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Quantitative Estimation of Pollution Loading from Hwaseong Watershed using BASINS/HSPF (BASINS/HSPF를 이용한 화성유역 오염부하량의 정량적 평가)

  • Jung, Kwang-Wook;Yoon, Chun-G.;Jang, Jae-Ho;Kim, Hyung-Chul
    • Journal of The Korean Society of Agricultural Engineers
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    • v.49 no.2
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    • pp.61-74
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    • 2007
  • A mathematical modeling program called Hydrological Simulation Program-FORTRAN (HSPF) developed by the United States Environmental Protection Agency (EPA) was applied to Hwaseong watershed. It was run under BASINS (Better Assessment Science for Integrating Point and Nonpoint Sources) program, and the model was validated using monitoring data of $2002{\sim}2005$. The model efficiency of runoff ranged from good to fair in comparison between simulated and observed data, while it was from very good to poor in the water quality parameters. But its reliability and performance were within the expectation considering complexity of the watershed and pollutant sources. The nonpoint source (NPS) loading for T-N and T-P during the monsoon rainy season (June to September) was about 80% of total NPS loading, and runoff volume was also in a similar range. However, NPS loading for BOD ($55{\sim}60%$) didn't depend on rainfall because BOD was mostly discharged from point source (more than 70%). And water quality was not necessarily high during the rainy season, and showed a decreasing trend with increasing water flow. BASINS/HSPF was applied to the Hwaseong watershed successfully without difficulty, and it was found that the model could be used conveniently to assess watershed characteristics and to estimate pollutant loading including point and nonpoint sources in watershed scale.

Event Mean Concentration of Nitrogen and Phosphorus from a Dairy and Crop Farming Complex Watershed

  • Yoon, Kwang-Sik;Shirmohammadi, Adel;Choi, Woo-Jung;Jung, Jae-Woon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.48 no.7
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    • pp.65-72
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    • 2006
  • Event mean concentration (EMC) of nitrogen (N) and phosphorus (P) is primary information for non-point source pollution assessment of a watershed. The EMCs for various types of agriculture such as dairy and crop farming under different climate and geologic conditions are not fully investigated. A diary- and cropfarming complex agricultural watershed in Piedmont region in Maryland, USA has been monitored for 10 years as a section 319 national monitoring program of US EPA. Dairy manure was the main source of fertilizer for crop farming in this watershed. Observed mean concentrations of N and P for each event were analyzed. Distribution of EMCs for N and P showed a wide range of variations. Representative EMCs of T-N and $NO_{3}-N$ tended to be higher than those reported for other agricultural watersheds. This study confirmed that site-specific EMC information for various agricultural practices is required for better assessment of non-point source pollution using EMC method.

Effect n-3 Polyunsaturated Fatty Acids on Serum Lipoprotein and Lipid Compositions in Human Subjects (사람에서 n-3계 불포화지방산이 Serum Lipoprotein과 지질조성에 미치는 영향)

  • 박현서
    • Journal of Nutrition and Health
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    • v.21 no.1
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    • pp.61-74
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    • 1988
  • Ten college women were divided into 5 groups and treated in randomized block design for 5 weeks with 1 interval between treatments and subjects serving as their own controls. The experimental diets were corn oil diet as a source of n-6 linoleic acid, perilla oil diet as a source of n-3 $\alpha$-linolenic acid, and fish oil diet as a source of n-3 EPA and DHA. Dietary fat was supplied at 30% Cal and modified to give the total amount of saturated fatty acids and monoenoic acids at constant level. There was no significant effect on serum cholesterol level by different PUFA. However, on a gram-for-gram basis, there was a trend that the decrease in serum cholesterol was proportionate to the degree of fat unsaturation. On the other hand, only fish oil diet significantly decreased TG level but no significant effect on the relative proportion of TG in VLDL. The degree of hypotriglyceridemia did not corrleate with the degree of unsaturation. The relative proportion of CE in LDL was reduced by all PUFA diets but significant only by perilla oil diet. The relative amount of apoprotein in LDL was significantly reduced by n-3 PUFA. HDL-Chol content was significantly increased only in fish oil diet but no change in the relative proportion of its chemical components of HDL.

