• Title/Summary/Keyword: Electrokinetic

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Development of Numerical Analysis Program Considering Variation of Soil Properties During Electrokinetic Remediation (Electrokinetic 정화 처리 중 토체내의 특성변화를 고려한 수치해석 프로그램 개발)

  • 한상재;김치열;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.202-205
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    • 2001
  • In this study, the electrokinetic remediation test for the kaolin contaminated by lead was performed and voltage, zeta potential, pH distribution, current, contamination transport in soil sample were studied and finite differential numerical analysis program(HERP) for a contaminated soil were compared with those of test. From the result of HERP, in the anode it was represented that the rest concentration was decreased with the voltage. Hence, if treatment time was continued for a long in the constant voltage, comparing with sample having no change in the rest concentration, it is considered that the voltage gradient is the control factor of the rest concentration.

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Electrokinetic Soil Flushing with Nonionic Surfactant for Removal of Phenanthrene

  • 이유진;박지연;김상준;기대정;양지원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.356-359
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    • 2003
  • Polycyclic aromatic hydrocarbons (PAHs) are representative hydrophobic organic carbons (HOCs). Surfactant-enhanced electrokinetic (EK) remediation is an innovative in-situ technology that can effectively remove HOCs from low-permeability soils. In this study, the electrokinetic remediation using Tergitol 15-S-12, a nonionic surfactant, was conducted for the removal of phenanthrene from kaolinite. Tergitol 15-S-12 was used at concentrations of 1.5, 2.0, 2.5 and 7.5 g/L to enhance the solubility of phenanthrene. When the surfactant solution was applied to EK system, high electrical potential gradient was maintained and the amount of electroosmotic flow decreased. Removal efficiency of phenanthrene was proportional to the concentration of Tergitol 15-S-12 because the solubility and mobility of phenanthrene was enhanced by surfactant micelle. Therefore, the suitable concentration of nonionic surfactant Tergitol 15-S-12 is expected to improve the removal efficiency of PAHs in EK remediation.

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비친수성유기물질(HOC)로 오염된 토양의 정화를 위한 동전기-생물활성화공정의 개발

  • 양지원;김상준;박지연;이유진;기대정
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.326-329
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    • 2003
  • When an electrokinetic process is applied to a HOC-contaminated soil, hybrid types combined with soil flushing, chemical oxidation, and bioremediation are generally used. Especially when the electrokinetic process is combined with bioremediation, the hybrid technology can solve several limits of bioremediation such as low microbial mobility, low soil temperature, and shortage of nutrients in subsurface circumstance. Because microbial surface is charged negatively, the microorganism moves from cathode to anode under electrical field. In this study, mixed culture mainly-consisted by Pseudomonas sp. was applied to remediate pentadecane-contaminated kaolinite with particle size less than 300${\mu}{\textrm}{m}$. This remediation system was named ‘electrokinetic bioaugmentation’ and consisted of model aquifer, electrode reservoirs, bioreactor, power supply, and pump. The mixed culture above 0.5 of optical density in bioreactor was supplied to two reservoirs and penetrated soil when the electric current was applied. To enhance the removal efficiency, the optimal medium composition, electric current, and voltage were investigated.

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A study on relation of Pb treatment and pH variation characteristics during Electrokinetic remediation of clayey soil (점성토에서의 Electrokinetic 정화기법에 의한 납 제거와 pH변화 특성의 상관성에 관한 연구)

  • 한상재;김정환;조성호;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2000.11a
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    • pp.140-144
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    • 2000
  • In treatment of contaminated ground by electrokinetic remediation, pH control is the main prolllem for enhancinfi remediation efficiency. In this study, analysed pH variation characteristics according to contaminant(Pb$^{2+}$) concentration and estimated remediation efficiency with organic acid to prevent precipitation in cathode due to hydroxide ion occurrence. Because most of transported Pb$^{2+}$ is precipitatecl according as pH is increased at specimen adjacent to cathode reservoir, little magnitude of Pb$^{2+}$ is flowed out of specimen.cimen.

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The remediation of contaminated kaolinite by phenanthrene using Electrokinetic-Fenton process (Electrokinetic-Fenton 공정에 의한 Phenanthrene으로 오염된 카올린의 정화)

  • 김정환;김익현;한상재;김수삼
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.10a
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    • pp.593-596
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    • 2002
  • This study examined the feasibility of Electrokinetic-Fenton process for remediation of contaminated kaolinite by phenanthrene. The test using 7% H$_2$O$_2$as anode purging solution indicated the higher electrical current and electroosmotic flow than the test using 3.5% H$_2$O$_2$. And distribution in the soil of H$_2$O$_2$concentration showed the higher value of the former than the latter. Furthermore, the test using 7% H$_2$O$_2$and 0.01N H$_2$SO$_4$was the highest electrical current and electroosmotic flow and H$_2$O$_2$was effectively introduced to the cathode region. As it turned out, the treatment effect of phenanthrene was improved in compare with the other tests.

