• Title/Summary/Keyword: Electrode spacing

Search Result 100, Processing Time 0.029 seconds

Effectiveness of Uranium Recovery by the Electrodeposition Method (전기정착법(電氣定着法)에 의한 우라늄의 회수효과(回收效果))

  • Lee, Byung-Ki;Hong, Jong-Sook;Jung, Lae-Eak
    • Journal of Radiation Protection and Research
    • /
    • v.8 no.2
    • /
    • pp.36-40
    • /
    • 1983
  • Uranium radionuclides are electrodeposited on inexpensive stainless steel cathode from a mixed oxalate-chloride electrolyte. The factors affecting the optimum condition for the deposition are determined by studying the effects of deposition time, initial current, electrode spacing, pH of electrolyte and uranium concentration in the electrolyte at fixed cathode area. The experiment which was repeated 3 times at each uranium concentration with 60 minutes of deposition time, gave an error of less than 4% standard deviation at the 90% confidence level with average yield greater than 99%.

  • PDF

Power Durability Properties of Surface Acoustic Wave Filters for Mobile Telecommunications (이동통신용 표면탄성파 필터의 내전력 특징)

  • Nam, Hyo-Duk;Kim, Dong-Su;Kim, Hung-Rak;Kim, Kwang-Il
    • Journal of Sensor Science and Technology
    • /
    • v.9 no.4
    • /
    • pp.327-333
    • /
    • 2000
  • Transversal SAW(Surface Acoustic Wave) filters of 340MHz were fabricated on piezoelectric substrates of the LN $128^{\circ}$ Y-X wafers. Both of spacing and width of IDT were $1.435{\mu}m$. For improving the power durability characteristics, titanium layer was inserted between aluminum electrode and piezoelectric substrate since it has high density, low thermal expansion coefficient, and good adhesive properties. Power durability was evaluated with respect to the thickness of inserted titanium layer and the temperature of heat treatment. Power durability is improved with increasing the thickness of the inserted titanium layer. Moreover, it is remarkably improved by heat treatment at the temperature of $300^{\circ}C$.

  • PDF

Single Crystalline ${\beta}$-Na0.33V2O5 Nanowires Based Supercapacitor

  • Trang, Nguyen Thi Hong;Shakir, Imran;Kang, Dae-Joon
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.02a
    • /
    • pp.587-587
    • /
    • 2012
  • Supercapacitors, which can deliver significant energy with high power density, have attracted a lot of attention due to their potential application in energy storage. Among various oxide materials, sodium vanadate has been recognized as one of the most promising electrode materials because of high electrical conductivity. In addition, larger layer spacing of ${\beta}$-Na0.33V2O5 compared to V2O5 makes easier Li+ insertion. Moreover, ${\beta}$-Na0.33V2O5 has a tunnel like structure along b axis with 3 kinds of V site allowing it to enhance the ion intercalation by introducing three different intercalation sites along the tunnel. The tunnel can act as a fast diffusion path for ion diffusion, which can improve the overall charge storage kinetics. In this study, high quality single crystalline sodium vanadate (${\beta}$-Na0.33V2O5) nanowires were grown directly on Pt coated $SiO_2$ substrate by a facile chemical solution deposition method without employing catalyst, surfactant or carrier gas. The results show that great enhancement in capacitance was observed compared with previous reports.

  • PDF

Ruthenium Oxide Nanoparticles Electrodeposited on the Arrayed ITO Nanorods and Its Application to Supercapacitor Electrode

  • Ryu, Ilhwan;Lee, Jinho;Park, Dasom;Yim, Sanggyu
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.02a
    • /
    • pp.296-296
    • /
    • 2013
  • Supercapacitor is a capacitor with extraordinarily high energy density, which basically consists of current collector, active material and electrolyte. Ruthenium oxide ($RuO_2$) is one of the most widely studied active materials due to its high specific capacitance and good electrical conductivity. In general, it is known that the coating of $RuO_2$ on nanoarchitectured current collector shows improved performance of energy storage device compared to the coating on the planar current collector. Especially, the surface structure with standing coaxial nanopillars are most desirable since it can provide direct paths for efficient charge transport along the axial paths of each nanopillars and the inter-nanopillar spacing allows easy access of electrolyte ions. However, well-known fabrication methods for metal or metal oxide nanopillars, such as the process using anodize aluminum oxide (AAO) templates, often require long and complicated nanoprocess.In this work, we developed relatively simple method fabricating indium tin oxide (ITO) nanopillars via sputtering. We also electrodeposited $RuO_2$ nanoparticles onto these ITO nanopillars and investigated its physical and electrochemical properties.

