• Title/Summary/Keyword: Effects of Si

Search Result 3,603, Processing Time 0.034 seconds

Corrosion Behavior of Silicon Carbide/7091 Aluminum Matrix Composites (탄화규소/7091알루미늄 복합재료의 부식거동)

  • Kang, Wooseung
    • Corrosion Science and Technology
    • /
    • v.11 no.4
    • /
    • pp.108-111
    • /
    • 2012
  • The effects of volume fraction (15-30%) of SiC particulate reinforcements on the corrosion behavior of SiCp/7091 Al composites in the 3.5% NaCl solution were studied by electrochemical techniques and scanning electron microscopy. The results showed that the amount of SiC particulate reinforcements did not cause much difference in the corrosion behavior of SiCp/7091 Al composites but the corrosion rate was proportional to the amount of SiCp reinforcement. And numerous pits and severe dissolution of the matrix was observed probably due to the discontinuities and galvanic effects between Al matrix and SiC reinforcements.

Effects hydrogen ambients on the characteristics of poly-crystalline 3C-SiC thin films (수소 분위기가 다결정 3C-SiC 박막의 특성에 미치는 영향)

  • Kim, Kang-San;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.11a
    • /
    • pp.134-135
    • /
    • 2007
  • Growth of cubic SiC has been carried out on oxided Si substrate using atmospheric pressure chemical vapor deposition (APCVD). Hexamethyldisilane (HMDS) was used as the single precursor and nonflammable mixture of Ar and $H_2$ was used as carrier gas. Epitaxial growth had performed depositions under the various $H_2$ conditions which were adjusted from 0 to 100 seem. The effects of $H_2$ was characterized by surface roughness, thickness uniformity, films quality and elastic modulus. Thickness uniformity and films quality were performed by SEM. Surface roughness and elastic modulus were investigated by AFM and Nano-indentor, respectively. According to the $H_2$ flow rate, Poly 3C-SiC thin film quality was improved not only physical but also mechanical properties.

  • PDF

Enhanced Crystallization of Si at Low Temperature by $O_2$ Flow during Deposition

  • Nam, Hyoung-Gin;Koo, Kyung-Hwan
    • Journal of the Semiconductor & Display Technology
    • /
    • v.6 no.2 s.19
    • /
    • pp.15-18
    • /
    • 2007
  • Effects of $O_2$ flow during deposition on Si crystallization at low substrate temperature were studied. Silicon thin films were prepared on $SiO_2$ substrates in a low-pressure chemical vapor deposition chamber using a mixture of $SiH_4$ and $H_2$. In some cases $O_2$ was intentionally introduced during deposition. Growth of poly silicon was observed at the substrate temperature as low as $480^{\circ}C$ when $O_2$ was flowed during deposition implying that crystallization of Si was enhanced by $O_2$ flow. On the other hand, $O_2$ flow did not show any significant effects at higher substrate temperature, where deposition rate is relatively fast. Enhancement mechanism of Si crystallization by $O_2$ flow was suggested from these results.

  • PDF

Electromigration Characteristics in PSG/SiO$_2$ Passivated Al-l%Si Thin Film Interconnections

  • Kim, Jin-Young
    • Journal of Korean Vacuum Science & Technology
    • /
    • v.7 no.2
    • /
    • pp.39-44
    • /
    • 2003
  • Recent ULSI and multilevel structure trends in microelectronic devices minimize the line width down to a quarter micron and below, which results in the high current densities in thin film interconnections. Under high current densities, an EM(electromigration) induced failure becomes one of the critical problems in a microelectronic device. This study is to improve thin film interconnection materials by investigating the EM characteristics in PSG(phosphosilicate glass)/SiO$_2$ passivated Al-l%Si thin film interconnections. Straight line patterns, wide and narrow link type patterns, and meander type patterns, etc. were fabricated by a standard photholithography process. The main results are as follows. The current crowding effects result in the decrease of the lifetime in thin film interconnections. The electric field effects accelerate the decrease of lifetime in the double-layered thin film interconnections. The lifetime of interconnections also depends upon the current conditions of P.D.C.(pulsed direct current) frequencies applied at the same duty factor.

