• Title/Summary/Keyword: Electric decomposition

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Experimence Study of Trace Water and Oxygen Impact on SF6 Decomposition Characteristics Under Partial Discharge

  • Zeng, Fuping;Tang, Ju;Xie, Yanbin;Zhou, Qian;Zhang, Chaohai
    • Journal of Electrical Engineering and Technology
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    • v.10 no.4
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    • pp.1786-1795
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    • 2015
  • It is common practice to identify the insulation faults of GIS through monitor the contents of SF6 decomposed components. Partial discharges (PD) could lead to the decomposition of SF6 dielectric, so new reactions usually occur in the mixture of the newly decomposed components including traces of H2O and O2. The new reactions also cause the decomposed components to differ due to the different amounts of H2O and O2 even under the same strength of PD. Thus, the accuracy of assessing the insulation faults is definitely influenced when using the concentration and corresponding change of decomposed components. In the present research, a needle-plate electrode was employed to simulate the PD event of a metal protrusion insulation fault for two main characteristic components SO2F2 and SOF2, and to carry out influence analysis of trace H2O and O2 on the characteristic components. The research shows that trace H2O has the capability of catching an F atom, which inhibits low-sulfide SFx from recombining into high-sulfide SF6. Thus, the amount of SOF2 strongly correlates to the amount of trace H2O, whereas the amount of SO2F2 is weakly related to trace H2O. Furthermore, the dilution effect of trace O2 on SOF2 obviously exceeds that of SO2F2.

Study on Combustion and Explosion Hazard of Rice Bran Dusts (쌀겨 분진의 연소 및 폭발 위험성에 관한 연구)

  • 이창우;현성호;이한철;허윤행
    • Journal of environmental and Sanitary engineering
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    • v.14 no.4
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    • pp.93-98
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    • 1999
  • We had investigated combustion properties of rice bran dusts. Decomposition of rice bran dusts with temperature were investigated using DSC and the weight loss according to temperature using TGA in order to find the thermal hazard of rice bran dusts, and the properties of dust explosion in variation of their dust with the same particle size. Using Hartman's dust explosion apparatus which estimate dust explosion by electric ignition after making dust disperse by compressed air, dust explosion experiments have been conducted by varying concentration and size of rice bran dust.According to the results for thermodynamic stability of rice bran dust, there are little change of initiation temperature of heat generation and heating value for used particle size. But initiation temperature of heat generation decreased with high heating rate whereas decomposition heat increased with particle size. Average maximum explosion pressure was $10kgf/cm^2$ for 60/70 mesh and $1.5mg/cm^2$ dust concentration.

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Corrective-mode based Security constrained Benders decomposition approach toward Preventive-mode Optimal Reactive Power Planning (안전도 제약 Benders 분해법을 적용한 예방모드 무효전력투입 최적화 방안)

  • Jeong, Jong-Hoon;Song, Hwa-Chang;Lee, Byoung-Jun;Kwon, Sae-Hyuk
    • Proceedings of the KIEE Conference
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    • 1999.11b
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    • pp.184-186
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    • 1999
  • This paper presents a method for security constrained optimal reactive power planning in electric power systems. This method deals with corrective mode optimal reactive power dispatch in each (n-1)contingency system state and determination of the location and amount of reactive sources in preventive mode. In this paper the proposed scheme uses Benders decomposition method to determine the proper amount and location of reactive support in order to maintain a proper voltage profile and minimize active power transmission losses. This method is tested on IEEE 30 bus test system to prove effectiveness.

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An Approach to Implementing Distributed Optimal Power Flow (최적조류계산의 분산처리기법에 관한 연구)

  • Kim, Ho-Woong;Kim, Bal-Ho;Kim, Jung-Hoon
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.182-186
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    • 1997
  • This paper presents a mathematical approach to implementing distributed optimal power flow (OPF), wherein a regional decomposition technique is adopted to parallelize the OPF. Three mathematical decomposition coordination methods are introduced firs to implement the proposed distributed scheme: the Auxiliary Problem Principle (APP), the Predictor-Corrector Proximal Multiplier Method (PCPM), and the Alternating Direction Method (ADM). Then two alternative schemes for modeling distributed OPF are introduced; the Dummy Generator-Dummy Generator (DGDG) scheme and Dummy Generator-Dummy Load (DGDL) scheme. We present the mathematical analyses of the proposed approach, and demonstrate the approach on several test, systems, including IEEE Reliability Test Systems and parts of the ERCOT (Electric Reliability Council of Texas) system.

