• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.487-490
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• 2000

The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Electrochemical capacitor(supercapacitor) cell of CP composite electrode with 1M LiClO$_4$PC bring out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding l5wt%SP270(PAnS15) and PT composite electrode adding 50wt%SP270 (PTS50) was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PTS50(+)/PAnS15(-) in 1st and 20th cycles was 38F/g and 28F/g at current density of 1mA/cm$^2$. Supercapacitor cell with PTS50(+)/PAnS15(-) showed good capacitance and stability with cycling.

• ETRI Journal
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• 제42권1호
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• pp.129-137
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• 2020

All-solid-state batteries are promising energy storage devices in which high-energy-density and superior safety can be obtained by efficient cell design and the use of nonflammable solid electrolytes, respectively. This paper presents a systematic study of experimental factors that affect the electrochemical performance of all-solid-state batteries. The morphological changes in composite electrodes fabricated using different mixing speeds are carefully observed, and the corresponding electrochemical performances are evaluated in symmetric cell and half-cell configurations. We also investigate the effect of the composite electrode thickness at different charge/discharge rates for the realization of all-solid-state batteries with high-energy-density. The results of this investigation confirm a consistent relationship between the cell capacity and the ionic resistance within the composite electrodes. Finally, a concentration-gradient composite electrode design is presented for enhanced power density in thick composite electrodes; it provides a promising route to improving the cell performance simply by composite electrode design.

• Tribology and Lubricants
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• 제31권3호
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• pp.79-85
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• 2015

RC delay is a critical issue for achieving high performance of ULSI devices. In order to minimize the RC delay time, we uses the CMP process to introduce high-conductivity Cu and low-k materials on the damascene. The low-k materials are generally soft and fragile, resulting in structure collapse during the conventional high-pressure CMP process. One troubleshooting method is electrochemical mechanical polishing (ECMP) which has the advantages of high removal rate, and low polishing pressure, resulting in a well-polished surface because of high removal rate, low polishing pressure, and well-polished surface, due to the electrochemical acceleration of the copper dissolution. This study analyzes an electrochemical state (active, passive, transpassive state) on a potentiodynamic curve using a three-electrode cell consisting of a working electrode (WE), counter electrode (CE), and reference electrode (RE) in a potentiostat to verify an electrochemical removal mechanism. This study also tries to find optimum conditions for ECMP through experimentation. Furthermore, during the low-pressure ECMP process, we investigate the effect of current density on surface roughness and removal rate through anodic oxidation, dissolution, and reaction with a chelating agent. In addition, according to the Faraday’s law, as the current density increases, the amount of oxidized and dissolved copper increases. Finally, we confirm that the surface roughness improves with polishing time, and the current decreases in this process.

• 전기의세계
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• 제22권2호
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• pp.57-69
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• 1973

The aim of this study was to investigate the behaviors of plasma jet under coaxial magnetic field in paralled with it for controlling optical characteristics and input power of plasma jet without impurity and instability of arc plasma column. Because the discharge characteristics of plasma jet were so distinctively different according to the existence or non-existence of magnetic field, the input power, luminous intensity of plasma jet and thermal efficiency were comparatively studied in respect of such variables as arc current, gap of electrode, quantity of argon flow, magnetic flux density, diameter and length of nozzle, with the use of several materials which were different in diameter and length of nozzel. The results were as follows; 1) The voltage tends to show a drooping characteristic at law current and then rises gradually. The luminous intensity of plasma jet increases exponentially with arc current. 2) Arc voltage increases and luminous intensity tends to decrease gradually as gap of electrode increases. 3) Arc voltage and luminous intensity tends to decrease gradually as gap of electrode increases. 3) Arc voltage and luminous intensity increase in accordance with the quantity of argon flow. 4) At first step, arc voltage increases to maximum value with the growth of flux density and then tends to show a gradual decrease. Luminous intensity decreases with the growth flux density. 5) Arc voltage decreases as the constriction length of nozzle increases, maximum decrease is shown at the constriction length of 20(mm) and it increases beyond that value. The luminous intensity decreases as the constriction length grows. 6) Arc voltage and luminous in tensity increase with the growth of diameters of nozzle. 7) Thermal efficiency has values between 50% and 75%, being influenced by arc current, the quantity of argon flow, flux density, the length of electrode gap and the constriction length of nozzle.

