• 제목/요약/키워드: Electrical potential energy

검색결과 550건 처리시간 0.027초

카바졸과 페노시아진을 이용한 염료감응형 태양전지의 염료 합성과 광적특성 (Synthesis and Photovoltaic Properties of Dendritic Photosensitizers containing Carbazole and Phenothiazine for Dye-sensitized Solar Cells)

  • 김명석;정대영;김재홍
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.89.1-89.1
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    • 2010
  • Since Gratzel and co-workers developed a new type of solar cell based on the nanocrystalline $TiO_2$ electrode, dye-sensitized solar cells (DSSCs) have attracted considerable attention on account of their high solar energy-to-conversion efficiencies (11%), their easy manufacturing process with low cost production compared to conventional p-n junction solar cells. The mechanism of DSSC is based on the injection of electrons from the photoexcited dye into the conduction band of nanocrystalline $TiO_2$. The oxidized dye is reduced by the hole injection process from either the hole counter or electrolyte. Thus, the electronic structures, such as HOMO, LUMO, and HOMO-LUMO gap, of dye molecule in DSSC are deeply related to the electron transfer by photoexcitation and redox potential. To date, high performance and good stability of DSSC based on Ru-dyes as a photosensitizer had been widely addressed in the literatures. DSSC with Ru-bipyridyl complexes (N3 and N719), and the black ruthenium dye have achieved power conversion efficiencies up to 11.2% and 10.4%, respectively. However, the Ru-dyes are facing the problem of manufacturing costs and environmental issues. In order to obtain even cheaper photosensitizers for DSSC, metal-free organic photosensitizers are strongly desired. Metal-free organic dyes offer superior molar extinction coefficients, low cost, and a diversity of molecular structures, compared to conventional Ru-dyes. Recently, novel photosensitizers such as coumarin, merocyanine, cyanine, indoline, hemicyanine, triphenylamine, dialkylaniline, bis(dimethylfluorenyl)-aminophenyl, phenothiazine, tetrahydroquinoline, and carbazole based dyes have achieved solar-to-electrical power conversion efficiencies up to 5-9%. On the other hand, organic dye molecules have large ${\pi}$-conjugated planner structures which would bring out strong molecular stacking in their solid-state and poor solubility in their media. It was well known that the molecular stacking of organic dyes could reduce the electron transfer pathway in opto-electronic devices, significantly. In this paper, we have studied on synthesis and characterization of dendritic organic dyes with different number of electron acceptor/anchoring moieties in the end of dendrimer. The photovoltaic performances and the incident photon-to-current (IPCE) of these dyes were measured to evaluate the effects of the dendritic strucuture on the open-circuit voltage and the short-circuit current.

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multi-chromophore를 가지는 유기염료의 DSSC 광전변환거동 (Photovoltaic Properties of Dendritic Photosensitizers containing multi-chromophore for Dye-sensitized Solar Cells)

