• Title/Summary/Keyword: Effective carbon number

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A Study of the Gas Liquid Partition Coefficients of Eleven Normal, Branched and Cyclic Alkanes in Sixty Nine Common Organic Liquids: The Effect of Solute Structure

  • Cheong, Won-Jo
    • Bulletin of the Korean Chemical Society
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    • v.23 no.3
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    • pp.459-468
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    • 2002
  • Literature data measured by the author have been processed to report on the effect of solute structure on gas liquid partition coefficients of eleven normal, branched and cyclic alkanes ranging in carbon number from five to nine in sixty nine low molecular weight liquids. The alkane solutes are n-pentane(p), n-hexane(hx), n-heptane(hp), n-octane(o), n-nonane(n), 2-methylpentane(mp), 2,5-dimethylpentane(dp), 2,5-dimethylhexane(dh), 2,3,4-trimethylpentane(tp), cyclohexane(ch), and ethylcyclohexane(ec). The solvent set encompasses most of those studied by Rohrschneider as well as three homologous series of solvents (n-alkanes, 1-alcohols and 1-nitriles) and several perfluorinated alkanes and highly fluorinated alcohols. An excellent linear relationship was observed between lnK and the carbon number of n-alkanes. The effective carbon numbers of branched and cyclic alkanes were determined in a similar fashion to the method of Kovats index. We found that the logarithm of solute vapor pressure multiplied by solute molar volume was a perfect descriptor for the linear relationship with the median effective carbon number.

A Study on Fatigue Behaviors of RC Beams Strengthened with Carbon Fiber Sheets (CFS로 보강된 RC보의 피로거동에 관한 연구)

  • Park, Jeong-Yong;Cheung, Jin-Hwan;Kim, Seong-Do;Cho, Baik-Soon;Jang, Jun-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05a
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    • pp.35-38
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    • 2005
  • Carbon fiber sheets are widely used for strengthening the deteriorated RC structures. However most studies on the strengthening method of RC structures with carbon fiber sheets are concerning static problems. The purpose of this experimental study is to present the basic data on fatigue behaviors of. RC beams strengthened with carbon fiber sheets. The experimental parameters of this study are ; 1) the existence of U-shaped carbon fiber sheets at the ends for anchoring, 2) the number of carbon fiber sheet layers in strengthening the RC beams, 3) the load levels of $60\%\~90\%$ of the static bending moment strength, which is obtained form the static tests. Experimental results are estimated from the relationships of load level, displacement, number of repeated load and released energy. It is concluded that U-shaped carbon fiber sheets for end anchoring is very effective and the beams strengthened with one layer of carbon fiber sheet have longer fatigue life than that with three layers.

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A Kinetic Study on the Phosphorus Adsorption by Physical Properties of Activated Carbon (활성탄 물성에 따른 인 흡착의 동력학적 연구)

  • Seo, Jeongbeom;Kang, Joonwon
    • Journal of Korean Society on Water Environment
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    • v.26 no.3
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    • pp.491-496
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    • 2010
  • This study aimed to obtain equilibrium concentration on adsorption removal of phosphorus by activated carbon, to express the adsorption characteristics following Freundlich isotherm and also, based on the value obtained, to investigate the relationship between physical properties of activated carbon and dynamics of phosphorus removal by obtaining rate constant and effective pore diffusivity. The results summarized from this study are as follows. Phosphorus adsorption equilibrium reaching time of powdered activated carbon was reduced as the dosage of activated carbon increases, while granular activated carbon despite increased dosage did not have influence on adsorption equilibrium reaching times of phosphorus as well, taking more than 10 hours. It was also noted that powdered activated carbon showed better adsorption ability than granular activated carbon. The value of constant (f) of Freundlich isotherm of powered activated carbon on phosphorus was 4.26 which is bigger than those of granular activated carbon. The adsorption rate constant on phosphorus of powered activated carbon with low effective diameter and iodine number was highest as $8.888hr^{-1}$ and the effective pore diffusivity ($D_e$) was lowest as $2.45{\times}10^{-5}cm^2/hr$, and the value of phosphorus adsorption rate constant of granular activated carbon was $0.174{\sim}0.372hr^{-1}$, It was revealed that, with the same amount of dosage, the adsorptive power of activated carbon with lower effective diameter was better and its rate constant was also high.

