• Title/Summary/Keyword: Electrode treatment

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Synthesis and Characterization of Hollow Silicon-Carbon Composites as a Lithium Battery Anode Material

  • Han, Won-Kyu;Ko, Yong-Nam;Yoon, Chong-Seung;Choa, Yong-Ho;Oh, Sung-Tag;Kang, Sung-Goon
    • Korean Journal of Materials Research
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    • v.19 no.10
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    • pp.517-521
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    • 2009
  • Si-C composite with hollow spherical structure was synthesized using ultrasonic treatment of organosilica powder formed by hydrolysis of phenyltrimethoxysilane. The prepared powder was pyrolyzed at various temperatures ranging from 900 to 1300 $^{\circ}C$ under nitrogen atmosphere to obtain optimum conditions for Li-ion battery anode materials with high capacity and cyclability. The XRD and elemental analysis results show that the pyrolyzed Si/C composite at 1100 $^{\circ}C$ has low oxygen and nitrogen levels, which is desirable for increasing the electrochemical capacity and reducing the irreversible capacity of the first discharge. The solid Si-C composite electrode shows a first charge capacity of $\sim$500 mAhg$^{-1}$ and a capacity fade within 30 cycles of 0.93% per cycle. On the other hand, the electrochemical performance of the hollow Si-C composite electrode exhibits a reversible charge capacity of $\sim$540 mAhg$^{-1}$ with an excellent capacity retention of capacity loss 0.43% per cycle up to 30 cycles. The improved electrochemical properties are attributed to facile diffusion of Li ions into the hollow shell with nanoscale thickness. In addition, the empty core space provides a buffer zone to relieve the mechanical stresses incurred during Li insertion.

A Changes of Electromyogram Activities in Deltoideus and Supraspinatus During Shoulder Abduction Using TheraBand (TheraBand를 이용한 견관절 외전시 삼각근과 극상근의 근전도 변화)

  • Park, Kwan-Yong;Lee, Suk-Min;Lee, Jae-Koo
    • Journal of Korean Physical Therapy Science
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    • v.9 no.3
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    • pp.77-87
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    • 2002
  • The purpose of this study was to compare the changes of muscle activities in deltoid with those in supraspinatus using electromyography(EMG) while subjects abducted their shoulder to different angles with different resistance. Methods : 20 volunteers who were comprised of 10 males(mean age: $21.2{\pm}2.0$) and 10 females(mean age: $20.2{\pm}1.6$) were collected. Surface electrodes were attached on deltoid and supraspinatus muscle for recording. Each reference electrode was located 3 cm to the each recording electrode. Muscle action potentials were recorded with changing the angle of shoulder abduction, $30^{\circ}$, $60^{\circ}$, $90^{\circ}$. This procedure was repeated with different resistance 0 pound, 2 pounds, 4.5pounds. The angle of shoulder abduction was determined by clinical goniometer. SPSS(Statistical Program for Social Science)/WIN 10.0 was used for statistics. Analysis included ANOVA, T-test. Results : The following results were obtained in this study. 1. There was significant differences during isometric shoulder abduction $30^{\circ}$, $60^{\circ}$, $90^{\circ}$ comparing muscle activity in deltoid and supraspinatus muscles at 0 pound, 2pound, 4.5pound resistance(p<0.05). 2. There was no useful significant in the deltoid and supraspinatus muscles activity EMG compared by physical condition. 3. Their was significant in the deltoid EMG compared by gender t=-5.41, P<0.01, but no difference in the supraspinatus EMG(P=0.333 >a=0.05). Conclusions: There are many previous studies on influence of shoulder angles and speeds of muscle activity. However most of them placed the focus on isotonic or isokinetic exercise, or shoulder function. But this study was done during isometric exercise, which is better for early assessment and treatment for injured patients. There is strong relationship between the shoulder angle with resistance in deltoid supraspinatus muscle activity. We conclude that it is important to apply isometric shoulder abduction exercise with correct angle and resistance especially in early stage.

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Fabrication and Characteristics of Lateral Type Field Emitter Arrays

  • Lee, Jae-Hoon;Kwon, Ki-Rock;Lee, Myoung-Bok;Hahm, Sung-Ho;Park, Kyu-Man;Lee, Jung-Hee
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.2 no.2
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    • pp.93-101
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    • 2002
  • We have proposed and fabricated two lateral type field emission diodes, poly-Si emitter by utilizing the local oxidation of silicon (LOCOS) and GaN emitter using metal organic chemical vapor deposition (MOCVD) process. The fabricated poly-Si diode exhibited excellent electrical characteristics such as a very low turn-on voltage of 2 V and a high emission current of $300{\;}\bu\textrm{A}/tip$ at the anode-to-cathode voltage of 25 V. These superior field emission characteristics was speculated as a result of strong surface modification inducing a quasi-negative electron affinity and the increase of emitting sites due to local sharp protrusions by an appropriate activation treatment. In respect, two kinds of procedures were proposed for the fabrication of the lateral type GaN emitter: a selective etching method with electron cyclotron resonance-reactive ion etching (ECR-RIE) or a simple selective growth by utilizing $Si_3N_4$ film as a masking layer. The fabricated device using the ECR-RIE exhibited electrical characteristics such as a turn-on voltage of 35 V for $7\bu\textrm{m}$ gap and an emission current of~580 nA/l0tips at anode-to-cathode voltage of 100 V. These new field emission characteristics of GaN tips are believed to be due to a low electron affinity as well as the shorter inter-electrode distance. Compared to lateral type GaN field emission diode using ECR-RIE, re-grown GaN emitters shows sharper shape tips and shorter inter-electrode distance.

