• Title/Summary/Keyword: EH-1

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Environmental Assessment for Acid Mine Drainage by Past Coal Mining Activities in the Youngwol, Jungseon and Pyungchang areas, Korea (영월, 정선 및 평창지역 폐 석탄광 산성광산배수의 환경오염 평가)

  • 정명채
    • Economic and Environmental Geology
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    • v.36 no.2
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    • pp.111-121
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    • 2003
  • The objective of this study is to investigate the physical and chemical properties for environmental assessment of water system affected by acid mine drainage (AMD) from coal mining activities in the Youngwol, Jungseon and Pyungchang areas in Korea. During November 2000 to July 2002, 6 times of water samples were collected season-ally from acid mine drainage and nearby streams at 13 coal mines in the study area. The physical and chemical properties including pH, Eh, TDS, salinity, bicarbonates and DO were measured in the field. Eighteen cations includ-ing Al, Ca, Fe, Mg, Mn and Zn, and 6 anions including nitrates and sulfates were also analyzed by ICP-AES and If, respectively. Acid water from the Jungam coal mine has typical characteristics of AMD with very low pH(3∼4) and high TDS(1,000∼5,000 mg/1). Relatively high concentrations(mg/kg) of heavy meals, especially for Al(380), Fe(80), Mn(44) and Zn(8), were found in water samples from the Jungam coal mine area. Water samples from the Seojin, Sebang and Sungjin coal mines also contained over 50 mg/l of Al, >100 mg/1 of Fe and )10 mg/1 of Mn. In addition to anioins, over 1,000 mg/l of sulfate was found in several water samples. Seasonally, the concentrations of metals and sulfates varied; wet season samples were relatively higher in metals and sulfates than dry season samples. It is needed to establish the proper remediation and environmental monitoring of the AMD continuously.

Seasonal and Spatial Variations of CO2 Fluxes Between Surface and Atmosphere in Foreshore, Paddy Field and Woods Sites (갯벌, 논 및 산림 부지에서 지표와 대기 사이의 이산화탄소 플럭스 계절/공간 변동 분석)

  • Kang, Dong-Hwan;Kwon, Byung-Hyuk;Yu, Hun-Sun;Kim, Park-Sa;Kim, Kwang-Ho
    • Journal of Environmental Science International
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    • v.20 no.8
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    • pp.963-975
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    • 2011
  • For this research, they were monitored $CO_2$ flux and environmental factors ($CO_2$ concentration, soil temperature, soil moisture, soil organic carbon, soil pH, soil Eh) in foreshore, paddy field and woods sites at the winter season (January 2009) and the summer season (September 2009). Seasonal and spatial variations for monitored data were analyzed, and linear regression functions of $CO_2$ flux as environmental factors were estimated. $CO_2$ fluxes averaged between surface and atmosphere monitored in foreshore and paddy field at the winter season were shown $-8\;mgCO_2m^{-2}hr^{-1}$ and $-25\;mgCO_2m^{-2}hr^{-1}$, respectively. $CO_2$ fluxes averaged between surface and atmosphere monitored in foreshore and paddy field at the summer season were shown $47\;mgCO_2m^{-2}hr^{-1}$ and $117\;mgCO_2m^{-2}hr^{-1}$, respectively. Thus, $CO_2$ was sunk from atmosphere to surface at the winter season and it was emitted from surface to atmosphere at the summer season. $CO_2$ fluxes in woods site were emitted $145\;mgCO_2m^{-2}hr^{-1}$ at the winter season and $279\;mgCO_2m^{-2}hr^{-1}$ at the summer season.

