• Title/Summary/Keyword: Electrode systems

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Electrochemical Oxidation of Ethanol at Nickel Hydroxide Electrodes in Alkaline Media Studied by Electrochemical Impedance Spectroscopy

  • Kim, Jae-Woo;Park, Su-Moon
    • Journal of the Korean Electrochemical Society
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    • v.8 no.3
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    • pp.117-124
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    • 2005
  • Electrochemical oxidation of ethanol at nickel electrodes has been studied in 1 M KOH solution containing 0.20M ethanol using electrochemical impedance spectroscopy. Equivalent circuits have been worked out by simulating the impedance data, and the results were used to model the oxidation of ethanol as well as the passivation of the electrode. The maximum rate of oxidation of $Ni(OH)_2$ to NiOOH was observed at about 0.37V vs. Ag/AgCl reference electrode, while the maximum rate of ethanol oxidation at the Ni electrode was observed at about 0.42V, The charge-transfer resistance for oxidation of the electrode itself became smaller in the presence of ethanol than in its absence. These results suggest that the $\beta-Ni(OH)_2/\beta-NiOOH$ redox couple is acting as an effective electron transfer mediator far ethanol oxidation. The kinetic parameters also were obtained by the experimental and simulated results.

Characteristics of Premixed Propane Flame in Electric Field according to Electrode Position (전극위치에 따른 전기장 내 프로판 예혼합 화염의 특성)

  • Taehun Kim;Minseok Kim;Hyemin Kim
    • Journal of ILASS-Korea
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    • v.28 no.3
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    • pp.134-142
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    • 2023
  • Electric field assisted combustion is a method that reduces instability in lean combustion. In this study investigated the effects of electrode position on propane-air flame characteristic using a ring electrode. Results showed that burning velocity was not affected by electrode position, but positive voltage expanded the flammability limit while negative voltage contracted it. The effect of voltage polarity on the flammability limit decreased as the electrode position increased. Expanding the flammability limit with a positive voltage can reduce NOx emissions.

Field Control Type Electrostatic Charge Neutralizer (전계 제어형 정전하 중화장치)

  • Jeong, Seok-Hwan;Lee, Dae-Hui;Mun, Jae-Deok
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.6
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    • pp.469-474
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    • 1999
  • Methods and systems to remove static electricity are requested in the field of industry because the static electricity causes a flammable gas explosion or fire and a reduction of production rate in manufacturing semiconductor devices and so on. This paper is a basic study about a new structure of electrode system to control the quantities of generated ions and to solve the problem of dust attachment to needle electrode. In addition, a new type field controlled electrostatic charge neutralizer was proposed, and it could control the electric field in the end of the needle electrode by controlling the voltage of the third electrode around the tip of the needle electrode. As aresult, it was possible to control the quantities of generated ion by controlling the electric field in the needle electrode with the third electrode, which shows the possibilities to solve the nonequilibrium of generated ions in ac power source and the problem of the dust in the needle electrode.

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Comparison of discharging electrodes for the electrostatic precipitator as an air filtration system in air handling units (에어핸들링 유닛의 공기정화용 전기집진기의 방전극 비교)

  • Shin, Dongho;Woo, Chang Gyu;Kim, Hak-Joon;Kim, Yong-Jin;Han, Bangwoo
    • Particle and aerosol research
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    • v.13 no.1
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    • pp.11-16
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    • 2017
  • Indoor air quality is of increasing concern because it is closely related human health. An air handling unit (AHU) can be used to control the indoor air quality related to particulate matters and $CO_2$ as well as air conditioning such as temperature and humidity of indoor air. An electrostatic precipitator has a high collection efficiency and low pressure drop, however, ozone can possibly generate from its chargers, which is one of drawbacks to apply it for indoor air control. Here we compared four charging electrodes such as a $50{\mu}m$ tungsten wire, a $100{\mu}m$ tungsten wire, a $16{\mu}m$-thickness Al foil and a carbon fabric comprised of $5-10{\mu}m$ fibers. The carbon fabric electrode showed a superior particle collection efficiency and a lower ozone generation at a given power consumption compared to tungsten wires of 50, $100{\mu}m$ and an Al foil electrode. This low ozone generating, micro-sized electrode can be applied to the electrostatic precipitator in AHU for indoor air control.

APPLICATION OF HP-DISCONTINUOUS GALERKIN FINITE ELEMENT METHODS TO THE ROTATING DISK ELECTRODE PROBLEMS IN ELECTROCHEMISTRY

  • Okuonghae Daniel
    • Journal of applied mathematics & informatics
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    • v.22 no.1_2
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    • pp.1-20
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    • 2006
  • This paper presents the interior penalty discontinuous Galerkin finite element methods (DGFEM) for solving the rotating disk electrode problems in electrochemistry. We present results for the simple E reaction mechanism (convection-diffusion equations), the EC' reaction mechanism (reaction-convection-diffusion equation) and the ECE and $EC_2E$ reaction mechanisms (linear and nonlinear systems of reaction-convection-diffusion equations, respectively). All problems will be in one dimension.

