• Title/Summary/Keyword: Effects of Mo

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Effects of Alloying Element and Tempering on the Mechanical Properties of Cr-Mo Plastic Mold Steels (Cr-Mo계 금형강의 기계적 성질에 미치는 합금원소 및 템퍼링의 영향)

  • Kim, Nam-Kyu;Kim, Byoung-Ok;Lee, Oh-Yeon
    • Journal of the Korean Society for Heat Treatment
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    • v.25 no.4
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    • pp.196-205
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    • 2012
  • The purpose of this study is to enhance the hardenability and the mechanical properties by the addition of alloying elements such as Ni, Cr, Mo and B for the development of Cr-Mo plastic mold steel with uniform hardness and microstructure. The ingots were prepared by vacuum induction melting and forged to ${\Phi}35mm$ round bar. Forged bars were quenched and tempered at $200{\sim}600^{\circ}C$ for 1.5 hour. Jominy test, boron distribution observation, microstructual observation, tensile test and charpy impact test were conducted. It was confirmed that the hardenablity of these steels was improved by increasing of alloying elements and further promoted by the addition of boron. The critical rate of cooling required to obtain the bainitic structure for 0.27C-1.23Cr-0.28Mo-B steel was $0.5^{\circ}C/sec$. Hardness and strength of Cr-Mo steels decreased with increasing tempering temperature, but elongation and reduction of area increased with increasing tempering temperature. However, impact energy tempered at $400^{\circ}C$ showed the lowest value in the range $200{\sim}600^{\circ}C$ due to the temper embrittlement.

The Effects of Co-substitution on the Magnetic Properties of Nanocrystalline Nd-Fe-B based Alloy Containing α-Fe as Main Phase (Co 치환이 α-Fe기 초미세결정립 Nd-Fe-B계 합금의 자기특성에 미치는 영향)

  • Cho, D.H.;Cho, Y.S.
    • Journal of the Korean Magnetics Society
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    • v.12 no.1
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    • pp.30-33
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    • 2002
  • The Effects of Co-substitution in the nanocrystalline Nd-Fe-B-Mo-Cu alloys were investigated. $\alpha$-Fe based nanocrystalline Nd-Fe-B-Mo-Cu alloys were prepared by crystallization process of amorphous Nd-Fe-B-Mo-Cu alloy produced by rapid solidification process. The substitution of Co resulted in the decrease of grain size and improves the hard magnetic properties. The remanence, coercivity, and Curie temperature of nanocrystalline N $d_4$(F $e_{0.85}$ $Co_{0.15}$)$_{82}$ $B_{10}$M $o_3$Cu alloy showed more improved magnetic properties than those of Co-free alloy. The grain size was measured to be about 15 nm. The coercivity, remanence and maximum energy product were 239 kA/m, 1.41, and 103.5 kJ/ $m^3$, respectively, for the nanocrystalline N $d_4$(F $e_{0.85}$ $Co_{0.15}$)$_{82}$ $B_{10}$M $o_3$Cu alloy annealed for 0.6 ks at 640 $^{\circ}C$.

Phase Cooperation Between Mo-V-O and Metal Oxide in Selective Oxidation of Acrolein (아크롤레인 선택 산화반응에서 Mo-V-O와 금속산화물의 상간협동)

  • Park, D.W.;Na, S.E.;Kim, K.H.;Lee, W.H.;Chung, J.S.
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.327-336
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    • 1994
  • The synergistic effects in mechanical mixture catalysts of Mo-V-O and metal oxide were investigated for the selective oxidation of acrolein. The metal oxides used are $SnO_2$, ${\alpha}-Sb_2O_4$, $WO_3$, ${\alpha}-Al_2O_3$, CuO, $MnO_2$, $Cu_2O$, MgO, CoO, and ZnO. Mechanical mixtures of Mo-V-O plus $SnO_2$ or ${\alpha}-Sb_2O_4$ had resulted in higher conversion of acrolein and higher yield of acrylic acid than Mo-V-O. The origin of the synergy is attributed to the cooperation of Mo-V-O and $SnO_2$ or ${\alpha}-Sb_2O_4$, in which $SnO_2$ or ${\alpha}-Sb_2O_4$ forms dissociated oxygens at their oxygen vacancies and transports them to Mo-V-O. $Cu_2O$, MgO, CuO, and $MnO_2$, increased conversion of acrolein but decreased yield of acrylic acid. CoO and ZnO inhibited the catalytic performance of Mo-V-O. The different role of these metal oxides is explained in terms of their oxidation-reduction properties.

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A Study on Electrical $MoSi_2$ High Temperature Heating Elements by Additives (첨가제 변화에 따른 $MoSi_2$ 고온발열체의 전기적 특성)

  • Lee, H.I.;Han, S.O.;Koo, K.W.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1405-1407
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    • 2001
  • It was studied to prepare high temperature heating elements using molybdenum disilicide($MoSi_2$). Molybdenum disilicide is widely used as material for manufacturing high temperature heating elements. $MoSi_2$ heating elements could be used at 1700-1900$^{\circ}C$. However, it is relatively expensive, and its demand depends on import. $MoSi_2$ powders was mixed with 4-5wt% of montmorillonites type bentonite as plasticizer and a small amount of $Si_3N_4$, $ThO_2$, and B as additives to prepare specimen of heating elements. Then, it was extruded, dried, sintered and machined followed by heating test. Effects of sintering conditions and amount of additives were investigated, It was sintered effectively at 1,350$^{\circ}C$ for five hours. Electrical resistivity was decreased with increasing of sintering temperature and time, and related with apparent density of the specimens. It was linealy decreased with increasing of sintered density. The heating elements thus prepared was stable at 1700$^{\circ}C$ and the physical properties such as specific electrical resistivity, hardness, apparent density, thermal expansion coefficient, and bending strength were almost identical with those of commercial heating elements.

