• Title/Summary/Keyword: EFFECTIVE AVERAGE PERMEABILITY

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Preparation and Characterization of Crosslinked Block and Random Sulfonated Polyimide Membranes for Fuel Cell (블록 및 랜덤 가교 술폰화 폴리이미드막의 제조 및 연료전지특성 평가)

  • Lee, Young-Moo;Park, Chi-Hoon;Lee, Chang-Hyun;Chung, Youn-Suk
    • Membrane Journal
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    • v.16 no.4
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    • pp.241-251
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    • 2006
  • In this study, crosslinked copolyimides with random (r-) and block (b-) structure were fabricated using N,N-bis(2-hydroxyethyl)-2-aminoethanesulfonic acid and pentanediol as crosslinkers. Linear r- and b-sulfonated copolyimides were also fabricated for comparison. Ion exchange capacities of r- and b-copolyimides were very similar to each other owing to their strong dependence of sulfonic acid content. The physical crosslinking via dimerization of carboxylic acid groups induced a reduced average interchain distance in b-copolyimide without crosslinkers. Consequently, its water uptake and methanol permeability were lower than those of r-sulfonated copolyimides. Simultaneously, the reduced interchain distance increased the content of fixed-charged ions per unit volume. The high fixed-charged ion density contributed to an enhancement of proton conductivity In the b-sulfonated copolyimide. Crosslinking caused the reduction of average interchain distance between polymer chains irrespective of types of crosslinker and polymer structure, leading to low methanol permeability. On the contrary, their proton conductivity was improved owing to formation of effective hydrophilic channels responsible for proton conduction. In particular, this trend was observed in r-copolyimide containing a fixed charged ion.

Study on the Consolidation Characteristics of Marine Clay by CRS and Conventional Tests (일정변헝률 및 표준압밀시험을 이용한 해성점토의 압밀특성 연구)

  • Lee, U-Jin;Im, Hyeong-Deok;Lee, Won-Je
    • Geotechnical Engineering
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    • v.14 no.4
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    • pp.47-60
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    • 1998
  • A series of conventional tests and CRS consolidation tests with different rates of strain were performed to investigate the consolidation characteristics of marine clay. Preconsolidation pressures were evaluated by applying previously proposed methods for both the conventional tests and CRS tests results in order to check the legitimacy of those methods. The effects of strain rate on effective consolidation stress strain relationship, porewater pressure, and preconsolidation pressure were also discussed It was found that the effective stress strain relationship and the preconsolidation pressure are a function of strain rate imposed during consolidation test, but compression index isn't. The preconsolidation pressure ratio ($a_2=\sigma'_{pCRS}/\sigma'_{pConv}$)of marine clay appears proportional to the logarithm of strain rate, with average values ranging from 1.11 to 1.30 for strain rates between $1\timesx10^{-4} %/sec\; and\; 4\times10 %/sec$. The porewater pressure ratio during CRS teats does not exceed 6.0% except when the strain rate is $6.67\times10^{-4} %/sec$. Coefficient of consolidation or coefficient of permeability at normally consolidated range was not affected by the type of consolidation tests and the strain rate. Typical values of compression index (C.), coefficient of consolidation(c.), and coefficient of permeability (k.) at normally consolidated range were 0.56-0.95, $0.56\times10^{-4}~3.0\times10^{-4}cm2/sec,\; and\; 2.0\times10^{-8}~7.0\time10^{-4}cm/sec,$ respectively.

