• 제목/요약/키워드: Electric double-layer

검색결과 262건 처리시간 0.023초

전기이중층 캐패시터 전극용 meso-pore구조의 미소구형 활성탄소 제조 (Preparation of Micro-spherical Activated Carbon with Meso-porous Structure for the Electrode Materials of Electric Double Layer Capacitor)

  • 엄의흠;이철태
    • 공업화학
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    • 제20권4호
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    • pp.396-401
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    • 2009
  • 전기이중층 캐패시터의 성능향상을 위한 전극물질로서 resorcinol-formaldehyde수지를 탄소원으로 사용하여 meso-pore 비율 52~64%의 기공특성을 지니며 직경 $2{\sim}10{\mu}m$의 미세구형 활성탄을 제조하였다. 이 활성탄을 전기이중층에 적용한 결과, meso-pore구조의 미세구형활성탄은 전하전달저항의 저감 및 충방전율 수용능력 향상에 효과적인 영향을 나타내어 전기이중층 캐패시터의 성능향상을 위한 효과적인 전극물질이 될 수 있음을 확인할 수 있었다.

EnhAnced Electric Double Layer Capacitance of New Poly Sodium 4-tyrenesulfonate Intercalated Graphene Oxide Electrodes

  • 정혜경
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.287.2-287.2
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    • 2013
  • We synthesized a new composite of poly sodium 4-styrenesulfonate intercalated graphene oxide for energy storage devices by controlling oxidation time in the synthesis of graphite oxide. Specific capacitance was improved from 20 F/g of the previous composites to 88 F/g of the new composite at the current density of 0.3 A/g. The capacitance retention was 94% after 3000 cycles, indicating that the new composites of high cyclic stability, prominent performance as electric double layer capacitor, and even low resistance could be an excellent carbon based electrode for further energy storage devices.

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전압형 컨버터와 EDLC의 협조 제어에 의한 직류전기철도 회생에너지 이용률 및 전압 제어 능력 향상 (Improving Regenerative Break Energy Efficiency and Voltage Regulation Capability of DC Electric Railway by Coordination of VSC and EDLC)

  • 전고운;유형준;박재세
    • 전기학회논문지
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    • 제64권1호
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    • pp.176-181
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    • 2015
  • In the DC electric railway system, the effective use of regenerative break energy is an important issue. Since regenerative break energy causes voltage rise or drop in the system, it should be also solved effectively. To solve the problems, applying electric double layer capacitor (EDLC) or voltage source converter (VSC) to the DC electric railway system has been studying. In this paper, the coordination of EDLC and VSC is proposed to solve the problem effectively with its coordinated control algorithm. The proposed method is tested to show its feasibility using Matlab/Simulink.

An Overview of the Activated Carbon Fibers for Electrochemical Applications

  • Lee Gyoung-Ja;Pyun Su-Il
    • 전기화학회지
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    • 제9권1호
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    • pp.10-18
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    • 2006
  • This article is concerned with the overview of the activated carbon fibers. Firstly, this review provides a comprehensive survey of the overall processes for the synthesis of the activated carbon fibers from the carbonaceous materials. Subsequently, the physicochemical properties such as pore structures and surface oxygen functional groups of the activated carbon fibers were discussed in detail. Finally, as electrochemical applications of the activated carbon fibers to electrode materials for electric double-layer capacitor (EDLC), the electrochemical characteristics of the activated carbon fiber electrodes and the various methods to improve the capacitance and rate capability were introduced. In particular, the effect of pore length distribution (PLD) on kinetics of double-layer charging/discharging was discussed based upon the experimental and theoretical results in our work. And then we discussed in detail the applications of the activated carbon fibers to adsorbent materials for purification of liquid and gas.

Cost-effective Power System with an Electronic Double Layer Capacitor for Reducing the Standby Power Consumption of Consumer Electronic Devices

  • Park, Kyung-Hwa;Yi, Kang-Hyun
    • Journal of Power Electronics
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    • 제13권3호
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    • pp.362-368
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    • 2013
  • Commercial home appliances using remotely controlled systems consume electric power while in standby mode to prepare for receiving a remote turn-on signal. The proposed power system can significantly reduce standby power consumption without increasing cost. Furthermore, since a Electronic Double Layer Capacitor (EDLC) is used as an auxiliary power storage element, the life cycle is longer and system reliability can be better than with existing approaches. When the energy of the EDLC is not sufficient for turning on the appliance, the power system charges the EDLC without affecting the main system. The proposed power system is verified with a commercial LCD TV and a 3.93mW standby consumption is obtained. This standby consumption can be regarded as zero standby equipment according to the IEC-62031 standard.

General Characteristic of Fractional Slot Double Layer Concentrated Winding Synchronous Machine

  • Seo, Un-Jae;Chun, Yon-Do;Choi, Jae-Hak;Chung, Shi-Uk;Han, Pil-Wan;Koo, Dae-Hyun
    • Journal of Electrical Engineering and Technology
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    • 제8권2호
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    • pp.282-287
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    • 2013
  • The concentrated winding configurations offer significant advantage for reducing end windings. These machines are generally used in low speed high torque application due to relatively low copper loss. However, numbers of fractional slot construction make the designer hard to properly choose pole and slot numbers for the certain application. This paper provides the general information of possible fractional slot concentrated double layer winding machine.

