• Title/Summary/Keyword: Effect of alkalinity

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Dyeing Fastness and Functional Properties of Cotton Dyed with Astringent Persimmon Juice

  • Jung, Jin-Soun
    • International journal of advanced smart convergence
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    • v.8 no.3
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    • pp.27-38
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    • 2019
  • I reviewed about dyeing fastness and functional properties of the non-mordant dyed cotton and iron mordant dyed cotton with astringent persimmon juice. In the UV-VIS spectrum of astringent persimmon juice, the maximum absorption wavelength of the juice was 272.0 nm, which was a characteristic peak of tannin. In dyeing fastness, light fastness of the non-mordant dyed cotton was a little low at grade 2~3. But by the iron mordant treatment, the light fastness was good at grade 4. Dry cleaning fastness to discoloration and contamination was excellent at grade 4~5 for both the non-mordant dyed cotton and iron-mordant dyed cotton. Their rub fastness were grade 3 and grade 2~3 respectively, in the dry condition, and grade 2~3 and grade 3 respectively, in the wet condition. In the perspiration fastness of the non-mordant dyed cotton, the discoloration from acidity and alkalinity was grade 3~4 and grade 3, respectively, and contamination from acidity and alkalinity was relatively good at grade 4. Meanwhile, in the perspiration fastness of the non-mordant dyed cotton, discoloration from acidity and alkalinity was fair, both recording grade 3~4, and contamination from acidity and alkalinity was very good, both recording grade 4~5. In the ultraviolet protection effect of the non-mordant dyed cotton and iron-mordant dyed cotton, the ultraviolet protection factor was both 50+, both of which showed an excellent ultraviolet blocking effect. And the protection rate of UV-A appeared 98.4% and 99.1%, respectively, and the protection rate of UV-B showed 98.7% and 99.2, respectively. In addition, both exhibited an excellent deodorization rate over 99.9% or more, irrespective of the passage of time. Also, both showed an excellent antimicrobial activity over 99.9% or more against Staphylococcus aureus and Klebsiella pneumoniae.

Explanation of the Effect of Limestone on the Dissolution of a Phosphate with the Visual MINTEQ Model (Visual MINTEQ모델을 이용한 인산염의 용해에 미치는 석회석의 영향 규명)

  • Kim, Hag Seong;Jeong, Yeon Tae
    • Journal of Korean Society on Water Environment
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    • v.24 no.3
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    • pp.285-290
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    • 2008
  • This study was done to explain the role of limestone which might intervene in the phosphorus cycle in a lake. The effects of limestone on the dissolution of phosphate were estimated by simulations with the computer model Visual MINTEQ, which is designed for the chemical equilibrium calculations. According to the calculations limestone shows remarkable effects for the suppression of phosphate dissolution. The limestone can suppress the dissolution of phosphates by sacrificing themselves to acids, and as a consequence can increase the hardness and alkalinity of the lake. Both hardness and alkalinity play an important role in reducing soluble P and thus alleviate the eutrophication potential.

A Study on the Leachability of Heavy Metals from Steel Mill Slags (제철소 Slag의 중금속 용출특성에 관한 연구)

  • 유재형;이한철
    • Journal of Environmental Science International
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    • v.1 no.1
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    • pp.89-96
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    • 1992
  • In this study , we have investigated leaching characteristics of heavy metals and alkalinity centering around steel mill slags by several extraction methods, for the purpose of risk assessment that exert influence on environment and offer of the foundation data of reuse by slags. Korean standard method, U.S.EPA Extraction Procedure, alkalinity extraction test and 9 step sequential fractionation experiment by Miller et al. were carried out for investigating teachability of steel mill slags. As a result of this experiment, heavy metals were little detected and it was considered that alkalinity does not exert a bad effect around environment in slabs with large particle size. By the result of 9 step fractionation experiment, heavy metal contents in slags were not plentiful, in addition, even comparatively plentiful contended heavy metals, for the most part, were likely to detained or bonded in silica matrix. Therefore, in case of slags with large particle size, it seems that teachability of heavy metals were next to impossible that is existed as a safety condition.

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Impact of Temperature and Alkalinity on Nitrogen Removal in the Start-up Period of Partial Nitrification in a Sequence Batch Reactor