  • 김명석;천종훈;정대영;김재홍
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.117.2-117.2
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    • 2011
  • Since Gratzel and co-workers developed a new type of solar cell based on the nanocrystalline TiO2 electrode, dye-sensitized solar cells (DSSCs) have attracted considerable attention on account of their high solar energy-to-conversion efficiencies (11%), their easy manufacturing process with low cost production compared to conventional p-n junction solar cells. The mechanism of DSSC is based on the injection of electrons from the photoexcited dye into the conduction band of nanocrystalline TiO2. The oxidized dye is reduced by the hole injection process from either the hole counter or electrolyte. Thus, the electronic structures, such as HOMO, LUMO, and HOMO-LUMO gap, of dye molecule in DSSC are deeply related to the electron transfer by photoexcitation and redox potential. To date, high performance and good stability of DSSC based on Ru-dyes as a photosensitizer had been widely addressed in the literatures. DSSC with Ru-bipyridyl complexes (N3 and N719), and the black ruthenium dye have achieved power conversion efficiencies up to 11.2% and 10.4%, respectively. However, the Ru-dyes are facing the problem of manufacturing costs and environmental issues. In order to obtain even cheaper photosensitizers for DSSC, metal-free organic photosensitizers are strongly desired. Metal-free organic dyes offer superior molar extinction coefficients, low cost, and a diversity of molecular structures, compared to conventional Ru-dyes. Recently, novel photosensitizers such as coumarin, merocyanine, cyanine, indoline, hemicyanine, triphenylamine, dialkylaniline, bis(dimethylfluorenyl)-aminophenyl, phenothiazine, tetrahydroquinoline, and carbazole based dyes have achieved solar-to-electrical power conversion efficiencies up to 5-9%. On the other hand, organic dye molecules have large ${\pi}$-conjugated planner structures which would bring out strong molecular stacking in their solid-state and poor solubility in their media. It was well known that the molecular stacking of organic dyes could reduce the electron transfer pathway in opto-electronic devices, significantly. In this paper, we have studied on synthesis and characterization of dendritic organic dyes with different number of electron acceptor/anchoring moieties in the end of dendrimer. The photovoltaic performances and the incident photon-to-current (IPCE) of these dyes were measured to evaluate the effects of the dendritic strucuture on the open-circuit voltage and the short-circuit current.

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전기자동차용 고신뢰성 파워모듈 패키징 기술 (Power Module Packaging Technology with Extended Reliability for Electric Vehicle Applications)

  • 윤정원;방정환;고용호;유세훈;김준기;이창우
    • 마이크로전자및패키징학회지
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    • 제21권4호
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    • pp.1-13
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    • 2014
  • The paper gives an overview of the concepts, basic requirements, and trends regarding packaging technologies of power modules in hybrid (HEV) and electric vehicles (EV). Power electronics is gaining more and more importance in the automotive sector due to the slow but steady progress of introducing partially or even fully electric powered vehicles. The demands for power electronic devices and systems are manifold, and concerns besides aspects such as energy efficiency, cooling and costs especially robustness and lifetime issues. Higher operation temperatures and the current density increase of new IGBT (Insulated Gate Bipolar Transistor) generations make it more and more complicated to meet the quality requirements for power electronic modules. Especially the increasing heat dissipation inside the silicon (Si) leads to maximum operation temperatures of nearly $200^{\circ}C$. As a result new packaging technologies are needed to face the demands of power modules in the future. Wide-band gap (WBG) semiconductors such as silicon carbide (SiC) or gallium nitride (GaN) have the potential to considerably enhance the energy efficiency and to reduce the weight of power electronic systems in EVs due to their improved electrical and thermal properties in comparison to Si based solutions. In this paper, we will introduce various package materials, advanced packaging technologies, heat dissipation and thermal management of advanced power modules with extended reliability for EV applications. In addition, SiC and GaN based WBG power modules will be introduced.

소형 풍력발전시스템의 직류전원 적용을 위한 운전제어 및 AC/DC변환 통합장치 개발 (Development of Operation Control and AC/DC Conversion Integrated Device for DC Power Application of Small Wind Power Generation System)

  • 홍경진
    • 한국인터넷방송통신학회논문지
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    • 제19권3호
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    • pp.179-184
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    • 2019
  • 전기가 부족한 개발도상국 같은 많은 나라에서는 Off Grid 형태의 소형풍력발전이 전력공급 문제를 해결하기 위한 효율적인 핵심 솔루션이다. 몇몇 국가에서는 전력계통의 확장과 전기가 부족한 지역의 감소로 소규모 풍력을 도시의 도로 조명, 모바일 통신 기지국, 양식업 및 해수 담수 등의 분야에 이용하기도 한다. 이런 변화에 따라 소형 풍력 산업 규모는 대규모 풍력보다 큰 잠재력이 기대되고 있다. 소형 풍력발전의 경우 발전기는 가변 속도로 제어되는 특성이 있으며 발전기에서 발생하는 전압 및 전류에는 많은 고조파 성분을 가지고 있다. 이를 해결하기 위해서 본 논문에서는 소형 풍력발전시스템의 직류전원 적용을 위한 운전제어 및 AC/DC 변환 통합장치를 제안하며 기존 AC to DC 컨버터는 단일 스위치를 갖는 3상 승압형 방식의 컨버터로서 인덕터 전류가 불연속모드로 제어되며, 입력전류의 고조파를 제거하여 단위역률을 갖는 특성을 갖는다. 제안된 컨버터는 입력단에 LCL 필터 및 3상 정류 승압형 컨버터, 계통연계를 위한 단상 풀브릿지 형태로 구성되어 있으며 에너지저장시스템(ESS) 기능이 부가된 제어 시스템으로 풍력발전을 이동 평준화 방식에 의해 급변하는 전력에 대해 계통 안정화를 추구할 수 있다.

