• 제목/요약/키워드: Electrical conductivities

검색결과 293건 처리시간 0.028초

다공성 실리카 에어로겔을 이용한 복합단열재의 특성에 관한 연구 (A Study on Properties of Thermal Insulation Board Prepared by Porous Silica Aerogel)

  • 윤종국;구경완
    • 전기학회논문지
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    • 제61권9호
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    • pp.1362-1367
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    • 2012
  • High porous silica aerogel/polyurethane polymer composite was manufactured by cross-linking polymerization of polyurethane foaming process. The properties of microstructure, mechanical strength, and thermal properties were investigated for its various applications. The superhydrophobic silica aerogel powders were used for highly thermal insulation filler materials. The thermal conductivities can be resulted 0.07 W/mK to 0.13 W/mK, by decreasing the contents of silica aerogels in composite materials. It is found that the polymerization formulation by organic binders can be applied to heavy industires, building materials, and various industries.

N-docosyl pyridinium(TCNQ) LB막의 NO$_2$가스탐지 특성에 관한 연구 (A Study of The NO$_2$Gas Detect Properties of N-docosyl pyridinium(TCNQ) LB Film)

  • 유병호;조형근;김형석;이창희;김정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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    • pp.75-78
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    • 1994
  • Organic ultra thin films about 500${\AA}$ in thickness are fabricated by LB(Langmuir-Blodgett) technique and their gas detect properties are investigated. The LB films deposited are made of the specimen named as N-docosyl pyridinium(TCNQ) and the deposition is verified by capacitance conductivity measurement. From the study of gas detect properties with I-V characteristics and UV spectrum we have found that their conductivities were increased about 3 times of magnitude and peaks of UV spectrum were decreased.

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고효율 냉각용 나노분말/절연유 분산액의 제조 및 열전달특성 (Preparation and Heat Transfer Properties of Nanoparticle-in-Transformer Oil Dispersions as Advanced Energy-efficient Coolants)

  • 최철;오제명
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.81-82
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    • 2006
  • The purposes of the present study are to produce a high thermal efficient of oil-based nanofluids which can be used as ultra-high voltage transformer oil, and to investigate their thermal and physical properties under static and dynamic conditions. Three kinds of nanofluids are prepared by dispersing $Al_2O_3$ or AlN nanoparticles in transformer oil. The thermal conductivities of the nanoparticles-oil mixtures increase with temperature, particle volume concentration and thermal conductivity of solid particle itself. It was quite important to eliminate $H_2O$ as byproducts of esterification and excess oleic acid which did not form stable chemical bonds with powder surface to get high dispersion stability.

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Effect of post-annealing on single-walled carbon nanotubes synthesized by arc-discharge

  • Park, Suyoung;Choi, Sun-Woo;Jin, Changhyun
    • Journal of Ceramic Processing Research
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    • 제20권4호
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    • pp.388-394
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    • 2019
  • In this study, high-purity single-walled carbon nanotubes (SWCNTs) were prepared by removing the unreacted metal constituents and amorphous carbon impurities using a post-annealing process. Unlike conventional thermal processing techniques, this technique involved different gas atmospheres for efficient removal of impurities. A heat treatment was conducted in the presence of chlorine, oxygen, and chlorine + oxygen gases. The nanotubes demonstrated the best characteristics, when the heat treatment was conducted in the presence of a mixture of chlorine and oxygen gases. The scanning electron microscopy, transmission electron microscopy, ultraviolet absorbance, and sheet resistance measurements showed that the heat treatment process efficiently removed the unreacted metal and amorphous carbon impurities from the as-synthesized SWCNTs. The high-purity SWCNTs exhibited improved electrical conductivities. Such high-purity SWCNTs can be used in various carbon composites for improving the sensitivity of gas sensors.

$({\alpha}-Nb_2O_5)_{1-x^-}(PbO)_x$ 고용체의 전기전도도 (Study of the Electrical Conductivity of the $({\alpha}-Nb_2O_5)_{1-x^-}(PbO)_x$ Solid Solution)

  • 노권선;류광선;전종호;이성주;여철현
    • 대한화학회지
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    • 제35권6호
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    • pp.625-629
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    • 1991
  • Lead Oxide를 2.5, 5.0, 7.5 및 10.0 mol%를 함유하는 Niobium Oxide-Lead Oxide계의 전기전도도를 2.0${\times}$$10^{-1}$${\sim}$1.0${\times}$$10^{-5}$ atm의 산소 부분압력하에서 700${\sim}$$1100^{\circ}C$의 온도에서 측정하였다. 본 계의 전기전도도는 PbO mol%가 증가함에 따라 감소하며 $10^{-5}$${\sim}$$10^{-1}$ $ohm^{-1}$ $cm^{-1}$ 범위에서 변하였다. 전기전도도의 활성화에너지는 약 1.70 eV이다. 전기전도도의 산소 부분압력 의존성은 높은 산소 부분압력에서는 이온 및 전자 전도성을 가진 혼합 전도체이고 낮은 산소 부분압력에서는 산소 부분압력의 -1/4승에 비례하는 의존성을 가진 n-type 전자 전도성을 나타내고 있다. 그 계의 결합구조와 전기전도 메카니즘을 얻어진 데이타와 관련시켜 논의하였다.

