• 제목/요약/키워드: Electrode life

검색결과 294건 처리시간 0.028초

Determination of Cadmium(II) Ion Using the Nafion-Ethylenediamine-Modified Glassy Carbon Electrode (Nafion-Ethylenediamine이 수식된 유리탄소전극에 의한 Cd(II) 이온의 정량)

  • Kim, Jin Ah;Ko, Young Chun;Park, Chan Ju;Park, Byung Ho;Chung, Keun Ho
    • Analytical Science and Technology
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    • 제14권2호
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    • pp.123-130
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    • 2001
  • Determination of cadmium(II) ion with a perfluorinated sulfonated polymer-ethylenediamine(nafion-en) modified glassy carbon electrode was studied. It was based on the chemical reactivity of an immobilized layer(nafion-en) to yield complex $[Cd(en)_2]^{2+}$. The reduction peak potential by differential pulse voltammetry(DPV) was observed at $-0.780({\pm}0.005)V$ vs. As/AgCl. The linear calibration curve was obtained in cadmium(II) ion concentration range $5.0{\times}10^{-7}-2.0{\times}10^{-5}M$, and the detection limit(3s) was $2.20{\times}10^{-7}M$. The detection limit of nafion-en modified glassy carbon electrode has been shown about 14 higher sensitivity than a bare glassy carbon electrode.

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A Study on Performance Evaluation for Electrocardiography Signal Measurement Electrode based on Conductive Fabric (전도성 섬유 기반 심전도 전극의 성능 평가에 관한 연구)

  • Kang, Bo Kyu;Yoo, Sun Kook
    • Journal of the Institute of Electronics and Information Engineers
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    • 제50권2호
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    • pp.210-220
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    • 2013
  • Recently, as we move toward a society with an increasingly aged population, wearable U-health devices in various shapes with smart wear have been developed in order to conveniently measure health variables without using hands in daily life or at home. However, the problem is that only supply of the wearable U-health devices is focused and its applicable devices are studied and developed, which has resulted in lack of awareness of importance of performance evaluation. In this study, two electrodes were fabricated using conductive fabric which can be used as electrode if attached to wearable U-health devices or smart wear in order to measure ECG signal. Two electrodes those were fabricated using conductive fabric were compared the correlation, impedance and CMRR with patch typed Ag-AgCl electrode-normally used for measurement of ECG signal, so that the study would find out if the fabricated electrode can be used with the wearable U-health devices by testing and evaluating performances.

The Effect of Process Parameters on Sealing Quality for Ir-192 Radiation Source Capsule using Resistance Spot Welding (Ir-192 방사선원의 밀봉 용접부 품질에 미치는 저항용접 공정변수의 영향)

  • Han, In-Su;Son, Kwang-Jae;Lee, Young-Ho;Lee, You-Hwang;Lee, Jun-Sig;Jang, Kyung-Duk;Park, Ul-Jae;Park, Chun-Deuk
    • Journal of Welding and Joining
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    • 제27권1호
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    • pp.65-70
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    • 2009
  • Ir-192 radiation sealed sources are widely employed to the therapeutic applications as well as the non-destructive testing. Production of Ir-192 sources requires a delicate but robust welding technique because it is employed in a high radioactive working environment. A GTA(Gas Tungsten Arc) welding technique is currently well established for this purpose. However, this welding method requires a frequent replacement of the electrode, which results in the delay of the production to take a preparatory action such as to isolate the radiation sources from the working place before getting access to the welding machine. Hence, a resistance welding technique is considered as an alternative method of the GTA welding technique. The advantages of resistance welding are high welding speed and high-rate production. Also it has very long life of electrode comparing to GTA welding. In this study, the resistance welding system and proper welding conditions were established for sealing Ir-192 source capsule. As a results of various experiments, it showed that electrode displacement can be employed as a indicator to predict welding quality. We proposed two mathematical models(linear and curvilinear) to estimate electrode displacement with process parameters such as applied force, welding current and welding time by using regression analysis method. Predicting results of both linear and curvilinear model were relatively good agreement with experiment.

