• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.281-285
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• 2001

This technology Provides an economical Production of high value added goods applicable to electro chemicals by recycling of waste products in EGL(Electro Galvanizing Line). The waste products produced in EGL contain potassium chloride (KCI), nickel and zinc. Highly pure KCI and Zinc Chloride which are raw material of electro plating, can be produced by the development of the recycling process. The scope of this study ranges from laboratory experiments to pilot test in plant. We have developed the whole process of recycling technology such as purification method of waste products, fabrication methods of electro chemicals, basic design of plant, pilot scale production and evaluation of pilot goods, Developed electro chemicals were pure enough to satisfy the specification of steel company.

• Corrosion Science and Technology
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• v.22 no.5
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• pp.341-350
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• 2023

In the present study, effects of a thin Zn-flash coating on hydrogen evolution, infusion, and embrittlement of advanced high strength steel during electro-galvanizing were examined. The electrochemical permeation technique in conjunction with impedance spectroscopy was employed under applied cathodic polarization. Moreover, a slow-strain rate test was conducted to evaluate loss of elongation (i.e., indicative of hydrogen embrittlement (HE)) and examine fracture surfaces. Results showed that the presence of a thin Zn-flash coating, even when it was not distributed uniformly, reduced hydrogen evolution rate and substantially impeded infusion of hydrogen into the steel substrate. This was primarily due to a hydrogen overvoltage on Zn coating and trapping of hydrogen at the interface of Zn coating/flash coating/steel substrate. Consequently, the sample with flash coating had a smaller HE index than the sample without flash coating. These results suggest that a thin Zn-flash coating could be an effective technical strategy for mitigating HE in advanced high-strength steels.

• Corrosion Science and Technology
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• v.17 no.2
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• pp.74-80
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• 2018

The electronic industries require environmentally-friendly and highly functional materials to enhance the quality of human life. Home appliances require insect repellent steels that work to protect household microwave ovens from incurring damage by insects such as fire ants and cockroaches in tropical regions. Thus, POSCO has developed new types of functional steels, coated with an array of organic-inorganic hybrid composites on the steel surface, to cover panels in microwave ovens and refrigerators. The composite solution uses a fine dispersion of hybrid solution with polymeric resin, inorganic and a pyrethroid additive in aqueous media. The hybrid composite solution coats the steel surface, by using a roll coater and is cured using an induction curing furnace on both the continuous galvanizing line and the electro-galvanizing line. The new steels were evaluated for quality performances, salt spray test for corrosion resistance and biological performance for both insect repellent and antimicrobial activity. The new steels with organic-inorganic composite coating exhibit extraordinarily biological functionalities, for both insect repellent and antimicrobial activities for short and long term tests. The composite-coating solution and experimental results are discussed and suggest that the molecular level dispersion of insecticide on the coating layer is key to biological functional performances.

• Corrosion Science and Technology
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• v.23 no.3
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• pp.215-220
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• 2024

Recently, the demand for Zn-Ni electrogalvanized steel sheets for home appliances and automobiles is increasing. Products should have a thick plating (30 to 40 g/m²) on both side with a thin thickness (≤ 0.8 mm) and the highest surface quality. By a high current density operation, current is concentrated in the edge part of the steel sheet, resulting in large surface dent defects due to dendritic plating. This can lead to a low productivity due to low line speed operation. To solve this problem, this study aimed to identify factors influencing dendritic plating. A cylindrical electroplating device was manufactured. Effects of cut edge shape and thickness of steel plate, current density, temperature, flow rate, electrolyte concentration, and pH on dendrite generation of Zn-Ni electroplating were examined. To investigate effect of edge shape of the steel sheet, the steel sheet was manufactured using three processing methods: shearing, polishing after shearing, and laser. Relative effects thickness and cut edge processing methods of the steel plate, current density, temperature, flow rate, electrolyte concentration, and pH of plating solution on dendrite plating were investigated. To prevent dendrite plating, an edge mask was manufactured and its application effect was investigated.

• Corrosion Science and Technology
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• v.14 no.5
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• pp.213-217
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• 2015

Recently, household electronic industries require environmentally-friendly and highly functional steels in order to enhance the quality of human life. Customers especially require both excellent corrosion and abrasion resistant anti-fingerprint steels for digital TV panels. Thus POSCO has developed new functional electro-galvanized steels, which have double coated layers with organic-inorganic composites on the zinc surface of the steel for usage as the bottom chassis panel of TVs. The inorganic solution for the bottom layer consists of inorganic phosphate, magnesium, and zirconium compounds with a small amount of epoxy binder, and affords both improved adhesion properties by chemical conversion reactions and corrosion resistance due to a self-healing effect. The composite solution for the top layer was prepared by fine dispersion of organic-inorganic ingredients that consist of a urethane modified polyacrylate polymer, hardener, silica sol and a titanium complex inhibitor in aqueous media. Both composite solutions were coated on the steel surface by using a roll coater and then cured through an induction furnace in the electro-galvanizing line. New anti-fingerprint steel was evaluated for quality performance through such procedures as the salt spray test for corrosion resistance, tribological test for abrasion resistance, and conductivity test for surface electric conductance regarding to both types of polymer resin and coating weight of composite solution. New composite coated anti-fingerprint steels afford both better corrosion resistance and abrasion properties compared to conventional anti-fingerprint steel that mainly consists of acrylate polymers. Detailed discussions of both composite solutions and experimental results suggest that urethane modifications of acrylate polymers of composite solutions play a key role in enhanced quality performances.

