• Title/Summary/Keyword: E.A. property

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Novel polyvinyl alcohol film dosimeter containing 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide dye for high dose application

  • Khalid A. Rabaeh;Ahmed A. Basfar;Issra' M.E. Hammoudeh
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3383-3387
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    • 2023
  • A new dyed polyvinyl alcohol (PVA) film dosimeter based on 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MMT) tetrazolium dye is proposed in this study for measuring high gamma radiation dose. Gamma cell irradiator that contains Co-60 gamma-ray source was used to expose the novel MMT-PVA films to different doses up to 25 kGy. The changed in optical property of irradiated and unirradiated films were characterized by UV-Vis spectrophotometer. The results show that the dose sensitive and the linear range of irradiated films were increased considerably with increase of MMT concentration from 1 to 5 mM. The dose response of dyed PVA film changed substantially with changing relative humidity (12-74%) as well as irradiation temperature (10-40 ℃). The absorbance of the unirradiated films does not change up to 10 days in dark while a significant increase in their absorbance was reported for similar films under fluorescent light. The irradiated dosimeters that kept in dark showed a perfect stability for 54 days. It was found that no obvious impact of dose rate on the irradiated MMT-PVA film dosimeters.

The Effect of Radar Data Assimilation in Numerical Models on Precipitation Forecasting (수치모델에서 레이더 자료동화가 강수 예측에 미치는 영향)

  • Ji-Won Lee;Ki-Hong Min
    • Atmosphere
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    • v.33 no.5
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    • pp.457-475
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    • 2023
  • Accurately predicting localized heavy rainfall is challenging without high-resolution mesoscale cloud information in the numerical model's initial field, as precipitation intensity and amount vary significantly across regions. In the Korean Peninsula, the radar observation network covers the entire country, providing high-resolution data on hydrometeors which is suitable for data assimilation (DA). During the pre-processing stage, radar reflectivity is classified into hydrometeors (e.g., rain, snow, graupel) using the background temperature field. The mixing ratio of each hydrometeor is converted and inputted into a numerical model. Moreover, assimilating saturated water vapor mixing ratio and decomposing radar radial velocity into a three-dimensional wind vector improves the atmospheric dynamic field. This study presents radar DA experiments using a numerical prediction model to enhance the wind, water vapor, and hydrometeor mixing ratio information. The impact of radar DA on precipitation prediction is analyzed separately for each radar component. Assimilating radial velocity improves the dynamic field, while assimilating hydrometeor mixing ratio reduces the spin-up period in cloud microphysical processes, simulating initial precipitation growth. Assimilating water vapor mixing ratio further captures a moist atmospheric environment, maintaining continuous growth of hydrometeors, resulting in concentrated heavy rainfall. Overall, the radar DA experiment showed a 32.78% improvement in precipitation forecast accuracy compared to experiments without DA across four cases. Further research in related fields is necessary to improve predictions of mesoscale heavy rainfall in South Korea, mitigating its impact on human life and property.

Electrical Property of the Li2O-2SiO2 Glass Sintered by Spark Plasma Sintering (Spark Plasma Sintering으로 제조한 Li2O-2SiO2 유리 소결체의 전기적 특성)