  • Nguyen Van Tuyen;Tran Hung Thuan;Chu Xuan, Quang;Nhat Minh Dang
    • Applied Chemistry for Engineering
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    • v.34 no.5
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    • pp.541-547
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    • 2023
  • The effect of temperature and influent alkalinity/ammonia (K/A) ratio on the start-up of the partial nitrification (PN) process for an activated sludge-based domestic wastewater treatment was studied. Two different sequence batch reactors (SBR) were operated at 26 ℃ and 32 ℃. The relationship between temperature and the concentration of free ammonia (FA) and free acid nitrite (FNA) was investigated. A stable PN process was achieved in the 32 ℃ reactor when the influent ammonium concentration was lower than 150 mg-N/L. In contrast, the PN process in the 26 ℃ reactor had a higher nitrite accumulation rate (NAR) and ammonium removal efficiency (ARE) when the influent ammonia concentration was increased to more than 150 mg-N/L. Then three different ranges of the K/A ratio were applied to an SBR reactor. In the K/A range of 2.48~1.65, the SBR reactor achieved the highest NAR ratio (75.78%). This ratio helps to achieve the appropriate level of alkalinity to maintain a stable pH and provide a sufficient amount of inorganic carbon source for the activity of microorganisms. At the same time, FA and FNA values also reached the threshold to inhibit nitrite-oxidizing bacteria (NOB) without a significant effect on ammonia-oxidizing bacteria (AOB). Results showed that the control of temperature and K/A ratio during the start-up period may be important in establishing a stable and steady PN process for the treatment of domestic wastewater.

The Effect of Sulfur/Limestone Ratio on the Efficiency of Sulfur-Utilizing Denitrification (황/석회석 충전비가 황-이용 탈질효율에 미치는 영향)

  • Shin, Hyung-Soon;Lee, Il-Su;Hwang, Yong-Yoo;Bae, Jae-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.3
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    • pp.271-280
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    • 2000
  • This study was conducted to determine the applicable loading rate and to evaluate the possibility of using limestones as an alkalinity source for the removal of ${NO_3}^{-}-N$ remaining after denitrification/nitrification process with the down-flow sulfur packed bed reactor(SPBR). The pretreated sewage was fed to SPBR. Three SPBRs were filled with elemental sulfur particles and limestones and the volumetric ratios of sulfur to limestone were 0%, 12.5% and 25% for R-0%, R-12.5% and R-25%, respectively. The applicable loading rate was evaluated increasing flow rate with influent ${NO_3}^{-}-N$ concentration of 20 mg/L. For R-0% with external alkalinity supply, denitrification efficiency was greater than 96% up to loading rate of $354.8g\;{NO_3}^{-}-N/m^3{\cdot}day$, and corresponding EBCT was 1.4hr. For R-12.5% and R-25%, where alkalinity was supplied by the limestone filled in the reactor, denitrification efficiency was greater than 94% up to loading rate of $283.8g\;{NO_3}^{-}-N/m^3{\cdot}day$, and corresponding EBCT was 1.7hr. The slightly better performance of R-12.5 compared to R-25 suggests that the volumetric sulfur to limestone ratio of 12.5% was enough for the supply of alkalinity required for sulfur-utilizing denitrification. DO was appeared not showing inhibitory effect on sulfur-utilizing denitrification. The clogging of SPBR caused by the produced gas can effectively be eliminated by regular introduction of treated water in up-flow mode.

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Dynamics of Hexavalent Chromium in Four Types of Aquaculture Ponds and Its Effects on the Morphology and Behavior of Cultured Clarias gariepinus (Burchell 1822)

  • Mustapha, Moshood Keke
    • Toxicological Research
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    • v.33 no.2
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    • pp.119-124
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    • 2017
  • Hexavalent chromium is a bio accumulative toxic metal in water and fish. It enters aquaculture ponds mainly through anthropogenic sources. Hexavalent chromium concentrations and its effects on the morphology and behavior of Clarias gariepinus were investigated from four aquaculture ponds for 12 weeks. Chromium was measured using diphenyl carbohdrazide method; alkalinity and hardness were measured using colometric method and analyzed with Bench Photometer. Temperature and pH were measured using pH/EC/TDS/Temp combined tester. Temporal and spatial replications of samples were done with triplicates morphological and behavioural effects of the metal on fish were observed visually. Chromium ranged from no detection to 0.05 mg/L, alkalinity 105 to 245 mg/L, hardness 80 to 165 mg/L, pH 6.35 to 8.03 and temperature 29.1 to $35.9^{\circ}C$. Trend in the chromium concentrations in the ponds is natural > earthen > concrete > collapsible. There was a significant difference (P < 0.05) in chromium, alkalinity, water hardness, pH and temperature among the four ponds. Significant positive correlation also existed between alkalinity, water hardness, pH, with chromium. Morphological and behavioural changes observed in the fish include irregular swimming, frequent coming to the surface, dark body colouration, mucous secretion on the body, erosion of gill epithelium, fin disintegration, abdominal distension and lethargy. High chromium concentration in natural pond was due to anthropogenic run-off of materials in to the pond. Acidic pH, low alkalinity, low water hardness also contributed to the high chromium concentration. Morphological and behavioural changes observed were attributed to the high concentrations, toxicity and bio accumulative effect of the metal. Toxicity of chromium to fish in aquaculture could threaten food security. Watershed best management practices and remediation could be adopted to reduce the effects of toxicity of chromium on pond water quality, fish flesh quality and fish welfare.