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Direct Effects of Copper and Selenium Supplementation and Its Subsequent Effects on Other Plasma Minerals, Body Weight and Hematocrit Count of Grazing Philippine Goats

  • Orden, E.A.;Serra, A.B.;Serra, S.D.;Nakamura, K.;Cruz, L.C.;Fujihara, T.
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.3
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    • pp.323-328
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    • 2000
  • The administration of soluble glass bolus (SGB) with cobalt (Co), selenium (Se) and copper (Cu), among 50 upgraded does in the farm of Central Luzon State University, Philippines, was effective in improving the mineral status of the animals. After one year, blood Se and plasma Cu had been significantly increased; subsequently plasma molybdenum (Mo) level had been reduced, but other macro-minerals were not affected. Soluble glass bolus supplementation did not affect plasma calcium (Ca), magnesium (Mg), and sodium (Na), although the treated does had higher plasma phosphorus (P), potassium (K), and zinc (Zn) in some parts of the year. Hematocrit count of the animals was also improved reaching 32% level after 9 months; although it was still 6% below the lower limit of a normal range of 38 to 45%. The desired improvement in Se, Cu and Mo was not able to influence live weight among the animals. After one year, body weight was not significantly different from the control group of animals. Nevertheless, the study showed the effectiveness of SGB in improving Cu and Se levels, and subsequently reducing the plasma Mo levels of grazing goats in a typical Philippine farm.

Advanced Indentation Studies on the Effects of Hydrogen Attack on Tensile Property Degradation of Heat-Resistant Steel Heat-Affected Zones

  • Choi, Yeol;Jang, Jae-il;Lee, Yun-Hee;Kwon, Dongil;Kim, Jeong-Tae
    • Corrosion Science and Technology
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    • v.2 no.6
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    • pp.266-271
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    • 2003
  • Safety diagnosis of various structural components and facilities is indispensable for preventing catastrophic failure of material by time-dependent and environment accelerating degradation. Also, this diagnosis of operating components should be done periodically for safe maintenance and economical repair. However, conventional standard methods for mechanical properties have the problems of bulky specimen, destructive procedure and complex procedure of specimen sampling. So, a non-destructive and simple mechanical testing method using small specimen is needed. Therefore, an advanced indentation technique was developed as a potential method for non-destructive testing of in-field structures. This technique measures indentation load-depth curve during indentation and analyzes the mechanical properties related to deformation such as yield strength, tensile strength and work-hardening index. In this paper, we characterized the tensile properties including yield and tensile strengths of the V-modified Cr-Mo steels in petro-chemical and thermo-electrical plants. And also, the effects of hydrogen-assisted degradation of the V-modified Cr-Mo steels were analyzed in terms of work-hardening index and yield ratio.

Effects of Heat Treatments on Microstructure , Hardness and Abrasive Wear Resistance in 3%C-10%Cr-5%Mo-5%W White Cast Iron (3%C-10%Cr-5%Mo-5%W 백주철에 있어서 열처리가 현미경조직, 경도 및 내마모성에 미치는 영향)

  • Yu, Sung-Kon
    • Journal of Korea Foundry Society
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    • v.19 no.1
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    • pp.33-37
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    • 1999
  • White cast iron of 3%C-10%Cr-5%Mo-5%W was casted, and then heat treated with three different methods such as homogenizing, austenitizing and tempering to observe its effects on the microstructure, hardness and abrasive wear resistance. In uni-directional soldification, bamboo tree-like $M_7C_3$ carbide grew along with the heat flow direction, and fishbone-like $M_6C$ carbide was dispersed randomly among $M_7C_3$ carbides. While almost pearlitic structures were observed in the as-cast specimen, those of the heat treated specimens consisted of secondary carbide, retained austenite and tempered martensite. In austenitized specimen, the amounts of retained austenite were 60.88% due to the higher cooling rate encountered in forced air cooling. On the other hand, the amounts of retained austenite were reduced from 60.88% to 23.85% in tempered specimen due to the transformation of austenite into tempered martensite. The hardness of tempered specimen showed the highest value, and then decreased in the order of austenitized, as-cast and homogenized specimens. But, the abrasive wear resistance of austenitized specimen was the highest, and then decreased in the order of tempered, as-cast and homogenized specimens.

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Multiple Deletions in Logistic Regression Models

  • Jung, Kang-Mo
    • Communications for Statistical Applications and Methods
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    • v.16 no.2
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    • pp.309-315
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    • 2009
  • We extended the results of Roy and Guria (2008) to multiple deletions in logistic regression models. Since single deletions may not exactly detect outliers or influential observations due to swamping effects and masking effects, it needs multiple deletions. We developed conditional deletion diagnostics which are designed to overcome problems of masking effects. We derived the closed forms for several statistics in logistic regression models. They give useful diagnostics on the statistics.