• Macromolecular Research
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• v.13 no.3
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• pp.223-228
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• 2005

In the present work, a low-density polyethylene (LDPE) composite, filled with Zn-ion coated structural silica encapsulated with the diglycidyl ether of bisphenol-A (DGEBA), was synthesized using the conventional melt-blending technique in a sigma internal mixer. The catalytic activity of the Zn-ions (originating from the structural silica) towards the oxirane group (diglycidyl ether of bisphenol-A (DGEBA): encapsulating agent) was assessed by infrared spectroscopy. Two composites, each with a filler content of $2.5 wt\%$ were developed. The first one was obtained by melt blending the Zn-ion coated structural silica with LDPE in a co-rotating sigma internal mixer. The second one was obtained by melt blending the same LDPE, but with DGEBA encapsulated Zn-ion coated structural silica. Epoxy resin encapsulation of the Zn-ion coated structural silica resulted in its having good interfacial adhesion and a homogeneous dispersion in the polymer matrix. Furthermore, the encapsulation of epoxy resin over the Zn-ion coated structural silica showed improvements in both the mechanical and thermal properties, viz. a $33\%$ increase in the elastic modulus and a rise in the onset degradation temperature from 355 to $371^{\circ}C$, in comparison to the Zn-ion coated structural silica.

• Korean Journal of Materials Research
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• v.11 no.12
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• pp.1009-1013
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• 2001

The effects of coupling agent on the interface characteristics between epoxy resin and natural zeolite were studied by SEM, optical microscope and universal testing machine (UTM). Epoxy resin as a matrix was diglycidyl ether of bisphenol A (DGEBA)/4,4'-methylene dianiline (MDA)/malononitrile (MN) system and natural zeolite as an inorganic fillet was produced in Korea. With the increment of zeolite content, tensile strength decreased and it was due to the different elastic moduli of two materials. When external stress was loaded on the composites, the stress concentrated on the weakly bonded interface and crack grew easily. To improve the interface characteristics, the surface of the natural zeolite was treated with the silane coupling agent and it was found that the tensile strength was increased. The morphology of the interface showed that the bonding characteristics were modified by coupling agent.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2004.10a
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• pp.438-441
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• 2004

In this study, we investigated compressive characteristics of seawater-absorbed carbon-epoxy composite under hydrostatic pressure environment. The hydrostatic pressures applied were 0.1 MPa, 100 MPa, 200 MPa, and 270 MPa. The results showed that the compressive elastic modulus increased about 10 ％ as the hydrostatic pressure increased from 0.1 MPa to 200 MPa. The modulus increased 2.3 ％ more as the pressure increased to 270 MPa. Fracture strength and fracture strain increased with pressure in a linear fashion. Fracture strength increased 28 ％ and fracture strain increased 8.5 ％ as the hydrostatic pressure increased from 0.1 MPa to 270 MPa.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.30 no.10
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• pp.641-645
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• 2017

In this study, an epoxy insulation barrier for high voltage GIS was developed using epoxy and a filler with a Young's modulus of 11 GPa. The material was investigated using a simulation of the principal stress, displacement, and safety factors while optimizing the profile shape. The simulation showed that thelarger Young's modulus of the $Al_2O_3$ filler compared to the $SiO_2$ in the epoxy insulation can contribute to an increase in resistance to mechanical fracturing for theoptimized profile barrier in high voltage GIS. In addition, the safety factor was improved by 10%. It can be concluded that the mechanical fracturing properties of the insulation barrier can be enhanced by increasing the content of the elastic filler, $Al_2O_3$, for high voltage GIS applications.

• The Korean Journal of Rheology
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• v.3 no.1
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• pp.22-29
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• 1991

In an effort to predict the long term durability of carbon fiber/epoxy composites in a space environ-ment interlaminar shear strength (ILSS) of the composites was measured as a function of 0.5 MeV electron radiation dosage. For the ILSS measurements a notch method (ASTM D3846) was used with and without side-supports. the supports were used to prevent peeling or bending during the test. The ILSS of both T300/ 5209 longitudinal composite system increases monotonically with radiation when the test is corried out without the support the ILSS of the composites increases initially but then decreases with further radiation. It is also observed that the ILSS of the unsupported case is much lower than that of the supported case. Measurement of epoxy modulus shows that the elastic modulus increases monotonically with radiation. But the breaking strength of the epoxy decreases with radiation. Electron Spectroscopy for Chemcal Analysis shows that the oxygen contents at both the pure epoxy surface and the composite fracture surface increase with radiation dose resulting in the increase of polarity at the interfacial region. This may be a supporting evidence for the increase in the ILSS of the composites.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.406-409
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• 2004

