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Metal Complexes of Ambidentate Ligand(Ⅳ). Nickel(Ⅱ) and Palladium(Ⅱ) Complexes of bis(isonitrosoacetylacetone)diimine Derivatives (Ambidentate 리간드의 금속착물 (제 4 보). Bis(isonitrosoacetylacetone)diimine 유도체를 리간드로 하는 니켈(Ⅱ) 및 팔라듐(Ⅱ) 착물)

  • Man-Ho Lee;Seon-Ho Lee
    • Journal of the Korean Chemical Society
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    • v.32 no.5
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    • pp.428-435
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    • 1988
  • Some nickel(Ⅱ) and palladium(Ⅱ) complexes of the ambidentate ligands derived from condensation of the isonitrosoacetylacetone and various diamines, $Ni(IAA)_2-en$, $Ni(IAA)_2-pn$, $Ni(IAA)_2-tn$, $Pd(IAA)_2-en$, PdCl(IAA)-pn, and $Pd(IAA)_2$-tn, where (IAA)$_2$-en, $(IAA)_2$-tn, and (IAA)-pn represent N,N'-enthylenbis(isonitrosoacetylacetone imine), N,N'-propylenebis(isonitrosoacetylacetone imine), N,N'-trimethylenebis(isonitrosoacetylacetone imine) and N-(2-aminopropyl)isonitrosoacetylacetone imine, respectively, have been prepared. The nickel(Ⅱ) and palladium(Ⅱ) complexes were characterized on the bases of the elemental analysis, IR, NMR, and electronic spectra. It is suggested that a isonitroso group of (IAA)$_2$-en or (IAA)$_2$-tn coordinates to the metal ion through the nitrogen atom to form five-membered ring, while the other isonitroso group of (IAA)$_2$-en or (IAA)$_2$-tn coordinates to the metal ion through the oxygen atom to form six membered ring in square-planar complexes of Ni(IAA)$_2$-tn and Pd(IAA)$_2$-en. And two isonitroso groups of (IAA)$_2$-en, (IAA)$_2$-pn, or (IAA)$_2$-tn coordinate to the metal ion through the nitrogen atom to form five-membered rings in square-planar complexes of Ni(IAA)$_2$-en, Ni(IAA)$_2$-pn, and Pd(IAA)$_2$-tn. On the other hand, square-planar PdCl(IAA)-pn is formed by the reaction of propylenediamine with a isonitrosoacetylacetone in the presence of palladium(Ⅱ)ion.

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Investigating the Use of Energy Performance Indicators in Korean Industry Sector (한국 산업부문의 에너지성과 지표 이용에 관한 연구)

  • Shim, Hong-Souk;Lee, Sung-Joo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.3
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    • pp.707-725
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    • 2021
  • Energy management systems (EnMS) contribute to sustainable energy saving and greenhouse gas reduction by emphasizing the role of energy management in production-oriented economies. Although understanding the methods used to measure energy performance is a key factor in constructing successful EnMS, few attempts have been made to examine these methods, their applicability, and their utility in practice. To fill this research gap, this study aimed to deepen the understanding of energy performance measures by focusing on four energy performance indicators (EnPIs) proposed by ISO 50006, namely the measured energy value, ratio between measured values, linear regression model, and nonlinear regression model. This paper presents policy and managerial implications to facilitate the effective use of these measures. An analytic hierarchy process (AHP) analysis was conducted with 41 experts to analyze the preference for EnPIs and their key selection criteria by the industry sector, and organization and user type. The findings suggest that the most preferred EnPI is the ratio between the measured values followed by the measured energy value. The ease of use was considered to be most important while choosing EnPIs.