Ozone Generation Effects and Microbial Sterilization using Boron-doped Diamond (붕소가 도핑된 다이아몬드 전극을 이용한 오존발생 효과 및 미생물 살균)

  • In, Jin-Kyung;Yoo, Ji-Young;Einaga, Y.;Fujishima, A.;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.818-821
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    • 2003
  • Ozonic use of sterilization and heat treatment of raw material to extend the conservation period of food recently is increased by hard vegetable or microorganism sterilization purpose of fruit. If ozone can create as is easy comparatively because do air or oxygen by raw material and schedule period passes, there is advantage that do not leave the second contaminant because being gotten restored by oxygen. Also, because the effect is big to decolorization beside sterilization effect about microorganism, deodorization, disjointing of venomousness hazardous substance, food save, indoor air purge, good hand processing, hydrospace agricultural chemicals processing etc. the use extent is wide. This research ran parallel a sterilization experiment of E.coli colitis germs by ozone that manufacture ozonizer that use doped diamond maund electrode (BDD) by boron and searched special quality electrochemistry enemy of the ozonizer and is created. E.coli. After cultivate E.coli colitis germs during 37C 1 day is LB ship, after do ozonation, was sterilized more than 90% by ozone as result that examine sterilizing power by substance microscope and could confirm excellency of diamond electrode.

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A Study on the Electrical Discharge Machining Tap by using Cu Electrodes of the Cold-Work Tool Steel (냉간 금형용 공구강의 Cu 전극을 이용한 방전 탭에 관한 연구)

  • Lee, Eun-Ju;Park, In-Soo;Kim, Hu-Kwon;Wang, Duck-Hyun;Chung, Han-Shik;Lee, Kwang-Sung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.15 no.5
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    • pp.131-136
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    • 2016
  • Currently, an EDM tapping procedure has comprised some parts of the engraving discharge process for the press die. Usually, tapping has been used in cases where we are unable to mechanically machine using steelwork processes due to an increase in the hardness of a material after heat treatment in relation to a design change or missing process. Here, we analyze the influence of discharge tap shape on discharge time, discharge current, and the number of repetition conditions when a cold-work tool steel (STD11) has been treated with a discharge tapped by a screw-shaped cu electrode. The most important influence on processing condition has been determined to be the number of discharge repetitions. As this number increases, the angle reduction of a thread closes to an angle of the electrode via a power generation reduction. The optimal combination of conditions has been determined to be three discharge repetitions, $180{\mu}s$ of discharge time (same as existing regulations), and 25.4A of peak current. A 0.2749db advantage has emerged after comparing between this combination of optimal conditions and the SN rate of existing regulations.

Electrospinning Method-based CNF Properties Analysis and Its Application to Electrode in Electrolysis Process (lectrospinning Method 기반 CNF의 물성분석과 전기분해 공정에서 전극으로의 응용)

  • Hwang, In-Hyuck;Choi, Sung-Yeol;Lee, Sang Hyun;Lee, Ye-Hwan;Lee, Sang Moon;Kim, Sung-Chul;Kim, Sung Su
    • Applied Chemistry for Engineering
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    • v.28 no.2
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    • pp.257-262
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    • 2017
  • In this study, CNF (carbon nanofiber) was prepared with different process variables of electrospinning method. Morphology of CNF was observed by SEM, and main parameters to form the CNF were applied voltage, TCD, polymer concentration and heat treatment condition. Comparison of toluene removal efficiency, as applying the prepared CNF to electrodes of an electrolysis process, showed the direct effect of cathode on electrolysis as well as anode.

