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CaYAlO4:Tb3+/Eu3+/Ce3+형광체의 광학적 특성 분석 (Optical Properties of CaYAlO4:Tb3+/Eu3+/Ce3+ Phosphors)

  • 강태욱;류종호;김종수;김광철
    • 반도체디스플레이기술학회지
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    • 제16권4호
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    • pp.86-90
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    • 2017
  • $Tb^{3+}$ or $Eu^{3+}$ or $Ce^{3+}$-doped $CaYAlO_4$ phosphor were synthesized by solid-state method. $CaYAlO_4:Tb^{3+}$ is shown that the $Tb^{3+}$-doping concentration has a significant effect on the $^5D_4/^5D_3{\rightarrow}7F_J$ (J=6,...,0) emission intensity of $Tb^{3+}$. The $CaYAlO_4:Tb^{3+}$ phosphors show tunable photoluminescence from blue to yellow with the change of doping concentration of $Tb^{3+}$ ions. The $CaYAlO_4:Eu^{3+}$ phosphors exhibit a red-orange emission of $Eu^{3+}$ corresponding to $^5D_0$, $_{1,2}{\rightarrow}^7F_J$ (J=4,...,0) transitions. The $CaYAlO_4:Ce^{3+}$ phosphors show a blue emission due to $Ce^{3+}$ ions transitions from the 5d excited state to the $^2F_{5/2}$ and $^2F_{7/2}$ ground states. The decay time of $CaYAlO_4:Tb^{3+}$ phosphors decrease from 1.33 ms to 0.97 ms as $Tb^{3+}$ concentration increases from 0.1 mol% to 7 mol%. The decay time of $CaYAlO_4:Eu^{3+}$ phosphors increase from 0.94 ms to 1.17 ms as $Eu^{3+}$ concentration increases from 1 mol% to 9 mol%.

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한·미·EU의 개인정보보호 동향 및 정책에 대한 고찰 (A Study on the Privacy Protection Trends and Policies of Korea·the U.S.·EU)

  • 조세홍
    • 한국항행학회논문지
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    • 제26권4호
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    • pp.244-248
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    • 2022
  • 최근에 사람들이 경험하고 있는 다양한 디지털 서비스는 일상 생활의 변화를 가져 오고 있고, 이러한 변화는 4차 산업혁명의 확산에 기인하고 있다. 4차 산업혁명은 정보통신 기술의 발전에 기반을 두고 있으며, ICT 기술은 필연적으로 공공데이터 활용뿐만 아니라 개인 정보의 활용과 보호라는 이슈를 발생시킨다. 이에 세계 각국은 법제정 등을 통하여 개인정보의 활용과 보호라는 서로 상충되는 쟁점을 현명하게 해결하여 신산업을 활성화를 시키고자 노력을 하고 있다. 한국, 미국, EU에서는 개인정보 보호와 활용에 있어 약간의 차이점을 보이고 있다. 우리나라에서는 데이터의 활용이 우선순위를 지닌 법 제정, 미국은 분야별로 개인정보 보호를 규율하는 개별 법률 제정, EU는 개인정보보호에 대한 강화를 명확히 하고 있다. 본 고에서는 우리나라와 미국, EU에서 개인정보보호를 어떻게 규정하고 있는지 제정된 법을 통하여 알아보고 정책에 대한 방향을 정리하고자 한다.

Eu3+ 이온의 몰 비 변화에 따른 MgMoO4:Dy3+,Eu3+ 형광체의 광학 특성 (Optical Properties of MgMoO4:Dy3+,Eu3+ Phosphors Prepared with Different Eu3+ Molar Ratios)

  • 김정대;조신호
    • 한국전기전자재료학회논문지
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    • 제29권3호
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    • pp.186-191
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    • 2016
  • The effects of $Eu^{3+}$ doping on the structural, morphological, and optical properties of $MgMoO_4:Dy^{3+},Eu^{3+}$ phosphors prepared by solid-state reaction technique were investigated. XRD patterns exhibited that all the synthesized phosphors showed a monoclinic system with a dominant (220) diffraction peak, irrespective of the content of $Eu^{3+}$ ions. The surface morphology of $MgMoO_4:Dy^{3+},Eu^{3+}$ phosphors was studied using scanning electron microscopy and the grains showed a tendency to agglomerate as the content of $Eu^{3+}$ ions increased. The excitation spectra of the phosphor powders were composed of a strong charge transfer band centered at 294 nm in the range of 230~340 nm and two intense peaks at 354 and 389 nm, respectively, arising from the $^6H_{15/2}{\rightarrow}^6P_{7/2}$ and $^6H_{15/2}{\rightarrow}^4M_{21/2}$ transitions of $Dy^{3+}$ ions. The emission spectra of the $Mg_{0.85}MoO_4$:10 mol% $Dy^{3+}$ phosphors without incorporating $Eu^{3+}$ ions revealed a strong yellow band centered at 573 nm resulting from the $^4F_{9/2}{\rightarrow}^6H_{13/2}$ transition of $Dy^{3+}$. As the content of $Eu^{3+}$ was increased, the intensity of the yellow emission was gradually decreased, while that of red emission band located at 614 nm began to appear, approached a maximum value at 10 mol%, and then decreased at 15 mol% of $Eu^{3+}$. These results indicated that white light emission could be achieved by controlling the contents of the $Dy^{3+}$ and $Eu^{3+}$ ions incorporated into the $MgMoO_4$ host crystal.