• Journal of the Korean Society for Precision Engineering
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• v.28 no.9
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• pp.1062-1069
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• 2011

In electro-galvanizing line to manufacture the electro-galvanized steel sheet, polishing system is required to maintain clean surface of conductor roll and to secure the quality of the steel sheet. At the same time, prediction and decision of the replacement cycle for felt material and its brush installed in the polishing system is also important because the brush is directly contacted on the conductor roll surface. In this study, the polishing system has been designed which the brush is repetitive translating according to the longitudinal direction of the conductor roll. Furthermore, the prediction on the wear-life of the felt material used for the brush is performed using the contact pressure extracted by finite element analysis. And to verify the predicted wear-life of the felt material, the experimental study is also carried out. From the comparison result between the predicted and the measured wear-life of the felt material, it is presented that the wear-life and the replacement cycle of the felt material are well predicted by considering a wear compensation factor, and the wear compensation factor is useful and reasonable.

• Corrosion Science and Technology
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• v.23 no.4
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• pp.302-309
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• 2024

The purpose of this study was to elucidate effects of a thin (tens to hundreds of nanometers) Ni-flash coating layer on hydrogen embrittlement (HE) and liquid metal embrittlement (LME) in ultra-high-strength electrogalvanized steel with a tensile strength of more than 1 GPa. Various experimental and analytical methods, including thermal desorption spectroscopy, slow strain rate testing, resistance spot welding, X-ray diffraction, and metallographic observation, were employed. Results showed that an increase in Ni target amount for flash coating resulted in a decrease in diffusible hydrogen content during electrogalvanizing, resulting in a significant decrease in HE sensitivity. Moreover, a Ni target amount of more than 1000 mg/m² drastically reduced the occurring frequency and average depth of LME. This reduction could be primarily attributed to formation of Zn-Ni intermetallic phases during the welding process that could inhibit liquefaction of intermetallic phases in the heat-affected zone. This study provides a desirable Ni target amount for Ni-flash coating on ultra-high-strength steels conducted in a continuous galvanizing line or a high-speed batch line to achieve high resistance to both HE and LME.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2013.05a
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• pp.149-149
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• 2013

본 연구에서는 선박, 자동차 및 가전 제품용 표면처리 강재 및 아연도금 소재를 대상으로 외관도장의 특성향상 방안에 대하여 검토하였다. 특히, 도장의 밀착성과 내충격성 향상을 위하여 제품의 소재특성으로부터 물리적 화학적 전처리와 인산염 피막처리 및 최종도장에 이르기까지 각 공정이 도장 특성에 미치는 영향을 분석하였다. 각 공정조건에 따라 처리한 도장특성 평가 결과에 의하면, 인산염 피막의 균일-미세한 분포가 도장의 밀착성과 내충격성 향상에 주요한 영향을 미친 것으로 확인되었다.

• Transactions of Materials Processing
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• v.6 no.2
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• pp.118-135
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• 1997

In order to analyze the deformation and residual curvature of steel sheets in the strip processing lines, a program for calculating curvature and work hardening of sheet was developed. Strip deformation caused by repeated bending under tension in the process lines was analyzed on the basis of the incremental-plasticity theory with the mixed hardenting model for the purpose of predicting the strip shape and the yield stress change. The developed calculation program was applied to predict curl and gutter of sheets within a 10% difference. The yield stress increment was also predicted with the similar accuracy. Application of the model to tension legvelling process showed that gutter could be controlled by intermesh and elongation. The yield stress increment in the electro-galvanizing line calculated by the developed program was found to be dependent on the yield strength, the applied tension and the diameter of the smallest roll.

• Journal of Surface Science and Engineering
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• v.31 no.5
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• pp.286-296
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• 1998

Galvannealing is becomming the main stream of the coating technology applied to automobile outer and inner panels due to its low cost and easy application applied to automobile outer and inner panels due to its low cost and easy application in thick Zn coating, compared to electro galvanizing. Despite of filed up data with an experience in this field, galvannealing in thick Zn coating is getting more difficult because of the absence of Fe deposition in Zn coating. As a result, it exhibits, with different steel sheet and grain size there is a proper temperature range which is good for the tarket coating thickness of galvannealing. In case of 1,200mm wide and 0.77 mm thick extra low carbon steel with 20$mu extrm{m}$ grain size, its proper temperature range for galvannealing of one side 60g/$\textrm{m}^2$ is 470-$480^{\circ}C$.