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The Characteristics of Hydrogeological Parameters of Unconsolidated Sediments in the Nakdong River Delta of Busan City, Korea

  • Khakimov, Elyorbek;Chung, Sang Yong;Senapathi, Venkatramanan;Elzain, Hussam Eldin;Son, JooHyeong
    • Journal of Soil and Groundwater Environment
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    • v.22 no.3
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    • pp.27-41
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    • 2017
  • This study dealt with the characteristics and the interrelations of hydrogeological parameters such as hydraulic conductivity, dispersivity and effective porosity of unconsolidated sediments for providing the basic data necessary for the planning of the management and preservation of groundwater quality in the Nakdong River Delta of Busan City, Korea. Groundwater quality in this area has been deteriorated due to seawater intrusion, agricultural fertilizer and pesticide, industrial wastewater, and contaminated river water. The physical properties (grain size distribution, sediment type, sorting) and aquifer parameters (hydraulic conductivity, effective porosity, longitudinal dispersivity) were determined from grain size analysis, laboratory permeability test and column tracer test. Among 36 samples, there were 18 Sand (S), 7 Gravelly Sand (gS), 5 Silty Sand (zS), 5 Muddy Sand (mS), and 1 Sandy Silt (sZ). Hydraulic conductivity was determined through a falling head test, and ranged from $9.2{\times}10^{-5}$ to $2.9{\times}10^{-2}cm/sec$ (0.08 to 25.6 m/day). From breakthrough curves, dispersivity was calculated to be 0.35~3.92 cm. Also, effective porosity and average linear velocity were obtained through the column tracer test, and their values were 0.04~0.46 and 1.06E-04~6.49E-02 cm/sec, respectively. Statistical methods were used to understand the interrelations among aquifer parameters of hydraulic conductivity, effective porosity and dispersivity. The relation between dispersivity and hydraulic conductivity or effective porosity considered the sample length, because dispersivity was affected by experimental scale. The relations between dispersivity and hydraulic conductivity or effective porosity were all in inverse proportion for all long and short samples. The reason was because dispersivity was in inverse proportion to the groundwater velocity in case of steady hydrodynamic dispersion coefficient, and groundwater velocity was in proportion to the hydraulic conductivity or effective porosity. This study also elucidated that longitudinal dispersivity was dependent on the scale of column tracer test, and all hydrogeological parameters were low to high values due to the sand quantity of sediments. It is expected that the hydrogeological parameter data of sediments will be very useful for the planning of groundwater management and preservation in the Nakdong River Delta of Busan City, Korea.

Studies on Improving Preservative Treatability of Japanese Larch Heartwood by Presteaming (증기(蒸氣) 전처리(前處理)에 의(依)한 낙엽송(落葉松) 심재(心材)의 방부제(防腐劑) 처리도(處理度) 개선(改善)에 관(關)한 연구(硏究))

  • Kang, Sung-Mo;Paik, Ki-Hyon;Kim, Gyu-Hyeok
    • Journal of the Korean Wood Science and Technology
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    • v.25 no.1
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    • pp.15-22
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    • 1997
  • The effectiveness of presteaming for improving CCA treatability on refractory Japanese larch heartwood was investigated in this study. Presteaming was effective on improving treatability, and the extent of improvement was dependent on moisture contents of wood specimen and steaming conditions. Green wood showed higher average value in both preservative retention and penetration than dry wood, and steaming under pressure conditions also had higher treatability than steaming at atmospheric conditions. The degree of improvement for treatability was increased with the extension of steaming period. Treatability of dry wood pres teamed under pressure conditions more than 6 hours and green wood for 3 hours was similar to that enhanced by conventional incising. Presteaming green wood under pressure conditions more than 6 hours was more effective than conventional incising in improvement of CCA treatability, and resultant treatability satisfied a minimum value required for CCA-treated wood for being used at the regions of hazard class H3 and H4. In addition, an improvement of treatability by presteaming was due to an increase in permeability resulted from the degradation of hemicelluloses within aspirated pit membrane and cell wall, not the removal of extractives from pit membrane. The reduction in strength, measured as longitudinal compressive strength, due to pres teaming was related with the degradation of hemicelluloses, and was increased as steaming conditions were severe. The degree of strength reduction associated with presteaming treatment to obtain required treatability could be quantified from the relatively good relation between the increase in treatability and the decrease in strength.

