• Journal of the Korea Organic Resources Recycling Association
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• v.32 no.1
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• pp.21-29
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• 2024

In this study, EMC(Epoxy molding compound) waste from the semiconductor molding process is recycled and synthesized into silica nanoparticles, which are then applied as abrasive materials contains CMP(Chemical mechanical polishing) slurry. Specifically, silanol precursor is extracted from EMC waste according to the ultra-sonication method, which provides heat and energy, using ammonia solution as an etchant. By employing as-extracted silanol via a facile sol-gel process, uniform silica nanoparticles(e-SiO₂, experimentally synthesized SiO₂) with a size of ca. 100nm are successfully synthesized. Through physical and chemical analysis, it was confirmed that e-SiO₂ has similar properties compared to commercially available SiO₂(c-SiO₂, commercially SiO₂). For practical CMP applications, CMP slurry is prepared using e-SiO₂ as an abrasive and tested by polishing a semiconductor chip. As a result, the scratches that are roughly on the surface of the chip are successfully removed and turned into a smooth surface. Hence, the results present a recycling method of EMC waste into silica nanoparticles and the application to high-quality CMP slurry for the polishing process in semiconductor packaging.

• Korean Journal of Construction Engineering and Management
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• v.7 no.3 s.31
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• pp.149-158
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• 2006

For construction projects, it is required to estimate the Environmental Management Cost(EMC) for pollution prevention, using the calculation standards prescribed in the Construction Technology Management Law(CTML). However, the EMC standards are difficult to utilize without definite site information. Therefore, it is needed a new calculation method reflecting project site information. According to the definition of EMC in the CTML, this study identifies the EMC items and classifies them into the pollution types such as air, water, noise, waste and others. With this EMC classification, the stud:』 analyzes using the SPSS the EMC for the 78 new multi-housing projects, which were executed during the past three years, 2000-2002. And then an EMC estimating matrix is developed with simple information such as site location and size of area from historical data. The proposed matrix can be effectively used to check and control budgeting and estimating the EMC of the multi-housing projects. In addition, the proposed EMC matrix are validated through a case study.

• Journal of the Korea Organic Resources Recycling Association
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• v.31 no.1
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• pp.5-14
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• 2023

In this study, LiDAR-reflective black hollow-structured silica/titania(B-HST) materials are successfully synthesized by employing the NaBH₄ reduction and etching method on silica/titania core/shell(STCS) materials, which also effectively enhance near-infrared(NIR) reflectance. Moreover, core-etched supernatant solutions are collected and recycled for the synthesis of extracted silica(e-SiO₂) process, which successfully applies as filler materials for semiconductor epoxy molding compound(EMC). In detail, B-HST materials, fabricated by the sequential experimental steps of sol-gel, reduction, and sonication-mediated etching method, manifest blackness(L^*) of 13.2 similar to black paint and excellent NIR reflectance(31.1%). Consequently, B-HST materials are successfully prepared as LiDAR-reflective black materials. Additionally, core-etched supernatant solution with silanol precursors are employed for synthesis of homogeneous silica filler materials via sol-gel method. As-synthesized silica fillers are incorporated with epoxy resin and carbon black for the preparation of semiconductor EMC. Experimentally synthesized EMC exhibits comparable mechanical-chemical properties to commercial EMC. Conclusively, this study successfully proposes designing procedure and practical experimental method for simultaneously synthesizing the NIR-reflective black materials for self-driving vehicles and EMC materials for semiconductors, which are materials suitable for the industrial 4.0 era, and presented their applicability in future industries.

• Journal of the Korean Wood Science and Technology
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• v.26 no.2
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• pp.6-15
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• 1998

A total of forty five-ply, 30- by 30-cm lauan and larch plywood sheets were manufactured in the laboratory using commercial urea and phenol resin adhesives; half of these sheets were treated with fresh concrete. Each sheet was carbonized for 2, 4, and 6hours at $400^{\circ}C$, $600^{\circ}C$, and $750^{\circ}C$, respectively, and their physical properties were measured. The yie1d of charcoal decreased as carbonization temperature and time increased. Charcoal yield was greater in plywood than in veneer, and slightly greater in plywood treated with concrete compared to untreated plywood. Plywood manufactured with phenol resin adhesive had higher pH, higher equilibrium moisture content (EMC), and greater adsorption of methylene-blue dye compared to plywood manufactured with urea resin. For concrete-treated plywood, pH was greater than 10 even when the sheets were carbonized for 2hours at $400^{\circ}C$. Although the EMC of the phenol resin plywood was higher than that of the urea resin plywood, EMC of the phenol resin was lower than that of the urea resin. The larch phenol resin plywood that was carbonized for 6 hours at $750^{\circ}C$ adsorbed more methylene-blue than did the commercia1 wood-based activated charcoal as a result of total pore volume and surface area.

• Journal of Biosystems Engineering
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• v.19 no.4
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• pp.358-368
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• 1994

Major factors in reducing the stacking strength of corrugated fiberboard boxes in cold storage or transport conditions are high relative humidity, causing elevated moisture absorption by the boxes. The bottom boxes in a stack will deform to the critical deflection causing agricultural products damage there, and eventually additional deflection will cause box collapse and finally toppling of the stack. The study was conducted to determine the water absorption characteristics and the compressive strength of the corrugated fiberboard boxes being widely used in packaging agricultural products in Korea. The sample boxes for the study were selected from the regular slotted containers (RSC) types, and one was the box used in apple packaging (Box A), another one was the box used in pear packaging (Box B). The corrugated shipping containers were made from a large portion of recycled fibers in Korea, and comparing with Box B, Box A was fabricated from fiberboard which contained more percentage of old corrugated containers (OCC) imported from foreign countries than domestic waste paper. The results obtained from the study were summarized as follows ; 1. Equilibrium moisture content (EMC) of the sample boxes was established after about 20 hours, and the EMC by absorption was lower than that by desorption. The EMC increased with the increasing of relative humidity and with the decreasing of temperature, and the rate of increasing was much higher above the relative humidity of 50%. 2. The maximum compressive strength of Box A was about 100 kgf greater than that of Box B on the same enviromental conditions. The strength of the sample boxes decreased rapidly with the increasing of relative humidity. The effect of relative humidity on the strength was a little higher than that of temperature. 3. As the applied load was progressively increased and a level was reached, the vertical side panels ($L{\times}D$) deflected laterally inwards or outwards. The panels deflected laterally inwards at higher relative humidity. 4. The maximum compressive deflection ratio and the critical deflection ratio of the sample boxes were increased linearly with the increasing of relative hunidity, but trends for its ratios showed inconsistant response to temperature.

• Korean Journal of Ecology and Environment
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• v.34 no.2 s.94
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• pp.126-132
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• 2001

Urbanization and population increase result in the construction of STPs (Sewage Treatment Plants). Discharge from STPs greatly influences on the water quality in the stream which receives discharges. The decision of STP location should be considered with the discharge capacity of STP and self-purification of river in the water quality perspectively. In this study, a change of dissolved oxygen (DO) in a river being affected by STP discharge was simulated by the STELLA model. Minimum DO was 4.98 ppm in 42.6 km downstream of STP. Approximately, it takes 8days to recover the DO by the self-purification and this location is 340 km down-stream from the STP. If the model run for the consideration of the self-purification without phytoplankton algorithms, minimum DO was 4.92 ppm. It took 0.25 day longer to be the minimum DO than that with the phytoplankton functions. Without the phytoplankton algorithm, it took 11days to recover the DO. This proves the importance of phytoplankton in the self-purification processes. Additionally, the effect of adjacent STP discharge should be considered in the construction of new STP.