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Effect of Dietary Lipid Sources on Body Fatty Acid Composition of Chinese Longsnout Catfish Leiocassis longirostris

  • Choi, Jin;Lee, Sang-Min
    • Fisheries and Aquatic Sciences
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    • v.18 no.4
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    • pp.359-365
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    • 2015
  • We investigated the effects of dietary lipid sources on growth and fatty acid composition of juvenile Chinese longsnout catfish. Triplicate groups of fish (initial average weight, 3.8 g) were fed four diets containing either fish oil (FO), soybean oil (SO), linseed oil (LO) and lauric acid (LA) for 10 weeks. There were no differences among the groups in body weight, feed intake, feed efficiency, protein efficiency ratio, and body proximate composition of fish fed the diets containing different lipid sources (P > 0.05) during the study. However, fatty acids compositions of the whole body were influenced by dietary lipid source. Fish fed the SO diet had high concentration of linoleic acid, whereas those of fish fed the LO diet were rich in linolenic acid and arachidonic acid. Fish fed the FO diet had significantly (P < 0.05) higher levels of monounsaturated fatty acids such as 18:1n-9 and 20:1n-9 than those of fish fed the SO and LO diets. Eicosapentaenoic acid (EPA; 20:5n-3) and docosahexaenoic acid (DHA; 22:6n-3) composition of body were not influenced by dietary lipid source. The results suggest that each of FO, SO, LO or LA can be used as a lipid source in the diets of Chinese longsnout catfish without any negative effects on growth and feed utilization and these data demonstrate the potential impact which dietary fat composition can change the body fatty acid profile.

Unambiguous Identification of Fugitive Pollutants and Determination of Annual Emission Flux as Diurnal Monitoring Mode

  • Chang, Shih-Yi;Tso, Tai-Ly;Lo, Jiunn-Gung;Huang, Jer-Luen;Lin, Cheng Ming
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.731-738
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    • 1995
  • Toxic air pollutants are investigated in a petrochemical industrial park in Taiwan by using a movable open path FTIR. The results show the qualitative and quantitative analysis of emission gases from plants, and also provide the emission rate of different compounds. More than twenty compounds under usual operation are found from this industrial park. The concentration variation with time can be correlated exactly with wind direction. It means that by changing the measuring points, the source of emission can be unambiguously identified. An EPA proved PAL model is applied to estimate the emission rate of either a point or an area source. Local atmospheric stability is determined by releasing the $SF_6$ tracer. The origins of errors come mainly from the uncertainty of source's configuration and the variation of meteorological condition. Through the continuous measurement (half an hour base in this study) of OP-FTIR sensor, the maximum value of emission rate and the annual amount of emission can be derived. The emission rate of the measured toxic gases are derived by the model technique and the results show that the emission amount are in the order of ten to hundred tons per year.

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Fatty Acid Composition and Oxidation of the Lipids in Sweetfish Cultured in Korea (국내 양식 은어 지방의 지방산 조성 및 저장 중 지방 산화)

  • Lee, Hee-Jae;Jung, Ha-Na;Lee, Sae-Rom;Jeong, Ji-Hyun;Lee, Min-Woo;Hwang, Keum-Teak;Hwang, In-Kyeong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.39 no.6
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    • pp.853-858
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    • 2010
  • The purpose of the study was to determine fat contents and fatty acid compositions of the lipids in sweetfish cultured in Korea and lipid oxidation during storage at refrigeration temperature ($2^{\circ}C$). Whole or minced sweetfish were vacuum-packaged or treated with ascorbic acid. Changes in thiobarbituric acid (TBA) values, peroxide values (PV) and free fatty acid (FFA) in the fish were determined. Sweetfish contained 72.5% moisture, 5.3% lipid and 1.1% ash. Palmitic acid was the highest (27.4% (w/w) of the total fatty acids) among the saturated fatty acids. Total monounsaturated fatty acids (MUFA) were 33.9% and oleic acid (21.0%) was the highest, followed by palmitoleic acid (7.8%). Total PUFA were 28.2%. Predominant PUFA were linoleic acid (8.1%), EPA (5.7%) and DHA (12.1%). TBA values and PV of the whole sweetfish treated with ascorbic acid and vacuumpackaged were not different from the control. TBA values of the minced sweetfish treated with ascorbic acid were significantly lower than the other groups (p<0.05). PV of the fish treated with ascorbic acid and vacuum packaging were significantly lower than the other groups (p<0.05). The result of this study suggests that cultured Korean sweetfish may be a good source of unsaturated fatty acids including EPA and DHA, and vacuum packaging and addition of ascorbic acid may protect lipids from oxidation.