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Hydrodynamic Dispersion Characteristics of Multi-soil Layer from a Field Tracer Test and Laboratory Column Experiments (현장추적자시험과 실내주상실험을 이용한 복합토양층의 수리분산특성 연구)

  • Kang, Dong-Hwan;Yang, Sung-Il;Kim, Tae-Yeong;Kim, Sung-Soo;Chung, Sang-Yong
    • Journal of Soil and Groundwater Environment
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    • v.13 no.4
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    • pp.1-7
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    • 2008
  • This study analyzed for hydrodynamic dispersion characteristics of multi-soil layer (Silt and clay, Find sand, Coarse sand), data of a field tracer test on the multi-soil layer and data of laboratory column experiments on the samples on each soil layers. Through the analysis of permeability and flow, MS (Silt and clay) and FS (Fine sand), which were low effective porosity, were higher average linear velocity while CS (Coarse sand), which was high effective porosity, was higher hydraulic conductivity. Hydraulic conductivity function based on average soil particle diameter was assumed Y=$3.49{\times}10^{-8}e^{15320x}$ and coefficient of determination was 0.90. Average linear velocity function based on average soil particle diameter was assumed Y=$1.88{\times}10^{-7}e^{11459x}$ and coefficient of determination was 0.81. Longitudinal dispersivity function based on average soil particle diameter was Y = 0.00256$e^{5971x}$ and coefficient of determination was 0.98. According to the linear regression analysis of average linear velocity and longitudinal dispersivity, assumed function was Y = 21.7527x + 0.0063, and coefficient of determination was 0.9979. The ratio of field scale/laboratory scale was 54.09, it exhibited scale-dependent effect of hydrodynamic dispersion. Field longitudinal dispersivity (1.39m) was 7.47 times as higher than longitudinal dispersivity estimated by the methods of Xu and Eckstein (1995). Hydrodynamic dispersion on CS layer was occurred mainly by diffusion flow in the test aquifer.

Structural analysis and design proposal of fine dust mask with nanofiber filter fabricated using electrospinning (전기방사 나노섬유 필터를 활용한 미세먼지 마스크의 구조 분석 및 디자인 제안)

  • Han, Sang Yun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.4
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    • pp.191-195
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    • 2017
  • The microstructures of nonwoven fabric with and without nanofibers used as a filter for air purification type mask were investigated using scanning electron microscope. Moreover, we proposed a new mask design which is effective in the improvement of the fine dust blocking property. When comparing to nonwoven fabrics of which an average diameter was $25{\mu}m$, the nanofibers formed by the electrospinning process had a tight mesh structure arranged irregularly with a relatively large specific surface area, which could be associated with their much smaller diameter ranging from 25 to 120 nm. Such a prominent structural feature at nanofibers led to mechanical adsorption of fine particles, resulting in enhancement of filtering behavior maintaining high permeability. In addition to the excellent performance of the mask filter, wearing the mask properly is expected to maximize the blocking property of fine dust. To meet such a requirement, a new mask design that can be closely attached to the face in order to effectively block fine dust entering the gap between the face and the mask.

A Study on the Structure Characteristics of Planting Ground in Incheon International Airport, Korea (인천국제공항 식재기반 구조 및 토양특성 연구)

