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Magnetic Circular Dichroism Study of co Thin Films on Pd(111) Surface

  • Kim, Wookje;Kim, Wondong;Kim, Hyunjo;Kim, Jae-Young;Hoon Kho;Park, J.H.;Oh, S.J.
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.169-169
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    • 1999
  • We studied magnetic properties of co thin films deposited on Pd (111) surface, which attracted much attention recently due to the perpendicular magnetic anisotropy, using magnetic circular dichroism(MCD). Special attention was paid on the effect of Pd capping and interface roughness on the direction of magnetic easy axis, and for that purpose MCD signals for all Co thicknesses were measured with two different ways : in-plane and out-of-plane geometry. In case of bare Co films deposited on smooth Pd(111) surface, no MCD signal was observed under 4$\AA$ co thickness. At 4$\AA$ Co thickness, MCD signal at the out-of-plane geometry was observed, and for thicker Co films, only in-plane MCD signal was measured. This type of magnetic easy axis transition has been reported for other cases like Co/Pt system. The effect of 5$\AA$ Pd capping on these bare Co films made an remarkable change on the transition of magnetic easy axis. Out-of-plane MCD signals exists up to 20$\AA$ Co thickness, and disappears at 24$\AA$ Co thickness. In-plane MCD signals first appears at 10$\AA$ Co thickness and gradually increases up to 24$\AA$ Co thickness. Between 10$\AA$ and 20$\AA$ Co thickness, in-plane and out-of-plane MCD signal coexist. The formation of multi-domain structure or the existence of tilted magnetic easy axis is an possible scenario for such an interesting coexistence. The effect of interface roughness was also tested by measuring MCD signal on Co films deposited on un-annealed Pd(111) surface. Out-of-plane MCD signal was observed up to 8$\AA$ Co thickness and the anisotropy of MCD signal at 4$\AA$ Co thickness was very large with respect to that of Co film deposited on the smooth substrate. Above 8$\AA$ thickness, there exists only in-plane MCD signal. From above results, it was concluded that both Pd capping and interface roughness induce and reenforce the perpendicular magnetic anisotropy. The large perpendicular magnetic anisotropy of Co/Pd multilayer system made by sputtering method can be well understood from our results.

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Structure and Magnetic Properties of $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ Compounds ($(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ 화합물의 구조 및 자기특성)

  • 김희태;김윤배;김창석;김택기;권혁무
    • Journal of the Korean Magnetics Society
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    • v.3 no.3
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    • pp.196-200
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    • 1993
  • $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ compounds have tetragonal $ThMn_{12}$-type structure and show the uniaxial magnetocrystalline anisotropy with the easy magnetization c-axis. Among the $(Sm_{0.5}RE_{0.5})Fe_{11}Ti$ series, RE=Sm shows the highest anisotropy field of 11200 kA/m(140 kOe). On the other hand, RE=Nd has the highest saturation magnetization of $122.3\;Am^{2}/kg$(122.3 emu/g) and RE=Gd the highest Curie temperature of $326^{\circ}C$.

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Electric Characteristics of $V_2O_5-P_2O_5$ Glass Semiconductor ($V_2O_5-P_2O_5$계 유리반도체의 전기적 특성)

  • 이강호
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.8 no.1
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    • pp.12-16
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    • 1983
  • This paper is dealing a $V_3O_5-P_2O_5$ metal oxide glass semiconductor. This semiconductor is easy to fabricate in the atmospheric condition at relatively low temperature. The element is made like a bead, and platinum segments are used as electrodes. Other kind of metal withstanding high temperature near 1000C can also be used as electrode. Experiment verifies that the fabricated element has the resistance in the order of about ~$10^5\;\Omega$, and shows negative resistance characteristics and switching characteristics with respect to temperature. An equivalent circuit of the element is proposed based on its electrical characteristcs.

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A Study of Correlation between Experiment and Analysis of Nonlinear Behaviors of A 1:5 Scale RC Frame with Nonseismic Details (비내진 상세를 가진 1:5 축소 철근콘크리트 골조의 비선형 거동에 대한 실험과 해석의 상관성 연구)

  • 이한선;우성우;허윤섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.483-486
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    • 1999
  • A series of dynamic and static tests were conducted to observe the actual responses of a 1:5 scale 3-story reinforced concrete (RC) frame which was designed only for gravity loads. One of the major objectives of these experiments are to provide the calibration to the available static and dynamic inelastic techniques. In this study, the experimental results were simulated by using a nonlinear analysis program for reinforced concrete frame, IDARC-2D. The evaluation of the degree of the simulation leads to the conclusion that while the global behaviors such as story drifts and shears can be in general simulated with the limited accuracy in the dynamic nonlinear analysis, it is rather easy and simple to get the fairly high level of accuracy in the prediction of global and local behaviors in the static nonlinear analysis by using IDARC-2D.

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A Study on the Microstructure and Mechanical Properties for the Weldment with Variation of Welding Process of the API 5L-B42 Pipeline for Natural Gas Transmission (천연가스 수송용 API 5L-X42 강관의 용접방법에따른 용접부의 미세조직과 기계적 특성에 관한 연구)

  • Baek Jong-Hyun;Kim Cheol-Man;Kim Young-Pyo;Kim Woo-Sik
    • 한국가스학회:학술대회논문집
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    • 1997.09a
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    • pp.33-38
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    • 1997
  • Demand of the clean and convenient natural gas has continuously increased with recognizing of the environment problem since liquefied natural gas was introduced in Korea. Clean fuel natural gas was supplied to each city through high tensile strength pipeline connected by welding. Grades of pipeline were divided into the high and middle pressure according to supply pressure. Pipeline was welded mainly SMA welding process due to its easy handling, the other welding process was adopted according to the constructing condition. We were examined on the microstructure variation and mechanical properties of weld metal for high pressure pipeline, API 5L X-42.

