• 공업화학
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• 제30권3호
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• pp.331-336
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• 2019

본 연구에서는 리튬이차전지의 초기 효율과 율속 특성의 향상을 위해 피치계 소프트 카본 음극재의 요구 물성 및 제조 공정변수에 대한 실험을 진행하였다. 피치는 석유계 잔사유를 사용하여 공정 온도를 변수로 합성하였다. 공정온도를 각각 360, 370, $410^{\circ}C$에서 3 h 진행하여, 86, 98, $152^{\circ}C$의 연화점을 갖는 피치를 제조하였다. 피치의 원소분석과 열적 특성을 EA 분석과 TGA 분석을 통해 고찰한 결과, 높은 연화점을 갖는 경우 낮은 H/C 및 발달된 열적안정성을 관찰할 수 있었다. 얻어진 피치를 $1,200^{\circ}C$에서 1 h 동안 탄화 열처리 공정을 진행하여 소프트 카본계 음극재를 제조하였다. XRD 분석을 통해 결정 구조를 고찰한 결과, 연화점이 높은 피치에서 제조된 소프트 카본은 상대적으로 고비점의 성분들로 구성되어 탄화 열처리공정 시 증발 성분의 감소 및 고리화에 참여하는 성분들의 증가로 인하여 결정성이 증가하였음을 고찰할 수 있었다. 결정성이 향상된 소프트 카본계 음극재에서 향상된 초기 효율과 율속 특성의 결과를 얻을 수 있었다. 향상된 초기 효율 및 율속 특성은 소프트 카본계 음극재의 발달된 결정 구조에서 기인하는 메커니즘에 대하여 논의하였다.

• Korean Chemical Engineering Research
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• 제61권3호
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• pp.472-478
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• 2023

본 연구에서는 공기청정기 필터용 활성탄의 아세트알데하이드 제거 특성이 금속 촉매 첨착 및 관능기 도입 방법을 사용하여 조사되었다. 야자각 차의 KOH 활성화를 통해 고 비표면적(1700 m²/g)과 미세기공이 발달한 활성탄을 제조하였으며, 금속촉매 첨착과 관능기 개질을 위해 침지 후 기공 내 건조조건에 따른 첨착 효율을 조사하였다. 제조된 활성탄의 물성은 비표면적 및 기공 분석(BET), 유도결합 플라즈마 분광 분석(ICP), 유기 원소 분석(EA) 및 푸리에변환 적외선 분광 분석(FT-IR) 등을 통해 분석하였으며, 활성탄 성능 확인을 위해 침지 농도에 따른 아세트알데하이드 흡착성능을 가스크로마토그래피(GC)로 분석하였다. 첨착용액의 농도가 증가함에 따라 금속촉매 첨착량은 증가하였으며, 비표면적은 감소하는 경향을 보였다. 각 금속촉매 첨착 및 표면개질 활성탄의 파과시험 결과 MgO10@AC, CaO10@AC, EU10@AC, H-U3N1@AC 조성에서 우수한 아세트알데하이드 흡착성능을 보여주었다. 흡착성능이 가장 뛰어난 MgO10@AC에 대해 파과 시간은 533.8 분, 흡착량은 57.4 mg/g으로 측정되었으며, 이는 활성탄에 나노 크기의 MgO 촉매를 첨착할 경우 아세트알데하이드의 카보닐기와 상호작용하여 흡착성능이 개선됨을 알 수 있었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 춘계학술대회 논문집 센서 박막재료연구회 및 광주 전남지부
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• pp.121-122
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• 2008

Blue emitting materials have been explored by various researchers. However, blue-emitting materials with high luminous efficiency, good color purity, and thermal stability are still much desired. In this study, we synthesized a new blue luminescent material, $SnDP(HPB)_2$ which is low molecular compound and thermal stability. The PL spectrum of $SnDP(HPB)_2$ was observed blue at the wavelength of 447nm. The ionization potential(IP) and the electron affinity(EA) of $SnDP(HPB)_2$ was measured to be 6.7 eV and 3.0 eV, respectively. The fundamental structure of the OLED was ITO/NPB/$SnDP(HPB)_2/Alq_3$/LiF/Al. As a Result, we obtained to enhance the performance of blue OLED.

• KIEAE Journal
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• 제14권2호
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• pp.21-28
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• 2014

This paper provides the up to date review of the shading effects on PV module performance and the associated detection algorithm related to the maximum power point tracking. It includes the brief explanations of the MMP variations due to the shading occurrence on the PV modules. Review of experimental and simulation studies highlighting the significant impacts of shading on PV efficiencies were presented. The literature indicates that even the partial shading of a single cell can greatly drop the entire module voltage and power efficiency. The MMP tracking approaches were also reviewed in this study. Both conventional and advanced soft computing methods such as ANN, FLC and EA were described for the proper tracking of MMP under shaded conditions. This paper would be the basic source and the comprehensive information associated with the shading effects and relevant MPP tracking technique.

• International Journal of Control, Automation, and Systems
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• 제1권2호
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• pp.184-193
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• 2003

Biaffine Matrix Inequality (BMI) is known to provide the most general framework in control synthesis, but problems involving BMI's are very difficult to solve because nonconvex optimization should be solved. In the previous paper, we proposed a new solver for problems involving BMI's using Evolutionary Algorithms (EA). In this paper, we solve several control synthesis examples such as Reduced-order control, Simultaneous stabilization, Multi-objective control, $H_{\infty}$ optimal control, Maxed $H_2$ / $H_{\infty}$control design, and Robust $H_{\infty}$ control. Each of these problems is formulated as the standard BMI form, and solved by the proposed algorithm. The performance in each case is compared with those of conventional methods.

