• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.659-662
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• 2005

Electrochemical impedance spectroscopy (EIS) has been extensively used to try to evaluate the corrosion state of the steel/concrete system. This technique is attractive because, in theory, used in a wide range of frequencies, it can give detailed information about the mechanisms and kinetics of the electrochemical reactions. Impedance measurements were performed using potential control and measuring the corresponding current response. One-year-old southern exposure test. specimens were used in the current study. The effectiveness of corrosion inhibiting additives was evaluated. The corrosion current densities estimated by impedance measurements were confirmed by those determined using linear polarization techniques. The purpose of this study was to evaluate the long-term-performance potential of the corrosion inhibitors in chloride contaminated reinforce concrete.

• 한국세라믹학회지
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• 제54권5호
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• pp.413-421
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• 2017

In this work, we studied a fluorite structure oxides: Yttria stabilized zirconia, (YSZ); Gd doped $CeO_2$ (GDC); erbia stabilized $Bi_2O_3$ (ESB); Zr doped erbia stabilized $Bi_2O_3$ (ZESB); Ca doped erbia stabilized $Bi_2O_3$ (CESB) in the temperature range of 250 to $600^{\circ}C$ using electrochemical impedance spectroscopy (EIS). As is well known, grain boundary blocking effect was observed in YSZ and GDC. However, there is no grain boundary effect on ESB, ZESB, and CESB. The Nyquist plots of these materials exhibit a single arc at low temperature. This means that there is no space charge effect on ${\delta}-Bi_2O_3$. In addition, impedance data were analyzed by using the brick layer model. We indirectly demonstrate that grain boundary ionic conductivity is similar to or even higher than bulk ionic conductivity on cubic bismuth oxide.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2007년도 제38회 하계학술대회
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• pp.274-275
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• 2007

The investigation of the equivalent circuit models for the electrode/electrolyte interface has been pursued for a long time by several researchers. Previous circuit models fit the experimental results in limited conditions such as frequency range, type of electrode, or electrolyte. This paper describes a new electrical circuit model and its capability of fitting the experimental results. Electrochemical impedance spectroscopy was used to characterize the interface for Au, Pt, and stainless steel electrode in 0.9% NaCl solution. Both the proposed model and the previous model were applied to fit the measured impedance results for comparison. The proposed model fits the experimental data more accurately than other models especially at the low frequency range, and it enables us to predict the impedance at very low frequency range, including DC, using the proposed model.

• 방사성폐기물학회지
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• 제18권1호
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• pp.1-18
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• 2020

Molten salt solutions consisting of eutectic LiCl-KCl and concentrations of samarium chloride (0.5 to 3.0 wt%) at 500℃ were analyzed using both cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The CV technique gave the average diffusion coefficient for Sm³⁺ over the concentration range. Equipped with Sm³⁺ diffusion coefficient, the Randles-Sevcik equation predicted Sm³⁺ concentration values that agree with the given experimental values. From CV measurements; the anodic, cathodic, and half-peak potentials were identified and subsequently used as a parameter to acquire EIS spectra. A six-element Voigt model was used to model the EIS data in terms of resistance-time constant pairs. The lowest resistances were observed at the half-peak potential with the associated resistance-time constant pairs characterizing the reversible reaction between Sm³⁺ and Sm²⁺. By extrapolation, the Voigt model estimated the polarization resistance and established a polarization resistance-concentration relationship.

• Corrosion Science and Technology
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• 제16권6호
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• pp.298-304
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• 2017

Coil spring steels from the automobile suspension part after field exposure for 10 years and those after anti-corrosion validation test in proving ground of 5,000 ~ 10,000 km were examined for corrosion damages. Partial loss of paint, accumulation of corrosion product, and cracking of paint and superficial material were observed. The surface and subsurface region of spring steels had compressive residual stress and high hardness by shot peening. The surface hardness values of the specimens were 620 ~ 670 Hv. They were 60 ~ 80 Hv higher than those of the samples taken from the middle part of the spring. The maximum compressive stress was -916 ~ -1208 MPa measured at depth of about $100{\mu}m$. Electrochemical impedance spectroscopy showed that the resistances of charge transfer and the paint layer of the spring steels ranged from several tens to millions ${\Omega}{\cdot}cm^2$. The resistance of the field samples was much higher than that of the proving ground samples used in this study, implying that the proving ground test condition would be more corrosive than the field environment.