  • PDF

Effects of Pulse Modulations on Particle Growth m Pulsed SiH4 Plasma Chemical Vapor Deposition Process (펄스 SiH4 플라즈마 화학기상증착 공정에서 입자 성장에 대한 펄스 변조의 영향)

  • Kim, Dong-Joo;Kim, Kyo-Seon
    • Journal of Industrial Technology
    • /
    • v.26 no.B
    • /
    • pp.173-181
    • /
    • 2006
  • We analyzed systematically particle growth in the pulsed $SiH_4$ plasmas by a numerical method and investigated the effects of pulse modulations (pulse frequencies, duty ratios) on the particle growth. We considered effects of particle charging on the particle growth by coagulation during plasma-on. During plasma-on ($t_{on}$), the particle size distribution in plasma reactor becomes bimodal (small sized and large sized particles groups). During plasma-off ($t_{off}$), there is a single mode of large sized particles which is widely dispersed in the particle size distribution. During plasma on, the large sized particles grows more quickly by fast coagulation between small and large sized particles than during plasma-off. As the pulse frequency decreases, or as the duty ratio increases, $t_{on}$ increases and the large sized particles grow faster. On the basis of these results, the pulsed plasma process can be a good method to suppress efficiently the generation and growth of particles in $SiH_4$ PCVD process. This systematical analysis can be applied to design a pulsed plasma process for the preparation of high quality thin films.

  • PDF

Effect of Alternate Bias Stress on p-channel poly-Si TFT`s (P-채널 다결정 실리콘 박막 트랜지스터의 Alternate Bias 스트레스 효과)

  • 김영호;조봉희;강동헌;길상근;임석범;임동준
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.14 no.11
    • /
    • pp.869-873
    • /
    • 2001
  • The effects of alternate bias stress on p-channel poly-Si TFT\`s has been systematically investigated. We alternately applied positive and negative bias stress on p-channel poly-Si TFT\`s, device Performance(V$\_$th/, g$\_$m/, leakage current, S-slope) are alternately appeared to be increasing and decreasing. It has been shown that device performance degrade under the negative bias stress while improve under the positive bias stress. This effects have been related to the hot carrier injection into the gate oxide rather than the generation of defect states within the poly-Si/SiO$_2$ interface under alternate bias stress.

  • PDF

Effects of Ti-capping Layers on the Thermal Stability of NiSi (Ti-capping층이 NiSi의 열적안정성에 미치는 영향)

  • Park, Soo-Jin;Lee, Keun-Woo;Kim, Ju-Youn;Jun, Hyung-Tak;Bae, Kyoo-Sik
    • Korean Journal of Materials Research
    • /
    • v.13 no.7
    • /
    • pp.460-464
    • /
    • 2003
  • Ni and Ti films were deposited by the thermal evaporator, and then annealed in the N$_2$ ambient at 300-80$0^{\circ}C$ in a RTA(rapid thermal annealing) system. Four point probe, AEM, FESEM, AES, and XPS were used to study the effects of Ti-capping layers on the thermal stability of NiSi thin films. The Ti-capped NiSi was stable up to $700^{\circ}C$ for 100 sec. RTA, while the uncapped NiSi layers showed high sheet resistance after $600^{\circ}C$. These results were due to that the Ni in-diffusion and Si out-diffusion were retarded by the capping layer, resulting in the suppression of the formation of NiSi$_2$and Si grains at the surface.

Effects of Pressure, Superheat and Si Content on the Fluidity of Al-Si Alloy during Squeeze Casting (Al-Si 합금의 용탕 단조시 유동도에 미치는 압력, 과열 및 규소 함량의 영향)

  • Lee, Hag-Ju;Jung, Ki-Hwan;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
    • /
    • v.26 no.3
    • /
    • pp.133-139
    • /
    • 2006
  • The effects of applied pressure, superheat and silicon content on the fluidity of Al-Si alloy during squeeze casting were investigated. The Fluidity of Al-7.0wt%Si alloy during squeeze casting was increased with applied pressure up to 60 MPa, meanwhile it rather decreased beyond that. Therefore, the optimum squeeze casting pressure was 60 MPa. The fluidity was increased with superheat up to $150^{\circ}C$. On the other hand, it rather decreased at the superheat of $200^{\circ}C$. The fluidity of Al-Si alloy during squeeze casting was decreased with silicon content in the range of $0.0{\sim}3.0\;wt%$, increased in the range of $3.0{\sim}13.0\;wt%$. The fluidity of Al-15.0 wt%Si alloy was lower than that of Al-13.0 wt%Si alloy.

