• Title/Summary/Keyword: Effects of Mo

Search Result 1,901, Processing Time 0.033 seconds

Effect of Mo Addition on the Sinterability and Mechanical Properties of TiB$_2$-Fe Cermets (TiB$_2$-Fe 서메트의 소결성 및 기계적성질에 미치는 Mo첨가의 영향)

  • 최덕순
    • Journal of the Korean Ceramic Society
    • /
    • v.36 no.5
    • /
    • pp.471-477
    • /
    • 1999
  • Fe and Fe-Mo binder were used to produce TiB2 based cermet by a pressureless sintering. The densification behaviour of TiB2-Fe-Mo cermet during liquid-phase sintering in argon was studied in relation to binder phase charactertics. The effects of Mo addition and sintering condition on the sintering behaviour and mechanical properties were also investigated. TiB2-based cermets with Fe-Mo binder composition showed a better sinterability than the cermets with only Fe binder. In TiB2-Fe-Mo cermet higher densities in the wide temperature range were obtained and also fully densified sintered cermet were obtained at 1873K The enhancement in the densification phenomenon of TiB2-Fe-Mo system can be explained by improved liquid phase wettability associated with the roles of Mo components as solute atoms. When Fe-Mo binders were used cermets with a finer grain size and enhanced mechanical properties wereproduced and new phases such as Fe2B and Mo2FeB2 were observed in the sintered cermet. The highest bending strength was obtained from the 20vol% Fe-Mo cermet and these hardness-fracture toughness combination in the wide binder compositions is better than that of TiB2-Fe cermet. In order to improve mechanical properties microstructure control with high purity powders is desirable because high purity powders prevent the formation of Fe2B and Mo2FeB2 phase which comsume the ductile binder phase.

  • PDF

Effects of Mo additions on the room-temperature deformation behavior of polysynthetically twinned (PST) crystals of TiAl

  • O, Myeong-Hun;Kim, Min-Cheol;Wi, Dang-Mun
    • Korean Journal of Materials Research
    • /
    • v.5 no.2
    • /
    • pp.157-168
    • /
    • 1995
  • The effects of Mo additions on the microstructure and the room temperature deformation behavior of polysynthetically twinned (PST) crystals of TiAl were studied in order to get a basic conception for alloying additions on the two-phase TiAl compounds with the lamellar structure. It was found that the Mo additions in TiAl PST crystals increase both the yield stress and tensile elongation to fracture but the increase in yield stress deppend on the angle $\Phi$at which the lamellar boundaries lie from the loading axis. The large difference in yield stress between specimens deformed parallel($\Phi = 0^\circ$)or perpendicular($\Phi = 90^\circ$) to the loading axis and those deformed in intermediate orientations could be plained by the difference in Mo content between the TiAl and the $$Ti_{3}Al$ phases. It was also found that the Mo-doped specimens with intermediate orientation fail by cracking zigzag across to the lamellar boundaris, which is the same fracture mode as that of binary specimens with intermediate orientations tested in vacuum This suggests that Mo atoms are thought to play a role to reduce the environmental embrittlement of binary PST crystals, resulting in increasing the tensile ductility.

  • PDF

Effects of Mo and Nb on Tensile and Charpy Impact Properties of API X80 Linepipe Steels (API X80 라인파이프 강의 인장 및 샤르피 충격 특성에 미치는 Mo 및 Nb의 영향)

  • Min, Kyung-Zoon;Bae, Jin-Ho;Kim, Ki-Soo;Lee, Doh-Jae
    • Korean Journal of Metals and Materials
    • /
    • v.49 no.10
    • /
    • pp.766-773
    • /
    • 2011
  • In this study, three kinds of linepipe steels were processed by changing the amount of Mo and Nb to investigate the effects on microstructures, tensile and Charpy impact properties. All the specimens consisted of acicular ferrite, granular bainite and secondary phases such as martensite and austenite constituents (MA). The increase in Mo raised the volume fractions of the granular bainite and MA, and raised the number of fine precipitates, which increased the yield and tensile strengths and decreased the upper self energy and energy transition temperatures. In the steel having less Mo and more Nb, the volume fractions of the granular bainite and MA decreased, and a finer microstructure was observed. This microstructure suppressed the formation of separation during Charpy impact testing and led to a higher upper shelf energy and lower energy transition temperature, while the yield and tensile strengths were lower than those of the steels with more Mo and less Nb.