Influence of Dietary n3 Polyunsaturated Fatty Acids on Plasma Lipid-Lowering Effect and Peroxidation Level In Rats (쥐에서 n3계 불포화지방산 식이의 혈장지질 저하효과와 과산화물형성에 미치는 영향)

  • Choi, Joo Sun
    • Journal of Nutrition and Health
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    • v.23 no.6
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    • pp.408-417
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    • 1990
  • To compare the hypolipidemic effect of n6 linoleic acid n3 $\alpha$-linolenic acid and n3 eicosapentaenoic acid plus docosahexaenoic acid, male Sprague Dawley rats weighing about 450g were fed the experimental diets for 6 weeks which composed of fat at 15%(W/W) level and were different only in dietary PUFA. Dietary fat was corn oil, perilla oil, and fish oil concentrate as a source of n6 linoleic acid, n3 $\alpha$-linolenic acid, and n3 eicosapentaenoic acid+docosahexaenoic acid, respectively. Plasma total Chol and HDL-chol levels were significantly-lower in fish oil group than in corn oil and erilla oil groups. Plasma cholesterol lowering effect of PUFa was in the order of n3 EPA+DHA>n3 $\alpha$-linolenic acid>n6 linoleic acid. Plasma TG was significantly lower in both fish oil and perilla oil groups than in corn oil group. Plasma TG-lowering effect was greater by n3 PUFA (EPA+DHA, $\alpha$-linolenic acid) than by n6 PUFA(linoleic acid). However, there were no significant effects on lipoprotein pattern hemolysis, and the levels of tocopherol and malondialdehyde in plasma and RBC by difference dietary fat with sufficient tocopherol supplement. Liver superoxide dismutase activity was significantly increased in proportion to the degree of fat unsaturation, thereby resulted in the lower level of MDA in fish oil group. In conclusion, fish oil and perilla oil rich in n3 PUFA may have important nutritional applications in the prevention and treatment of atherosclerotic disease.

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A Study on BASINS/WinHSPF for Evaluation of Non-point Source Reduction Efficiency in the Upstream of Nam-Han River Watershed (BASINS/WinHSPF를 이용한 남한강 상류 유역의 비점오염원 저감효율평가)

  • Yoon, Chun-Gyeong;Shin, Ah-Hyun;Jung, Kwang-Wook;Jang, Jae-Ho
    • Journal of Korean Society on Water Environment
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    • v.23 no.6
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    • pp.951-960
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    • 2007
  • Window interface to Hydrological Simulation Program-FORTRAN (WinHSPF) developed by the United States Environmental Protection Agency (EPA) was applied to the upstream of Nam-Han river watershed to examine its applicability for loading estimates in watershed scale and to evaluate non-point source control scenarios using BMPRAC in WinHSPF. The WinHSPF model was calibrated and verified for water flow using Ministry of Construction and Transportation (MOCT, 3 stations, 2003~2005) and water qualities using Ministry of Environment (MOE, 5 station, 2000~2006). Water flow and water quality simulation results were also satisfactory over the total simulation period. But outliers were occurred in the time series data of TN and TP at some regions and periods. Therefore, it required more profit calibration process for more various parameters. As a result, all the study was performed within the expectation considering the complexity of the watershed, pollutant sources and land uses intermixed in the watershed. The estimated pollutant load for annual average about $BOD_5$, T-N and T-P respectively. Nonpoint source loading had a great portion of total pollutant loading, about 86.5~95.2%. In WinHSPF, BMPRAC was applied to evaluate non-point source control scenarios (constructed wetland, wet detention ponds and infiltration basins). All the scenarios showed efficiency of non-point source removal. Overall, the HSPF model is adequate for simulating watersheds characteristics, and its application is recommended for watershed management and evaluation of best management practices.