LiF-${Li_2}O-{B_2}{O_3}-{P_2}{O_5}$계 유리고체전해질에 관한 연구 (Studies on LiF-${Li_2}O-{B_2}{O_3}-{P_2}{O_5}$ based Glassy Solid Electrolytes)

  • 박강석;강은태;김기원;한상목
    • 한국재료학회지
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    • 제3권6호
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    • pp.614-623
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    • 1993
  • 높은 알칼리량을 함유하는 LiF-$Li_{2}O-B_{2}O_{3}-P_{2}O_5$계 유리의 전기적 특성을 분석하였다. $Li_{+}$ 이온은 모두 전기전도에 기여하지 않으나 조성에 따른 전기전도도의 변동은 약전해질 모델을 따르지 않았다. 또한 이동이온의 농도를 구하는데 사용되는 승법칙(power law)의 적용이 가능하지 않았다. 이들 계에서 조성에 따른 전기전도도의 변동은 유리내에서의 이동 가능한 $Li^{+}$이온의 농도변화만으로 또는 이동도의 변화만으로는 설명할 수 없었다. 전도도의 향상은 $(B-O-P)^{o}$ 보다 $Li^{+}$이온의 확산에 부가적인 자리를 제공하는$(B-O-P)^-,di^-$, 및 metaborate가 형성된 것과 관련이 있었다. 전기전도성이 가장 좋은 조성의 $150^{\circ}C$에서의 전기전도도는 $2.43 \times 10^{-4}$S/cm였고 분해포텐샬은 5.94V, emf는 3.14V였고 에너지 밀도는 22Wh/Kg이었다.

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액정 디스플레이 배향막을 위한 이온빔 표면조사에 관한 연구 (Ion beam irradiation for surface modification of alignment layers in liquid crystal displays)

  • 오병윤;김병용;이강민;김영환;한정민;이상극;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 춘계학술대회 및 기술 세미나 논문집 디스플레이 광소자
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    • pp.41-41
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    • 2008
  • In general, polyimides (PIs) are used in alignment layers in liquid crystal displays (LCDs). The rubbing alignment technique has been widely used to align the LC molecules on the PI layer. Although this method is suitable for mass production of LCDs because of its simple process and high productivity, it has certain limitations. A rubbed PI surface includes debris left by the cloth, and the generation of electrostatic charges during the rubbing induces local defects, streaks, and a grating-like wavy surface due to nonuniform microgrooves that degrade the display resolution of computer displays and digital television. Additional washing and drying to remove the debris, and overwriting for multi-domain formation to improve the electro-optical characteristics such as the wide viewing angle, reduce the cost-effectiveness of the process. Therefore, an alternative to non-rubbing techniques without changing the LC alignment layer (i.e, PI) is proposed. The surface of LC alignment layers as a function of the ion beam (IE) energy was modified. Various pretilt angles were created on the IB-irradiated PI surfaces. After IB irradiation, the Ar ions did not change the morphology of the PI surface, indicating that the pretilt angle was not due to microgrooves. To verify the compositional behavior for the LC alignment, the chemical bonding states of the ill-irradiated PI surfaces were analyzed in detail by XPS. The chemical structure analysis showed that ability of LCs to align was due to the preferential orientation of the carbon network, which was caused by the breaking of C=O double bonds in the imide ring, parallel to the incident 18 direction. The potential of non-rubbing technology for fabricating display devices was further conformed by achieving the superior electro-optical characteristics, compared to rubbed PI.