Reactive sputtered tin adhesion for wastewater treatment of BDD electrodes (TiN 중간층을 이용한 수처리용 BDD 전극)

  • KIM, Seo-Han;KIM, Shin;KIM, Tae-Hun;SONG, Pung-Keun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 한국표면공학회 2017년도 춘계학술대회 논문집
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    • pp.69-69
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    • 2017
  • For several decades, industrial processes consume a huge amount of raw water for various objects that consequently results in the generation of large amounts of wastewater. There effluents are mainly treated by conventional technologies such are aerobic, anaerobic treatment and chemical coagulation. But, there processes are not suitable for eliminating all hazardous chemical compounds form wastewater and generate a large amount of toxic sludge. Therefore, other processes have been studied and applied together with these techniques to enhance purification results. These techniques include photocatalysis, absorption, advanced oxidation processes, and ozonation, but also have their own drawbacks. In recent years, electrochemical techniques have received attention as wastewater treatment process that show higher purification results and low toxic sludge. There are many kinds of electrode materials for electrochemical process, among them, boron doped diamond (BDD) attracts attention due to good chemical and electrochemical stability, long lifetime and wide potential window that necessary properties for anode electrode. So, there are many researches about high quality BDD, among them, researches are focused BDD on Si substrate. But, Si substrate is hard to apply electrode application due to the brittleness and low life time. And other substrates are also not suitable for wastewater treatment electrode due to high cost. To solve these problems, Ti has been candidate as substrate in consideration of cost and properties. But there are critical issues about adhesion that must be overcome to apply Ti as substrate. In this study, to overcome this problem, TiN interlayer is introduced between BDD and Ti substrate. TiN has higher electrical and thermal conductivity, melting point, and similar crystalline structure with diamond. The TiN interlayer was deposited by reactive DC magnetron sputtering (DCMS) with thickness of 50 nm, $1{\mu}m$. The microstructure of BDD films with TiN interlayer were estimated by FE-SEM and XRD. There are no significant differences in surface grain size despite of various interlayer. In wastewater treatment results, the BDD electrode with TiN (50nm) showed the highest electrolysis speed at livestock wastewater treatment experiments. It is thought to be that TiN with thickness of 50 nm successfully suppressed formation of TiC that harmful to adhesion. And TiN with thickness of $1{\mu}m$ cannot suppress TiC formation.

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A Study on Intrinsic Noise of Capacitively Coupled Active Electrode (용량성 결합 능동 전극의 내부 잡음 분석)

  • Lim, Yong-Gyu
    • Journal of the Institute of Convergence Signal Processing
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    • 제13권1호
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    • pp.44-49
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    • 2012
  • The indirect-contact ECG measurement is a newly developed method for unconstrained and nonconscious measurement in daily Life. This study is the first step to reducing the large background noise appearing in indirect-contact ECG. This study built the thermal noise model of capacitively coupled active electrode which is used in indirect-contact ECG. The results show that the level of thermal noise estimated by the thermal noise model is much the same as that of actual background noise for the capacitively coupled active electrode alone. By applying the actual electrical properties of a sample cotton cloth to the thermal noise model, the theoretical level of thermal noise in the indirect-contact ECG was estimated. The results also show that the level of op-amp's intrinsic noise is so small that it can be negligible in comparison with thermal noise of resistors. The relationship between the level of thermal noise and the resistance of the bias resistor was derived, and it is the base for the further study how to choice the optimal resistance for the bias resistor.

Development of Retinal Prosthesis Module for Fully Implantable Retinal Prosthesis (완전삽입형 인공망막 구현을 위한 인공망막모듈 개발)

  • Lee, Kang-Wook;Kaiho, Yoshiyuki;Fukushima, Takafumi;Tanaka, Tetsu;Koyanagi, Mitsumasa
    • Journal of Biomedical Engineering Research
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    • 제31권4호
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    • pp.292-301
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    • 2010
  • To restore visual sensation of blind patients, we have proposed a fully implantable retinal prosthesis comprising an three dimensionally (3D) stacked retinal chip for transforming optical signal to electrical signal, a flexible cable with stimulus electrode array for stimulating retina cells, and coupling coils for power transmission. The 3D stacked retinal chip is consisted of several LSI chips such as photodetector, signal processing circuit, and stimulus current generator. They are vertically stacked and electrically connected using 3D integration technology. Our retinal prosthesis has a small size and lightweight with high resolution, therefore it could increase the patients` quality of life (QOL). For realizing the fully implantable retinal prosthesis, we developed a retinal prosthesis module comprising a retinal prosthesis chip and a flexible cable with stimulus electrode array for generating optimal stimulus current. In this study, we used a 2D retinal chip as a prototype retinal prosthesis chip. We fabricated the polymide-based flexible cable of $20{\mu}m$ thickness where 16 channels Pt stimulus electrode array was formed in the cable. Pt electrode has an impedance of $9.9k{\Omega}$ at 400Hz frequency. The retinal prosthesis chip was mounted on the flexible cable by an epoxy and electrically connected by Au wire. The retinal prosthesis chip was cappted by a silicone to pretect from corrosive environments in an eyeball. Then, the fabricated retinal prosthesis module was implanted into an eyeball of a rabbit. We successfully recorded electrically evoked potential (EEP) elicited from the rabbit brain by the current stimulation supplied from the implanted retinal prosthesis module. EEP amplitude was increased linearly with illumination intensity and irradiation time of incident light. The retinal prosthesis chip was well functioned after implanting into the eyeball of the rabbit.

