• 한국재료학회지
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• 제26권9호
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• pp.472-477
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• 2016

Microstructure evolutions of thermosetting resin coating layers fabricated by electrostatic spray deposition (ESD) at various processing conditions were investigated. Two different typical polymer systems, a thermosetting phenol-formaldehyde resin and a thermoplastic polyvinylpyrrolidone (PVP), were employed for a comparative study. Precursor solutions of the phenol-formaldehyde resin and of the PVP were electro-sprayed on heated silicon substrates. Fundamental differences in the thermomechanical properties of the polymers resulted in distinct ways of microstructure evolution of the electro-sprayed polymer films. For the thermosetting polymer, phenol-formaldehyde resin, vertically aligned micro-rod structures developed when it was deposited by ESD under controlled processing conditions. Through extensive microstructure and thermal analyses, it was found that the vertically aligned micro-rod structures of phenol-formaldehyde resin were formed as a result of the rheological behavior of the thermosetting phenol-formaldehyde resin and the preferential landing phenomenon of the ESD method.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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• pp.857-863
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• 2017

본 논문은 다단연소사이클 엔진의 연소실 내벽을 고온, 고압의 환경으로부터 보호하기 위한 열차폐 코팅 공정 개발에 관한 내용이다. 기존 연소기 내벽에는 열차폐 특성이 우수한 Zr 기반의 세라믹용사코팅을 적용했지만, 세라믹의 특성상 연소실 내벽(금속)과 열팽창계수 차이로 인해 박리가 발생할 수 있다. 때문에 로켓 선진국에서는 열차폐 효과를 다소 희생 하더라도 밀착력 향상을 위하여 금속계 코팅인 Ni-Cr 도금을 적용하고 있다. 본 연구에서는 연소기에 적용 가능한 상향 순환식 유동셀을 적용한 도금조를 개발했으며, 반복적인 공정 개선을 통해 도금 두께 $100{\mu}m$이상, ${\pm}10%$의 두께 균일도를 만족하는 Ni, Cr 도금 공정조건을 확립했다.

• Corrosion Science and Technology
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• 제17권2호
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• pp.74-80
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• 2018

The electronic industries require environmentally-friendly and highly functional materials to enhance the quality of human life. Home appliances require insect repellent steels that work to protect household microwave ovens from incurring damage by insects such as fire ants and cockroaches in tropical regions. Thus, POSCO has developed new types of functional steels, coated with an array of organic-inorganic hybrid composites on the steel surface, to cover panels in microwave ovens and refrigerators. The composite solution uses a fine dispersion of hybrid solution with polymeric resin, inorganic and a pyrethroid additive in aqueous media. The hybrid composite solution coats the steel surface, by using a roll coater and is cured using an induction curing furnace on both the continuous galvanizing line and the electro-galvanizing line. The new steels were evaluated for quality performances, salt spray test for corrosion resistance and biological performance for both insect repellent and antimicrobial activity. The new steels with organic-inorganic composite coating exhibit extraordinarily biological functionalities, for both insect repellent and antimicrobial activities for short and long term tests. The composite-coating solution and experimental results are discussed and suggest that the molecular level dispersion of insecticide on the coating layer is key to biological functional performances.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2015년도 제46회 하계학술대회
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• pp.1153-1154
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• 2015

In this study, electro-polymerization was used for coating PEDOT:SDS films on CNTs, thereby producing hybrid-type electrodes. The CNTs were deposited on PET substrates using a spray method. For the fabricated hybrid electrodes, their surface morphologies, electric sheet resistances, visible transmittances, and chromatic properties were characterized as functions of the polymerization conditions used for coating PEDOT, and compared with those of conventional CNTs. The experiment results confirmed that the sheet resistance of CNTs was decreased significantly by coating of PEDOT via electropolymerization, and also indicated that the fabricated hybrid electrodes revealed desirable properties as a transparent electrode for touch screen panels.

• Corrosion Science and Technology
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• 제14권5호
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• pp.213-217
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• 2015