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롤투롤 공정의 이해 및 동향 (Understanding and Trends of Roll-to-Roll Operation)

  • 하영우;김기환;임동찬
    • 한국전기전자재료학회논문지
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    • 제37권1호
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    • pp.36-42
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    • 2024
  • 롤투롤 공정은 제조 환경에서 필수적인 위치를 차지하고 있으며, 그 중요성은 수많은 산업에 걸쳐 반향을 일으키고 있다. 이 다목적 기술 플랫폼은 다양한 공정 방법을 포괄하고 광범위한 재료 범주를 수용하여 현대 생산의 초석이 되고 있다. 이 광범위한 영역에서 일반적으로 사용되는 두 가지 코팅 기술인 슬롯 다이와 그라비아 코팅 방식은 완벽한 코팅을 구현하는 정밀도와 효율성으로 각광받고 있다. 또한 건조 공정은 열 건조, 적외선(IR) 건조, 자외선(UV) 건조 방식에 크게 의존하여 재료를 액체 또는 반액체 상태에서 바로 사용할 수 있는 고체 제품으로 신속하게 전환한다. 롤투롤 공정의 중요성은 제조 공정을 간소화하고 비용을 절감하며 제품 품질을 향상시킬 수 있다는 점이 있다. 이 글에서는 이러한 일반적인 롤투롤 공정 방법의 복잡성에 대해 자세히 살펴봄으로써 이러한 중요성의 깊이를 파악하고자 한다. 엄격한 연구와 세심한 데이터 수집을 통해 이러한 기술이 다양한 산업을 형성하고 제조 세계를 발전시키는 데 중추적인 역할을 하는 것을 조명하고자 한다. 롤투롤 공정의 중요성을 이해함으로써 롤투롤 공정의 잠재력을 최대한 활용하고 생산 혁신과 우수성을 위한 기반을 마련할 수 있을 것이다.

Vertical Variation Doping 구조를 도입한 1.2 kV 4H-SiC MOSFET 최적화 (Optimization of 1.2 kV 4H-SiC MOSFETs with Vertical Variation Doping Structure)

  • 김예진;박승현;이태희;최지수;박세림;이건희;오종민;신원호;구상모
    • 한국전기전자재료학회논문지
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    • 제37권3호
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    • pp.332-336
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    • 2024
  • High-energy bandgap material silicon carbide (SiC) is gaining attention as a next-generation power semiconductor material, and in particular, SiC-based MOSFETs are developed as representative power semiconductors to increase the breakdown voltage (BV) of conventional planar structures. However, as the size of SJ (Super Junction) MOSFET devices decreases and the depth of pillars increases, it becomes challenging to uniformly form the doping concentration of pillars. Therefore, a structure with different doping concentrations segmented within the pillar is being researched. Using Silvaco TCAD simulation, a SJ VVD (vertical variation doping profile) MOSFET with three different doping concentrations in the pillar was studied. Simulations were conducted for the width of the pillar and the doping concentration of N-epi, revealing that as the width of the pillar increases, the depletion region widens, leading to an increase in on-specific resistance (Ron,sp) and breakdown voltage (BV). Additionally, as the doping concentration of N-epi increases, the number of carriers increases, and the depletion region narrows, resulting in a decrease in Ron,sp and BV. The optimized SJ VVD MOSFET exhibits a very high figure of merit (BFOM) of 13,400 KW/cm2, indicating excellent performance characteristics and suggesting its potential as a next-generation highperformance power device suitable for practical applications.