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Opto-electrokinetic Technique for Microfluidic Manipulation of Microorganism (광-전기역학 기술을 이용한 미생물의 미세유체역학적 제어)

  • Kwon, Jae-Sung
    • Journal of the Korean Society of Visualization
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    • v.17 no.1
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    • pp.69-77
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    • 2019
  • This paper introduces microfluidic manipulation of microorganism by opto-electrokinetic technique, named rapid electrokinetic patterning (REP). REP is a hybrid method that utilizes the simultaneous application of a uniform electric field and a focused laser to manipulate various kinds and types of colloidal particles. Using the technique in preliminary experiments, we have successfully aggregated, translated, and trapped not only spherical polystyrene, latex, and magnetic particles but also ellipsoidal glass particles. Extending the manipulation target to cells, we attempted to manipulate saccharomyces cerevisiae (S. cerevisiae), the most commonly used microorganism for food fermentation and biomass production. As a result, S. cerevisiae were assembled and dynamically trapped by REP at arbitrary location on an electrode surface. It firmly establishes the usefulness of REP technique for development of a high-performance on-chip bioassay system.

Removal of As, Cadmium and Lead in Sandy Soil with Sonification-Electrokinetic Remediation (초음파동전기기법을 이용한 비소, 카드뮴, 납으로 오염된 사질토 정화 연구)

  • Oh, SeungJin;Oh, Minah;Lee, Jai-Young
    • Journal of Soil and Groundwater Environment
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    • v.18 no.7
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    • pp.1-11
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    • 2013
  • The actively soil pollution by the toxic heavy-metals like the arsenic, cadmium, lead due to the industrialization and economic activity. The uses the electrokinetic remediation of contaminated soil has many researches against the fine soil having a small size in the on going. However, it is the actual condition which the research result that is not effective due to the low surface charge of the particle and high permeability shows in the electrokinetic remediation in comparison with the fine soil in the case of the sandy soil in which the particle size is large. In this research, the electrokinetic remediation and ultrasonic wave fetch strategy is compound applied against the sandy soil polluted by the arsenic, cadmium, and lead removal efficiency of the sandy soil through the comparison with the existing electrokinetic remediation tries to be evaluated. First of all, desorption of contaminants in soil by ultrasonic extraction in the Pre-Test conducted to see desorption effective 5~15%. After that, By conducted Batch-Test results frequency output century 200 Khz, reaction time 30 min, contaminated soil used in experiment was 500 g. Removal efficiency of arsenic, cadmium, lead are 25.55%, 8.01%, 34.90%. But, As, Cd, Pb remediation efficiency less than 1% in EK1(control group).

The Effect of Inorganic Electrolyte on the Electrokinetic Features of Calcium Carbonate Particles in Aqueous Environment (수중 탄산칼슘 입자의 전기적 거동에 미치는 무기염류의 영향)

  • O, Se-Jin;Choi, Eun-Jin;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.26 no.1
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    • pp.89-95
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    • 2010
  • The electrokinetic potential of $CaCO_3$, which takes an important part in aquatic system, has been measured and the variation of total energy between $CaCO_3$ particles with the distance of particles was estimated based on DLVO theory. The electrokinetic potential of particles was observed to increase to positive direction as the charge valence of cations which was added to suspension was increased. Also, the total interaction energy between particles was estimated to be more negative as the charge valence of cation was higher and its concentrations was raised. When a mixture of cations with different charge valences was added, the influence of cation with a higher charge valence was more significant on the total interaction energy between particles. When anion was added to the suspension of $CaCO_3$, the total energy estimated by DLVO theory was examined to move to positive direction and the electrokinetic potential of particles became more negative. Likewise cations, the effect of anions on the electrokinetic potential of particles and total interaction energy between them was observed to be proportional to their charge valence and the influence of the mixture of anions with different charge valence became more remarkable as the mixing ratio of the anion with a higher charge valence was increased.

Development of Electrokinetic-Flushing Equipment for a Remediation of Soil Contaminated with Radionuclides (방사성오염토양 제염을 위한 동전기세정장치 개발)

  • Kim, Gye-Nam;Jung, Yun-Ho;Lee, Jung-Joon;Moon, Jei-Kwon;Jung, Chong-Hun;Chung, Un-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.1
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    • pp.1-9
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    • 2008
  • This study examined the effect of an electrokinetic-flushing remediation for a soil of a high permeability. The soil was sampled from the site around a research atomic reactor which had high hydro-conductivities due to a high content of sand in the soil. The flow rate of the washing reagent was fast at the beginning but it was reduced as time lapsed. In the case of using citric acid as a washing reagent, the flow rate was fastest, 78.7 ml/day. The removal efficiencies of $Co^{2+}$ and $Cs^+$ from a soil cell with acetic acid were the highest, which were 95.2% and 84.2% respectively. The soil waste-solution volume generated from the electrokinetic remediation was reduced to about 1/20 of that from the soil washing remediation. Meanwhile, the electrokinetic-flushing method enhanced the removal efficiencies of $Co^{2+}$ and $Cs^+$ from the soil by about 6% and 2% respectively, compared to those by the electrokinetic method. Consequently, it was found that the electrokinetic-flushing method was more effective for the remediation of a soil with a high permeability.

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