MAISONS JAOUL DE LE CORBUSIER: UN PROTOTYPE POUR LA CITE HORIZONTALE EN SERIE (르 꼬르뷔지에의 자울주택: 대량생산용 저층 집합주거의 원형)

  • Chong, Sung-Hyun
    • Journal of architectural history
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    • v.5 no.1 s.9
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    • pp.102-112
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    • 1996
  • Cette etude vise a trouver I'intention originelle de Le Corbusier(1887-1968) dans les Maisons Jaoul a Neuilly-sur-Seine (1951-1955). En general, on regarde ces maisons comme no autre architecture do Le Corbusier ou un des oeuvres do Brutalisme International. Mais, en consideration du developpement architectural de Le Corbusier, les Maisons Jaoul a ete we des deux realisations de la maison economique en serie que Le Corbusier a etudiee pour la vie: l'un a ete l'Unite d'Habitation a Marseille(1947-1952) pour la cite verticale en serie et l'autre les Maisons Jaoul pour une cite horizontale en serie. Pourtant, ces maisons ne sont pas parfaites pour l'homme. Selon Marie Jaoul qui est une petite-fille d'Andre Jaoul, Le Corbusier a prefere l'harmonie entre la nature et l'architecture plutot qu'entre l'homme et l'architecture.

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Charge Distributions in Polyethylene/Ethylene n-Butyl Acrylate Blends (Polyethylene/Ethylene n-Butyl Acrylate Blends의 전하형성특성)

  • Kim, Ok;Lee, Chang-R.;Lee, Mi-Kyung;Suh, Kwang-S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.143-147
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    • 1995
  • The space charge formation in polyethylene (PE)/ethylene n-butyl acrylate (EnBA) blends were investigated. Heterocharge was found in PE and EnBA containing 5 mole% of nBA while homocharge was found in EnBAs containing 19 and 20% of nBA. All PE/EnBA blends except the one with the EnBA containing 5% nBA showed heterocharge formation. Heterocharge was also found in crosslinked PE/EnBA blends, which was attributed to the volatile residuals generated by the thermal decomposition of peroxide.

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A study of English affixes: Concentrated on the affixes -en and -ing (영어의 접사 연구: 접사 -en, -ing 를 중심으로)

  • Park, Soon-Bong
    • English Language & Literature Teaching
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    • v.15 no.3
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    • pp.301-314
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    • 2009
  • This study explores the function of the affixes -en and -ing that could influence the theta-roles of verbs to which the affixes are attached. The two affixes often appear in the synthetic compounds in English. The results are as follows. First, the affixes -en and -ing link the theta-role realized in the subject of the verb to the noun followed, which is proposed as Theta-linking Principle: that is, the affixes -en and -ing link the theta-role realized in the subject of the verb to the noun followed. Second, in the synthetic compounds including the affixes -en and -ing, the left element must not be the subject of the verb, which is the Synthetic Compound Constraint. And the affix -er link thematic roles of the sentential subject, such as Agent, Instrument. Thus, this study aims to find out the function of the affixes on the point of lexical functional approach.

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Isolation of Cholesterol Utilizing Bacteria and Their Degradation Pattern (콜레스테롤 이용 박테리아의 분리 및 분해 특성)

  • 최민호;조도현;박연희
    • Microbiology and Biotechnology Letters
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    • v.22 no.4
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    • pp.340-346
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    • 1994
  • Six bacterial strains capable to grow on medium containing cholesterol as sole carbon source were isolated from soil, pork fat and cheese. Three of them were tentatively identified as Rhodococcus species, Rhodococcus sp. CD-1, R. sp. CD-2, and R. sp. CD-3. All the isolates showed a varying amount of cholest-4-en-3-one as the degradation product, and three strains of Rhodococcus spp. showed rapid degradation of cholesterol. Radioisotopic studies revealed that cholesterol was degraded to non-sterol hydrophilic compounds via cholest-4-en-3-one, and presumably to C0$_{2}$- These strains showed two distinct patterns in further degradation of cholest-4-en-3-one. By one group, R. sp. CD-1 and R. sp. CD-3, cholest-4-en-3-one was rapidly converted to non-sterol inter- mediates without significant accumulation of sterol derivatives in the culture broth. In contrast, by another group, R. sp. CD-2, the substantial amount of cholest-4-en-3-one was accumulated indica- ting a lower conversion of the compound to the next metabolites.