PIGMENT STABILIZATION OF FRESH UNDARIA PINNATIFIDA WHEN TREATED WITH ASHES (재(회) 처리의 미역 색소 안정화 효과)

  • Kim Sang-Ae;Lee Bang-Bo;PARK Dong-Bun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.3 no.2
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    • pp.120-128
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    • 1970
  • In this study, changes in chlorophyll and carotenoid pigment in fresh and ash treated Undaria pinnetifida were determined by column chromatography. And pigment stabilizing effects of ashes were discussed. The results obtained are summarized as follows: 1. The main carotenoids of Undaria pinnetifida are fucoxanthin, violaxanthin, lutein and $\beta-carotene$. 2. In storage of fresh Undaria pinnetifida at $2-5^{\circ}C$ for 30 days, chlorophyll a decreased rapidly and mainly converted to pheophytin a. Among carotenoids, lutein was markedly lost while the others retained approximately $30\%$ after 30 days' storage. 3, By treating the sample with ashes, the loss of chlorophyll a was restrained whereas that of carotenoids seemed to be promoted. It is considered that pigment stabilization was attributed to both effect, the pH control effect by the alkalinity of ashes and the fixation of the pigment by heavy metals in ashes. The stabilizing effect of chlorophyll a differed from the kind of ashes used. Reed ashes showed better effect than others such as straw or pine ashes. 4. Since fucoxanthin is extremely sensitive to alkali the treatment of ashes with a high alkalinity resulted in rapid decrease of the pigment during storage. 5. In the analysis of ashes, reed ashes which had better effect on chlorophyll a retention than the other ashes showed the highest content of iron.

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Synthesis of zeolite from power plant fly ash (화력발전소 비산회를 이용한 제올라이트합성)

  • 김재환;연익준;김광렬
    • Journal of environmental and Sanitary engineering
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    • v.12 no.1
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    • pp.49-58
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    • 1997
  • A study on the synthesis of zeolite from bituminous coal ESP fly ash as a raw material, which was emitted from the power plant, was carried out to reduce environmental problems and reuse of the industrial wastes. Bituminous coal fly ash was used as the source of silica and alumina. Zeolite was synthesized by hydrothermal reaction in aqueous NaOH solution with sodium aluminate as additive. The objective of this study is to elucidate the effect of several experimental variables on the synthesis of zeolite. The effects of preroasting temperature, mixing speed, leaching alkalinity, and molar ratio of Na$_{2}$O/SiO$_{2}$ and SiO$_{2}$/Al$_{2}$O of the products were investigated. The synthesized zeolite was proved to be NaA, which is known as 4A type, by comparing with SEM images, and X-ray diffraction analysis. And also we know that the transformation of zeolite A take places into other types of zeolites, i.e. Hydroxysodalite, zeolite P, with the variation of leaching alkalinity.

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The Effect of Temperature on the Stable Region of Magnesium Ion in Aqueous System (수중 마그네슘이온의 안정영역 변화에 대한 온도효과)

  • Kim, Hee-Jin;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.27 no.4
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    • pp.438-444
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    • 2011
  • Magnesium is one of the abundant natural resources in the earth crust and seawater, which is directly related to various organisms activities interconnecting with water-rock system. In aqueous system, magnesium is known to predominantly exist in the form of $Mg^{2+}$ ion which is verified in its $E_h-pH$ diagram. When it is at equilibrium in aqueous system, temperature takes an essential role to complete equilibrium states. This study represents the change of the stable region of magnesium ion according to temperature, and how the consequences would affect aquatic organisms. It was revealed that there is a noticeable tendency shrinking the stable region of magnesium ion in a diagram as temperature increases, and as a result, aquatic bio-species presumably have difficulties to absorb the nutrient. Also, it was considered that the water system would be acidified by decreasing alkalinity.

The Effects of pH and Alkalinity Adjustment on Internal Corrosion Control and Water Quality in Drinking Water Pipelines (정수의 pH 및 알칼리도 동시 조절이 상수도관의 내부부식 제어 및 수질에 미치는 영향)

  • Lee, Hyun-Dong;Jung, Hae-Ryong;Kwak, Phill-Jae;Chung, Won-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.661-669
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    • 2000
  • This research was carried out to evaluate effect of metallic release and change of water corrosive indices by the pH and alkalinity adjustment using the SDLS (Simulated Distribution Loop System) which consist of six types of pipe loop with DCIP, PVC, PE, STS304, CP, GSP, respectively, and its effects on water quality changes which were microbes quality(SPC), residual chlorine. THMs and other parameters. And it was to propose optimal criteria of water quality control for the field application. According to the results, water control system by pH and alkalinity adjustment showed the changing of corrosive water and reducing of metallic release rate and it was not affects of THMs formation, microbes regrowth and variation of other parameters. Water quality stability and corrosion control were due to calcium carbonate precipitation film formation of pipe inner by water quality control. Therefore, corrosive water control system by pH and alkalinity adjustment can be attributed to effective water quality management in water distribution system according to water quality stability of pH and TIC(Total Inorganic Carbonate concentration) that affect the precipitation and dissolution of solids.

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