Effect of Ni and Mo on Mechanical Properties of Submerged Arc Welds with Flexible Glasswool Backing (FGB SAW 용접부 물성에 미치는 Ni과 Mo의 영향에 관한 연구)

  • Jee, C.H.;Choi, J.T.;Kim, D.J.
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.55-55
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    • 2009
  • FGB(Flexible Glasswool Backing) Submerged Arc Welding has been one of the main welding processes for one side butt welding in shipbuilding industries, which can efficiently improve the welding productivity by the addition of a supplementary filler metal into the molten weld pool. As recent ships have become larger in size, the application of high tensile and higher grade of steels has been continuously increased. Single pass FGB SA welding process accompanies such a high heat input when welding thick plates that the mechanical properties of weld metal can be dramatically degraded. This study has been performed in order to obtain high toughness and tensile properties of high heat input FGB SA welds, and to evaluate the effect of alloy elements on their mechanical properties. To complete welding 25mm-thick EH36 grade steel plate by single pass, 1.2mm diameter and 1.0mm long cut wires has been distributed in the groove before welding, and three different test coupons have been made using C-1.5%Mn, C-1.8%Mn-0.5%Mo, and C-1.4%Mn-1.7%Ni cut wires to investigate the influence of nickel(Ni) and molybdenum(Mo) on the mechanical properties of welds. Test results showed that the addition of Ni and Mo effectively promotes the formation of Acicular Ferrite(AF), while significantly reducing the amount of Grain Boundary Ferrite(GBF) in weld metal microstructures, which resulted in a beneficial effect on low temperature impact toughness and strength.

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Production of Fine Cobalt Metal Powders from Stellite Scrap (Stellite 스크랩으로 부터 Co 미분말의 제조)

  • 박문경;신동성
    • Resources Recycling
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    • v.3 no.1
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    • pp.9-16
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    • 1994
  • Fine cobalt metal powders was produced from domestic Stellite scrap by decomposing it with molten sodium hydroxide. Complete decomposition of the scrap could be obtained with the weigth ratio of sodium hydroxide to Stellite being about 2 at the temperature ranges of $750~800^{\circ}C$ for an hour. The cobalt-bearing compound was identified as $Co_2O_3{\dot}H_2O$ by X-ray analysis and D.T.-T.G.a.. The compound was then digested in HCI to form cobalt chloride, and after iron removal by adjusting the pH of the solution, cobaltous or cobaltic hydroxide was precipitated at the pH of about 13 or 4, respectively. The precipitates were reduced by hydrogen in the temperatures of $400~500^{\circ}C$ to fine cobalt powders of high purity with the size of 1.0 to $1.5\mu\textrm{m}$. The recovery of cobalt from Stellite scrap was about 75~86% by weight.

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Development of the National Integrated Daily Weather Index (DWI) Model to Calculate Forest Fire Danger Rating in the Spring and Fall (봄철과 가을철의 기상에 의한 전국 통합 산불발생확률 모형 개발)

  • Won, Myoungsoo;Jang, Keunchang;Yoon, Sukhee
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.20 no.4
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    • pp.348-356
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    • 2018
  • Most of fires were human-caused fires in Korea, but meteorological factors are also big contributors to fire behavior and its spread. Thus, meteorological factors as well as topographical and forest factors were considered in the fire danger rating systems. This study aims to develop an advanced national integrated daily weather index(DWI) using weather data in the spring and fall to support forest fire prevention strategy in South Korea. DWI represents the meteorological characteristics, such as humidity (relative and effective), temperature and wind speed, and we integrated nine logistic regression models of the past into one national model. One national integrated model of the spring and fall is respectively $[1+{\exp}\{-(2.706+(0.088^*T_{mean})-(0.055^*Rh)-(0.023^*Eh)-(0.014^*W_{mean}))\}^{-1}]^{-1}$, $[1+{\exp}\{-(1.099+(0.117^*T_{mean})-(0.069^*Rh)-(0.182^*W_{mean}))\}^{-1}]^{-1}$ and all weather variables significantly (p<0.01) affected the probability of forest fire occurrence in the overall regions. The accuracy of the model in the spring and fall is respectively 71.7% and 86.9%. One integrated national model showed 10% higher accuracy than nine logistic regression models when it is applied weather data with 66 random sampling in forest fire event days. These findings would be necessary for the policy makers in the Republic of Korea for the prevention of forest fires.

