• 제목/요약/키워드: Effects of Mo

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Mo첨가가 $Al_2O_3$ 세라믹스의 미세구조 및 기계적 성질에 미치는 영향 (Effects of Mo Addition on the Microstructures and Mechanical Properties of $Al_2O_3$ Ceramics)

  • 박정현;문성환;백승수;정동익
    • 한국세라믹학회지
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    • 제25권3호
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    • pp.201-206
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    • 1988
  • Mo 입자의 첨가가 Al_2O_3$ 세라믹스의 미세구조와 기계적 성질에 미치는 영향을 알아보기 위하여 평균입경이 2-micron인 Mo와 6-micron인 Mo를 Al_2O_3$에 각 분산시켜 1$600^{\circ}C$, $H_2$ 분위기에서 5시간 소결하였다. Mo는 Al_2O_3$의 입자성장을 억제시켰으며 Mo의 입자가 작을 때 그 효과는 크게 나타났다. 2-micron Mo를 분산한 경우 꺽임강도와 파괴인성은 크게 증가하여하였으며, 6-micron Mo를 분산한 경우 강도는 증가하지 않았으나 파괴인성은 다소 증가하였다. Al_2O_3$-Mo계의 인성증진기구는 균열편향에 의한 파단면의 증가와 미세균열에 의한 균열전파에너지의 분산에 의한 것으로 보인다.

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Effects of Sintering Conditions on the Properties of Sintered Molybdenum

  • Kadokura, Takanori;Hiraoka, Yutaka;Nakabayashi, Seiji;Yamamoto, Yoshiharu
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1153-1154
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    • 2006
  • Effects of sintering conditions such as sintering temperature and heating rate on oxygen content, density, microstructure and toughness of sintered Mo were investigated. The oxygen content of the sintered Mo significantly depended on the sintering conditions. The oxygen content of the primary sintered(below 1673 K) Mo influenced the densifications. The number of pores at grain boundaries of the secondary sintered(at 2073 K)Mo depended on the oxygen content of the primary sintered Mo. Grain growth of the secondary sintered Mo was inhibited by the existence of pores at the grain boundaries. The secondary sintered Mo having larger number of pore and smaller grain size demonstrated higher strength.

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Sodium molybdate가 납중독 랫드의 말초신경내 인지질 대사에 미치는 영향 (Effects of sodium molybdate on phospholipid metabolism in peripheral nerves of lead-intoxicated rats.)

  • 박성환;정명규;곽영규
    • 환경위생공학
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    • 제16권3호
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    • pp.14-21
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    • 2001
  • The effects of sodium molybdate(Mo) on phospholipid metabolism in sciatic nerve isolated from lead-intoxicated rat were investigated. Four weeks aged albino rats were divided into four groups : normal control group, lead(10 ppm)-treated group, Mo(1 mg/kg)-treated group, lead and Mo-treated group. As a result of the study, Mo significantly increased the rate of incorporation of $2-[^3H]$myo-inositol into polyphosphinositides in lead-intoxicated rat. Mo also increased the rate of phosphatidylcholine metabolism in normal and lead-intoxicated rats. However, Mo did not affect the metabolism of phosphatidylserine and phosphatidylethanola-mine in normal and lead-intoxicated status. These results suggest that Mo might improve lead-intoxicated status by principally enhancing the metabolism of myo-inositol-related phospholipids and by partly phosphatidylcholine in sciatic nerve.

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Effects of Co-Existent Additives and the Role of Reacted Surface Film on the Friction with an Organo-Molybdenum Compound

  • Kim, Young-Hwan
    • Tribology and Lubricants
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    • 제10권4호
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    • pp.43-50
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    • 1994
  • In order to elucidate the effects of co-existing additives (S$_{8}$, TBP: Tri butyl phosphate, ZnDTP: Zinc-dialkyl dithiophosphate) and the role of reacted surface film on the friction behavior of MoDTP (molybdenum dialkyl dithiophosphate), a friction experiment using a dual circular pipe edge surface type friction tester and XPS (X-ray photoelectronic spectrum) surface analysis were conducted. Friction reduction with MoDTP lubricant was proved to be greatly influenced by co-existing additive species. It was dependent on the properties of the film formed through the reaction between the additive and the surface. Phosphate film reduced the friction coefficient of MoDTP through suppression of diffusion of Mo compounds towards the metal substrate. On the other hand, sulfate film, which is inherently rich in lattice defects, did not lead to any appreciable friction reduction with MoDTP since the diffusion of the Mo compound towards the metal substrate was not effectively suppressed. With ZnDTP additive, the sulfide film formed through decomposition greatly influenced the lubricating performance of MoDTP. As such, properties of surface films formed from additives were proved to yield significant influence on the lubrication performance of MoDTP.

Optoelectric properties of gate-tunable n-MoS2/n-WSe2 heterojunction with proper electrode metals

  • 이섬균;박민지;유경화
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.332.2-332.2
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    • 2016
  • Two dimensional transition-metal dichalcogenides (TMDs) semiconductors are attractive materials for optoelectric devices because of their direct energy bandgap and transparency. To investigate the feasibility of transparent p-n junctions, we have fabricated a p-n heterojunction consisting of p-type WSe2 and n-type MoS2 flakes since WSe2 and MoS2 with proper electrode metals exhibit p-type and n-type behaviors, respectively. These heterojunctions exhibits gate-tunable rectifying behaviors and photovoltaic effects (ECE ~ 0.2%) indicating that p-n junctions were formed. In addition, photocurrent and photovoltaic effects were observed under light illumination, which were dependent on the gate voltage. In addition, the photocurrent mapping images indicate that the photovoltaic effects comes from the junction area. Possible origins of gate-tunability are discussed.