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Influence on Relative Electrode Wear by Material and Size of Electrode (전극의 재료와 크기가 전극소모에 미치는 영향)

  • 전언찬
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.5
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    • pp.671-677
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    • 1999
  • This study has been performed to investigate REW(relative electrode wear) in condition of vari-ous pulse-on duration using the copper and graphite electrode with change of the electrode size on the heat treated STD11 which is extensively used for metallic molding steel with the EDM. The results obtained are as follows; a) Graphite has much benefits than copper electrode when rapid machining is done without electrode wear, b) Neative REW result from the electrode that is very liable attach to decomposition carbide c)Increasing of machining time cause to increase wear length of the copper electrode and decrease wear length of the graphite electorde d)The more pulse-on duration copper electrode has the less REW. e) The edge portion of the electorde wears remarkably at the beginning of machining,.

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Phase Transitions of $LiMn_2O_4$ on $CO_2$ Decomposition (($CO_2$ 분해시 $LiMn_2O_4$의 상변화)

  • Kwoen, Tae-Hwan;Yang, Chun-Mo;Park, Young-Goo;Cho, Young-Koo;Rim, Byung-O
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.1
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    • pp.33-43
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    • 2003
  • $LiMn_2O_4$ catalyst for $CO_2$ decomposition was synthesized by oxidation method for 30 min at 600$^{\circ}C$ in an electric furnace under air condition using manganese(II) nitrate $(Mn(NO_3)_2{\cdot}6H_2O)$, Lithium nitrate ($LiNO_3$) and Urea $(CO(NH_2)_2)$. The synthesized catalyst was reduced by $H_2$ at various temperatures for 3 hr. The reduction degree of the reduced catalysts were measured using the TGA. And then $CO_2$ decomposition rate was measured using the reduced catalysts. Phase-transitions of the catalysts were observed after $CO_2$ decomposition reaction at an optimal decomposition temperature. As the result of X-ray powder diffraction analysis, the synthesized catalyst was confirmed that the catalyst has the spinel structure, and also confirmed that when it was reduced by $H_2$, the phase of $LiMn_2O_4$ catalyst was transformed into $Li_2MnO_3$ and $Li_{1-2{\delta}}Mn_{2-{\delta}}O_{4-3{\delta}-{\delta}'}$ of tetragonal spinel phase. After $CO_2$ decomposition reaction, it was confirmed that the peak of $LiMn_2O_4$ of spinel phase. The optimal reduction temperature of the catalyst with $H_2$ was confirmed to be 450$^{\circ}C$(maximum weight-increasing ratio 9.47%) in the case of $LiMn_2O_4$ through the TGA analysis. Decomposition rate(%) using the $LiMn_2O_4$ catalyst showed the 67%. The crystal structure of the synthesized $LiMn_2O_4$ observed with a scanning electron microscope(SEM) shows cubic form. After reduction, $LiMn_2O_4$ catalyst became condensed each other to form interface. It was confirmed that after $CO_2$ decomposition, crystal structure of $LiMn_2O_4$ catalyst showed that its particle grew up more than that of reduction. Phase-transition by reduction and $CO_2$ decomposition ; $Li_2MnO_3$ and $Li_{1-2{\delta}}Mn_{2-{\delta}}O_{4-3{\delta}-{\delta}'}$ of tetragonal spinel phase at the first time of $CO_2$ decomposition appear like the same as the above contents. Phase-transition at $2{\sim}5$ time ; $Li_2MnO_3$ and $Li_{1-2{\delta}}Mn_{2-{\delta}}O_{4-3{\delta}-{\delta}'}$ of tetragonal spinel phase by reduction and $LiMn_2O_4$ of spinel phase after $CO_2$ decomposition appear like the same as the first time case. The result of the TGA analysis by catalyst reduction ; The first time, weight of reduced catalyst increased by 9.47%, for 2${\sim}$5 times, weight of reduced catalyst increased by average 2.3% But, in any time, there is little difference in the decomposition ratio of $CO_2$. That is to say, at the first time, it showed 67% in $CO_2$ decomposition rate and after 5 times reaction of $CO_2$ decomposition, it showed 67% nearly the same as the first time.