Carbon Ion Therapy: A Review of an Advanced Technology

  • Kim, Jung-in;Park, Jong Min;Wu, Hong-Gyun
    • Progress in Medical Physics
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    • v.31 no.3
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    • pp.71-80
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    • 2020
  • This paper provides a brief review of the advanced technologies for carbon ion radiotherapy (CIRT), with a focus on current developments. Compared to photon beam therapy, treatment using heavy ions, especially a carbon beam, has potential advantages due to its physical and biological properties. Carbon ion beams with high linear energy transfer demonstrate high relative biological effectiveness in cell killing, particularly at the Bragg peak. With these unique properties, CIRT allows for accurate targeting and dose escalation for tumors with better sparing of adjacent normal tissues. Recently, the available CIRT technologies included fast pencil beam scanning, superconducting rotating gantry, respiratory motion management, and accurate beam modeling for the treatment planning system. These techniques provide precise treatment, operational efficiency, and patient comfort. Currently, there are 12 CIRT facilities worldwide; with technological improvements, they continue to grow in number. Ongoing technological developments include the use of multiple ion beams, effective beam delivery, accurate biological modeling, and downsizing the facility.

Modeling of Thermal Conductivity of Carbon Spun Yarn (탄소 방적사의 열전도도 모델링)

  • Cho Young Jun;Sul In Hwan;Kang Tae Jin;Park Jong Kyoo
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.186-189
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    • 2004
  • A thermal model of carbon spun yam is presented. The unit cell of spun carbon yam is divided into a number of volume elements and the local material properties have been given to each element. By using Finite Difference Method (FDM), temperature distribution in the unit cell can be obtained. Effective thermal conductivity of the spun carbon yam unit cell is calculated using the temperature distribution and thermal conductivities of local elements.

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Single Manufacturer and Multiple Retailers Multi-Product Inventory Model under Cap-and-Trade Mechanism (배출권거래제 하에서 단일 제조업자-다소매업자의 공급사슬에서 다품목의 재고모형)

  • Kim, Dae-Hong
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.42 no.1
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    • pp.158-166
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    • 2019
  • In pursuing carbon emission reduction efforts, companies have focused for the most part on reducing emissions due to the more efficient equipment and facilities. However they overlook a significant source of carbon emissions, one that is driven by operational policies. Currently companies are looking for solutions to reduce carbon emissions associated with their operations. Operational adjustments, such as modifications in order quantities could an effective way in reducing carbon emissions in the supply chain. Also, Cap-and-Trade mechanism is generally accepted as on of the most effective market-based mechanism to reduce carbon emissions. In this paper, we investigate a supply chain with single manufacturer and multiple retailers multi-product inventory model under the cap-and-trade system incorporating the carbon emissions caused by transportation and warehousing activities. Also, we provide an iterative solution algorithm and derive the common order interval and the number of intervals for each product. We show by numerical example that the inventory model incorporating cap & trade mechanism can reduce total cost and carbon emissions compared to the classical inventory model. Using the numerical examples, we also investigates different carbon price on the performance of the inventory model.

Evaluation of Physical Properties and Adsorption Capacity of Regeneration GAC (재생 활성탄의 물성 및 흡착능 평가)

  • Mun, Ji-Young;Chae, Seon-Ha;Wang, Chang-Keun
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.4
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    • pp.407-416
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    • 2009
  • The objective of this study was to evaluate the variation of physical properties and adsorption capacity after regeneration of Granular Activated Carbon (GAC). It was found that the loss rate of regenerated carbon was related to the usage time of GAC. The correlations between iodide number and loss rate also determined. Effective size and uniformity coefficient for regenerated GAC were within a similar range compared to virgin GAC. This result indicated that the function as media is recovered. Although iodide number and specific surface area for regenerated GAC were not completely recovered compared to that of virgin GAC, cumulative pore volumes of regenerated GAC were increased. Removal efficiency of organic matter in regenerated GAC was resulted the same or slightly higher than that of virgin GAC. This result indicates that the number of mesopore responsible for removal of organic matter was increased after regeneration.