Effects of dietary supplementation with a combination of plant oils on performance, meat quality and fatty acid deposition of broilers

  • Long, Shenfei;Xu, Yetong;Wang, Chunlin;Li, Changlian;Liu, Dewen;Piao, Xiangshu
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.31 no.11
    • /
    • pp.1773-1780
    • /
    • 2018
  • Objective: This study was to evaluate effects of mixed plant oils (identified as mixed oil 1 [MO1] and mixed oil 2 [MO2]) on performance, serum composition, viscera percentages, meat quality, and fatty acid deposition of broilers. Methods: A total of 126 one-day-old Arbor Acres male broiler chicks (weighing $44.91{\pm}0.92g$) were randomly allocated to 1 of 3 treatments with 7 replicate pens per treatment (6 broilers per pen). Dietary treatments included a corn-soybean basal diet supplemented with 3% soybean oil (CTR), basal diet with 3% MO1 (a mixture of 15% corn oil, 10% coconut oil, 15% linseed oil, 20% palm oil, 15% peanut oil and 25% soybean oil; MO1), or basal diet with 3% MO2 (a combination of 50% MO1 and 50% extruded corn; MO2). The trial consisted of phase 1 (d 1 to 21) and phase 2 (d 22 to 42). Results: Compared to CTR, broilers fed MO (MO1 or MO2) had greater (p<0.05) average daily gain in phase 1, 2, and overall (d 1 to 42), redness in thigh muscle, concentrations of serum glucose, serum albumin, saturated fatty acids (SFA) and n-6/n-3 polyunsaturated fatty acids (PUFA) ratio in breast muscle, while these broilers also showed lower ($p{\leq}0.05$) drip loss and concentrations of C18:3n-3 and PUFA/SFA ratio in breast muscle. Broilers fed MO2 had higher (p<0.05) liver percentage, while broilers fed MO1 had lower ($p{\leq}0.05$) feed conversion ratio in phase 1 and increased (p<0.05) contents of C18:2n-6, C20:5n-3, C22:6n-3, and n-3 PUFA in breast muscle compared to CTR. Conclusion: Mixed plant oils had positive effects on performance, serum parameters, meat quality, liver percentage and fatty acid deposition in broilers, which indicates they can be used as better dietary energy feedstocks than soybean oil alone.

Effects of Mo Content on Surface Characteristics of Dental Ni-Ti Alloys (치과용 Ni-Ti합금의 표면특성에 미치는 Mo함량의 영향)

  • Han-Cheol Choe;Jae-Un Kim;Sun-Kyun ark
    • Corrosion Science and Technology
    • /
    • v.22 no.1
    • /
    • pp.64-72
    • /
    • 2023
  • Ni-Ti shape memory alloy for dental nerve treatment devices was prepared by adding Mo to Ni-Ti alloy to improve flexibility and fatigue fracture characteristics and simultaneously increase corrosion resistance. Surface properties of the alloy were evaluated. Microstructure analysis of the Ni-Ti-xMo alloy revealed that the amount of needle-like structure increased with increasing Mo content. The shape of the precipitate showed a pattern in which a long needle-like structure gradually disappeared and changed into a small spherical shape. As a result of XRD analysis of the Ni-Ti-xMo alloy, R-phase structure appeared as Mo was added. R-phase and B2 structure were mainly observed. As a result of DSC analysis, phase transformation of the Ti-Ni-Mo alloy showed a two-step phase change of B2-R-B19' transformation with two exothermic peaks and one endothermic peak. As Mo content increased, R-phase formation temperature gradually decreased. As a result of measuring surface hardness of the Ti-Ni-Mo alloy, change in hardness value due to the phase change tended to decrease with increasing Mo content. As a result of the corrosion test, the corrosion potential and pitting potential increased while the current density tended to decrease with increasing Mo content.

