전해 니켈 도금박막과 폴리이미드 사이의 계면접착력 평가)

  • Min, Kyoung-Jin;Park, Sung-Cheol;Lee, Jee-Jeong;Lee, Kyu-Hwan;Lee, Gun-Hwan;Park, Young-Bae
    • Journal of the Microelectronics and Packaging Society
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    • v.14 no.4
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    • pp.49-56
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    • 2007
  • Effects of post-baking treatment conditions on the interfacial adhesion between electroless plated Ni and polyimide film were evaluated using $180^{\circ}C$ peel test. Measured peel strength values monotonically decrease from $38.6{\pm}1.1g/mm\;to\;26.8{\pm}2.2g/mm$ for the variations of post-baking treatment temperatures from $80^{\circ}C\;to\;180^{\circ}C$, respectively. Wet chemical treatment on the polyimide surface produces carboxyl and amide functional groups on the surface which is closely related to the change in interfacial adhesion between electroless Ni and polyimide films. It is speculated that interfacial adhesion seems to be controlled by carbonyl oxygen bonding near cohesive failure region during post-baking treatment.

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Study for Mechanical Properties of Electroless (Ni/Au) Plated Monodisperse Polymer Particles (무전해 (니켈/금) 도금 처리된 단분산 가교고분자 미립자의 기계적 물성 연구)

  • Kim, Dong-Ok;Jin, Jeong-Hee;Shon, Won-Il;Oh, Seok-Heon
    • Polymer(Korea)
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    • v.31 no.5
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    • pp.410-416
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    • 2007
  • Monodisperse polymer particles were prepared via one- step seeded polymerization using PMMA as seed particles, and HDDA, triEGDMA or EGDMA as crosslinking monomer. For the study, the effects of 1) the ratio of the absorbed monomer to the seed polymer particles (swelling ratio), 2) the characteristics of crosslinking monomer, 3) electroless Ni plating, and 4) electroless Au Plating on the variation of mechanical properties of polymer particles, such as recovery rate, K-values, breaking strength and breaking displacement were investigated by using MCT (micro compression test). It was observed that swelling ratio of polymer particles influenced only on breaking strength of polymer Particles, while electroless plating did on recovery rate, K-values ($K_{10}\;and\;K_{20}$) and breaking strength of electroless plated polymer particles. However, breaking displacement and K-values ($K_{30}{\sim}K_{50}$) were more or less insensitive to electroless plating.

A Study on the Mechanism for the Formation of Partices in electroless Ni Composite Coating(II) (무전해 Ni 복합도금 과정에서 분말의 공석기구에 대한 연구(II))

  • 이원해;이승평
    • Journal of Surface Science and Engineering
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    • v.22 no.2
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    • pp.78-87
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    • 1989
  • Mechanism of formation of electroless composite coatings is similar to that of electrodeposited composite coating, but the amount of particles entraped in electroless coating is higher that the one of electrodeposited coatings. The methol of entrapment by the metal for SiC and Al2O3 particles is different from that for WC particles. In the former case the particles are gracually engulfed by the depositing metal, wheran with WC a metal envelope is rapidly fomed around each particles. This difference can be attributed to the difference in electrical resistivity of the particles. Inclusion density of SiC and Al2O3 particles during copeposition depend on the particle size, agitation condition, vabration conditions and electrolyte temperatures.

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Effect of Fabric Structure and Plating Method on EMI Shielding Property of Conductive Fabric (도전섬유의 전자파 차폐특성에 미치는 섬유구조 및 도금방법의 영향)

  • Kim, DongHyun;Lee, SeongJoon
    • Journal of Surface Science and Engineering
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    • v.48 no.4
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    • pp.149-157
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    • 2015
  • We investigated the effects of the fabric structure or the kinds of plated metals on the electromagnetic interference shielding effectiveness (EMI SE) by means of electroless plating on polyester fabric. We found that the weight of deposited metal, EMI SE, and flexibility of the conductive fabric for EMI shield is affected by morphology of fabric and structure of fiber. The EMI SE of conductive fabric plated Ni/Cu/Ni by electroless plating method on draw textured yarn (DTY) polyester was in the practically useful range of above 70 dB over a wide frequency range of 10 MHz to 1.0 GHz at the surface resistivity of $0.05{\Omega}/{\square}$. Au or Ag plated conductive fabric by immersion plating method is not able to provide for a good EMI SE.

Plating Rate of Electroless Nikel-Copper-Phosphorus Plating and Change in Microhardness and Corrosion Rate depending on. Heat treatment (무전해 니켈-구리-인 도금의 도금속도와 열처리에 따른 경도 및 내삭성 변화)

  • 오이식;황용길
    • Journal of Surface Science and Engineering
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    • v.23 no.4
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    • pp.208-217
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    • 1990
  • Electroless Ni-Cu-P plating was performed was performed to investigate for plating and changes in microhardness and corrosion rate of of electroless deposits depending on heat treatment. The activation energy for $75~85^{\circ}C$ were calculated to be 66.7KJ/mole. Plating rate increased to 34% with addition of 200ppm of NaF and 0.8ppm of thiourea to the bath. The highest hardness value was obtained by heat treatment deposits layer at$ 400^{\circ}C$, 1 hour. The increase in hardness of deposits by heating was confirmed to be associated with crystallization of the amorphous deposits. Corrosion resistance of deposir layer, which had been heated up to $300^{\circ}C$, was found to be exellent when immersed in 1N-H2SO4 solution, Change of the corrosion resistance seems to have some important bearing on content of amorpous, Ni3P and Cu3P.

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