  • Lee, Seung-Won;Han, Bong-Ho;Lee, Kyong-Jae;Kwak, Jeong-In;Yeum, Jung-Hun
    • Journal of the Korean Institute of Landscape Architecture
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    • v.43 no.3
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    • pp.77-91
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    • 2015
  • This study aims to suggest adequate soil management through the analysis of physicochemical properties of soil in the planting grounds of Incheon International Airport, which was constructed on a massive land reclamation site. Study areas were 5 sites at the international business complex, the passenger terminal, the airport support complex, the free trade zone, and the access road. Soil profile analysis showed that 9 plots out of the 27 plots were hardpan and heterospere within 80cm from the soil surface. The earth laid on the ground was categorized as gravel based soil(4 plots), dredged soil from the sea bottom and mixed reclamation materials(2 plots), clay with poor permeability(3 plots) and waste construction material(1 plot). Average soil hardness was $11.5kg/cm^2$ and soil textures were sandy soil, sandy loam and loamy sand. Average soil pH was 6.7 and average organic matter content was 0.7%. Electrical conductivity was 0.0dS/m and exchangeable cation concentrations were $Ca^{2+}$ 3.4cmol/kg, $Mg^{2+}$ 1.5cmol/kg, $K^+$ 0.3cmol/kg and $Na^+$ 1.0cmol/kg. Average cation exchange capacity was 11.0cmol/kg. Although average figures in Solum mostly meet the landscape design criteria, properties of each soil layer showed various values sometimes over the limit. Base saturations were $Ca^{2+}$ 29.9%, $Mg^{2+}$ 13.3% and $K^+$ 3.7% for lower soil, $Ca^{2+}$ 33.3%, $Mg^{2+}$ 17.0% and $K^+$ 2.7% for mid-soil and $Ca^{2+}$ 32.6%, $Mg^{2+}$ 12.2% and $K^+$ 1.9% for upper soil. Exchangeable sodium percentages were 16.4% for lower soil, 7.5% for mid-soil and 4.7% upper soil. Sodium adsorption rates were 0.8 for lower soil, 0.3 for mid-soil and 0.2 for upper soil. Factors affecting to the vegetation growth were heterogeneity and poorness of solum, disturbance of dredged soils, high soil hardness including hardpan in the subsurface soil layer and shallow effective soil depth, high soil acidity, imbalance of base contents, low organic matter content and low available phosphate levels in the soil.

Studies on the Mechanical Properties of Weathered Granitic Soil -On the Elements of Shear Strength and Hardness- (화강암질풍화토(花崗岩質風化土)의 역학적(力學的) 성질(性質)에 관(關)한 연구(硏究) -전단강도(剪斷强度)의 영향요소(影響要素)와 견밀도(堅密度)에 대(對)하여-)