• 한국전기전자재료학회논문지
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• 제19권10호
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• pp.912-917
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• 2006

In this paper, Trench emitter electrode IGBT structure is proposed and studied numerically using the device simulator, MEDICI. The breakdown voltage, on-state voltage drop, latch up current density and turn-off time of the proposed structure are compared with those of the conventional trench gate IGBT(TIGBT) structures. Enhancement of the breakdown voltage by 19 % is obtained in the proposed structure due to dispersion of electric field at the edge of the bottom trench gate by trench emitter electrode. In addition, the on-state voltage drop and the latch up current density are improved by 25 %, 16 % respectively. However increase of turn-off time in proposed structures are negligible.

• 대한화학회지
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• 제15권6호
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• pp.324-329
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• 1971

In order to evaluate the mechanism of electrolytic oxidation of iodate and to determine the optimum conditions for the electrolysis, studies were made using the cells without diaphragm and the lead peroxide anode. Results are summarized as followings: 1) Current density vs. anode potential curve by lead peroxide electrode had the different limiting current densities from platinum electrode and was more positive than platinum electrode. 2) Additions of potassium bichromate in the electrolyte contribute to maintain high current efficiency. 3) In the acid and alkaline regions, the current efficiencies decreased by reduction of iodate and discharge of hydroxyl ion, so maximum current efficiency was shown at pH 7. 4) Higher current density lowered the current efficiency in the region of 60-80% conversion of iodate. 5) Influence of the conversion on current efficiency in the region of 60-80% conversion of iodate.

• Bulletin of the Korean Chemical Society
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• 제32권2호
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• pp.571-575
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• 2011

Graphite-based electrodes were prepared using synthetic graphite (MCMB 1028) or natural graphite (NG) powder using a dimensionally stable anode (DSA) as a substrate. Their electrochemical properties were investigated in vanadiumbased electrolytes to determine how to increase the durability and improve the energy efficiency of redox flow batteries. Cyclic voltammetry (CV) was performed in the voltage range of -0.7 V to 1.6 V vs. SCE at various scan rates to analyze the vanadium redox reaction. The graphite-based electrodes showed a fast redox reaction and good reversibility in a highly concentrated acidic electrolyte. The increased electrochemical activity of the NG-based electrode for the $V^{4+}/V^{5+}$ redox reaction can be attributed to the increased surface concentration of functional groups from the addition of conductive material that served as a catalyst. Therefore, it is expected that this electrode can be used to increase the power density and energy density of redox flow batteries.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2008년도 제39회 하계학술대회
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• pp.1197-1198
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• 2008

There have been few papers using finite element method(FEM) to analyze arc driving force for spiral type vacuum interrupter electrode up to date while there have been many papers dealing with AMF type electrode by means of FEM. AMF analysis is very important in AMF type electrode because it has proportional relation with effective area which means the area of magnetic flux density above critical magnetic flux density to diffuse arc. In the same manner, arc driving force is an important factor to drive arc by Lorentz force. In this paper two models were calculated and compared by using commercial FEM software Maxwell 3D.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 하계학술대회 논문집 C
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• pp.1658-1661
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• 2002

Up to now, one of the most serious problems in AC PDP is low luminous efficiency. One possible candidate for solving such problem is using high density Xe. But an increase of the Xe percentage cause rising of the driving voltage and so even if brightness is being increased, luminous efficiency is decreased. In this study, to solve this problem, we proposed new electrode structure. A test panel fabricated using new electrode shows an improvement of efficiency by 25% and a lowering of sustain voltage by 20% compared with the conventioned structure.

• 대한안전경영과학회:학술대회논문집
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• 대한안전경영과학회 2003년도 추계학술대회
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• pp.335-343
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• 2003

In the electrode fabrication of unit cell, it was ascertained that electrochemical characteristics were greatly increased with 90 wt.% of BP-20, 5 wt.% of Super P and 5 wt.% of mixed binder [P(VdF-co-HFP) : PVP =7 : 3] The self-discharge of unit cell showed that diffusion process was controlled by the ion concentration difference of initial electrolyte due to the characteristics of Electric Double Layer Capacitor (EDLC) charged by ion adsorption in the beginning, but this by current leakage through the double-layer at the electrode/electrolyte interface had a minor effect and voltages of curves were remained constant regardless of electrode material. The electrochemical characteristics of 2.3 V/3,000 F grade EDLC were as follows: 0.35 m of DC-ESR (100 A discharge), 0.14 mof AC-ESR (AC amplitude 100 mV), 2.80 Wh/kg (3.73 Wh/L) of energy density and 4.64 kW /kg (6.19 kW/L) of power density. Power output was compatible with electric vehicle applications, uninterrupted power supply and engine starter, in due consideration of Ragone relations.