Recently, household electronic industries require environmentally-friendly and highly functional steels in order to enhance the quality of human life. Customers especially require both excellent corrosion and abrasion resistant anti-fingerprint steels for digital TV panels. Thus POSCO has developed new functional electro-galvanized steels, which have double coated layers with organic-inorganic composites on the zinc surface of the steel for usage as the bottom chassis panel of TVs. The inorganic solution for the bottom layer consists of inorganic phosphate, magnesium, and zirconium compounds with a small amount of epoxy binder, and affords both improved adhesion properties by chemical conversion reactions and corrosion resistance due to a self-healing effect. The composite solution for the top layer was prepared by fine dispersion of organic-inorganic ingredients that consist of a urethane modified polyacrylate polymer, hardener, silica sol and a titanium complex inhibitor in aqueous media. Both composite solutions were coated on the steel surface by using a roll coater and then cured through an induction furnace in the electro-galvanizing line. New anti-fingerprint steel was evaluated for quality performance through such procedures as the salt spray test for corrosion resistance, tribological test for abrasion resistance, and conductivity test for surface electric conductance regarding to both types of polymer resin and coating weight of composite solution. New composite coated anti-fingerprint steels afford both better corrosion resistance and abrasion properties compared to conventional anti-fingerprint steel that mainly consists of acrylate polymers. Detailed discussions of both composite solutions and experimental results suggest that urethane modifications of acrylate polymers of composite solutions play a key role in enhanced quality performances.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.124.2-124.2
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• 2016

Corrosion resistance and adhesion of electro-paint (E-paint) with fluoride conversion coating (FCC) on AZ31 Mg alloy were studied. Corrosion resistance and adhesion were studied as a function of FCC-treatment time and concentration of FCC-bath. Aqueous hydrogen fluoride (HF) solutions, with concentrations ranging from 0.5 M to 5 M, were used to form FCC on chemically polished AZ31 Mg alloy samples for six different times; 10, 30, 60, 90, 120, and 180s. The results from salt spray test (SST) showed that corrosion resistance of E-paint appeared to decrease with increasing FCC treatment times in low concentration FCC baths. The number of blisters formed on the FCC-treated samples increased with increasing FCC treatment time of more than 1 min in low concentration (0.5 M to 1 M) solutions. On the other hand, samples treated in the 5 M HF solution for 120s showed no delamination or blistering even after 1200h of SST.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 봄 학술논문 발표대회
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• pp.67-68
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• 2021

Social infrastructure facilities can be destroyed instantly when exposed to EMP (ElectroMagnetic Pulse), causing social chaos. However, concrete structures with low electrical conductivity cannot expect EMP shielding effect. Therefore, in this study, a metal sprayed thin film showing excellent EMP shielding performance was applied to a concrete structure to evaluate the metal spray welding efficiency and adhesion performance of the thin film according to the concrete surface treatment method. As a result according to the concrete surface treatment method, It was confirmed that the use of a roughening agent that generates physical irregularities in order to improve the welding efficiency and adhesion performance increases the physical performance of the concrete and metal sprayed thin film.

• 공업화학
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• 제31권5호
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• pp.502-508
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• 2020

Dual drug-eluting stents (DES) is a primary treatment method for coronary arterial diseases in current interventional cardiology practice. However, their pathological results according to the sequence of coating of drugs have not been reported yet. The peptide-dopamine dissolved in acetonitrile was coated onto the Chonnam National University Hospital (CNUH) stent using an electrospinning coating machine. For secondary coating (e.g., sirolimus coating, designated as SPS), sirolimus (SRL) and poly lactic-glycolic acid (PLGA) were mixed in tetrahydrofuran (THF), and the solution was then coated on the CNUH stent that had underwent the primary peptide coating using an electrospinning and spray technique. Next, the peptide-dopamine was coated on the SRL-PLGA coated stent (PSS). In this study, it was confirmed that endothelialization was promoted without being significantly affected by the coating order (SPS or PSS). The sequence of drug and peptide coating may affect the development of restenosis and PSS was effective in the prevention of restenosis compared to that of using SPS.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.2067-2072
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• 2007

Understanding of the impinging behavior of an electrically charged spray is essential in determining appropriate operating conditions for electro-spraying of paints, surface coating materials and insecticides. In the present work, as an initial step, the wall impact of an electrically charged droplet has been experimentally investigated. The charged drops were directed on the surface of a paraffin wax, and the impinging behavior was visualized and recorded using a CCD camera to identify the impingement regime. The spread-rebound boundary for the charged drop turned out to be smaller compared to that for an electrically neutral droplet under the same surface condition. The shift of the transition criterion is considered to be due to the discrepancy between the maximum spread ratio of the electrically charged droplet and that of the neutral droplet.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.2995-3000
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• 2008

Understanding of the impinging behavior of an electrically charged spray is essential in determining appropriate operating conditions for electro-spraying of paints, surface coating materials and insecticides. In the present work, the wall impact behavior of an electrically charged drop has been investigated and compared with that of a neutral drop experimentally. The critical Sommerfeld number representing the spread-splash boundary for the charged drop impacting on the dielectric substrate turned out to be larger compared to that for the neutral drop with the same surface condition. The change of the transition boundary is due to the increase in the surface wettability of the drop on the substrate. However, with the electrically conducting substrates, the charging effect on the transition boundary appeared negligible. This is because the electric discharging time is much shorter than the time required for the flattened drop to reach its maximum extent.