페놀계 활성탄소섬유 전극과 수용성 전해질을 사용하는 전기이중층 캐패시터의 비축전용량 특성 (Specific Capacitance Characteristics of Electric Double Layer Capacitors with Phenol Based Activated Carbon Fiber Electrodes and Aqueous Electrolytes)

  • 김종휘;안계혁;신경희;류민웅;김동국
    • 공업화학
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    • 제10권6호
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    • pp.814-821
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    • 1999
  • 고비표면적의 활성탄소섬유(ACF: activated carbon fiber)를 분극성 전극으로 이용한 전기이중층 캐패시터(electric double layer capacitor)의 단위 cell test를 통하여, ACF의 비표면적, 세공의 크기 및 전기전도도가 캐패시터의 비축전용량에 커다란 영향을 미치고 있음을 확인할 수 있었고, 전해질은 $H^+$ 이온을 함유한 $H_2SO_4$이 가장 좋은 축전용량을 나타내었으나, 집전체 부식 등의 문제로 인하여, 실용화에 있어서는 우수한 충방전 거동을 나타낸 KOH계 전해질이 적당한 것으로 확인되었다. 분극성 전극으로 사용되는 ACF를 탄화 또는 후활성화 등이 후처리를 통하여 비축전용량을 급격히 증가시킬수 있었고, 3만회까지의 연속 충방전 실험에서 전기이중층 캐패시터는 2차전지에서는 찾아 볼 수 없는 매우 높은 충방전 효율과 긴 사용수명을 가지는 것을 확인할 수 있었다.

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PVA-LiBF$_4$ 콤퍼지트 고체 전해질을 사용한 전기 이중층 커패시터의 특성 (Characteristics of Electric Doub1e Layer Capacitor using Polyvinylalcohol-Lithium Salts Solid Electrolyte)

  • 이운용;이광우;신달우;박흥우;임기조
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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    • pp.211-214
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    • 1998
  • The composite of polyvinylalcohol(PVA) and lithium salts(LiBF$_4$) is prepared for a solid-state electrolyte of electric double layer capacitor. The composite shows a good ionic conductivity. The solid-state electric double layer capacitor is made of PVA-LiBF$_4$ composite, activated carbon and etc.. As evaluation of characteristics of capacitor, capacitance change which measured by charge-discharge test with 2.2V~0V at 8$0^{\circ}C$ for 800 hours, was about 10%. The gravimetric and volumetric capacitance were 10.0 F/g~30.0 F/g and 16.0F/㎤~F/㎤, respectively.

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The Effect of External DC Electric Field on the Atmospheric Corrosion Behaviour of Zinc under a Thin Electrolyte Layer

  • Liang, Qinqin;YanYang, YanYang;Zhang, Junxi;Yuan, Xujie;Chen, Qimeng
    • Corrosion Science and Technology
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    • 제17권2호
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    • pp.54-59
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    • 2018
  • The effect of external DC electric field on atmospheric corrosion behavior of zinc under a thin electrolyte layer (TEL) was investigated by measuring open circuit potential (OCP), cathodic polarization curve, and electrochemical impedance spectroscopy (EIS). Results of OCP vs. time curves indicated that the application of external DC electric field resulted in a negative shift of OCP of zinc. Results of cathodic polarization curves measurement and EIS measurement showed that the reduction current of oxygen increased while charge transfer resistance ($R_{ct}$) decreased under the external DC electric field. Variation of OCP negative shift, reduction current of oxygen, and $R_{ct}$ increase with increasing of external DC electric field strength as well as the effect of external DC electric field on double-layer structure in the electrode/electrolyte interface and ions distribution in thin electrolyte layer were analyzed. All results showed that the external DC electric field could accelerate the corrosion of zinc under a thin electrolyte layer.

Unsteady Electroosmotic Channel Flows with the Nonoverlapped and Overlapped Electric Double Layers

  • Kang, Sang-Mo;Suh, Yong-Kweon
    • Journal of Mechanical Science and Technology
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    • 제20권12호
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    • pp.2250-2264
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    • 2006
  • In micro- and nanoflows, the Boltzmann distribution is valid only when the electric double layers (EDL's) are not overlapped and the ionic distributions establish an equilibrium state. The present study has numerically investigated unsteady two-dimensional fully-developed electroosmotic flows between two parallel flat plates in the nonoverlapped and overlapped EDL cases, without any assumption of the Boltzmann distribution. For the study, two kinds of unsteady flows are considered: one is the impulsive application of a constant electric field and the other is the application of a sinusoidally oscillating electric field. For the numerical simulations, the ionic-species and electric-field equations as well as the continuity and momentum ones are solved. Numerical simulations are successful in accurately predicting unsteady electroosmotic flows and ionic distributions. Results show that the nonoverlapped and overlapped cases are totally different in their basic characteristics. This study would contribute to further understanding unsteady electroosmotic flows in micro- and nanofluidic devices.