  • Yoon, Hae-Won;Song, Chul-Ho;Yang, Yong-Seok;Yoon, Su-Jong
    • Korean Journal of Materials Research
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    • v.22 no.2
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    • pp.61-65
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    • 2012
  • A $Li_2O-2SiO_2$ ($LS_2$) glass was investigated as a lithium-ion conducting oxide glass, which is applicable to a fast ionic conductor even at low temperature due to its high mechanical strength and chemical stability. The $Li_2O-2SiO_2$ glass is likely to be broken into small pieces when quenched; thus, it is difficult to fabricate a specifically sized sample. The production of properly sized glass samples is necessary for device applications. In this study, we applied spark plasma sintering (SPS) to fabricate $LS_2$ glass samples which have a particular size as well as high transparency. The sintered samples, $15mm\phi{\times}2mmT$ in size, ($LS_2$-s) were produced by SPS between $480^{\circ}C$ and $500^{\circ}C$ at 45MPa for 3~5mim, after which the thermal and dielectric properties of the $LS_2$-s samples were compared with those of quenched glass ($LS_2$-q) samples. Thermal behavior, crystalline structure, and electrical conductivity of both samples were analyzed by differential scanning calorimetry (DSC), X-ray diffraction (XRD) and an impedance/gain-phase analyzer, respectively. The results showed that the $LS_2$-s had an amorphous structure, like the $LS_2$-q sample, and that both samples took on the lithium disilicate structure after the heat treatment at $800^{\circ}C$. We observed similar dielectric peaks in both of the samples between room temperature and $700^{\circ}C$. The DC activation energies of the $LS_2$-q and $LS_2$-s samples were $0.48{\pm}0.05eV$ and $0.66{\pm}0.04eV$, while the AC activation energies were $0.48{\pm}0.05eV$ and $0.68{\pm}0.04eV$, respectively.

Cryoprotective Properties of Exopolysaccharide (P-21653) Produced by the Antarctic Bacterium, Pseudoalteromonas arctica KOPRI 21653

  • Kim, Sung-Jin;Yim, Joung-Han
    • Journal of Microbiology
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    • v.45 no.6
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    • pp.510-514
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    • 2007
  • Twenty-five bacterial strains that secrete mucous materials were isolated from sediment obtained from King George Island, Antarctica. Seven of these strains proved capable of producing cryoprotective exopolysaccharides. The strain KOPRI 21653 was selected for the further study of an anti-ice-nucleating polysaccharide (ANP), which originated from a polar region. KOPRI 21653 was identified as Pseudoalteromonas arctica as the result of 16S rRNA analysis. The exopolysaccharide, P-21653, was purified completely from the KOPRI 21653 cell culture via column chromatography and protease treatment. The principal sugar components of P-21653 were determined to be galactose and glucose, at a ratio of 1:1.5, via GC-MS analysis. The cryoprotective activity of P-21653 was characterized via an E. coli viability test. In the presence of 0.1% (w/v) P-21653, the survival ratio of E. coli cells was as high as 82.6% over three repeated freeze-thaw cycles. The survival ratio decreased drastically to 71.5 and 48.1 %, respectively, in five and seven repeated cycle conditions; however, the survival ratios were greater over three (96.6-92.1%) to seven (100.5-91.6%) freeze-thaw cycles in the presence of 0.5 and 1.0% (w/v) P-21653. In addition, at much lower concentrations (0.1-1.0%), P-21653 resulted in survival ratios (83.1-98.4%) similar to those of two commercially available cryoprotectants ($V_{EG}$ plus X-1000, 92.9% and $V_{M3}$, 95.3%), which were utilized at the recommended concentrations (90%). The biochemical characteristics of exopolysaccharide P-21653 reflect that this compound may be developed as a useful cryoprotectant for use in medical applications and in the food industry.

Photoluminescence and Long-phosphorescent Characteristics of SrAl2O4:Eu2+,Dy3+ Phosphor by Glycine-nitrate Combustion Method (글리신-질산염 연소법으로 합성된 SrAl2O4:Eu2+,Dy3+ 형광체의 발광 및 장잔광 특성)