  • PDF

Electrochemical Characteristics of Carbon-coated Si/Cu/graphite Composite Anode

  • Kim, Hyung-Sun;Chung, Kyung-Yoon;Cho, Won-Il;Cho, Byung-Won
    • Bulletin of the Korean Chemical Society
    • /
    • v.30 no.7
    • /
    • pp.1607-1610
    • /
    • 2009
  • The carbon-coated Si/Cu powder has been prepared by mechanical ball milling and hydrocarbon gas decomposition methods. The phase of Si/Cu powder was analyzed using X-ray diffraction (XRD), dispersive Raman spectroscopy, electron probe microanalysis (EPMA) and transmission electron microscope (TEM). The carbon-coated Si/Cu powders were used as anode active material for lithium-ion batteries. Their electrochemical properties were investigated by charge/discharge test using commercial LiCo$O_2$ cathode and lithium foil electrode, respectively. The surface phase of Si/Cu powders consisted of carbon phase like the carbon nanotubes (CNTs) with a spacing layer of 0.35 nm. The carbon-coated Si/Cu/graphite composite anode exhibited a higher capacity than commercial graphite anode. However, the cyclic efficiency and the capacity retention of the composite anode were lower compared with graphite anode as cycling proceeds. This effect may be attributed to some mass limitations in LiCo$O_2$ cathode materials during the cycling.

Oxidation-treated of Oxidized Carbons and its Electrochemical Performances for Electric Double Layer Capacitor (산화처리 탄소 및 이를 이용한 EDLC 특성)

  • Yang, Sun-Hye;Kim, Ick-Jun;Jeon, Min-Je;Moon, Seong-In;Kim, Hyun-Soo;An, Kye-Hyeok;Lee, Yun-Pyo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.20 no.6
    • /
    • pp.502-507
    • /
    • 2007
  • The oxidation treatment of several carbon materials with a sodium chlorate and 70 wt.% of nitric acid, combined with heat treatment, were attempted to achieve an electrochemical active material with a larger capacitance. Among pitch, needle coke, calcinated needle coke and natural graphite, the structure of needle coke and calacinated needle coke were changed to the graphite oxide structure with the expansion of the inter-layer. On the other hand, the calcinated needle coke after oxidation and heating at $200^{\circ}C$ has exhibited largest capacitance per weight and volume of 29.5 F/g and 24.5 F/ml at the two-electrode system in the potential range of 0 to 2.5 V. The electrochemical performance of the calcinated needle coke was discussed with the phenomenon of the electric field activation and the formation of new pores between the expanded inter-layer at first charge.

Thermal Characteristics of Heating Films Including Conductive Graphite (전도성 흑연을 포함하는 발열 필름의 열적 특성)

  • Choi, Gyuyeon;Oh, Weontae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.33 no.6
    • /
    • pp.500-504
    • /
    • 2020
  • Heating films were prepared with composites of poly (methyl methacrylate) and conductive graphite. The as-prepared composite was deposited on a PET film and then fabricated using a bar coater to produce a film with uniform thickness. Copper electrodes were attached to both ends of the as-prepared film, and the heating characteristics of the film were analyzed while applying a DC voltage. The electrical conductivity and heating temperature of the heating films depended on the size, structure, content, and the dispersion characteristics of the graphite in the composite. The thermal energy was adjusted by controlling the electrical energy, based on the Joule heating theory. The electrical resistance of the film was altered in proportion to Ohm's law, and the heating temperature was changed according to the structure of the film (interelectrode spacing or electrode length) and the conductive graphite content. When the content of conductive graphite in the film increases, the electrical resistance decreases, and the heating temperature increases; however, there is no significant change above a certain content (50%).