In this study, we investigated compressive characteristics of seawater-absorbed carbon-epoxy composite under hydrostatic pressure environment. The hydrostatic pressures applied were 0.1 MPa, 100 MPa, 200 MPa, and 270 MPa. The results showed that the compressive elastic modulus increased about 10 % as the hydrostatic pressure increased from 0.1 MPa to 200 MPa. The modulus increased 2.3 % more as the pressure increased to 270 MPa. Fracture strength and fracture strain increased with pressure in a linear fashion. Fracture strength increased 28 % and fracture strain increased 8.5 % as the hydrostatic pressure increased from 0.1 MPa to 270 MPa.

• Composites Research
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• v.12 no.1
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• pp.59-67
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• 1999

The effects of fiber waviness on tensile/compressive nonlinear elastic behaviors of graphite/epoxy unidirectional composite materials are studied theoretically and experimentally. New constitutive models are proposed to predict elastic properties and tensile/compressive nonlinear behaviors of composite materials. Three types of wavy pattern are considered: uniform, graded and localized fiber waviness. Complementary energy density and incremental method are used to incorporate the material and geometrical nonlinearities due to fiber waviness. Tensile/compressive tests are conducted on the specimens with fiber waviness. It is found that the predictions are in good agreement with the experimental results.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2001.05a
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• pp.1-4
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• 2001

A new non-destructive fatigue prediction model of the composite laminates is developed. The natural frequencies of fatigue-damaged laminates under extensional loading are related to the fatigue lift of the laminates by establishing the equivalent flexural stiffness reduction as a function of the elastic properties of sublaminates. The flexural stiffness is derived by relating the $90^{\circ}$-ply elastic modulus reduction, and using the laminate plate theory to the degraded elastic modulus and the intact elastic modulus of other laminate. The natural frequency reduction model, in which the dominant fatigue mode can be identified from the sensitivity scale factors of sublaminate elastic properties, provides natural frequency vs. fatigue cycle curves for the composite laminates. Vibration tests were also conducted on $[\textrm{90}_{2}\textrm{0}_{2}]_s$ carbon/epoxy laminates to verify the natural frequency reduction model. Correlations between the predictions of the model and experimental results are good.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.20 no.10
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• pp.3211-3223
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• 1996

In this paper, the propagation of elastic wave generated by loading impact to plates made of isotropic of anisotropic material was studied. And the influence of boundary conditions (free or clamped edge) upon the reflection of elastic wave was anlyzed. Also, double exposure holographic interferometer using ruby pulse laser was formed in order to investigate transient waves. Before the elasitc wave was reflected from the edges, the elastic wave of isotropic plate such as aluminum plate showed circular interferometric fringe pattern, whereas that of anisotropic plate such as epoxy composite laminates showed elliptical one. And the transverse displacement curves obtained from experiment and theory for both plates agreed well. Also, the waves reflected from the boundary edges showed much differences according to the boundary condition of edges.

• Composites Research
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• v.28 no.5
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• pp.260-264
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• 2015

In this paper, molecular dynamics (MD) simulation was carried to predict thermo-mechanical behaviors for carbon nanotube (CNT) reinforced epoxy composites and to analyze the trends. Total of six models having the volume fractions of CNT from 0 to 25% in epoxy were constructed. To predict thermal behaviors, temperature was increased constantly from 300 to 600 K, and the glass transition temperature ($T_g$) and coefficient of thermal expansion (CTE) analyzed using the relationship between temperature and specific volume. The elastic moduli that represented to the mechanical behaviors were also predicted by constant strain. Additionally, the effects of functionalization of CNT on mechanical behaviors of composite were analyzed. Models were constructed to represent CNTs functionalized by nitrogen doping and COOH groops, and interfacial behaviors and elastic moduli were analyzed. Results showed that the agglomerations of CNTs in epoxy cause by perturbations of thermo-mechanical behaviors, and the functionalization of CNTs improved the interfacial response as well as mechanical properties.