• 로봇학회논문지
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• 제18권1호
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• pp.59-65
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• 2023

This paper proposes an Extended and Adaptive Inverse Perspective Mapping (EA-IPM) model that can obtain an accurate bird's-eye view (BEV) from the forward-looking monocular camera on the sidewalk with various curves. While Inverse Perspective Mapping (IPM) is a good way to obtain ground information, conventional methods assume a fixed relationship between the camera and the ground. Due to the nature of the driving environment of the mobile robot, there are more walking environments with frequent motion changes than flat roads, which have a fatal effect on IPM results. Therefore, we have developed an extended IPM process to be applicable in IPM on sidewalks by adding a formula for complementary Y-derive processes and roll motions to the existing adaptive IPM model that is robust to pitch motions. To convince the performance of the proposed method, we evaluated our results on both synthetic and real road and sidewalk datasets.

• 설비공학논문집
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• 제25권7호
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• pp.392-397
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• 2013

To fulfill the demands concerning energy efficiency for zero energy buildings, various technologies of architects and engineers are required. This study aims to estimate the thermal performance of heat source equipment in which part load characteristics are considered in an office building. Overestimation of heat source equipment was reviewed through literature survey, and heating and cooling loads depending on the capacity and division of the equipment were analyzed through a simulation program (DOE-2.1E). The conclusions gained from this study are as follows; 1) The more the division of equipment, the less the heating and cooling energy consumption. 2) When a large item of equipment is divided into two small items of equipment, the optimum application rate showed as 5:5 for chiller, and 7:3 for boiler, respectively.

• 한국산학기술학회논문지
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• 제18권3호
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• pp.452-459
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• 2017

최근 특수 구조물의 경량화를 위해 프리스트레스트 콘크리트 대신 SCP(Steel Concrete Plate)와 같은 합성형 강판 콘크리트 구조모듈의 사용이 증가하고 있다. 다량의 스터드가 결합된 SCP 모듈의 경우 복잡한 단면과 내부구조로 인하여 유동성과 충전성이 우수한 고유동 콘크리트의 사용이 요구된다. 따라서 본 연구에서는 팽창재 및 수축저감제 사용에 따른 영향을 검토하여 스터드에 의한 수축거동을 방지하고, 잔골재율 및 잔골재 종류별 혼입비율을 검토하여 재료의 사용성 및 충전성을 극대화 시킬 수 있는 최적 배합을 도출하고자 하였다. 그 결과 팽창재 또는 수축저감제의 단독사용보다 병행하여 사용할 경우 가장 적은 수축거동을 나타내어 SCP 모듈 충전용 고유동 콘크리트의 제조에 가장 적합한 것으로 판단된다. 잔골재율이 너무 높은 경우 강도 저하 및 수축량 증가의 우려가 있어 최종배합으로 부순모래와 세척사의 비율을 5:5로 선정하였으며, 잔골재율은 55.6%가 적합한 것으로 판단된다. 대형 SCP 모듈 내 고유동 콘크리트 채움성능 평가를 위해 타설을 진행한 결과 SCP 모듈내 고유동 콘크리트 채움성은 양호한 결과를 나타냈다.

• 한국태양에너지학회 논문집
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• 제35권2호
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• pp.93-101
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• 2015

Zero energy building is a self sufficient building that minimizes energy consumption through passive elements such as insulation, high performance window system and installing of high efficiency HVAC system and uses renewable energy sources. The Korea Government has been strengthening the building energy efficiency standard and code for zero energy building. The building energy performance is determined by the performance of building envelope. Therefore it is important to optimize facade design such as insulation, window properties and shading, that affect the heating and cooling loads. In particular, shading devices are necessary to reduce the cooling load in summer season. Meanwhile, BIPV shading system functions as a renewable energy technology applied in solar control facade system to reduce cooling load and produce electricity simultaneously. Therefore, when installing the BIPV shading system, the length of shadings and angle that affect the electricity production must be considered. This study focused on the facade design applied with BIPV shading system for maximizing energy saving of the selected standard building. The impact of changing insulation on roof and walls, window properties and length of BIPV shading device on energy performance of the building were investigated. In conclusion, energy consumption and electricity production were analyzed based on building energy simulations using energyplus 8.1 building simulation program and jEPlus+EA optimization tool.

• 설비공학논문집
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• 제8권3호
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• pp.423-436
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• 1996

Thermodynamic performance of eight zeotropic R-22 alternative refrigerant mixtures selected by AREP(R-22 Alternative Refrigerants Evaluation Program) and R-32/R-125/R-134a(23%/25%/52%), namely R-407C were evaluated by the "drop-in" simulation method. An existing air conditioner was selected and its design data were used for the simulation. "ARI Test A" air conditions were applied. The degree of vapor superheat at the compressor inlet fixed at $5^{\circ}C$ for all the mixtures. The results of the simulation were compared with those of R-22. COPs of all mixtures except for R-32/R-227ea(35%/65%) and R-32/R-125/R-134a(10%/70%/20%), were higher than that of R-22 by 2%~8%, while the capacities were all lower than that of R-22 by 13%~27%. COP of R-32/R-134a(40%/60%) was 2.4% higher but the capacity was 15% lower than those of R-22. In the case of R-32/R-134a(30%/70%), COP and capacity were 5.5% higher and 15% lower than those of R-22, respectively. Among the ternary mixtures, R-407C and R-32/R-125/R-134a(30%/10%/60%) showed the best performance. COP of R-407C was 2.4% higher than those of R-22 but the capacity was 15% lower.