Comparison of the Electronic Methods of Raw Silk Testing and Grading with Those of the Current Methods I. Defference in Inspection Results and Grading to the Electronic Methods (생사검사에 있어서 현행방법과 전자식 방법에 대한 비교분석 I. 전자식 검사방법에 의한 검사성적과 등급비교)

  • 최병희;김한수
    • Journal of Sericultural and Entomological Science
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    • v.34 no.1
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    • pp.57-71
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    • 1992
  • These studies were carried out to establish Korean opinion about "The electronic method of raw silk testing and grading" which was taken shape along with the report by Silk Standard Committee(S.S.C.) at the meeting of International Silk Association(I.S.A) Directing Board session held in Zurich Swiss. This establishment was througly examine whether or not the above are the essential factors to be fulfilled in force as a international standard method of raw silk testing and grading.d grading.

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Speciation and Solubility of Major Actinides Under the Deep Groundwater Conditions of Korea

  • Dong-Kwon Keum;Min-Hoon Baik;Pil-Soo Hahn
    • Nuclear Engineering and Technology
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    • v.34 no.5
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    • pp.517-531
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    • 2002
  • The speciation and solubility of Am, Np, Pu and U have been analyzed by means of the geochemical code MUGREM, under the chemical conditions of domestic deep groundwater, in order to support the preliminary safety assessment for a Korean HLW disposal concept. Under the conditions of groundwaters studied, the stable solid phase is AmOHC $O_3$(s) or Am(OH)$_3$(s), soddyite((U $O_2$)$_2$ $SiO_2$.2$H_2O$) or N $a_2$ $U_2$ $O_{7}$ (c), Np(OH)$_4$(am), and Pu(OH)$_4$(am) for Am, U, Np, and Pu, respectively. The dominating aqueous species are as follows: the complexes of Am(III), Am(OH)$_2$$^{+}$ and Am(C $O_3$)$_2$$^{[-10]}$ , the complexes of U(VI), U $O_2$(OH)$_3$$^{[-10]}$ and U $O_2$(C $O_3$)$_3$$^{4-}$, the complexes of Np(IV), Np(OH)$_4$(aq) and Np(OH)$_3$C $O_3$, and the complexes of Pu(IV), Pu(OH)$_4$(aq) and Pu(OH)$_3$C $O_3$$^{[-10]}$ . The calculated solubilities exist between 1.9E-10 and 1.3E-9 mol/L for Am, between 5.6E-6 and 1.2E-4 mol/L for U, between 3.1E-9 and 1.3E-8 mol/L for Np, and between 6.6E-10 and 2.4E-10 mol/L for Pu, depending on groundwater conditions. The present solubilities of each actinide agree well with the results of other studies obtained under similar conditions.s.

Hydrogeochemistry of Supply Water in the Daedeok Campus of Chungnam National University, Korea (충남대학교 대덕캠퍼스내 상수도 물의 수리지구화학적 특성)

  • 이찬희
    • Economic and Environmental Geology
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    • v.33 no.3
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    • pp.181-193
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    • 2000
  • This study was undertaken to evaluate the drinking water quality based on physicochemical properties and chemical compositions of the supply water in the Daedeok Campus, and to verify the analytical reliabilities of ICP-MS and IC equipped in the Central Research Facilities at Chungnam National University , Korea. The supply water belongs to $Ca^{2+}-({HCO_3}^-+{SO_4}^{2-})$type, whereas the original water from the Daecheong lake belongs to $(Ca^{2+}-(Mg^{2+})-{HCO_3}^-$ type. Generally, temperature (14.1$^{\circ}C$), pH (6.95), Eh (0 mV), electrical conductivity (117${\mu}$S/cm) and TDS (86.975mg/l) of supply water were higher than those of original lake water . Results using WATEQ4F revealed that potentially toxic ions of the supply water might exist mainly as free metals ($M^{2+}$) and a small amount as ${CO_3}^{2-}$ and $OH^-$ complexes. Also, the water composition belongs to the kaolinite field. Calculated average enrichment indies of the supply water normalized to lake water for anions, mamor cations, toxic cations and total ions are 1.05 , 1.56, 13.05 and 1.17 , respectively. Those values of the ground water in the Daedeok Campus showed 1.71, 4.78, 5.71 and 2.49 , respectively. However , contents of all constituents of these water are within the drinking water standard. All samples were filtered before the chemical analysis. Pale yellow or yellowish brown colored materials of colloidal particles coated the filter paper to thickness of 0.02 to 0.2mm. these are mainly Fe-Cy-Zn compounds with traces of Ni and Pb, the net weights of which compounds range from 0.01to 3.20mg/l. Most elements did not show any conceivable filtering effect of Cu, Fe and Zn. Especially, mean concentration of total Fe decreased considerably from 168.52${\mu}g$/lto 42.58${\mu}g$/l by filtering .