우리나라, 미국 및 유럽의 대기환경기준 강도에 관한 비교 연구 (A Comparative Study on the Ambient Air Quality Standard Strength among Korea, the U.S.A. and the EU)

  • 박민빈;이태정;이은선;김동술
    • 한국대기환경학회지
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    • 제32권6호
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    • pp.559-574
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    • 2016
  • Based on air quality monitoring data ('10~'14) of Suwon City provided by the Korean Department of Environment, a fundamental statistic for 5 criteria pollutants such as $SO_2$, CO, $NO_2$, $O_3$, and $PM_{10}$ was initially investigated. The purpose of this paper was to review the ambient air quality standards(AAQS) of Korea, the U.S.A. and the EU and further to assess the degree of standard strength by the achievability of the AAQS comparing each national standard. Since the level and the way of standards for each air pollutant are various among countries, it is difficult to determine the degree of relative attainment using the same set of data above. Further when all the areas having bad air quality for a specific pollutant are classified as non-attainment case, it is more difficult to assess the degree of standard strength. Thus we introduced a new concept called the average concentration distance (ACD) to quantitatively estimate the strength. As results, the Korean 1-hr $NO_2$ AAQS is slightly stronger than the US standard and weaker than the EU standard. The Korean $O_3$ standard is strongest; however, the Korean $PM_{10}$ standard is weakest. Furthermore the equivalent levels of 8-hr $O_3$ standards in the U.S.A. and the EU were respectively estimated as 97.5 and 95.7 percentiles of the Korean standard with maintaining the existing standard of 60 ppb.

백색 LED용 청록색 BaSi2O2N2:Eu2+ 형광체의 합성 및 응용 (Synthesis and Application of Bluish-Green BaSi2O2N2:Eu2+ Phosphor for White LEDs)

  • 지순덕;최강식;최경재;김창해
    • 한국재료학회지
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    • 제21권5호
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    • pp.250-254
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    • 2011
  • We have synthesized bluish-green, highly-efficient $BaSi_2O_2N_2:Eu^{2+}$ and $(Ba,Sr)Si_2O_2N_2:Eu^{2+}$ phosphors through a conventional solid state reaction method using metal carbonate, $Si_3N_4$, and $Eu_2O_3$ as raw materials. The X-ray diffraction (XRD) pattern of these phosphors revealed that a $BaSi_2O_2N_2$ single phase was obtained. The excitation and emission spectra showed typical broadband excitation and emission resulting from the 5d to 4f transition of $Eu^{2+}$. These phosphors absorb blue light at around 450 nm and emit bluish-green luminescence, with a peak wavelength at around 495 nm. From the results of an experiment involving Eu concentration quenching, the relative PL intensity was reduced dramatically for Eu = 0.033. A small substitution of Sr in place of Ba increased the relative emission intensity of the phosphor. We prepared several white LEDs through a combination of $BaSi_2O_2N_2:Eu^{2+}$, YAG:$Ce^{3+}$, and silicone resin with a blue InGaN-based LED. In the case of only the YAG:$Ce^{3+}$-converted LED, the color rendering index was 73.4 and the efficiency was 127 lm/W. In contrast, in the YAG:$Ce^{3+}$ and $BaSi_2O_2N_2:Eu^{2+}$-converted LED, two distinct emission bands from InGaN (450 nm) and the two phosphors (475-750 nm) are observed, and combine to give a spectrum that appears white to the naked eye. The range of the color rendering index and the efficiency were 79.7-81.2 and 117-128 lm/W, respectively. The increased values of the color rendering index indicate that the two phosphor-converted LEDs have improved bluish-green emission compared to the YAG:Ce-converted LED. As such, the $BaSi_2O_2N_2:Eu^{2+}$ phosphor is applicable to white high-rendered LEDs for solid state lighting.