  • Lee, Young-Ki;Kim, Jung-Yeul;Lee, You-Kee
    • Korean Journal of Materials Research
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    • v.20 no.7
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    • pp.364-369
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    • 2010
  • A $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor powder with stuffed tridymite structure was synthesized by glycine-nitrate combustion method. The luminescence, formation process and microstructure of the phosphor powder were investigated by means of X-ray diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence spectroscopy (PL). The XRD patterns show that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was an amorphous phase. However, a crystalline $SrAl_2O_4 $ phase was formed by calcining at $1200^{\circ}C$ for 4h. From the SEM analysis, also, it was found that the as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor was in irregular porous particles of about 50 ${\mu}m$, while the calcined phosphor was aggregated in spherical particles with radius of about 0.5 ${\mu}m$. The emission spectrum of as-synthesized $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor did not appear, due to the amorphous phase. However, the emission spectrum of the calcined phosphor was observed at 520 nm (2.384eV); it showed green emission peaking, in the range of 450~650 nm. The excitation spectrum of the $SrAl_2O_4:Eu^{2+},Dy^{3+}$ phosphor exhibits a maximum peak intensity at 360 nm (3.44eV) in the range of 250~480 nm. After the removal of the pulse Xe-lamp excitation (360 nm), also, the decay time for the emission spectrum was very slow, which shows the excellent longphosphorescent property of the phosphor, although the decay time decreased exponentially.

The Effects of Lycium chinese Mill., Morus alba L. and Their Combination on the Asthmatic Murine Model (천식동물모델을 이용한 지골피(地骨皮), 상백피(桑白皮) 및 두 배합약물의 실험적 연구)

  • Seo, Chang-Woo;Lee, Young Cheol;Lee, Jang-Cheon
    • Herbal Formula Science
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    • v.21 no.1
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    • pp.36-50
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    • 2013
  • Objectives : To clarify the possible effect of Lycium chinese Mill (LC)., Morus alba L (MA)., and Lycium chinese Mill. +Morus alba L. (LC+MA), we have examined their influence on the development of pulmonary eosinophilic inflammation in the asthmatic murine model. Methods : Female Balb/c mice (5weeks) were immunized on two different days (21 days and 7 days before inhalational exposure) by intraperitonial injections of 0.2ml alum-precipitated Ag containing $100{\mu}g$ of OVA bound to 4 mg of aluminum hydroxide in PBS. Seven days after the second sensitization, mice were exposed to aerosolized ovalbumin for 30 minutes/day on 3 days/week for 8 weeks (at a flow rate of 250 L/min, 2.5% ovalbumin in normal saline) and, LC, MA, and LC+MA (500 mg/kg) were orally administered 3 times per a week for 8 weeks. Results : The suppressive effect of LC, MA, and LC+MA were demonstrated by the accumulation of eosinophills into airways, with the reduction of eosinophil, total lung leukocytes numbers. These were correlated with the marked reduction of IL-5, IL-13 and IL-4 levels in the BALF and serum. OVA-specific IgE levels were also decreased in serum and BAL from these mice. LC, MA, and LC+MA decreased eosinophil CCR3 expression and CD11b expression in lung cells. Conclusions : These results indicate that LC, MA, and LC+MA have high inhibitory effects on airway inflammation and hyper-responsiveness in the asthmatic murine model. The suppression of IL-5, IgE, eosinophil CCR3 expression and CD11b expression, and the increase of IFN-${\gamma}$ production in BALF seem to contribute to this effect. Hence, the results indicated that LC, MA, and LC+MA could act as a immuno-modulator which possesses anti-inflammatory and anti-asthmatic property by modulating the imbalance between Th1 and Th2 cytokines.

Low-Complexity and High-Speed Multi-Size Circular Shifter With Benes Network Control Signal Optimization for WiMAX QC-LDPC Decoder (Benes 네트워크 제어 신호 최적화를 이용한 WiMAX QC-LDPC 복호기용 저면적/고속 Multi-Size Circular Shifter)

  • Kang, Hyeong-Ju
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.19 no.10
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    • pp.2367-2372
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    • 2015
  • One of various low-density parity-check(LDPC) codes that has been adopted in many communication standards due to its error correction ability is a quasi-cyclic LDPC(QC-LDPC) code, which leads to comparable decoder complexity. One of the main blocks in the QC-LCDC code decoder is a multi-size circular shifter(MSCS) that can perform various size rotation. The MSCS can be implemented with many structures, one of which is based on Banes network. The Benes network structure can perform the normal MSCS operation efficiently, but it cannot use the properties coming from specifications like rotation sizes. This paper proposesd a scheme where the Benes network structure can use the rotation size property with the modification of the control signal generation. The proposed scheme is applied to the MSCS of IEEE 802.16e WiMAX QC-LDPC decoder to reduce the number of MUXes and the critical path delay.