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1 wt% Y2O3 첨가계 AlN 세라믹스의 소결 조건에 따른 전기전도도 (Effects of Sintering Conditions on the Electrical Conductivity of 1 wt% Y2O3-Doped AlN Ceramics)

  • 이원진;이성민;심광보;김형태
    • 한국세라믹학회지
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    • 제44권2호
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    • pp.116-123
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    • 2007
  • Electrical properties of AlN ceramics sintered with 1 wt% $Y_2O_3$ have been investigated. From the impedance spectroscopy, electrical conductivity of grain boundary was found to be much lower than that of grain. DC conductivity measurement showed the electrode polarization effects caused by blocking electrode. The heat-treatment at $1700^{\circ}C$ of the specimen sintered at $1850^{\circ}C$ transformed continuous pain boundary phases along triple boundary junctions into isolated particles in grain comers. The heat-treatment induced decreases both in grain and grain boundary conductivity, and in DC electrical conductivities. From the analysis on the transference number, ionic conductivity was shown to be more dominant than electron conductivity, which was due to ion compensation mechanism during oxygen incorporation into grain.

p-HP 고분자 LB초박막의 제작과 전기적 특성 (Electrical Properties and Fabrication of Ultra-thin Films using p-HP Polymer)

  • 유승엽;정상범;박재철;권영수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제51권7호
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    • pp.287-291
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    • 2002
  • We fabricated the crosslinked films using p-hexadecoxyphenol (p-HP), which is amphiphilic and can form polyion complexes with formaldehyde at the air-water interface. The behavior of polyion complexation at the air-water interface and the surface structure of LB films was investigated by Brewster angle microscope(BAM) and scanning Maxwell-stress microscope (SMM), respectively. Also, the electrical properties for crosslinking in phenol-formaldehyde LB films were investigated by measuring conductivity and dielectric constant. The conductivities of p-HP LB films are as follows: heat-treatment of 1% formaldehyde subphase(3.76$\times$10$^{-15}$ ~4.76$\times$10$^{-1}$5[S/cm])$\times$10$^{-14}$ ~1.74$\times$10$^{-14}$ [S/cm]). Also, relative dielectric constants of p-HP LB films were reduced from 6.76~7.84 (pure water) to 2.97~3.25 (heat-treatment of 1% formaldehyde subphase))

Al 치환이 BiCuOSe의 열전 특성에 미치는 영향 (The Effects of Al-substitution on Thermoelectric and Charge Transport Properties of BiCuOSe Compounds)

  • 안태호;임영수;서원선;박철희;박찬
    • 한국전기전자재료학회논문지
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    • 제28권12호
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    • pp.847-851
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    • 2015
  • The effects of Al-substitution on thermoelectric and charge transport properties of BiCuOSe compounds were investigated. The compounds were prepared by a solid-state reaction and consolidated by SPS (spark plasma sintering). In spite of the increase in the hole concentration with increasing Al amounts in BiCuOSe compound, the electrical conductivity at room temperature was kept constant due to the reduction of mobility. However, electrical conductivities of Al-substituted BiCuOSe compounds at elevated temperature (> 600 K) were higher than those of BiCuOSe, and this result was discussed in terms of it's the band gap energy. The Seebeck coefficient was drastically reduced when Al was substituted in Bi site, which indicated that the electronic structure was influenced by the Al-substitution into Bi-site.

초음파 스프레이 코팅과 레이저 소결 공정에 의해 유연 기판 표면에 형성된 탄소나노튜브-구리 하이브리드 박막 (Carbon Nanotube-Copper Hybrid Thin Film on Flexible Substrate fabricated by Ultrasonic Spray Coating and Laser Sintering Process)

  • 박채원;권진형;엄현진
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2016년도 추계학술대회 논문집
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    • pp.135-135
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    • 2016
  • Recently flexible electrode materials have attracted attention in various electrical devices. In general, copper(Cu) is widely used electrical conductive material. However, Cu film showed drastically reduction of electrical conductivities under an applied tensile strain of 10%. These poor mechanical characteristics of Cu have difficulty applying in flexible electronic applications. In this study, mechanical flexibilities of Cu thin film were improved by hybridization with carbon nanotubes(CNTs) and laser sintering. First, thin carbon nanotube films were fabricated on a flexible polyethylene terephthalate(PET) substrate by using ultrasonic spray coating of CNT dispersed solution. After then, physically connected CNT-Cu NPs films were formed by utilizing ultrasonic spray coating of Cu nanoparticles dispersed solution on prepared CNT thin films. Finally, CNT-Cu thin films were firmly connected by laser sintering. Therefore, electrical stabilities under mechanical stress of CNT-Cu hybrid thin films were compared with Cu thin films fabricated under same conditions to confirm improvement of mechanical flexibilities by hybridization of CNT and Cu NPs.

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Dependences on Heating Conditions and Applicabilities as an Additive for ECIA of Sr1-xBaxFe3+1-ΤFe4+ ΤO3-y Ferrite System

  • Lee, Eun-Seok
    • Bulletin of the Korean Chemical Society
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    • 제25권6호
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    • pp.859-864
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    • 2004
  • The solid solutions of the $Sr_{1-x}Ba_xFeO_{3-y)$ system (x = 0.0, 0.1, 0.2 and 0.3) having a perovskite structure were prepared in air at 1423 K and then heat-treated in air (A), $O_2(O)\;and\;N_2(N)$ to examine possibility of controlling the nonstoichiometry and applicability as an additive for electrical conducting inorganic adhesives (ECIA). In the samples heated in $N_2$ stream, there existed almost no $Fe^{4+}$ ions, and at constant temperature their electrical conductivities were considerably lower than those of the samples heat-treated in air or $O_2.\; Sr_{0.8}Ba_{0.2}Fe^{3+}_{0.49}Fe^{4+}_{0.51}O_{2.76}$ (SB2-A) whose $Fe^{3+}/Fe^{4+}$ ratio was nearly 1 (0.96) and whose conductivity values (1.04 $ohm^{-1}cm^{-1}$ at 283 K and 1.88 $ohm^{-1}cm^{-1}$ at 673 K) were higher than any other samples, was found to be the best additive for ECIA.