Microstructure and Mechanical Properties of Mo-Si-N Coatings Deposited by a Hybrid Coating System (하이브리드 코팅시스템에 의해 제조된 Mo-Si-N 박막의 미세구조 및 기계적 특성연구)

  • Heo, Su-Jeong;Yun, Ji-Hwan;Kang, Myung-Chang;Kim, Kwang-Ho
    • Journal of the Korean institute of surface engineering
    • /
    • v.39 no.3
    • /
    • pp.110-114
    • /
    • 2006
  • In this work, comparative studies on microstructure and mechanical properties between $Mo_2N$ and Mo-Si-N coatings were conducted. Ternary Mo-Si-N coatings were deposited on AISI D2 steel substrates by a hybrid method, where AIP technique was combined with a magnetron sputtering technique. Instrumental analyses of XRD, HRTEM, and XPS revealed that the Mo-Si-N coatings must be a composite consisting of fine $Mo_2N$ crystallites and amorphous $Si_3N_4$. The hardness value of Mo-Si-N coatings significantly increased from 22 GPa of $Mo_2N$ coatings to about 37 GPa with Si content of 10 at.% due to the refinement of $Mo_2N$ crystallites and the composite microstructure characteristics. The average friction coefficient of the Mo-Si-N coatings gradually decreased from 0.65 to 0.4 with increasing Si content up to 15 at.%. The effects of Si content on microstructure and mechanical properties of Mo-N coatings were systematically investigated.

Morphology and Electrical Properties of Back Electrode for Solar Cell Depending on the Mo : Na/Mo Bilayer Thickness (Mo : Na/Mo 이중층 구조 두께에 따른 태양전지 후면전극의 조직 및 전기적 특성)

  • Shin, Younhak;Kim, Myunghan
    • Korean Journal of Materials Research
    • /
    • v.23 no.9
    • /
    • pp.495-500
    • /
    • 2013
  • Mo-based thin films are frequently used as back electrode materials because of their low resistivity and high crystallinity in CIGS chalcopyrite solar cells. Mo:Na/Mo bilayer thin films with $1{\mu}m$ thickness were deposited on soda lime glass by varying the thickness of each layer using dc-magnetron sputtering. The effects of the Mo:Na layer on morphology and electrical property in terms of resistivity were systematically investigated. The resistivity increased from $159{\mu}{\Omega}cm$ to $944{\mu}{\Omega}cm$; this seemed to be caused by increased surface defects and low crystallinity as the thickness of Mo:Na layer increased from 100 nm to 500 nm. The surface morphologies of the Mo thin films changed from a somewhat coarse fibrous structures to irregular and fine celled structures with increased surface cracks along the cell boundaries as the thickness of Mo:Na layer increased. Na contents varied drastically from 0.03 % to 0.52 % according to the variation of Mo:Na layer thickness. The change in Na content may be ascribed to changes in surface morphology and crystallinity of the thin films.

An Experimental Study on Friction and Wear Characteristics of Air Curable $MoS_2$ Bonded Films with Polymeric Binder Materials (결합제 변화에 따른 상온 경화성 접착형 $MoS_2$ 고체윤활 피막의 마찰.마모 특성)

  • 한흥구;공호성;윤의성;권오관
    • Tribology and Lubricants
    • /
    • v.14 no.4
    • /
    • pp.72-78
    • /
    • 1998
  • In this work, the effects of binder materials on the tribological behavior were experimentally evaluated for air curable MoS$_2$bonded film lubricants. The binders tested were basically alkyd and acryl based resins, and also were modified by nitro-cellulose in various weight percentages. Effects on the binder ratio to solid lubricants and the molecular weight of binders were also investigated in all aspects of the tribological behavior. For the tests, LFW-1 and Falex tester were used to measure mainly the endurance life and load carrying capacity of bonded lubricants. Results showed that lubricants of methacrylic resin has the better performance than those of other resins, and also the properties of lubricants both of alkyd and acrylic resins could be improved by modification with nitro-cellulose. It was also shown that the optimum ratio of nitro-cellulose related closely to the binder material and the testing machine.

Effects of the Revolution Speed on the Mechanical Properties & Microstructure of Cr-Mo Steel during Vertical Centrifugal Investment Casting (Cr-Mo강의 수직 원심 정밀 주조시의 조직 및 기계적 성질에 미치는 회전 속도의 영향)

  • Hur, Yong-Hyuk;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
    • /
    • v.21 no.5
    • /
    • pp.296-303
    • /
    • 2001
  • The effects of the revolution speed on the mechanical properties and microstructure of Cr-Mo steel during vertical centrifugal casting using investment mold were investigated. The casting yield, tensile strength, hardness and absorbed energy during impact test were increased with increasing revolution speed. The effect of mass variation caused by the change in the revolution speed on the grain size was the most significant.

  • PDF