Effects of Hydrogen Plasma Treatment of the Underlying TaSiN Film Surface on the Copper Nucleation in Copper MOCVD

  • Park, Hyun-Ah;Lim, Jong-Min;Lee, Chong-Mu
    • Journal of the Korean Ceramic Society
    • /
    • v.41 no.6
    • /
    • pp.435-438
    • /
    • 2004
  • MOCVD is one of the major deposition techniques for Cu thin films and Ta-Si-N is one of promising barrier metal candidates for Cu with high thermal stability. Effects of hydrogen plasma pretreatment of the underlying Ta-Si-N film surface on the Cu nucleation in Cu MOCVD were investigated using scanning electron microscopy, X-ray photoelectron spectroscopy and Auger electron emission spectrometry analyses. Cu nucleation in MOCVD is enhanced as the rf-power and the plasma exposure time are increased in the hydrogen plasma pretreatment. The optimal plasma treatment process condition is the rf-power of 40 Wand the plasma exposure time of 2 min. The hydrogen gas flow rate in the hydrogen plasma pretreatment process does not affect Cu nucleation much. The mechanism through which Cu nucleation is enhanced by the hydrogen plasma pretreatment of the Ta-Si-N film surface is that the nitrogen and oxygen atoms at the Ta-Si-N film surface are effectively removed by the plasma treatment. Consequently the chemical composition was changed from Ta-Si-N(O) into Ta-Si at the Ta-Si-N film surface, which is favorable for Cu nucleation.

Antispasmodic Effects of Junsibaekchul-San In Vivo and In vitro

  • Hur, Jin-Il;Byun, Joon-Seok;Kim, Dae-Jun
    • Journal of Physiology & Pathology in Korean Medicine
    • /
    • v.24 no.1
    • /
    • pp.143-151
    • /
    • 2010
  • In Vivo and In vitro antispasmodic effects of Jun-Si-Baek-Chul-San, a Traditional Korean Polyherbal Medicineconsisted of 7 types of herbs were observed in the present study. To clarify the effects of Jun-Si-Baek-Chul-San, on accelerating small intestinal movement induced by the stimulation of cholinergic neurotransmission, we evaluated the effects of Jun-Si-Baek-Chul-San on In vivo carbachol (an acetylcholinergic agent)-accelerated mice small intestinal transit and on In vitro contractions induced by low-frequency electrostimulation, KCl, histamine or acetylcholine using isolated guinea pig ileum. To induce the acceleration of mice small intestinal transit, Carbachol 1 mg/kg was once subcutaneously dosed 15min before last administration of the test drugs. In the present study, Jun-Si-Baek-Chul-San 500, 250 and 125 mg/kg or domperidone 20 mg/kg were orally pretreated on the carbachol-accelerated mice small intestinal transit once a day for 7 days and the small intestinal transit rateof activated charcoal powder were monitored. In vitro assays, Jun-Si-Baek-Chul-San1, 0.1, 0.01 and 0.001 mg/ml or domperidone $2{\times}10^{-5}M$ were treated 10min before ileal contraction was induced by filed stimulation, acetylcholine, KCl and histamine, and the % changes of contractions were observed compared to the treatment of inducer alone. In spontaneous contraction, the % changes of contractions were observed compared to treatment of vehicle alone at 10min after Jun-Si-Baek-Chul-San or domperidone treatment. The efficacy of Jun-Si-Baek-Chul-San was compared to those of domperidone. High concentration, 1 mg/ml of Jun-Si-Baek-Chul-San was found to decrease the spontaneous contraction of the isolated guinea-pig ileum. In addition, Jun-Si-Baek-Chul-San decrease contractions induced by electrostimulation, acetylcholine, histamine and KCl in the isolated guinea-pig ileum. In addition, Jun-Si-Baek-Chul-San effectively inhibited the accelerated small intestinal movement induced by carbachol stimulation of cholinergic neurotransmission in In vivo. Based on the results, although the exact molecular or action mechanism and which herbs or compound in Jun-Si-Baek-Chul-San are responsible for actions, it was concluded that Jun-Si-Baek-Chul-San normalization in the accelerated intestinal motility might be interfere with a variety of muscarinic, adrenergic and histaminic receptor activities or with the mobilization of calcium ions required for smooth muscle contraction non-specificly. Therefore, it is expected that Jun-Si-Baek-Chul-San will be promising as a prescription of clinical treatment of digestive tract disorders such as accelerated the motility of intestine, diarrhea or intestinal painful contractions.