Identification of Reaction Mechanism to Produce High Quality Weld During Submerged Arc Welding

  • Kim, Jeong-Han;Kang, Kyong-Sik
    • Journal of Korean Society for Quality Management
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    • v.21 no.2
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    • pp.242-253
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    • 1993
  • The interpretation of the reaction mechanism is significant to produce the high quality welds and understand the welding processes. This investigation is important for the design of welding consumables and the selection of welding process parameters to develop the high quality welds. The objective of this study is to investigate the effect of electrochemical reactions on the transfer of alloy elements between slag and weld metal during submerged arc welding During submerged arc welding weld metal composition is shown to be controlled by two reaction mechanisms in four reaction zones. The responsible reaction mechanisms are thermochemical and electrochemical reactions. The possible reaction sites are the melted electrode tip, the detached droplet, the hot weld pool immediately below the moving electrode, and the cooling and solidifying weld pool behind the moving electrode. The possible reactions in submerged arc welding at different zones of the process is schematically shown in Figure 1.

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Electrode Properties for Water Electrolysis of Hydrophilic Carbon Paper with Thermal Anneal (열처리된 친수성 카본 페이퍼 전극의 전기 물 분해 특성)

  • Yoo, Il-Han;Seo, Hyungtak
    • Korean Journal of Materials Research
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    • v.26 no.5
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    • pp.241-245
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    • 2016
  • Hydrogen is considered a potential future energy source. Among other applications of hydrogen, hydrogen-rich water is emerging as a new health care product in industrial areas. Water electrolysis is typically used to generate a hydrogen rich water system. We annealed 10AA carbon paper in air to use it as an electrode of a hydrogen rich water generator. Driven by annealing, structural changes of the carbon paper were identified by secondary electron microscope analysis. Depending on the various annealing temperatures, changes of the hydrophilic characteristics were demonstrated. The crystal structures of pristine and heat-treated carbon paper were characterized by X-ray diffraction. Improvement of the efficiency of the electrochemical oxygen evolution reaction was measured via linear voltammetry. The optimized annealing temperature of 10AA carbon paper showed the possibility of using this material as an effective hydrogen rich water generator.

Preparation of nano composite metal-oxide electrode and its application for superrcapacitor (나노복합산화물 전극의 제조 및 수퍼커패시터로써의 응용)

  • Kim, Hong-Il;Lee, Ju-Won;Kim, Sang-Gil;Yuk, Gyung-Chang;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.801-804
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    • 2002
  • Electrochemical capacitors are becoming attractive energy storage systems particularly for applications involving high power requirements such as hybrid systems consisting of batteries and electrochemical capacitors for electric vehicle propulsion. Both of amorphous cobalt oxide and manganese dioxide were prepared by sol-gel process reported in our previous work. Nanostructured supramolecular oligomer of 1,5-diaminoanthraquinone(DAAQ) coated metal oxides were successfully prepared by electrochemical oxidation from an acidic non-aqueous medium. We established process parameters of the technique for the formation of nano-structured materials. Furthermore, improved the capacitive properties of the nano structured metal oxide electrodes using controlled solution chemistry. $CoO_2$ and $MnO_2$-based composite electrode showed relatively good electrochemical behaviors in acidic electrolyte system with respect to specific capacity and scan rate dependency.

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Measurement of Grounding Impedances in Large-scale Grounding Electrode Systems (대형접지전극시스템 접지임피던스의 측정)

  • Lee, Kyoung-Hoon;Choi, Jong-Hyuk;Choi, Young-Chul;Lee, Kyu-Sun;Lee, Bok-Hee
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2008.10a
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    • pp.193-196
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    • 2008
  • In these days, large structures are constructed and bonded with ground grid Because the distances between mesh and auxiliary electrodes are not enough in downtown areas, it is very difficult to measure the ground resistance of large scale grounding electrode systems. Actually the auxiliary electrodes for test are installed in grounding grid. This paper present the experimental results of ground resistance and impedance according to the location of auxiliary electrode. As a result, we get much lower resistances and impedances than real values the auxiliary electrodes are placed in the ground grid. In case that the auxiliary electrodes are located in the ground grid the resistances are very low and reactance only is inductive component.

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Graphene Oxide based Metal ion Hybrid Supercapacitor (산화그라핀 및 금속 이온 결합체를 이용한 슈퍼커패시터 특성 연구)

  • Jung, Youngmo;Jun, Seong Chan
    • Transactions of the Society of Information Storage Systems
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    • v.9 no.1
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    • pp.22-27
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    • 2013
  • In this paper we are presenting a architecture of Co ion decorated graphene oxide as an electrode for supercapacitor application. Graphene oxide, which is exfoliated by oxidant from graphite, is the material for solving the problem of mass production and coating on the surface of working electrode. The $Co^{2+}$ ions are coated by using layer by layer(LBL) method on graphene oxide foam. The metal ion decorated graphene oxide shows enhanced capacitance performance when tested as supercapacitor electrode, showing the specific capacitance of $827Fg^{-1}$.