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습식담지시 pH와 Ni/Mo 몰비가 Ni-Mo/AC 카바이드 촉매의 특성과 메탄건식개질 반응성에 미치는 영향 (A Study on the Effects of pH and Ni/Mo Mole Ratio during Wet Impregnation on the Characteristics and Methane Dry Reforming Reactivity of Activated Charcoal Supported Ni-Mo Carbide Catalyst)

  • 이동민;황운연;박형상;박성열;김성수
    • 한국수소및신에너지학회논문집
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    • 제25권4호
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    • pp.344-354
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    • 2014
  • Activated charcoal supported nickel molybdenum carbide (carburized Ni-Mo/AC) catalysts were prepared by wet-impregnation followed by temperature-programmed carburization using 20% $CH_4/H_2$ gas. The effects of pH and initial Ni/Mo mole ratio during wet-impregnation step on the characteristics of the carburized Ni-Mo/AC catalysts were investigated using ICP, XRD, XPS, BET and $CO_2$-TPD techniques, and correlated with the catalytic activity of the carburized Ni-Mo/AC in methane dry reforming reaction. Comparison of the results of methane dry reforming reaction kinetics with the results of characterization of the carburized Ni-Mo/AC catalyst showed that the catalytic activity in methane dry reforming reaction was higher at higher initial Ni/Mo mole ratio or at lower pH(3~natural value). This phenomenon was related to the crystal size of metallic Ni in the carburized Ni-Mo/AC catalyst.

CoCrTa/CrX (X=Mo, Si) 자성박막의 보자력에 미치는 Mo와 Si의 영향 (Effects of Mo and Si on the Coercivity of CoCrTa/CrMo and CoCrTa/CrSi Thin Film Media)

  • 조준식;남인탁;홍양기
    • 한국자기학회지
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    • 제9권4호
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    • pp.203-209
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    • 1999
  • CoCrTa/Cr 자성박막의 Cr 하지층에 Mo와 Si을 첨가하여 제조한 박막의 자기적 성질에 미치는 Mo와 Si의 영향에 대하여 조사하였다. 증착시 사용된 장비는 DC magnetron sputtering system이었고, CoCrTa 자성층의 두께는 30.0$\AA$으로 Cr 하지층의 두께는 700$\AA$으로 고정하였으며 기판의 가열온도는 26$0^{\circ}C$이었다. CrMo 하지층의 박막이 순수한 Cr 하지층에 비하여 약 200 Oe의 보자력 증가를 나타내었다. 하지만 Si을 첨가하였을 경우엔 첨가량의 증가에 따라 보자력이 점차 감소하는 것으로 나타났다. CrMo 하지층에서는Mo를 첨가함에 따라 Cr 하지츠의 (200)면의 결정배향성이 증가하였고, Mo를 첨가한 Cr(200)과 CoCrTa(110)의lattice misfit가 Si을 첨가한 경우보다 작았고, 이것이 보자력 증가의 원인이었다.

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고 Si 구상흑연주철의 조직과 기계적성질에 미치는 Si과 Mo의 영향 (The Effects of Si and Mo on the Structures and Mechanical Properties in High Si Spheroidal Graphite Cast Iron)

  • 김종연;나형용
    • 한국주조공학회지
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    • 제10권3호
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    • pp.225-234
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    • 1990
  • Spheroidal graphite cast irons which are Fe-3%C-(4-6)%Si-(0-0.5)%Mo were studied to improve not only heat resistance but also mechanical properties. With increasing Mo content, the graphitization was decreased and carbide volume fraction was increased. The graphite spheroidization ratio was not decreased in Fe-3%C-6%Si-Mo system cast iron with increasing Mo content, but that was decreased in Fe-3%C-4%Si-Mo system and Fe-3%C-5%Si-Mo system cast irons. Hardness was increased with the Si and Mo contents. At constant Si content, tensile strength was increased with increasing Mo content, but that was decreased at 6%Si. In the experiment of oxidation, weight gain was decreased as the Si and/or Mo content increased, but increased at 1.5%Mo content.

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오스템퍼드 구상흑연주철의 미세조직에 미치는 Mo의 영향 (Effects of Molybdenum on the Microstructure of Austempered Ductile Iron)

  • 이길홍;박윤우
    • 한국주조공학회지
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    • 제14권1호
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    • pp.35-44
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    • 1994
  • Mechanical properties of austempered ductile iron can be guaranteed if a good knowledge of its metallugical structure is obtained. In this paper, the effects of small Mo additions to austempered ductile iron on its metallurgical structures as a function of section size are examined. From the results, it is found that ${\gamma}-pool$ region and segregation of Mo in ${\gamma}-pool$ region are increased with increase in the section size.

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Cu가 함유된 구상흑연주철의 380℃에서 오스템퍼링 시 Mo이 기계적 특성에 미치는 영향 (Effects of Mo on the Mechanical Properties of Ductile Cast Iron with Cu Austempered at 380℃)

  • 김기엽
    • 열처리공학회지
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    • 제26권5호
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    • pp.219-224
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    • 2013
  • In this study, we investigated effect of Mo addition on mechanical properties of Cu added ADI. Ductile cast iron specimens were austenitized at $900^{\circ}C$ for 150 min and then austempered at $380^{\circ}C$ for the various time periods from 15 min to 480 min. Mo added ADI had a higher volume fraction of retained austenite, and the volume fraction of retained austenite was determined by XRD analysis. As decreasing volume fraction of retained austenite, the elongation was also decreased as expected. But the UTS and yield strength were not decreased.