고상반응법과 착체중합법으로 합성된 SrAl2O4: Eu2+, Dy3+ 축광성 형광체의 특성 및 열적 안정성 평가 (Characteristics and thermal stability of SrAl2O4: Eu2+, Dy3+ long afterglow phosphors synthesized solid state reaction and polymerized complex method)

  • 김태호;황해진;김진호;황광택;한규성
    • 한국결정성장학회지
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    • 제26권5호
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    • pp.193-200
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    • 2016
  • 고상반응법과 착체중합법 두 합성법에 의해 합성된 $SrAl_2O_4:Eu^{2+}$, $Dy^{3+}$ 축광성 형광체 분말의 특성을 비교 분석하였다. 열적 안정성을 평가하기 위해 산업 도자 제조공정에서 사용되는 열처리 조건($1250^{\circ}C$, 1시간 유지, LPG 환원분위기)을 적용하여 고상반응법과 착체중합법으로 합성된 $SrAl_2O_4:Eu^{2+}$, $Dy^{3+}$ 축광성 형광체 분말의 열처리 전후의 축광 특성변화를 관찰하였다. 두 합성법으로 합성된 분말과 고온 열처리 전후의 분말은 XRD 분석을 통해 결정구조 및 결정자 크기변화를 확인하였고, SEM과 PSA 분석을 이용하여 미세구조 및 입자 크기 변화를 관찰하였다. Spectrofluorometer 분석을 통해 $SrAl_2O_4:Eu^{2+}$, $Dy^{3+}$ 축광성 형광체의 여기 및 발광 특성, 장잔광 특성 변화를 확인하였다.

The Prominence of USD/CNY in China-EU and China-UK Trade

  • BAO, Ho Hoang Gia;LE, Hoang Phong
    • The Journal of Asian Finance, Economics and Business
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    • 제8권11호
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    • pp.47-66
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    • 2021
  • Despite the dominance of the USD as a vehicle currency in non-US trade, most studies on the exchange rate-trade balance relationship ignore its importance. Some recent J-curve papers have proved that incorporating the role of USD as vehicle currency as a crucial determinant of trade balance can well reflect the reality of global trade and provide more detailed findings. Motivated by this new approach and by the fact that USD is substantially used in the trade between China and the EU and the UK, this paper scrutinizes how the vehicle currency USD and the bilateral exchange rates asymmetrically affect China's trade balance with each EU country and the UK. The results of NARDL estimation indicate that the USD models outperform the bilateral exchange rate (BER) models in terms of detecting significant long-run and short-run coefficients, which confirms the usefulness of the new approach. Also, this paper finds that the USD/CNY exchange rate cannot be neglected in China's trade with the EU and the UK, which can supplement China's policies on international trade and foreign exchange management.

착체중합법을 이용한 SrAl2O4: Eu2+, Dy3+ 축광성 형광체의 합성 (Synthesis and Characteristics of SrAl2O4: Eu2+, Dy3+ Long Afterglow Phosphors by Polymerized Complex Method)

  • 김태호;황해진;김진호;황광택;한규성
    • 한국재료학회지
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    • 제26권10호
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    • pp.561-569
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    • 2016
  • $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphorescent phosphors were synthesized using the polymerized complex method. Generally, phosphorescent phosphors synthesized by conventional solid state reaction show a micro-sized particle diameter; thus, this process is restricted to applications such as phosphorescent ink and paint. However, it is possible to synthesize homogeneous multi-component powders with fine particle diameter by wet process such as the polymerized complex method. The characteristics of $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ powders prepared by polymerized complex method with one and two step calcination processes were comparatively analyzed. Temperatures of organic material removal and crystallization were observed through TG-DTA analysis. The crystalline phase and crystallite size of the $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphorescent phosphors were analyzed by XRD. Microstructures and afterglow characteristics of the $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphors were measured by SEM and spectrofluorometry, respectively.

A Study on Decommissioning Strategy for Wolsong-1

  • Park, Byeong Ik;Oh, Eu Tteum;Lee, Hyoung Woo;Jeon, Ji Han;Kim, Chang Lak
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2018년도 추계학술논문요약집
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    • pp.380-381
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    • 2018
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Effect of Cell Source and pH of Culture Medium on the Production of Canthin-6-one Alkaloids from the Cell Cultures of Tongkat Ali (Eurycoma longifolia Jack)

  • Mahmud, Luthfi-Aziz;Chan;Boey
    • Journal of Plant Biotechnology
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    • 제6권2호
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    • pp.125-130
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    • 2004
  • Callus and cell suspension cultures of Eurycoma longifolia Jack could be an alternative supply of 9-hydroxycanthin-6-one and 9-methoxycanthin-6-one. The callus tissues were initiated from leaves of different trees. The friable calli were used for the preparation of the cell suspension cultures of E. longifolia. The leaf explant of tree Eu-9 produced the most callus and also induced high cell biomass in the cell suspension culture, but it produced low quantity of 9-methoxycanthin- 6-one and 9-hydroxycanthin-6-one. The leaf explant from tree Eu-8 produced low quantity of callus and cell biomass, but produced the highest quantity of 9-methoxycanthin- 6-one and 9-hydroxycanthin-6-one. Optimum production of cell biomass was obtained on cell culture medium with pH 5.75 prior to autoclaving, but high alkaloids content could be induced in culture medium in acidic condition with pH 4.75 and 5.25 prior to autoclaving.