• 전력전자학회논문지
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• 제14권3호
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• pp.188-196
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• 2009

슈퍼커패시터는 전력밀도가 높고 사이클 수명이 길며 깨끗한 특성으로 인해 신재생에너지원의 동특성 보상 및 배터리의 동작시간이나 수명연장을 목적으로 널리 사용되고 있다. 본 논문에서는 개선된 슈퍼커패시터의 동특성 모델을 전기화학적 임피던스 분광법(Electrochemical Impedance Spectroscopy)을 이용하여 개발한다. 개발된 모델은 슈퍼커패시터의 정확한 동적 행동을 예측하거나 특정 충전상태(State-Of-Charge)에서의 정확한 정전용량 값을 계산하는데 사용될 수 있다. 주파수영역에서 개발된 모델은 Matlab/Simulink 시뮬레이션을 위하여 시간영역으로 등가 변환된다. 시뮬레이션 결과는 실험 결과와 일치하였으며, 이를 통해 개발된 모델의 유용함과 정확성을 증명하였다.

• Corrosion Science and Technology
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• 제17권6호
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• pp.257-264
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• 2018

Anti-graffiti coatings have become more important. These layers must guarantee excellent corrosion protection properties, and graffiti must be easily removable, without reducing protection and aesthetic properties. In this study, anti-graffiti and corrosion behavior of two anti-graffiti polyurethane powder coatings were studied. These layers were deposited on aluminum substrate, with two different surface finishes, smooth, and wrinkled. The action of four different removers are investigated. Graffiti were drawn on coatings by means of red acrylic spray paint. Methyl-ethyl-ketone (MEK) and a "commercial" remover were the most effective solvents, in terms of graffiti removal capability, producing limited change in aesthetical surface aspect for smooth finishing. The wrinkled surface was less resistant. Corrosion protection properties, after removal action and contact with the remover, were evaluate by electrochemical impedance spectroscopy. After approximately 5 hours, coatings were no longer protective due to formation of defects. To simulate the weathering effect, UV-B cyclic test (4 hours of UV exposure followed by 4 hours of saturated humidity at $50^{\circ}C$) were performed for 2000 hours. Gloss and color changes were measured, and electrochemical impedance spectroscopy measurements were performed after aging and graffiti removal.

• Journal of Power Electronics
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• 제11권2호
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• pp.237-243
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• 2011

Lithium batteries are widely used in mobile electronic devices due to their higher voltage and energy density, lighter weight and longer life cycle when compared to other secondary batteries. In particular, a high demand for lithium batteries is expected for electric cars. In the case of the lithium batteries used in electric cars, driving distance must be calculated accurately and discharging should not be done below a level that makes it impossible to crank. Therefore, accurate information on the state-of-charge (SOC) becomes an essential element for reliable driving. In this paper, a novel method for estimating the SOC of lithium polymer batteries using AC impedance is proposed. In the proposed method, the parameters are extracted by fitting the measured impedance spectrum on an equivalent impedance model and the variation in the parameter values at each SOC is used to estimate the SOC. Also to shorten the long length of time required for the measurement of the impedance spectrum, a novel method is proposed that can extract the equivalent impedance model parameters of lithium polymer batteries with the impedance measured at only two specific frequencies. Experiments are conducted on lithium polymer batteries, with similar capacities, made by different manufacturers to prove the validity of the proposed method.

• Journal of Electrochemical Science and Technology
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• 제13권4호
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• pp.462-471
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• 2022

In this study, the electrochemical impedance characteristics of CO₂/H₂O co-reduction to produce CO/H₂ syngas were investigated in a low-temperature single cell. The effect of the operating conditions on the single-cell performance was evaluated at different feed concentrations and cell voltages, and the corresponding electrochemical impedance spectroscopy (EIS) data were collected and analyzed. The Nyquist plots exhibited two semicircles with separated characteristic frequencies of approximately 1 kHz and tens of Hz. The high-frequency semicircles, which depend only on the catholyte concentration, could be correlated to the charge transfer processes in competitive CO₂ reduction and hydrogen evolution reactions at the cathodes. The EIS characteristics of the CO₂/H₂O co-reduction single cell could be explained by the equivalent circuit suggested in this study. In this circuit, the cathodic mass transfer and anodic charge transfer processes are collectively represented by a parallel combination of resistance and a constant phase element to show low-frequency semicircles. Through nonlinear fitting using the equivalent circuit, the parameters for each electrochemical element, such as polarization resistances for high- and low-frequency processes, could be quantified as functions of feed concentration and cell voltage.

• 대한화학회지
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• 제57권5호
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• pp.533-539
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• 2013

변전위법과 전기화학 임피던스 측정법을 이용하여 borate 완충용액에서 니켈 회전원판전극의 전기화학적 부식과 부동화를 연구하였다. Tafel 기울기, 임피던스, 회전원판전극의 회전속도, 그리고 부식전위와 부식전류의 pH 의존성으로부터 니켈의 부식과 부동화 반응 메커니즘과 환원반응에서의 수소 발생 반응구조를 제안하였다. EIS data로부터 등가회로를 제안하였으며 산화반응의 영역별로 전기화학적 변수들을 측정하였다. 부동화 반응에 의하여 생성된 $Ni(OH)_2$ 산화피막은 전기장의 영향을 받는 탈수반응에 의해 NiO로 전환되는 것으로 보인다.