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Syntheses of Rayon-like Polyester (Rayon-like 폴리에스터의 합성(合成))

  • Ahn, Young-Moo;Park, Young-Gi
    • Journal of Fashion Business
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    • v.11 no.5
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    • pp.155-164
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    • 2007
  • Viscose rayon has advantages such as vivid luster, good dyeability, low static electricity, good absorbance and good spinnability but also has flaws such as easy crease and decrease of physical properties when it gets wetting, and it requires dry cleaning. Therefore in order to synthesize the polymer to solve the problems of rayon while keeping the advantages of it, this study made the high specific gravity polyester for ultra drape property and high contraction polyester for rayon-like fiber having volume, soft and warm sense. The polyester with high specific gravity, 1.47 was made by adding 7 wt% of $BaSO_4$ as additive. High contraction polyester was made by copolymerization by using IPA 5 mole% to increase the amorphous region as comonomer and also using Newpol BPE-20(NPE) 1.5 wt% not to decrease the properties.

Studies on Air-bridge fabrication using thermal evaporation method and its aplication (열적 증착법을 이용한 air-bridge 제작과 그 응용에 관한 연구)

  • 이일형;김성수;윤관기;김상명;이진구
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.12
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    • pp.53-58
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    • 1996
  • In this paper, a simple fabrication technique of an air-bridge for interconnection of isolated electrodes of microwave active and passive devices and MMIC's is proposed. The proposed air-bridge proceses are mainly combinations of thermal evaporation, positive photoresist and image reversal processes for easy lift-off of up to 2.0 .mu.m thick metal. According to the resutls of air-birdge processes, it is confirmed that air-gap and thickness of theair-bridge are about 3.5.mu.m, and 2.0.mu.m, respectively. And it is also possible to make the fine air-bridge with widths of 5~60.mu.m and post-intervals of 25~200.mu.m withot collapse. finally, GaAs power MESFET's and rectangular spiral inductors are fabricatd and measured in order to confirm of feasibility of the proposed air-bridge processes. The MAG of the fabricated power MESFET's is 10dB at 10GHz, and the inductance of the (200.mu. * 6 turns) rectangular spiral inductors 4.5 nH inX-band.

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A Study on the Thermodynamic and Electrochemical Properties of MmNi5 System Hydrogen Absorbing Alloys Mixed with Nickel Powder (니켈분말 첨가에 따른 MmNi5계 수소저장합금의 열역학 및 전기화학적 특성)

  • Choi, Weon-Kyung;Cho, Tae-Hwan
    • Transactions of the Korean hydrogen and new energy society
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    • v.7 no.1
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    • pp.63-69
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    • 1996
  • Effect of nickel powder to added to the hydrogen absorbing alloy electrode of $MmNi_{4.5}-xCoxMn_{0.3}Al_{0.2}$ system alloy was investigated. The addition of nickel powder was effective for the improvement of discharging characteristic. It was found that the discharge capacity was 310mAhig when the alloy negative electrode was mixed $MmNi_{3.75}CO_{0.75}Mn_{0.3}Al_{0.2}$ and nickel powder with a mix of one to three. Still another, we have investigated thermodynamic stability of hydrogen in the alloy negative electrode. As a result, enthalpy of hydrogen and hydrogen equilibrium pressure in the alloy negative electrode were a suitable value to easy hydrogen absorption-desorption.

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A Study on the present and future trend of the new fabrics of apparel (의류용 섬유 신소재의 현재와 미래 동향에 관한 연구)

  • 김희선;구희경
    • Journal of the Korea Fashion and Costume Design Association
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    • v.2 no.1
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    • pp.5-20
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    • 2000
  • This study classified the new fabrics of apparel Which was published in the domestic magazines newspapers since late nineteen-nineties and analyzed the characteristics of each new fabrics. We propose the recent trend of the development of new fabrics and therefore, predict the new fabric trend of the future. The new fabrics of apparel were classified as, 1. Sanitation and health promoting new fabric. 2. Aesthetic promoting new ones. 3. High functional new ones. 4. Natural fabric oriented new ones. 5. Pro-environmental new ones. The developmental trend of future new fabrics were predicted as followings 1. The pursuit of development of Pro-environmental textile materials 2. The pursuit of development of health enhancing textile materials 3. The pursuit of development of easy-controlling textile materials 4. The pursuit of development of long lasting-comfortable textile materials 5. The pursuit of development of high-aesthetic textile materials 6. The pursuit of development of textile materials Which have the advantages of the natural fabrics Conclusively, the new fabrics of apparel will be developed as the one which has above complicated multi-function and chaotic ability to fitting to environmental change.

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Reactions with Halogenated Compound: Synthesis of Several New Pyrazolo[3,2-c] triazine and 2-Benzenesulfonylglyoxal arylhydrazone Derivatives

  • Abdelhamid, Abdou O.;Attaby, Fawzy A.;Khalifa, Fathy A.;Ghabrial, Sami S.
    • Archives of Pharmacal Research
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    • v.15 no.1
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    • pp.14-19
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    • 1992
  • Diazotized primary artomatic amines 4 coupled with the ketosulfones 1-3 in ethanol in the presence of sodium acetate at $0^\circ{C}$ to afford the corresponding bydrazones 5-7. Also diazotized 3-aminopyrazoles 14 coupled with 1-3 in ethanolic sodium acetate to give the pyrazolotriazines 18-20 in good yields. Compounds 5-7 and 18 can also be obtained from the reaction of hydraziodoyl halides 8-10 and 21 with sodium benzenesultinate. The hydrazones 11-13 can easy be oxidized to the hydrazones 5-7, using hydrogen peroxide in acetic acid.

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