Forward Calculation of Electric Potential, Electric Field and Resistivity Survey on Anisotropic Layered Half Space (이방성 층상구조에 대한 전위와 전기장 및 전기비저항탐사 계산 연구)

  • Na, Sung-Ho;Kim, Hyoung-Soo
    • Geophysics and Geophysical Exploration
    • /
    • v.24 no.3
    • /
    • pp.98-112
    • /
    • 2021
  • We followed and extended the algorithm originally made by Das (1995) to calculate the electric potential and field induced by electric current in arbitrary anisotropic layered structure. We confirmed all the theoretical contents and coded the corresponding program to acquire the electric potential and field. Further we extended to forward estimation of apparent resistivity to be attained by electrical resistivity survey on anisotropic layered structure with differing the electrode spacing and azimuth of anisotropy. The effects of anisotropy were reviewed by considering some examples.

Subsurtace Geological Structure of the Downstream Area of the Jangsung Lake (장성호 하류지역의 지하지질구조)

  • 김성균;김용준;오진용;김민선;서구원
    • The Journal of Engineering Geology
    • /
    • v.7 no.2
    • /
    • pp.101-112
    • /
    • 1997
  • Gravity and electrical resistivity surveys were carried out across the Kwangju fault in the downstream area of the Jangsung Lake, to investigate the location and geometrical feature of the fault. In the resistivity survey, dipole - dipole array method was adopted for 3 survey lines of which length and electrode spacing are 500m and 25m, respectively. Resistivity data are interpreted with aid of computer program "RESIS" which is widely used in resistivity data analysis and two dimensional resistivity profiles are obtained for 3 survey lines. Two large fracture zones relevant to the Kwangju fault are identified in the resistivity profiles. The total of 80 gravity data are observed with the mean spacing of 40 m and the exact leveling is accompanied to obtain more precise gravity anomalies. The subterranean density discontinuities calculated from the inverse method are appeared at the depths of 650rn and 120m. It is considered that the deep discontinuity indicates boundary between Jurassic granites and oveflying Cretaceous tuff formation. while, the shallow discontinuity is interpreted to be a boundary between alluvial deposits and basements. The subsurface geological structure to satisfy the observed Bouguer anomaly is determined from the iterative forward method in which results from existing surface geological informations, the inverse method, and from the resistivity interpretations are employed as an iuitial model. In conclusion, Kwangju fault is appeared to be a high angle normal fault mainly formed in tension stress filed.

  • PDF

Preparation of Graphite Oxide and its Electrochemical Double Layer Capacitor's Performances using Non-Aqueous Electrolyte (TEABF4 & TEMABF4) (산화흑연의 제조 및 전해질(TEABF4 & TEMABF4)에 따른 전기이중층 커패시터의 특성)

  • Yang, Sunhye;Kim, Ick-Jun;Jeon, Min-Je;Moon, Seong-In;Kim, Hyun-Soo;An, Kye-Hyeok;Lee, Yun-Pyo;Lee, Young-Hee
    • Applied Chemistry for Engineering
    • /
    • v.18 no.3
    • /
    • pp.291-295
    • /
    • 2007
  • The oxidation treatment of needle cokes with 70 wt% of nitric acid and sodium chlorate ($NaClO_3$) was attempted to achieve an electrochemically active material with a large capacitance. The structure of needle cokes was changed to graphite oxide after oxidation treatment of needle cokes with acidic solution having the composition ratio, $NaClO_3$/needle cokes, of 7.5, and the inter-layer distance of the oxidized needle cokes was extended to $6.9{\AA}$with increasing oxygen content. On the other hand, the electrochemical performance of oxidized needle cokes as a polarized electrode for an Electric Double Layer Capacitor (EDLC) was examined with an electrolyte of 1.2 M $TEABF_4$ (tetraethylammonium tetrafluoroborate) and $TEABF_4$ (triethylmethylammonium tetrafluoroborate) in acetonitrile. The capacitor cell using 1.2 M $TEABF_4$/acetonitrile has exhibited smaller electric resistance of $0.05{\Omega}$, and larger capacitance per weight and volume of 32.0 F/g and 25.5 F/mL at the two-electrode system in the potential range 0~2.5 V than that of the capacitor cell using $TEABF_4$. The observed electrochemical performance was discussed with the correlation between the inter-layer distance in graphite oxide structure and the anionic size of electrolyte.