Study on the Prediction of the Life-time in the Macroscopic Solid-Solid Interfaces (고체-고체 거시계면의 수명예측에 관한 연구)

  • 박정규;배덕권;정동회;오재한;김충혁;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.775-778
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    • 2000
  • In this paper, the life-time of macro interface between Epoxy/EPDM which consists in underground power cable joints is predicted. The electrode system of specimen is designed by FEM(finite elements method). The breakdown strength of specimens are observed by applying high AC voltage at the room temperature. The breakdown times under the constant voltage below the breakdown voltage were gained. As constant voltage is applied, the breakdown time is proportion to the breakdown strength. The life exponent n is gained by inverse power law, and the long breakdown life time can be evaluated.

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Effects of Pd Addition on Electrode properties of Metal Hydride (Pd 첨가가 금속수소화물 전극 특성에 미치는 영향)

  • Choi, Jeon;Lee, Kyung-Ku
    • Transactions of the Korean hydrogen and new energy society
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    • 제10권2호
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    • pp.141-149
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    • 1999
  • Recently the Ni/MH secondary battery has been studied extensively to achieve higher energy density, longer cycle life and faster charging-discharging rate etc. In this work, the electrode properties of $(LM)Ni_{4.49}Co_{0.1}Mn_{0.205}Al_{0.205}$ alloy and $Ti_{0.6}Zr_{0.4}V_{0.6}Ni_{1.4}$ alloy with addition of Pd were investigated. These alloys did not show any change in XRD pattern by Pd addition. As Pd was added as alloy element, the activation behavior was not affected significantly in both $AB_2$ type and $AB_5$ type electrodes and, On charging and discharging in high current density, Discharge capacity with increasing of Pd content was more decreased. But cycle life was showed increasing. Especially the electrode of $Ti_{0.6}Zr_{0.4}V_{0.6}Ni_{1.4}+0.5wt%$ Pd alloy was not almost decreased discharge capacity for 400cycles.

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Preparation and Characteristics of a Single-layer PVA Laminated CTA/PCL Membrane for Oxygen Biosensor Electrode (산소센서용 CTA/PCL 효소고정화막과 반투막을 단일화한 PVA적층막의 제조 및 특성)

  • Seo, Jong-Won;Kim, Tae-Jin;Jeong, Yong-Seob;Yoon, Jeong-Weon
    • Journal of Sensor Science and Technology
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    • 제8권3호
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    • pp.247-252
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    • 1999
  • The oxygen electrode of a biosensor needs enzyme immobilized membrane and a dialysis membrane to measure the oxygen concentration that remains after an enzyme reacts with its substrate. Accodingly, a single-layer PVA laminated CTA/PCL membrane was developed as an oxygen biosensor electrode. The enzymes were immobilized on a cellulose triacetate/polycarprolactone membrane using the 1,1'-carbonyl diimidazole(CDI) method, and then laminated with polyvinyl alcohol, aldehyde and acid. The alcohol oxidase and PVA laminated CTA/PCL membrane was tested with various concentration of enzyme substrates using a Yellow Springs Instrument(YSI) oxygen sensor. Under 5-10mmol substrates produced $0.37{\sim}0.83{\mu}A$(r=0.995) currents, and ater 8 weeks the glucose oxidase activity remained at about 56%, while the other activities remained very low. A SEM indicated a smooth surface and tightly attached PVA on the enzyme-immobilized CTA/PCL membranes.

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