Atmospheric Pressure Plasma Treatment of Aqueous Bisphenol A Solution (비스페놀 A 수용액의 대기압 플라즈마 처리)

  • Jo, Jin-Oh;Choi, Kyeong Yun;Gim, Suji;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.311-318
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    • 2015
  • This work investigated the plasma treatment of aqueous bisphenol A (BPA) solution and mineralization pathways. For the effective contact between plasmatic gas and aqueous BPA solution, the plasma was created inside a porous ceramic tube, which was uniformly dispersed into the aqueous solution through micro-pores of the ceramic tube. Effects of the gas flow rate, applied voltage and treatment time on the decomposition of BPA were examined, and analyses using ultraviolet (UV) spectroscopy, ion chromatography and gas chromatography-mass spectrometry were also performed to elucidate mineralization mechanisms. The appropriate gas flow rate was around $1.0L\;min^{-1}$; when the gas flow rate was too high or too low, the BPA decomposition performance at a given electric power decreased. The increase in the voltage improves the BPA decomposition due to the increased electric power, but the energy required to remove BPA was similar, regardless of the voltage. Under the condition of $1.0L\;min^{-1}$ and 20.8 kV, BPA at an initial concentration of $10L\;min^{-1}$ (volume : 1 L) was successfully treated within 30 min. The intermediates produced by the attack of ozone and hydroxyl radicals on BPA were further oxidized to stable compounds such as acetate, formate and oxalate.

Rapid Heating Concepts in Sintering

  • German, Randall M.
    • Journal of Powder Materials
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    • v.20 no.2
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    • pp.85-99
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    • 2013
  • Powder metallurgy applied rapid heating to sintering starting year 1900. Since 1970 the study has intensified. Now rapid sintering concepts embrace a spectrum of options ranging from dunk cycles to microwave, induction, exothermic, electric field, and spark approaches. Most of the efforts are targeting reduced microstructure coarsening during sintering, although reduced material decomposition is another common goal. The efforts are impressive for simple shapes and success metrics such a small grain size after densification. Several barriers need to be removed prior to application in powder metallurgy commercial sintering. Rapid heating research needs to focus on significant property gains, accurate product dimensions, and lower costs. So far each property gain obtained with rapid heating is matched by traditional sintering and composition changes. Several examples are cited to show the goals for the next round of innovations.

Angle-Range-Polarization Estimation for Polarization Sensitive Bistatic FDA-MIMO Radar via PARAFAC Algorithm

  • Wang, Qingzhu;Yu, Dan;Zhu, Yihai
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.14 no.7
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    • pp.2879-2890
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    • 2020
  • In this paper, we study the estimation of angle, range and polarization parameters of a bistatic polarization sensitive frequency diverse array multiple-input multiple-output (PSFDA-MIMO) radar system. The application of polarization sensitive array in receiver is explored. A signal model of bistatic PSFDA-MIMO radar system is established. In order to utilize the multi-dimensional structure of array signals, the matched filtering radar data can be represented by a third-order tensor model. A joint estimation of the direction-of-departure (DOD), direction-of-arrival (DOA), range and polarization parameters based on parallel factor (PARAFAC) algorithm is proposed. The proposed algorithm does not need to search spectral peaks and singular value decomposition, and can obtain automatic pairing estimation. The method was compared with the existing methods, and the results show that the performance of the method is better. Therefore, the accuracy of the parameter estimation is further improved.