Particle Size of Aerosol from 0.25% Cadmium Chloride Nebulizing Solution for Inhalation Toxicology Study (흡입독성 연구에 이용될 0.25% 염화카드뮴 네뷸라이징 용액 에어로졸의 입경)

  • Jeung Jae Yeal;Lee Ki Nam
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.17 no.5
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    • pp.1257-1263
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    • 2003
  • The modified engineering methodology and the modified electronic circuit in classical ultrasonic principles were applied to ultrasonic aerosol nebulizer for inhalation toxicology study of cadmium aerosol. 1532.96ppm Cd nebulizing solution was used to generate cadmium aerosol for particle size analysis with the modifying source and inlet temperatures. The results of particle size analysis for cadmium aerosol were as following. The highest particle counting for source temperature 20℃ was 399.75 × 10² in inlet temperature 100℃ and particle diameter 0.75㎛. The highest particle counting for source temperature 50℃ was 399.70 × 10² in inlet temperature 50℃ and particle diameter 0.75㎛. The highest particle counting for source temperature 70℃ was 411.14 × 10² in inlet temperature 100℃ and particle diameter 0.75㎛. The ranges of geometric mean diameter were 0.74-0.79㎛ in source temperature 20℃, 0.65-0.72㎛ in source temperature 50℃, and 0.65-0.80㎛ in source temperature 70℃. The smallest geometric mean diameter was 0.65㎛ in source temperature 50, 70℃ and inlet temperature 20, 50℃, and the largest geometric mean diameter was 0.80㎛ in source temperature 70℃ and inlet temperature 100℃. The ranges of geometric standard deviation were 1.71-1.80 in source temperature 20℃, 1.27-1.61 in source temperature 50℃, and 1.27-2.29 in source temperature 70℃. The lowest geometric standard deviation was 1.27 in source temperature 50, 70℃ and inlet temperature 20, 50℃, and the highest geometric standard deviation was 2.29 in source temperature 70℃ and inlet temperature 100℃. Generated aerosol for cadmium inhalation toxicology study was polydisperse aerosol with the above geometric standard deviation 1.2. The ranges of mass median diameter(MMD) were 1.75-2.25㎛ in source temperature 20℃, 1.27-1.61㎛ in source temperature 50℃, and 1.27-2.29㎛ in source temperature 70℃. The smallest MMD was 1.27㎛ in source temperature 50, 70℃ and inlet temperature 20, 50℃, and the largest MMD was 2.29㎛ in source temperature 70℃ and inlet temperature 100℃. Cadmium chloride concentration in nebulizing solution affected the particle size and distribution of cadium aerosol in air. MMO for inhalation toxicology testing in OECD and EU is less than 3㎛ and EPA guidance is less than 4㎛. In our results, in source temperatures of 20, 50, 70℃, and inlet temperatures of 20, 50, 100, 150, 200, 250℃ were conformed to the those guidance.

Chemical Characteristics and Source Apportionment ofPM2.5 in Seoul Metropolitan Area in 2010 (2010년도 서울시 대기 중 PM2.5의 성분특성 및 발생원 추정에 관한 연구)

  • Moon, Kwang-Joo;Park, Seung-Myung;Park, Jong-Sung;Song, In-Ho;Jang, Sung-Ki;Kim, Jong-Chun;Lee, Seok-Jo
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.711-722
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    • 2011
  • This study is aimed to estimate the $PM_{2.5}$ source apportionment at Seoul intensive monitoring site located in Seoul metropolitan area. Time-resolved chemical compositions of $PM_{2.5}$ are measured in real time using ambient ion monitor, semi-continuous carbon monitor, and on-line XRF at Seoul intensive monitoring site in 2010. The mass concentration of $PM_{2.5}$ was simultaneously monitored with eight ionic species (${SO_4}^{2-}$, $NO_3{^-}$, $Cl^-$, $NH_4{^+}$, $Na^+$, $K^+$, $Mg^{2+}$, $Ca^{2+}$), two carbonaceous species (OC and EC), and fourteen elements (Si, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Zn, As, Se, Pb) in 1-hr interval. The data sets were then analyzed using EPA PMF version 3 to identify sources and contributions to $PM_{2.5}$ mass. EPA PMF modeling identified eight PM2.5 sources, including soil dust, secondary sulfate, secondary nitrate, motor vehicle, coal combustion, oil combustion, biomass burning, and municipal incineration. This study found that the average $PM_{2.5}$ mass was apportioned to anthropogenic sources such as motor vehicle, fuel combustion, and biomass burning (61%) and secondary aerosols, including sulfate and nitrate (38%).