  • Cho, Hi Doo
    • Journal of Korean Society of Forest Science
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    • v.66 no.1
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    • pp.16-36
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    • 1984
  • It is very important in forestry to study the shear strength of weathered granitic soil, because the soil covers 66% of our country, and because the majority of land slides have been occured in the soil. In general, the causes of land slide can be classified both the external and internal factors. The external factors are known as vegetations, geography and climate, but internal factors are known as engineering properties originated from parent rocks and weathering. Soil engineering properties are controlled by the skeleton structure, texture, consistency, cohesion, permeability, water content, mineral components, porosity and density etc. of soils. And the effects of these internal factors on sliding down summarize as resistance, shear strength, against silding of soil mass. Shear strength basically depends upon effective stress, kinds of soils, density (void ratio), water content, the structure and arrangement of soil particles, among the properties. But these elements of shear strength work not all alone, but together. The purpose of this thesis is to clarify the characteristics of shear strength and the related elements, such as water content ($w_o$), void ratio($e_o$), dry density (${\gamma}_d$) and specific gravity ($G_s$), and the interrelationship among related elements in order to decide the dominant element chiefly influencing on shear strength in natural/undisturbed state of weathered granitic soil, in addition to the characteristics of soil hardness of weathered granitic soil and root distribution of Pinus rigida Mill and Pinus rigida ${\times}$ taeda planted in erosion-controlled lands. For the characteristics of shear strength of weathered granitic soil and the related elements of shear strength, three sites were selected from Kwangju district. The outlines of sampling sites in the district were: average specific gravity, 2.63 ~ 2.79; average natural water content, 24.3 ~ 28.3%; average dry density, $1.31{\sim}1.43g/cm^3$, average void ratio, 0.93 ~ 1.001 ; cohesion, $ 0.2{\sim}0.75kg/cm^2$ ; angle of internal friction, $29^{\circ}{\sim}45^{\circ}$ ; soil texture, SL. The shear strength of the soil in different sites was measured by a direct shear apparatus (type B; shear box size, $62.5{\times}20mm$; ${\sigma}$, $1.434kg/cm^2$; speed, 1/100mm/min.). For the related element analyses, water content was moderated through a series of drainage experiments with 4 levels of drainage period, specific gravity was measured by KS F 308, analysis of particle size distribution, by KS F 2302 and soil samples were dried at $110{\pm}5^{\circ}C$ for more than 12 hours in dry oven. Soil hardness represents physical properties, such as particle size distribution, porosity, bulk density and water content of soil, and test of the hardness by soil hardness tester is the simplest approach and totally indicative method to grasp the mechanical properties of soil. It is important to understand the mechanical properties of soil as well as the chemical in order to realize the fundamental phenomena in the growth and the distribution of tree roots. The writer intended to study the correlation between the soil hardness and the distribution of tree roots of Pinus rigida Mill. planted in 1966 and Pinus rigida ${\times}$ taeda in 199 to 1960 in the denuded forest lands with and after several erosion control works. The soil texture of the sites investigated was SL originated from weathered granitic soil. The former is situated at Py$\ddot{o}$ngchangri, Ky$\ddot{o}$m-my$\ddot{o}$n, Kogs$\ddot{o}$ng-gun, Ch$\ddot{o}$llanam-do (3.63 ha; slope, $17^{\circ}{\sim}41^{\circ}$ soil depth, thin or medium; humidity, dry or optimum; height, 5.66/3.73 ~ 7.63 m; D.B.H., 9.7/8.00 ~ 12.00 cm) and the Latter at changun-long Kwangju-shi (3.50 ha; slope, $12^{\circ}{\sim}23^{\circ}$; soil depth, thin; humidity, dry; height, 10.47/7.3 ~ 12.79 m; D.B.H., 16.94/14.3 ~ 19.4 cm).The sampling areas were 24quadrats ($10m{\times}10m$) in the former area and 12 in the latter expanding from summit to foot. Each sampling trees for hardness test and investigation of root distribution were selected by purposive selection and soil profiles of these trees were made at the downward distance of 50 cm from the trees, at each quadrat. Soil layers of the profile were separated by the distance of 10 cm from the surface (layer I, II, ... ...). Soil hardness was measured with Yamanaka soil hardness tester and indicated as indicated soil hardness at the different soil layers. The distribution of tree root number per unit area in different soil depth was investigated, and the relationship between the soil hardness and the number of tree roots was discussed. The results obtained from the experiments are summarized as follows. 1. Analyses of simple relationship between shear strength and elements of shear strength, water content ($w_o$), void ratio ($e_o$), dry density (${\gamma}_d$) and specific gravity ($G_s$). 1) Negative correlation coefficients were recognized between shear strength and water content. and shear strength and void ratio. 2) Positive correlation coefficients were recognized between shear strength and dry density. 3) The correlation coefficients between shear strength and specific gravity were not significant. 2. Analyses of partial and multiple correlation coefficients between shear strength and the related elements: 1) From the analyses of the partial correlation coefficients among water content ($x_1$), void ratio ($x_2$), and dry density ($x_3$), the direct effect of the water content on shear strength was the highest, and effect on shear strength was in order of void ratio and dry density. Similar trend was recognized from the results of multiple correlation coefficient analyses. 2) Multiple linear regression equations derived from two independent variables, water content ($x_1$ and dry density ($x_2$) were found to be ineffective in estimating shear strength ($\hat{Y}$). However, the simple linear regression equations with an independent variable, water content (x) were highly efficient to estimate shear strength ($\hat{Y}$) with relatively high fitness. 3. A relationship between soil hardness and the distribution of root number: 1) The soil hardness increased proportionally to the soil depth. Negative correlation coefficients were recognized between indicated soil hardness and the number of tree roots in both plantations. 2) The majority of tree roots of Pinus rigida Mill and Pinus rigida ${\times}$ taeda planted in erosion-controlled lands distributed at 20 cm deep from the surface. 3) Simple linear regression equations were derived from indicated hardness (x) and the number of tree roots (Y) to estimate root numbers in both plantations.

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