Improvement of Stimulus Pattern and Design of Discrimination System for Coincident ratio Elevation with Traditional Meridians (고전경락과의 부합율 향상을 위한 경혈자극방식의 개선 및 식별시스템의 설계)

  • Lee, Yong-Heum;Ko, Su-Bok;Jeong, Dong-Myong
    • Journal of IKEEE
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    • v.7 no.1 s.12
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    • pp.22-31
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    • 2003
  • Conventional stimulus patterns have used DC for discrimination of acupoint and meridian which is the basic object of diagnosis and medical treatment in oriental medicine. Those discriminate conduction points by stimulation on body skin with DC. But, it is insufficient to reliability in discrimination ratio, coincident ratio, body effect, reproductivity. Therefore, this paper has extracted the optimal parameter of frequency and waveform in order to improve conventional pattern, and proposed the SPAC(Single Power Alternative Current) stimulus pattern applying that. Also, We proposes algorithm which is able to discriminate with low pressure of the electrode by displaying in the level meter both the absolution and relation value of the skin current. It can decrease pain and body effect by electrode pressure and discriminate acupoint regardless of skin current in difficult discrimination spot. We have compared the performance of system applying the extracted optimal parameter and algorithm. We have compared discrimination, coincident ratio of both conduction point and traditional acupoints by acupoint stimulation pattern. In the results, we confirmed reliability of SPAC stimulus pattern.

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ELECTROSURGERY IN DENTAL PRACTICE-A CASE REPORT (Electrosurgery를 이용한 치료증례)

  • Yoon, Jae-Woong;Lee, Sang-Hoon;Lee, Kwang-Soo;Hahn, Se-Hyun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.23 no.3
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    • pp.631-639
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    • 1996
  • Electrosurgical technique have been used in dentistry as an aid to soft tissue management for nearly 60 years. However, it was not until the late 1960s that the principles of electrosurgery were understood and improved equipment became available. Electrosurgery is a surgical procedure performed on soft tissue utilizing controlled high frequency electricaI(radio-frequency) currents in the range of 1,500,000 to 7,500,000 cyclesper second. The radio-frequency energy used in electrosurgery is able to cut and coagulate tissue because it focuses the energy at the small, active electrode. Advantages of electrosurgery for soft-tissue management during dental procedures include improved hemostasis, ease of tissue modification, improved visibility and so on, but adverse healing responses-including necrosis of soft tissue and sequestration of alveolar bone-have been reported. The present report provides examples of treatment of soft tissue and pulp tissue of primary teeth by electrosurgery. The results are as follows; 1. Electrosurgical techniques can be used for various procedures in pedodontics. 2. Electrosurgical procedures provide improved hemostasis and visibility in the operating field, which enable to remove, reshape, and contour soft tissues easily. 3. In pulpotomy technique, it was difficult to expect the variable pulpal response based on the degree of heat accumulation and the conditions of pulp tissues. Therefore, electrosurgical pulpotomy could not be considered as a method superior to formocresol pulpotomy. 4. A greater degree of dexterity and experiences in manipulation of the electrode is required compared with the conventional scalpel surgery.

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A Study on the Fabrication of Flexible Composite Electrodes and Its Bonding Characteristics According to Surface Roughness (유연 복합재료 전극 제조 및 표면조도에 따른 접착 특성에 대한 연구)

  • Lee, Han-Young;Jung, Kyung-Chae;Han, Min-Gu;Chang, Seung-Hwan
    • Composites Research
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    • v.27 no.6
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    • pp.242-247
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    • 2014
  • The fabrication of flexible electrodes coated on the surface of a dielectric elastomer film, which is a type of electroactive polymer (EAP), was carried out. Controlled amounts of Xylitol powder were added (10, 30, 50 and 70 wt%) to the commercial conductive polymer (PEDOT:PSS) to enhance resilience of the electrode. To check resilience of the fabricated composite electrodes, tensile tests were carried out using silicone films coated with the polymer electrodes. From the test results, it was found that 70 wt% Xylitol containing conductive polymer had excellent elongation and high failure strains. Furthermore, surface of the silicone film was uniformly polished with various abrading papers to enhance the wettability of the conductive polymers on the surface of the silicone film. It was found that the silicone film polished with #120 abrading paper had the best wettability and guaranteed excellent bonding behavior.

Electrocatalytic Performances of La0.6Ca0.4CoO3 and Pb2Ru2O6 prepared by Amorphous Citrate Precursor Method (Amorphous Citrate Precursor 법으로 제조한 La0.6Ca0.4CoO3와 Pb2Ru2O6의 전기화학적 촉매능)

  • Lee, Churl Kyoung;Sohn, Hun-Joon
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.331-335
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    • 1999
  • The transition metal oxides have been of interest as bifunctional electrocatalysts for bifunctional air electrodes. The amorphous citrate precursor (ACP) process has been optimized to prepare perovskite (La0.6Ca0.4CoO3) and pyrochlore (Pb2Ru2O6) powders with high surface area, and consequent improvement of The electrocatalytic performance in an air electrode with thermal treatment. PTFE -bonded gas diffusion electrodes loaded with perovskitc and pyrochlore catalysts showed good bifunctional performances. The electrodes were fairly stable up to 100 hour in the galvanostatic mode at ${\pm}25mA/cm^2$, from which these electrodes offer promise as practical bifunctional air electrodes.

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