Catalytic Pyrolysis of Various Carbon Number Feed Oil Using a Spouted Bed Reactor (Spouted Bed Reactor를 이용한 다양한 탄소수 원료유 촉매 열분해)

  • Yoo, Kyeong Seun;Park, Sung Hoon;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.22 no.6
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    • pp.627-630
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    • 2011
  • We focus on a catalytic process based on direct injection method that can produce high-quality oils of gasoline and kerosene with various carbon-number feed oils. The reaction characteristics of a commercial catalyst were analyzed using a spouted bed reactor. Decane and pentadecane were used to compare the characteristics of the fixed bed and the spouted bed reactor. The yield of gasoline plus kerosene was highest at the reaction temperature of $550^{\circ}C$. For the spouted bed reactor, the at-a-pulse injection was more effective for catalytic cracking of feed oils than multiple consecutive injections. The reaction activity became higher as the carbon number of feed oil is larger.

Nonlinear finite element analysis of Concrete Filled Carbon Tube Columns Using Plasticity Theory (축하중을 받는 콘크리트 충전 탄소섬유튜브 기둥의 소성 이론을 적용한 비선형 유한요소해석)

  • Kim, Heecheul;Seo, Sang Hoon;Lee, Young Hak
    • KIEAE Journal
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    • v.7 no.6
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    • pp.119-126
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    • 2007
  • In the field of composite structures, the use of carbon tube for the confinement of concrete has been arisen since 1990's. However, experimental and analytical studies were limited to those of reinforced concrete and concrete filled steel tube. The carbon tube provides excellent confinement capabilities for concrete cores, enhancing compressive strength and ductility of concrete significantly. The carbon tube has high tensile strength, light weight, corrosion immunity and high fatigue strength properties. Since carbon fiber is an anisotropic material, carbon tube could be optimized by adjusting the fiber orientation, thickness and the number of different layers. In this study, both experimental and analytical studies of axial and lateral behavior of full-scale CFCT (Concrete Filled Carbon Tube) columns subjected to monotonic axial load were carried out using Drucker-Prager theory. And, based on comparison results between experiment results and analytical results, k factor estimation was proposed for effective analysis.

Steam Activated Carbon Preparation Using HTFBR from Biomass and its Adsorption Characteristics

  • Asirvatham, J. Herbert;Gargieya, Nikhar;Paradkar, Manali Sunil;Prakash Kumar, B.G.;Lima Rose, Miranda
    • Carbon letters
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    • v.9 no.3
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    • pp.203-209
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    • 2008
  • The objective of this work is to study the feasibility of the preparation of the activated carbon (AC) from coconut tree flowers using high temperature fluidized bed reactor (HTFBR). The activating agent used in this work is steam. The reactor was operated at various activation temperature (650, 700, 750, 800 and $850^{\circ}C$) and activation time (30, 60, 120 and 240 min) for the production of AC from coconut tree flowers. Effect of activation time and activation temperature on the quality of the AC preparation was observed. Prepared AC was characterized in-terms of iodine number, methylene blue number, methyl violet number, ethylene glycol mono ethyl ether (EGME) surface area and SEM photographs. The best quality of AC from coconut tree flowers (CFC) was obtained at an activation temperature and time of $850^{\circ}C$ and 1 hr restectively. The effectiveness of carbon prepared from coconut tree flowers in adsorbing crystal violet from aqueous solution has been studied as a function of agitation time, carbon dosage, and pH. The adsorption of crystal violet onto AC followed second order kinetic model. Adsorption data were modeled using both Langmuir and Freundlich classical adsorption isotherms. The adsorption capacity $q_m$ was 277.78 mg/g., equilibrium time was found to be 180 min. This adsorbent from coconut tree flowers was found to be effective for the removal of CV dye.