태양광 시스템의 냉각장치 개발 (Development of Solar Concentrator Cooling System)

  • 이희준;차귀수
    • 한국산학기술학회논문지
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    • 제15권7호
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    • pp.4463-4468
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    • 2014
  • 태양광 모듈 효율의 증가를 위해 렌즈나 반사판 등을 이용한 집광 시스템 개발이 활발하게 진행되고 있으며, 집광장치는 일반적으로 렌즈를 사용하거나 고집속비의 광학장치를 이용하여 태양광 추적형으로 설계하여 고집속화를 추구하고 있다. 그러나 집속비에 비례하여 열로 소산되는 에너지 밀도가 증가하므로, 고집속에 따른 태양전지 온도상승에 의한 태양전지 효율 저하를 방지하기 위해 집광장치의 냉각에 유의해야 한다. 본 논문에서는 이러한 여러 가지 제약 조건을 피하여, 저가격의 반사형 광학장치를 이용한 경제적인 저집광형 태양광 모듈 시스템을 연구 개발하였다. 일반모듈에 저집광장치를 사용하여 태양광 모듈의 발전효율을 증대 시키면서 집광으로 인해 발생하는 열을 냉각장치를 통해 방출하였다. 제안된 저집광형 냉각장치(MCS, Micro Cooling System)의 특징은 모세관력에 의한 자연 순환 방식으로서 외부 동력원이 불필요하며, 유체 상변환시의 잠열을 이용함으로써 고성능 냉각 구현이 가능하다. 117W 태양광 모듈에 반사판을 설치하고 냉각장치가 있는 모듈과 냉각장치가 없는 모듈을 비교 하였다. 냉각장치를 설치한 모듈에서의 발전량이 28% 증가하였다.

Processing Effects of Feeds in Swine - Review -

  • Chae, B.J.;Han, In K.
    • Asian-Australasian Journal of Animal Sciences
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    • 제11권5호
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    • pp.597-607
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    • 1998
  • Processing is generally employed to alter the physical and chemical properties of feeds used in pig diets, using hammer/roller mills, pellet mills and extruders/expanders. The reported optimum particle sizes of corn are approximately $500{\mu}m$, $500-700{\mu}m$, $400-600{\mu}m$, for nursery, growing-finishing, and breeder pigs respectively. Optimum particle size of grains are affected by diet complexity. There was a trend towards reducing particle size in order to increase ADG in pigs fed a simple diet, though such was not the case for pigs fed a complex diet. Uniformity of particle size also affects the nutritional values of swine feeds. Uniform particle sizes would consistently give greater nutrient digestibilities. In terms of pellet quality, it is reported that a higher incidence of fmes in pelleted feeds has a direct correlation with poorer feed conversion ratio in pigs. Particle and pellet sizes are also very important for pelleting in terms of grinding, digestibility, stomach ulceration and pellet durability. A particle size of $600{\mu}m$, or slightly less, seemed optimal for com in fmishing pigs, and the 5/32 in. diameter pellets supported the best efficiencies of gain during nursery and finishing phases. Extruder and/or expander processes would allow the feed industry an increased flexibility to utilize a wider spectrum of feed ingredients, and improve pellet quality of finished feeds. It would appear that extruded or expanded diets containing highly digestible ingredients have little effect on the growth performance of pigs, and the feeding values of the feeds over pelleted diets were not improved as pigs grew. The extruder or expander is much more effective than a pelletizer in salmonella control. Gastric ulcerations and/or keratinizations were consistently reported in pigs fed mash and processed diets containing finely ground grains, whereas carcass quality was not affected by diet processing methods such as pelleting, extruding or expanding. In corn- or sorghum-based diets, the electrical energy consumption is 4-5 times higher in the expanding than in the pelleting process. But the expander's processing cost was half of that shown by an extruder. Finally, the decision of which feed processing technology to adopt would depend on the processing cost, and any potential improvement in growth performance and digestibilities of nutrients should offset the increased operating and capital costs related to the extruder/expander technology over mash or pelleting processes in pigs.