A Study on the Joint Property by the Surface Treatment Method on the Jointing Method of PET Film using the High Hardness Liquid (고경질 도막을 이용한 PET 필름 접합공법의 필름 표면처리 방법에 따른 접합특성 연구)

  • Lee, Jong-Suk;Kim, Young-Sam;Shin, Hong-Chol;Kim, Young-Geun;Kang, Chung-Mo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.3
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    • pp.153-159
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    • 2014
  • This research reviewed the joint and duration characteristics depending on the surface treatment condition and lap spliced length in the PET film jointing method using the high hardness liquid material. As a result, the corona discharge treatment was improved to the contact angle, joint tensile strength, and joint peel resistance compared to non-treatment. Particularly, a surface treatment E (Corona discharge + Primer + PU bond + Polyester fabric) turned out to the best, and especially when the lap spliced length is longer than 15mm, stable joint performance was secured under the long term deterioration treatment of 16 weeks. Thus, the joint is considered to be applicable as the water-proof material.

A Study of the Effect of Degree of Cure on the Physical Properties of Rubber Compounds (가교정도에 따른 고무복합체의 물리적 특성에 관한 연구)

  • Kim, Hyeon-Jae;Kaang, Shin-Young;Nah, Chang-Woon
    • Elastomers and Composites
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    • v.33 no.4
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    • pp.281-289
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    • 1998
  • Tensile properties including Young's modulus and tear strength were measured for four different rubber compounds; natural rubber(NR), styrene-butadiene copolymer(SBR), ethylene-propylene diene monomer (EPDM), and brominated isobutylene-p-methyl-styrene copolymer(BIMS) as a function of temperature and degree of cure. To see the effect of over cure, a measurement was made of the tensile strength and swelling behavior of the over-cured rubber compounds. Young's modulus, E, was found to have linear dependency on the degree of cure for all rubber compounds. EPDM and BIMS showed the highest and lowest slopes, respectively. The slope of NR and SBR lay between EPDM and BIMS. Tear strength, Gc, decreased in the order of NR>BIMS>SBR>EPDM. As the cure time was extended the degree of cure of NR and SBR decreased, while that of BIMS increased. EPDM showed little change in the degree of cure.

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Theoretical Study for Thermally Activated Delayed Fluorescence (TADF) Property in Organic Light-Emitting Diode (OLED) Candidates (유기발광소재(OLED) 후보물질의 지연형광(TADF) 성질에 대한 이론적 연구)

  • Seo, Hyun-il;Jeong, Hyeon Jin;Yoon, Byung Jin;Kim, Seung-Joon
    • Journal of the Korean Chemical Society
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    • v.63 no.3
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    • pp.151-159
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    • 2019
  • The TADF properties for carbazol-dicyanobenzene, carbazol-diphenyl sulfone, carbazol-benzonitrile derivatives as OLED candidate materials are theoretically investigated using density functional theory (DFT) with $6-31G^{**}$, cc-pVDZ, and cc-pVTZ basis sets. The optimized geometries, harmonic vibrational frequencies, and HOMO-LUMO energy separations are predicted at the B3LYP/$6-31G^{**}$ level of theory. The harmonic vibrational frequencies of the molecules considered in this study show all real numbers implying true minima. The time dependent density functional theory (TD-DFT) calculations have been also applied to investigate the absorption and emission wavelength (${\lambda}_{max}$), energy differences (${\Delta}E_{ST}$) between excited singlet ($S_1$) and triplet ($T_1$) states of candidate materials.