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Electron Microscopic Study of the Cutaneous Erythrophore Differentiation in Bombina orientalis (무당개구리 (Bombina orientalis Boulenger) 皮膚 赤色素細胞 (Erythrophore)의 分化에 관한 電子顯微鏡的 硏究)

  • 문명진;김우갑;김창환
    • The Korean Journal of Zoology
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    • v.27 no.3
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    • pp.165-176
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    • 1984
  • The cutaneous erythrophore differentiation from larvae to adult in bombina orientalis-the Korean fire bellied toad-is discussed electron microscopically to reveal the structural changes of carotenoid vesicles and pterinosomes in the process of erythrophore differentiation. Typical structure of adult erythrophores distributed beneath the basement membrane is composed much carotenoid vesicles and a small quantity of pterinosomes. Marginal electron density of these carotenoid vesicles is higher than those of internal regions and pterinosomes have many concentric lamellae. The very first differentiated erythrophores are apeared before and after the foreleg developing stage of metamorphosis and red ventral color is just appeared about $1\\sim2$ weeks after metamorphosis. About 1 year after metamorphosis, external body color of the young toad is similar to adult but the morphology of pigment granules observed in these erythrophores differs from that of adult in structure and electron density. At this stage, the differentiated level of pterinosomes is not remarkable and the accumulation state of carotenoid pigments in erythrophores is also relatively low.

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Investigation of Stabilization Effect on Arsenic Contamination Soils using Zerovalent Iron and Industrial by-products (영가철 및 산업폐기물을 활용한 비소오염토양의 안정화 효과조사)

  • Yu, Chan;Yun, Sung-Wook;Baek, Seung-Hwan;Park, Jin-Chul;Lee, Jung-Hoon;Lim, Young-Cheol;Choi, Seung-Jin;Jang, Min
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.229-241
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    • 2008
  • In order to investigate stabilization effect on As-contaminated soils treated by zero-valent iron(ZVI) and industrial by-products, batch tests and column tests were carried out with As-contaminated soils collected from farmland around the abandoned mine site. In batch tests, ZVI and industrial by-products(blast furnace slag, steel refining slag and oyster shell powder) were used as treatment materials to reduce As. Industrial by-products were mixed with As-contaminated soils, in the ratio of 1%, 3%, 5% and 7% on the weight base of dried soil. After incubation, all samples showed the reduction of As concentration and it was expected that ZVI and steel refining slag were effective treatment materials to remove As among treatment materials used in batch test. In column tests, columns were made by acrylic with the dimension of diameter=10cm, height=100cm, thickness=1cm and these columns were filled with untreated soils and treated soils mixed with ZVI and steel refining slag(mixing ratio=3%). Distilled water was discharged into the columns with the velocity of 1 pore-volume/day. During test, pH, EC, Eh and As concentration were measured in the regular term(1 pore-volume). As a result, ZVI and steel refining slag were shown 93%, 62% reduction of As concentration respectively by comparison with untreated soils. Therefore, if ZVI and steel refining slag are used as treatment materials in As-contaminated soils, it is expected that the As concentration in soils is reduced effectively.

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