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Water Tree Characteristics of XLPE/EnBA Blends as a function of Crosslinking Coagent Contents (XLPE/EnBA에서의 가교조제에 따른 수트리 특성)

  • 오우정;서광석;김종은
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.219-222
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    • 1998
  • In this study, The water tree characteristics were investigated when crosslinking coagent was added in XLPE/EnBA blends. When XLPE was blended with EnBA, there was a decrease of water tree length as an increase of nBA contents in XLPE/EnBA20 blends. The effect of crosslinking coagent. A was better than those of other crosslinking coagents B, C and D in water tree retardation. In case of XLPE/EnBA/Crosslinking coagent blends, water tree length was increased as the crosslinking coagents were increased from 0.2 to 2 phr in 2.0 phr DCP content. To clarify the effects of crosslinking coagent, the DCP contents were changed from 1.5 to 2.0 par in the same crosslinking coagent contents. Then, there was a decrease of water tree length as an increase of crosslinking coagent contents in 1.5 and 1.8 phr DCP contents.

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A Residential 8kWh Energy Storage System (가정용 8kWh급 에너지 저장 시스템)

  • Seo, Jung-Hwa;Lee, Woo-Won;Lee, Su-Won;Han, Hee-Min;Han, Ki-Jun;Seo, Kwang-Duk
    • Proceedings of the KIPE Conference
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    • 2012.07a
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    • pp.548-549
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    • 2012
  • 본 논문은 가정용 8kWh 에너지 저장 시스템(ESS; Energy Storage System)을 제안한다. 제안하는 시스템은 신재생 에너지원으로 태양광, 에너지저장 장치로는 리튬 배터리가 적용되는 시스템으로, 단상 계통과 병렬로 연결되어 태양광 및 배터리의 직류전력을 상용 주파수 및 전압의 교류전력으로 변환하는 제어가 가능하며 또한, 계통의 교류전력을 배터리에 필요한 직류전력으로 변환하는 양방향 시스템이다. 제안하는 ESS의 제어 및 모니터링을 위하여 추가로 HMI(Human Machine Interface) 및 HMI 제어기를 사용하였다. HMI는 ESS를 원하는 형태로 동작시킬 수 있으며, 현재 시스템의 동작모드, 전력량, 배터리 정보 등의 표시 및 장애 이력을 관리한다. 그리고 HMI, PCS, 및 BMS는 서로 CAN통신으로 정보를 교환하도록 설계하였다.

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Approximate Entropy of hypertension: Effect of Anesthesia (정상혈압환자와 고혈압환자의 마취전후의 근사엔트로피의 비교)

  • Yum, M.K.;Kim, H.S.
    • Proceedings of the KOSOMBE Conference
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    • v.1996 no.11
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    • pp.368-371
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    • 1996
  • Background: Recently, measure of heart rate variability and the nonlinear "complexity" of heart rate dynamics have been used as indicators of cardiovascular health. Several investigators have demonstrated that heart rate variability decreased in aging, congestive heart failure and coronary heart disease. Because hypertensive patients showed alternation of cardiovascular homeostasis, we designed this study to evaluate the effect of anesthesia in hypertensive patients with approximate entropy (ApEn). Methods: With informed consent, eighteen normotensive patients and eighteen hypertensive patients were given no premedication. ECG data were collected from 10 minutes before induction to 15 minutes after induction. Collected ECG data were stored into computer binary files. We calculated ApEn from the collected ECG data. Results: Before induction, ApEn of hypertensive patients was significantly lower than normotensive patients(p<0.05). During induction and maintain of anesthesia, there was no difference of ApEn between two groups. During induction and maintain of anesthesia, in normotensive group, ApEn was significantly lower than that of preinduction(p<0.05). And ApEn during maintain of anesthesia was lower than that of induction(p<0.05). During maintain of anesthesia, in hypertensive group, ApEn was significantly lower than that of preinduction(p<0.05). Conclusions: Before induction, ApTn of hypertensive patients is significantly lower than normotensive patients. As anesthesia was deepened, ApEn of two groups were decreased. Because the baroreflex of hypertensive patients is already decreased, decreasing of ApEn of hypertensive patients during anesthesia is less than that of normotnesive patients.

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